CN101058555A - 从大蒜深加工废水中提取大蒜素的方法及用于大蒜素提取的大蒜素吸附树脂 - Google Patents
从大蒜深加工废水中提取大蒜素的方法及用于大蒜素提取的大蒜素吸附树脂 Download PDFInfo
- Publication number
- CN101058555A CN101058555A CN 200710016014 CN200710016014A CN101058555A CN 101058555 A CN101058555 A CN 101058555A CN 200710016014 CN200710016014 CN 200710016014 CN 200710016014 A CN200710016014 A CN 200710016014A CN 101058555 A CN101058555 A CN 101058555A
- Authority
- CN
- China
- Prior art keywords
- garlicin
- polymeric adsorbent
- initiator
- pore
- vinylbenzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 235000004611 garlic Nutrition 0.000 title claims abstract description 27
- 239000002351 wastewater Substances 0.000 title claims abstract description 19
- 239000011347 resin Substances 0.000 title claims abstract description 18
- 229920005989 resin Polymers 0.000 title claims abstract description 18
- 238000010521 absorption reaction Methods 0.000 title claims description 12
- 244000245420 ail Species 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- 240000002234 Allium sativum Species 0.000 claims abstract description 27
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003999 initiator Substances 0.000 claims abstract description 17
- 239000000178 monomer Substances 0.000 claims abstract description 5
- 239000003463 adsorbent Substances 0.000 claims description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 35
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000000284 extract Substances 0.000 claims description 17
- 238000002360 preparation method Methods 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 13
- 239000003480 eluent Substances 0.000 claims description 11
- 238000000605 extraction Methods 0.000 claims description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 10
- 239000000287 crude extract Substances 0.000 claims description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 10
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical group CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 10
- 239000000243 solution Substances 0.000 claims description 8
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 7
- 229960004756 ethanol Drugs 0.000 claims description 7
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 6
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 6
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 6
- 238000001179 sorption measurement Methods 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 4
- 229920000344 molecularly imprinted polymer Polymers 0.000 claims description 4
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 4
- 125000003944 tolyl group Chemical group 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000004064 recycling Methods 0.000 abstract description 3
- -1 acrylic ester Chemical class 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 230000013011 mating Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 description 9
- 238000007789 sealing Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 238000005189 flocculation Methods 0.000 description 5
- 230000016615 flocculation Effects 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000010557 suspension polymerization reaction Methods 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2007100160142A CN100491347C (zh) | 2007-06-05 | 2007-06-05 | 从大蒜深加工废水中提取大蒜素的方法及用于大蒜素提取的大蒜素吸附树脂 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2007100160142A CN100491347C (zh) | 2007-06-05 | 2007-06-05 | 从大蒜深加工废水中提取大蒜素的方法及用于大蒜素提取的大蒜素吸附树脂 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101058555A true CN101058555A (zh) | 2007-10-24 |
CN100491347C CN100491347C (zh) | 2009-05-27 |
Family
ID=38864877
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2007100160142A Expired - Fee Related CN100491347C (zh) | 2007-06-05 | 2007-06-05 | 从大蒜深加工废水中提取大蒜素的方法及用于大蒜素提取的大蒜素吸附树脂 |
Country Status (1)
Country | Link |
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CN (1) | CN100491347C (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102220296A (zh) * | 2011-06-02 | 2011-10-19 | 济宁益佳科技有限公司 | 从蒜片加工废水中提取大蒜超氧化物歧化酶的方法 |
CN102557181A (zh) * | 2012-01-20 | 2012-07-11 | 北京科技大学 | 一种利用大蒜废弃物吸附清除废水中重金属及染料的方法 |
CN106554297A (zh) * | 2016-11-14 | 2017-04-05 | 徐州黎明食品有限公司 | 一种从大蒜深加工废水中提取大蒜素的方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103131587B (zh) * | 2013-02-04 | 2014-12-03 | 暨南大学 | 一种无苦味柑肉果酒的无渣排放生产方法 |
-
2007
- 2007-06-05 CN CNB2007100160142A patent/CN100491347C/zh not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102220296A (zh) * | 2011-06-02 | 2011-10-19 | 济宁益佳科技有限公司 | 从蒜片加工废水中提取大蒜超氧化物歧化酶的方法 |
CN102220296B (zh) * | 2011-06-02 | 2013-01-30 | 济宁益佳科技有限公司 | 从蒜片加工废水中提取大蒜超氧化物歧化酶的方法 |
CN102557181A (zh) * | 2012-01-20 | 2012-07-11 | 北京科技大学 | 一种利用大蒜废弃物吸附清除废水中重金属及染料的方法 |
CN106554297A (zh) * | 2016-11-14 | 2017-04-05 | 徐州黎明食品有限公司 | 一种从大蒜深加工废水中提取大蒜素的方法 |
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Publication number | Publication date |
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CN100491347C (zh) | 2009-05-27 |
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Application publication date: 20071024 Assignee: SHANDONG SHUNBANG BIOTECHNOLOGY CO., LTD. Assignor: Chen Hua|Zheng Yongjun Contract record no.: 2014370000111 Denomination of invention: Method of extracting garlicin from garlic deep-processing waste water and garlicin absorption resin for extracting garlicin Granted publication date: 20090527 License type: Exclusive License Record date: 20140617 |
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