Summary of the invention
The objective of the invention is to propose a kind of CMP instrument and technology, the minimizing possibility that makes the substrate surface such as the Semiconductor substrate that semiconductor wafer or section processes are crossed corrode or damage also proposes the centre or the final semiconductor product that obtain by this technology.
Above-mentioned purpose realizes by the method according to this invention, equipment and semiconductor product.
The present invention proposes chemical mechanical planarization apparatus with at least two polished land, each polished land all has the device that is used for carrying out simultaneously treatment step, each step includes polishing step, and at least one of described treatment step also comprises the rinsing step after the polishing step.In the method according to the invention, each treatment step has total treatment step time, and described equipment also comprises control device, the duration that is adapted to pass through the adjusting rinsing step is provided with total treatment step time, makes that the treatment step essence on each polished land side by side finishes.Essence finishes side by side to mean that the difference of the concluding time of the processing step on each polished land is not more than 2 seconds.
According to the embodiment of the invention, described equipment can also comprise the device that is used for determining by concluding time of slow polishing step the concluding time of each treatment step, and described control device can have and is used for by regulating each duration, the device of the total processing time of setting of described at least one rinsing step.Described equipment can also comprise endpoint detector, is used for determining the concluding time of treatment step.
In the device in accordance with the invention, before wafer can being moved to next polished land, described wafer needn't be waited in air.Therefore, chemical-mechanical planarization according to the present invention has such advantage: between two polishings or polishing+rinsing step, do not exist or essence does not exist in the air of wet wafer and waits for, therefore can make the minimizing possibility of the damage such as erosion.
In embodiments of the present invention, each treatment step can comprise polishing step and rinsing step subsequently.Control device can be suitable for controlling the duration of each rinsing step, makes by concluding time of previous polishing step and the difference between concluding time of slow polishing step and carry out flushing during the minimum determined time period of washing time sum.In one embodiment, control device can be suitable for controlling minimum washing time between 1 to 60 second, preferably, and between 8 to 10 seconds.
In the equipment according to this embodiment of the invention, advantage is the negative interaction of tool production ability not to be taken place.Here do not increase the extra time, if set rinsing step for example the fixedly concluding time will be like this because must comprise margin of safety in this case.Another advantage according to this embodiment of the invention is to carry out polishing and flushing on identical chip carrier.In most prior art CMP instrument, flushing may be carried out on the chip carrier that is different from the chip carrier of carrying out polishing step.This has caused bigger instrument, because take the too many place of ultra-clean chamber for example but disadvantageous.
In an embodiment according to the present invention, described equipment can comprise first, second and the 3rd polished land.For example, first, second can be suitable for carrying out respectively copper CMP, barrier material CMP and polishing with the 3rd embodiment.
The invention allows for a kind of method that is used for the chemical-mechanical planarization of substrate.Described method comprises the treatment step of at least two whiles, each treatment step includes polishing step, and at least one of described treatment step also comprises the rinsing step after the polishing step, wherein, controlling whole treatment steps by the duration of regulating rinsing step makes whole treatment step essence side by side finish.
Can determine the concluding time of whole treatment steps by concluding time of slow polishing step, and can set total treatment step time by each duration of regulating described at least one rinsing step.
In the method according to the invention, before wafer can being moved to next polished land, described wafer needn't be waited in air.Therefore, the method that is used for chemical-mechanical planarization according to the present invention has the following advantages: do not have or do not exist in fact the aerial wait of wet wafer between two polishing steps or the polishing+rinsing step, the damage such as corroding is minimized.
In an embodiment of the present invention, each treatment step can comprise the rinsing step after the polishing step, and can be by concluding time of previous polishing step and the difference and described each rinsing step of execution during the minimum determined time period of washing time sum between concluding time of slow polishing step.
Method according to this embodiment of the invention has the following advantages: the negative interaction to the tool production ability does not take place.Here do not increase the extra time, if for example set rinsing step the fixedly concluding time will be like this because must comprise margin of safety in this case.Another advantage according to this embodiment of the invention is: carry out polishing and flushing on identical chip carrier.In most prior art CMP instrument, flushing may be carried out on the chip carrier that is different from the chip carrier of carrying out polishing step.This has caused bigger instrument, because take the too many place of ultra-clean chamber for example but disadvantageous.
