CN101017798A - Method of manufacturing a flash memeory device - Google Patents

Method of manufacturing a flash memeory device Download PDF

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Publication number
CN101017798A
CN101017798A CNA2006100988276A CN200610098827A CN101017798A CN 101017798 A CN101017798 A CN 101017798A CN A2006100988276 A CNA2006100988276 A CN A2006100988276A CN 200610098827 A CN200610098827 A CN 200610098827A CN 101017798 A CN101017798 A CN 101017798A
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China
Prior art keywords
etching
isolation structure
polysilicon layer
semiconductor substrate
isolation
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CNA2006100988276A
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Chinese (zh)
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CN100552922C (en
Inventor
李仁鲁
安明圭
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SK Hynix Inc
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Hynix Semiconductor Inc
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B41/00Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
    • H10B41/30Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/82Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
    • H01L21/822Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
    • H01L21/8232Field-effect technology
    • H01L21/8234MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
    • H01L21/823481MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type isolation region manufacturing related aspects, e.g. to avoid interaction of isolation region with adjacent structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/401Multistep manufacturing processes
    • H01L29/4011Multistep manufacturing processes for data storage electrodes
    • H01L29/40114Multistep manufacturing processes for data storage electrodes the electrodes comprising a conductor-insulator-conductor-insulator-semiconductor structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66825Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a floating gate

Abstract

Provided is a method of forming nonvolatile memory, comprising forming the first and second channels by etching substrate. The first and second channels are filled with insulating material to form the first and second isolating structure. The conducting layer is formed on the top of the first and second isolating structure and between the first and second isolating structure to form floating grid. The etching conducting layer and the first isolating structure forms the third channel with top and bottom. The top has a vertical side wall and the bottom has an inclined side wall. The third channel is filled with the conductive material to form control grid.