In an embodiment according to the present invention, substrate can be the Semiconductor substrate that semiconductor wafer or section processes are crossed.
The invention allows for a kind of computer program, be used for working as in the processing engine such as computer, on the embedded microprocessor, for example in microcontroller or the programmable gate array such as FPGA during the computer program product, setting is at the time period of the treatment step in the CMP technology of substrate, described computer program comprises code, be used to control and comprise at least two technologies with post-processing step, and at least one treatment step of described treatment step also comprises the rinsing step after the polishing step, and wherein all treatment step essence side by side finishes.
The invention allows for a kind of machine readable data storage device that computer program according to the present invention is stored.
In addition, a kind of method of making electric or electronic device has been proposed.Described method comprises the chemical-mechanical planarization of carrying out substrate, chemical-mechanical planarization comprises at least two treatment steps subsequently, each treatment step comprises polishing step, and at least one treatment step also comprises the rinsing step after the polishing step, wherein makes whole treatment step essence side by side finish by whole treatment steps of duration of regulating rinsing step.For example, described substrate can be the Semiconductor substrate that semiconductor wafer or section processes are crossed.
The invention allows for a kind of computer system, be applicable to receive parameter and these parameters are sent to the CMP instrument, be used for carrying out CMP technology according to the present invention.
In conjunction with the accompanying drawings, according to following detailed description, these and other characteristics of the present invention, feature and advantage will be conspicuous, and the principle of the invention is described by way of example.Only because the cause of giving an example provides this description, rather than limit the scope of the invention.The reference symbol of below quoting is referring to accompanying drawing.
The specific embodiment
To and the present invention be described with reference to the drawings to specific embodiment, but the present invention is not limited to this, because the present invention is only limited by claim.Any reference symbol in the claim should not be construed to limited field.Described accompanying drawing only is schematically, and is nonrestrictive.In the accompanying drawings, for illustrative purposes, can exaggerate, and not draw in proportion the size of some elements.The term of use " comprises " and does not get rid of other elements or step in this specification and right are wanted.Unless specifically stated otherwise uses under the situation of indefinite article and definite article when mentioning singular noun, comprises a plurality of these nouns.
In addition, the term first, second, third, etc. in specification and claim are used for distinguishing between like, and unnecessary description is continuous or time sequencing.It should be understood that under suitable environment the term that uses like this is tradable, and the embodiment of the invention described herein can according to describe here or the different sequential working of order of explanation.
It should be noted that the term that uses in the claim " comprises " should not be interpreted as being limited to listed subsequently device, does not get rid of other elements or step.Therefore, the scope of expression formula " equipment comprises device A and B " should not be confined to the equipment of only being made up of components A and B.Mean for the present invention, this equipment unique about parts be A and B.
The present invention proposes a kind of CMP instrument and CMP technology, wherein, avoid that polished substrate (for example, semiconductor wafer) is exposed in the air between two later step in the technology, or it is minimized.So, the substrate such as wafer just less even not can be subjected to may damage such as corroding.This substrate can be a semiconductor wafer, no matter be simply or partly to handle.This causes the production of high quality of products, for example electric device and electronic device.
Fig. 3 shows the schematic diagram of CMP instrument 10 as non-limiting example, comprises the load/unload station 11 with first chip carrier 12, first polished land 13 with second chip carrier 14, the 3rd polished land 17 that has second polished land 15 of the 3rd chip carrier 16 and have the 4th chip carrier 18.Following the providing of example of process allocation of polished land 13,15,17.It should be understood that this example only is for explanation and understanding easily, and do not limit the present invention.
For example, use CMP during can in the manufacturing process of for example electronic device, forming the copper-connection device.Copper CMP (Cu-CMP) is the optimal way that forms copper-connection, because since under relatively low temperature (for example, below 200 ℃) lack the volatile compound of copper and cause copper can not formed pattern by plasma etching, this is the essential feature of plasma etch process.In Cu-CMP, for example, the copper metallization that is used to interconnect can make up and realize by the suitable selection (for example, tantalum Ta or tantalum nitride TaN) of embedding technique that those of ordinary skills are known and barrier film materials etc.
Mosaic technology is a kind of mode that forms metallic circuit, comprising: deposition insulator, for example oxide; Etching groove in oxide; Plated metal everywhere; And return polishing (polishing back) with CMP, make metal only stay in the groove.This is the reverse order of traditional order, comprising: plated metal at first forms pattern with described metal by etching; And deposition oxide is to manage to fill the gap between the metal.Damascene process has been removed the gap and has been filled problem (obtaining oxide between metallic circuit).Use the different distributions of technology during damascene process also causes processing, promptly use oxide etching to replace metal etch, and use the metal CMP step to replace the oxide CMP step.Another advantage of mosaic technology is to form metallic circuit and path in a process cycle, and technology is being had a great attraction aspect electrical property, circuit reliability and the product cost.
JP-200144201 has described mosaic texture and the manufacturing thereof of using barrier film.Use the modification top section of sacrifice layer, and be present in below the barrier film as dielectric layer.Barrier film is as adhesion promoter and diffusion barrier material between copper and the following dielectric.During a CMP step, remove excessive copper.During the 2nd CMP step, remove barrier film.When removing barrier film, also removed copper further.After removing barrier film, remove expendable film with the speed higher (being up to 100 times) than copper.CMP allows to remove excessive copper and barrier film, and has realized the complanation of required tube core and wafer-scale.
For above-mentioned example, CMP instrument 100 can so that: first wafer can be loaded into load/unload station 11, and move to first polished land 13 subsequently, and second wafer is put into CMP instrument 10 by load/unload station 11.On first polished land 13, in the example that provides, can use such as the slurry from the obtainable EPL2361 of Rohm and Haas Electronic Materials and carry out copper CMP.This copper CMP slurry is used for removing the body copper film with high clearance.This technology should stop at the barrier film place effectively.This technology has the selectivity of high copper to barrier/oxide.For the about 1 micron copper layer of thickness, for example, the main processing time on first polished land 13 can be between 70 seconds to 90 seconds.The concluding time of this step can be triggered by endpoint detector.
Subsequently, first wafer moves to second polished land, 15, the second wafers and moves to first polished land 13, and the 3rd wafer is put into CMP instrument 10 by load/unload station 11.In second polished land 15,, can use such as carrying out barrier material CMP from the obtainable slurry such as CUS1351 of Rohm and HaasElectronic Materials for the example that provides.The effect of barrier material technology is in order to remove the barrier film materials such as Ta or TaN.The slurry that is used for the barrier film removal has higher selectivity, and this technology stops at sacrifice layer.For the example that provides, the main processing time on this second polished land 15 can be between 45 seconds and 60 seconds.Can trigger the concluding time by endpoint detector, the perhaps main processing time can have the fixedly duration.
Subsequently, first wafer is moved to the 3rd polished land 17, second wafer is moved to second polished land 15, the 3rd wafer is moved to first polished land 13, and the 4th wafer is put into load/unload station 11.For the example that provides, on the 3rd polished land 17, can remove sacrifice layer.In the semiconductor processes stage that substitutes, can on the 3rd polished land, carry out polishing.The slurry example that for example can be used for polishing can be the Klebosol 1501-50 that obtains from Rohm and Hass ElectronicMaterials.Polishing step as mechanical cleaning step reduces step as last complanation and defective.For the example that provides, the main processing time on the 3rd polished land 17 and had the fixedly duration between 10 seconds to 20 seconds usually.
Next, first wafer is moved to load/unload station 11 to take off from CMP instrument 10, second wafer is moved to the 3rd polished land 17, the 3rd wafer is moved to second polished land 15, the 4th wafer is moved to first polished land 13, and the 5th wafer is put in the CMP instrument 10 by load/unload station 11.
Can repeat above-mentioned sequence, leave CMP instrument 10 up to whole pending wafers.