Description

The manufacture method of flash memory
Technical field
The manufacture method of relate generally to semiconductor storage unit of the present invention, the manufacture method that more specifically relates to flash memory (flashmemory device), this method relate to by adopting autoregistration shallow trench isolation (SA-STI) method to reduce interference between the NAND flash memory unit.
Background technology
In the NAND flash memory, a plurality of data storage cells are connected in series a string to form.Between unit strings and drain electrode and unit strings and source electrode, form drain electrode respectively and select transistor and drain selection transistor.NAND flash memory unit forms by forming grid, and wherein tunnel oxide film, floating grid, dielectric layer and control grid sequence stack form linkage unit on Semiconductor substrate and in the both sides of this grid.
In the NAND flash memory, location mode is influenced by the operation of adjacent cells.Therefore, holding unit is in stable condition extremely important.When location mode owing to adjacent cells operation (especially procedure operation) when changing, this phenomenon is known as " interference ".More specifically, term " interference " is meant when carrying out second program of first module after being read, because the electric charge of the floating grid of Unit second changes and causes the electric capacity operation when reading first module, causes reading the phenomenon of the threshold voltage that is higher than first module.
In other words, do not change even interference is meant the electric charge of the floating grid of institute's reading unit, the state of actual cell seems because the change of adjacent cells state and the phenomenon of distortion.Location mode is owing to interference changes.This just causes failure rate to increase and yields descends.Therefore, effectively in stable condition the so that interference of holding unit minimizes.
Simultaneously, in the manufacture process of General N AND flash memory, isolation structure and floating grid partly form by the SA-STI method.Below the SA-STI method will be described simply.
After tunnel oxide film and first polysilicon layer are formed on the Semiconductor substrate, the presumptive area of etching tunnel oxide film and first polysilicon layer.Semiconductor substrate is etched to desired depth, forms raceway groove.In raceway groove, fill insulating barrier, and carry out polishing process to form isolation structure.
On total, form second polysilicon layer.With second polysilicon layer patternization, itself and isolation structure are partly overlapped, so just form the floating grid of wherein stacked first and second polysilicon layers.In order to remove the etch residue of second polysilicon layer fully, over etching second polysilicon layer.Thereby isolation structure is etched to desired depth.Therefore, be necessary to carry out abundant over etching so that remove the etch residue of second polysilicon layer fully.The amount of removing of isolation structure is about 100 .After dielectric layer is formed on the total, be formed for controlling the 3rd polysilicon layer of grid.
If utilize above-mentioned SA-STI method to make flash memory, then between as first polysilicon layer of floating grid and adjacent first polysilicon layer, form isolation structure.Therefore, interference may appear between first polysilicon layer.
In addition, because the etching isolation structure is to desired depth, thereby the Semiconductor substrate of active region and the distance of controlling between the grid are narrowed down.Therefore, because the influence of the controlled grid of Semiconductor substrate makes that circulation may take place lost efficacy.
Summary of the invention
An embodiment of the present invention provides a kind of method of making flash memory, and purpose is that the interference between first polysilicon layer that takes place when making the over etching isolation structure minimizes when carrying out the SA-STI process.
Another embodiment of the present invention provides a kind of method of making flash memory, thereby purpose is to prevent the circulation inefficacy that makes the distance between the control grid of Semiconductor substrate and active region narrow down and produce owing to over etching isolation structure when carrying out the SA-STI process.
According to an embodiment of the present invention, the manufacture method of flash memory may further comprise the steps: (a) the presumptive area place on Semiconductor substrate forms the tunnel oxide film and first polysilicon layer in proper order, and the presumptive area place on Semiconductor substrate forms isolation structure; (b) above first polysilicon layer and isolation structure, form second polysilicon layer, and make second polysilicon layer patternization, make second polysilicon layer and isolation structure partly overlap, thus the partial etching isolation structure; (c) under the condition that produces polymer, isolation structure is etched to desired depth; (d) above the isolation structure and second polysilicon layer, form dielectric layer and the 3rd polysilicon layer, and make dielectric layer and the 3rd polysilicon layer patternization.
Step (c) can utilize the oxidation film etching chamber to carry out, and condition is that the etch rate of second polysilicon layer is low, but the etch rate height of isolation structure.
In step (c), isolation structure can be etched to V-arrangement.
Step (c) can be used CF 4, CHF 3, CF 8And CH 2F 2Mist carry out.
In addition, step (c) can be by introducing the CF of the about 200sccm of about 50-in the oxidation film etching chamber 4, the about 200sccm of about 20-CHF 3, the about 30sccm of about 5-CF 8CH with the about 50sccm of about 10- 2F 2, and then introduce about 100sccm or argon still less (Ar) gas, and apply about 200W or lower bias voltage and carry out.
Execution in step (c) makes isolation structure be etched to the height identical with the semiconductor substrate surface height.
According to an embodiment of the present invention, the manufacture method of flash memory comprises: the presumptive area on Semiconductor substrate forms the tunnel oxide film and first polysilicon layer in proper order, and the presumptive area on Semiconductor substrate forms isolation structure; On total, form second polysilicon layer, thereby and second polysilicon layer patternization is partly overlapped at indoor second polysilicon layer and the isolation structure of making of etching polysilicon, partial etching isolation structure thus; Producing under the condition of polymer, is the V-arrangement of desired depth with the isolation structure etching in the oxidation film etching chamber; With formation dielectric layer and the 3rd polysilicon layer on total, and make dielectric layer and the 3rd polysilicon layer patternization.