After each polishing stage, carry out the wafer rinsing step.During this rinsing step, use deionized water or more generally use the cleaning solution of any appropriate, the BTA solution that for example has concentration between 0.0001 to 0.1M, wafer is polished (promptly with low-down pressure and lower speed) lightly, described solution is ejected on the polishing pad with elevated pressures.Usually, carry out rinsing step in the set time of several seconds (typically between 10 to 15 seconds) section.The purpose of rinsing step is in order to remove in chemical residual and the previous polishing step residue from wafer surface.After cleaning step, wafer is mentioned from polishing pad, and move to next polished land and be used for subsequently polishing stage.In the polishing order that the best is adjusted, directly take wafer to the next polishing stage, and need not any stand-by period.Yet in fact, and as mentioned above, wafer is always waited for the longest polishing step that the whole polished land 13,15,17 on the CMP instrument 100 are finished, because whole wafers are installed on the identical wafer transfer mechanism.For the example that provides, on second polished land 15 and the wafer on the 3rd polished land 17 before moving to next procedure, must wait for respectively that the other processing on first polished land 13 finishes about 10 to 45 seconds and 60 to 80 seconds.After flushing, airborne this wait is undesirable, and preferably will avoid, because the surface of wafer wets, and comprises coming the vestige of the chemical residual of already used slurry during the comfortable previous polishing step.In the atmosphere of the height of CMP instrument 10 chemistry active environment, wait for it not being the option of wishing, because this causes the metallicity damage (erosion) on the wafer in the example that provides.Reported evidence as the result's who in air, waits for during handling metal attack.In Fig. 4 A, the wafer 19a that shows continuous processing and therefore during handling, needn't in CMP instrument 10, wait for.Therefore Fig. 4 B shows and must wait in CMP instrument 10 during handling and can not processed continuously wafer 19b.As can be seen, the wafer 19a among Fig. 4 A comprises foxiness 20 on Waffer edge 21.This is to the wafer 19b shown in 4B, and the stand-by period in the CMP instrument 10 was greater than 1 minute.In this case, foxiness 20 is that bore hole is visible.At shorter stand-by period section, damage or foxiness 20 are microscopic.
The present invention has advised the variation of CMP tool configuration and control software, for example is used for eliminating and pending relevant erosion problem such as CMP instrument 10 wet wafers.This software comprises the code that is used to control technology.This software can the processing engine of any appropriate such as computer, such as microcontroller embedded microprocessor or (for example, FPGA) go up to carry out such as programmable gate array.This software can be stored in the storage medium of any appropriate, for example disk, hard disk drive, magnetic tape storage, the CD such as CD-ROM or DVD-ROM, solid-state memory etc.According to the present invention, the washing time section between two continuous polishing steps on each polished land 13,15,17 no longer has the fixedly duration.Replace, all the concluding time of the rinsing step on the polished land 13,15,17 must be triggered by last endpoint signal of whole polished land 13,15,17, and promptly the endpoint signal by the polished land 13,15,17 of polishing step cost maximum duration on it triggers.Can be after the set time section of polished land 13,15,17 be over and done with or endpoint detector detected reach home after, provide this endpoint signal.Can monitor terminal point by several method.Preferable methods is an optical means, depends on the variation of the optical property of polished surface.Can carry out optical measurement according to many modes, all these modes all are included in the scope of the present invention.For example, can using, the reflectivity properties of polished surface changes.In one embodiment of the invention, measure self-excitation light source, reflection on wafer surface during polishing, pass the light of the window that embeds in the polishing pad.Thereby when removing another different layers below exposing of material layer/material from wafer surface, by the quantitative changeization of the light of wafer reflection.Thereby reach home.Second method can be based on the engineering properties of polished surface.For example, in the other embodiment of the present invention, during polishing between measurement or monitoring wafer and the polishing pad and frictional force.When a kind of changes in material is another kind of material, frictional force changes.Therefore, when measuring change in friction force, arrived terminal point.Can carry out this rub measurement according to many modes, all these modes all are included in the scope of the invention.In a further embodiment, can use acoustic method to determine terminal point.Polishing can produce the acoustics energy that can monitor.When wafer surface is removed material layer, thereby when exposing another following different layers/material, acoustical signal will change.Can be used as terminal point.In a further embodiment, use electrical method.For example, can measure the electrical property of wafer.Thereby when removing another different layers below exposing of material layer/material from wafer surface, can be with the change of electrical property as terminal point.
Yet for this set, contingent is the difference of main technique between the time that depends on different polished land 13,15,17, and in the polished land 13,15,17 one or more do not had to carry out or carry out the seldom flushing of (promptly very few).Therefore, after the endpoint signal of the slowest polished land 13,15,17, all the flushing limited time period of continuation on the polished land 13,15,17 is important, and this need provide suitable and enough wafer surface to clean.Be called minimum washing time the extra time that is used for rinsing step according to the present invention.Minimum washing time can be between 1 second to 60 seconds, and typically between 8 seconds to 10 seconds.Need this minimum washing time to guarantee the suitable removal of chemical residual and residue.
So, rinsing step can start from temporal different first constantly in each different polished land 13,15,17, but the time that ends at is gone up second moment identical or that essence is identical, and temporal second can be determined by the polished land 13,15,17 of the polishing step that spends maximum duration constantly.By the time go up essence identical second constantly, mean that the difference in concluding time of the cleaning at each polished land 13,15,17 places or rinsing step is no more than 2 seconds.Therefore, rinsing step spends the different time periods at least two polished land, but may be on each of a plurality of different polished land 13,15,17, and opposite in prior art CMP instrument, no longer has the fixedly duration.
In order on the CMP instrument, to realize the present invention, software option can be set, allow the user in process program, to set specific minimum washing time.Then, when the last endpoint signal of whole polished land 13,15,17 triggers, add this minimum washing time to rinsing step in the time period, promptly actual washing time section is limited by the slowest glossing in any polished land 13,15,17 of CMP instrument 10.So, can be simultaneously or essence side by side mention wafer on whole polished land 13,15,17, and can be sent to immediately in next step polishing step, and need not in atmosphere, to wait for.
CMP instrument 10 can link to each other with computer system 25.By computer system 25, can set the parameter that is used for CMP technology, the rotary speed of platform 13,15,17 for example, the pressure on the platform 13,15,17, the duration of each treatment step etc.Alternatively, amplifier element can be positioned between CMP instrument 10 and the computer system 25, so that the signal that sends to CMP instrument 10 from computer system 25 is amplified.
Fig. 5 is the simplified block diagram of computer system 25, wherein can specific implementation method of the present invention.Suitably programming with the computer system such as system 25 that realizes the inventive method is a part of the present invention.
Computer system 25 comprises processor 26, and described processor 26 can be communicated by letter with many ancillary equipment via bus sub 27.For example, processor 26 can be a microprocessor.Processor 26 can also be a programmable gate array, for example programmable logic array (PLA), programmable logic array (PAL) or field programmable gate array (FPGA) etc.Ancillary equipment can comprise memory sub-system 28, user's input tool 29 (for example, being used for input parameter) and document storage system 30.Depend on specific implementation (computer system 25 can be desktop system, portable system or embedded controller), computer system 25 can also comprise display subsystem 31 and the output equipment such as printer 32.
Use term " bus system " so that comprise the such as required any mechanism of digital communication each other of the different parts of permission system.The different parts of computer system 25 do not need to be in identical physical location.The each several part of computer system 25 can link to each other via network medium, comprises wireless transmission medium.
Storage subsystem 28 comprises a memory at least, for example comprises many memories of main random access memory (" RAM ") 33 and read-only storage (" ROM ") 34, has stored the executable computer program instruction in described memory.In certain embodiments, can comprise dma controller 35, make it possible to need not by processor 26 just carry out from or to the transmission of memory.
Typically, user's input tool 29 comprises user interface adapter 36, is used for keyboard 37 and/or pointing device 38 are linked to each other with bus sub 27.Pointing device 38 can be the indirect pointing device such as mouse, trace ball, touch pad or graphic tablet, or the direct pointing device the touch panel device in being attached to display device 39.
Typically, display subsystem 31 comprises display controller 40, is used for display device 39 is linked to each other with bus sub 27.Display device 39 can be cathode-ray tube (" CRT "), the flat-panel devices such as LCD (" LCD ") gaseous plasma base flat-panel monitor or projector equipment etc.Display controller 40 provides control signal to display device 39, and generally includes display-memory 41, is used to be stored in the pixel that occurs on the display device 39.