According to another embodiment, a kind of method that forms nonvolatile semiconductor memory member comprises that etched substrate is to form first and second raceway grooves.First and second raceway grooves are filled with insulating material to form first and second layers of isolation structure.Forming conductive layer above first and second isolation structures and between first and second isolation structures, to form floating grid.The etching conductive layer and first isolation structure have the triple channel of upper and lower with formation, and described top has vertical sidewall, and described bottom has sloped sidewall.Triple channel is filled with electric conducting material to form the control grid.
Triple channel utilizes first and second etch step and forms, and wherein first etch step is used to form the top of triple channel, and second etch step is used to form the bottom of triple channel.Second etch step is used the etching gas that produces polymer in etching process.The etching gas of second etch step comprises CF 4, CHF 3, CF 8Or CH 2F 2The etching gas of second etch step comprises and is selected from CF 4, CHF 3, CF 8And CH 2F 2Combination.
Description of drawings
Figure 1A-1C illustrates the sectional view of flash memory manufacture method according to embodiments of the present invention.
Embodiment
Figure 1A-1C illustrates the sectional view of flash memory manufacture method according to embodiments of the present invention.
With reference to Figure 1A, tunnel oxide film 12 and first polysilicon layer, 13 orders are formed on the Semiconductor substrate 11.On first polysilicon layer 13, form the hard mask film (not shown).This hard mask film (not shown) is patterning by the photoetching method that adopts isolation mask.The hard mask film (not shown) that utilizes this patterning is as mask, and etching first polysilicon layer 13, tunnel oxide film 12 and Semiconductor substrate 11 are to desired depth, thus the formation raceway groove.
Form the insulating barrier of filling raceway groove, thereby then its polishing is exposed described hard mask film (not shown).Divest this hard mask film (not shown) and form isolation structure 14.On total, form second polysilicon layer 15.On second polysilicon layer 15, form photoresist film 16.Utilize mask with this photoresist film patternization, so that itself and isolation structure 14 parts overlap.
Second polysilicon layer 15 utilizes the photoresist film 16 of patterning to carry out etching as etching mask in first etching chamber, thereby forms the floating grid of wherein stacked first and second polysilicon layers 13 and 15.In order to remove the etch residue of second polysilicon layer 15 fully, second polysilicon layer 15 is carried out over etching.Therefore, etching isolation structure 14 extends to raceway groove 20 in the isolation structure to limit the lower end.
With reference to Figure 1B, after divesting photoresist film 16, the etched portions isolation structure 14 once more.In this implementation, this etch step is carried out in second etching chamber.Second etching chamber that is used for etched portions isolation structure 14 can be oxidation film etching chamber (for example, available from the e-MAX device of AMAT or available from the SCCM device of TEL).If isolation structure 14 carries out etching in the oxidation film chamber of for example e-MAX or SCCM equipment, then the etch rate of oxidation film can improve, but the etch rate of polysilicon layer descends.
In some embodiments, etching isolation structure 14 makes the bottom 22 of raceway groove 20 have angled side walls.The width of the bottom 22 of raceway groove 20 reduces along with the increase of the degree of depth.For example, the bottom after the etching 22 is similar to V-arrangement (Figure 1B).
Use produces polymer in etching process etching gas comes etching top 22.In this implementation, use CF 4, CHF 3, CF 8And CH 2F 2Mist.In other implementation, can adopt the combination of above-mentioned gas and/or other gas.If isolation structure 14 uses described gas to carry out etching, then cause the presumptive area of isolation structure 14 forming V-shape that can be etched owing to produce polymer.Below will describe the condition of described gas of using in detail with the presumptive area etching forming V-shape of isolation structure 14.
Etching process is by introducing the CF of the about 200sccm of about 50sccm-in such as the oxidation film etching chamber of SCCM device 4, the about 200sccm of about 20sccm-CHF 3, the about 30sccm of about 5sccm-CF 8CH with the about 50sccm of about 10sccm- 2F 2, and then introduce about 100sccm or argon still less (Ar) gas, and apply about 200W or lower bias voltage and carry out.The degree of depth that is etched into the isolation structure 14 of above-mentioned V-arrangement can have the height identical with the apparent height of Semiconductor substrate 11 (for example, about 500  of about 100-).
Simultaneously, to use the oxidation film etching chambers to carry out the cause description of etching as follows for isolation structure 14.If utilize the photoresist film 16 that remains on second polysilicon layer 15 to come over etching second polysilicon layer 15, then isolation structure 14 can be etched to about 100  or littler thickness.Yet, owing to do not have the nargin of photoresist film 16, so isolation structure 14 can not be etched to about 100  or the bigger degree of depth.
With reference to figure 1C, after dielectric layer 17 is formed on the total, be formed for controlling the 3rd polysilicon layer 18 of grid.Therefore the forming V-shape because the predetermined portions of isolation structure 14 is etched forms dielectric layer 17 and the 3rd polysilicon layer 18 at this part place.Afterwards, the 3rd polysilicon layer 18 comes etching by the photoetching process that adopts the control gate mask.Etching lower floor is to form the grid of wherein stacked floating grid and control grid subsequently.
As mentioned above, according to the present invention, utilized the oxidation film etching chamber to carry out the strange land etching by the isolation structure of partial etching during the etching second polysilicon layer etching, so that it has V-arrangement.Form dielectric layer and the 3rd polysilicon layer at this V-arrangement etched portions place.
Therefore, can reduce interference between first polysilicon layer.The threshold voltage that is distributed between the unit can improve by minimizing of interference.In addition, because the distance between Semiconductor substrate and the control grid increases, make the circulation threshold voltage to improve.
Though the present invention is described in conjunction with the embodiment that is regarded as embodiment at present, should be appreciated that to the invention is not restricted to disclosed embodiment.On the contrary, the invention is intended to cover various changes and equivalent arrangements within the spirit and scope that are included in claims.