Document storage system 30 is provided for permanent (non-volatile) memory of program and data files, and comprises I/0 adapter 42, is used for the ancillary equipment such as the Disk and tape driver is linked to each other with bus sub 27.Typically, ancillary equipment comprises at least one hard disk drive 43 and at least one floppy disk (" disk ") 44.Hard disk drive 43 can comprise cache memory subsystem 45, described cache memory subsystem 45 comprise fast storage with quicken from or to the transmission of hard disk drive.Can also there be other equipment such as CD-ROM drive 46 and CD drive.In addition, system 25 can comprise the hard disk drive that comprises the removable medium module type.Computer system 25 can be attachable by suitable communication adapter and modem and the wide area network such as the internet.
Will be understood by those skilled in the art that the hardware shown in Fig. 5 can depend on specific implementation and change.
For example saved software in the storage subsystem of computer system 25 or on disk, hard disk drive, magnetic tape storage, CD such as CD-ROM or DVD-ROM can be carried out on the processor 26 of computer subsystem 25.The user or must be for example by set via keyboard 37 input technological parameters such as regularly, special process parameter the speed parameter, perhaps must from memory, obtain these parameters.Then when carrying out CMP technology according to the present invention, by controller these parameters are used to control the driving of CMP instrument, be about to these parameters are used to control how long each that drive CMP platform 13,15,17 adopts, what rotary speed and pressure.These parameters make each platform have the identical processing time, appoint promptly to comprise polishing time and alternatively for processing time of the washing time of each platform.
Therefore, the flexible rinsing time period during the present invention has advised during CMP technology between two continuous polishing steps.At for example when making electronic device, having described the present invention forming the CMP technology of using during the copper-connection, but it should be understood that and CMP technology according to the present invention and instrument can also be can be applicable to the CMP technology in other manufacturing process, used.And the CMP instrument of having described 10 comprises three polished land 13,15,17.Yet at other application, alternatively, CMP instrument 10 can alternatively comprise the polished land of different numbers.
In the above-described embodiments, each treatment step on each polished land 13,15,17 includes polishing step and rinsing step.Yet it should be understood that the foregoing description and unrestricted the present invention.For example, the CMP technology according to other embodiments of the invention can be included in two treatment steps that different polished land 13,15,17 places carry out simultaneously.Each treatment step comprises polishing step, and at least one treatment step can also comprise rinsing step.For example, in CMP technology, first treatment step can comprise polishing step and the rinsing step with first duration.Second treatment step can include only the polishing step with second duration.According to the present invention, second duration can be greater than first duration.The total processing that can adjust first treatment step then is continuously applied, and makes both essence of first and second treatment steps side by side finish.Side by side finish by essence, mean that the difference between concluding time of the concluding time of first treatment step and second treatment step is not more than 2 seconds.Because the polishing time at concrete CMP technology has fixed duration, carry out the adjustment of total processing duration of first treatment step by the duration of regulating rinsing step.So, first wafer that experiences first treatment step needn't be waited for second wafer that experiences second treatment step.Similarly, in the CMP technology that comprises more than the processing steps of two whiles, can set the duration of different disposal step, make the whole treatment step essence on the different polished land 13,15,17 finish simultaneously, therefore, before being sent to next polished land 13,15,17, there is not wafer in air, to wait for.
Method and apparatus according to the invention shows two significant advantage.At first, do not exist or do not exist in fact the wet wafer between two polishing steps in air, to wait for, therefore can make the damage risk minimization such as corroding.Second advantage is that because the CMP stage of in the end finishing, the wafer of having handled only stands the rinsing step during the minimum washing time not to the negative interaction generation of tool production ability.Here do not increase the extra time, if for example set rinsing step the fixedly concluding time will be like this because must comprise margin of safety in this case.Another advantage of the present invention is to carry out polishing and flushing on identical chip carrier.In most prior art CMP instrument, flushing may be carried out on the chip carrier that is different from the chip carrier of carrying out polishing step.This has caused bigger instrument, because take the too many place of ultra-clean chamber for example but disadvantageous.
Although it should be understood that here and preferred embodiment, ad hoc structure and configuration and material have been discussed, under the situation that does not break away from the scope of the invention and spirit, can make different variations and change on form and the details at equipment according to the present invention.