Claims (14)

1. method of making flash memory comprises:
Presumptive area place on Semiconductor substrate forms the tunnel oxide film and first polysilicon layer in proper order, and the presumptive area place on Semiconductor substrate forms isolation structure;
Form second polysilicon layer above first polysilicon layer and isolation structure, and make second polysilicon layer patternization, make second polysilicon layer and isolation structure partly overlap, wherein said isolation structure is by partial etching;
Under the condition that produces polymer, the etching isolation structure is to desired depth; With
Above the isolation structure and second polysilicon layer, form dielectric layer and the 3rd polysilicon layer, and make described dielectric layer and the 3rd polysilicon layer patternization.
2. as the desired method of claim 1, wherein the step of etching isolation structure utilizes etching chamber to carry out.Described etching chamber is designed at the etch rate of second polysilicon layer low, and etching oxide under the high condition of the etch rate of isolation structure.
3. as the desired method of claim 1, wherein in the step of etching isolation structure, the isolation structure forming V-shape that is etched.
4. as the desired method of claim 1, wherein step (c) utilization comprises CF 4, CHF 3, CF 8And CH 2F 2Mist carry out.
5. as the desired method of claim 1, wherein the step of etching isolation structure is by introducing the CF of the about 200sccm of about 50-in the oxide-film etching chamber 4, the about 200sccm of about 20-CHF 3, the about 30sccm of about 5-CF 8CH with the about 50sccm of about 10- 2F 2, and then introduce about 100sccm or argon still less (Ar) gas, and apply about 200W or lower bias voltage and carry out.
6. as the desired method of claim 1, wherein carry out the step of etching isolation structure, make isolation structure be etched to and have the height identical with the semiconductor substrate surface height.
7. method of making flash memory comprises:
Presumptive area place on Semiconductor substrate forms the tunnel oxide film and first polysilicon layer in proper order, and the presumptive area place on Semiconductor substrate forms isolation structure;
On total, form second polysilicon layer, thereby and second polysilicon layer patternization is partly overlapped at indoor second polysilicon layer and the isolation structure of making of etching polysilicon, partial etching isolation structure thus;
Producing under the condition of polymer, is the V-arrangement of desired depth with the isolation structure etching in the oxide-film etching chamber; With
On overall structure, form dielectric layer and the 3rd polysilicon layer, and make described dielectric layer and the 3rd polysilicon layer patternization.
8. as the desired method of claim 7, wherein when etching second polysilicon layer, utilized the oxide-film etching chamber to carry out the strange land etching by the isolation structure of partial etching, to form the V-arrangement etched portions.
9. method that forms nonvolatile semiconductor memory member comprises:
Etched substrate is to form first and second raceway grooves;
With filling insulating material first and second raceway grooves, to form first and second isolation structures;
Forming conductive layer above first and second isolation structures and between first and second isolation structures, to form floating grid;
The etching conductive layer and first isolation structure have the triple channel of upper and lower with formation, and described top has vertical sidewall, and described bottom has sloped sidewall; With
Fill triple channel with electric conducting material, to form the control grid.
10. the method for claim 9, wherein said triple channel adopt first and second etch step to form.
11. the method for claim 10, wherein first etch step is used to form the top of triple channel, and second etch step is used to form the bottom of triple channel.
12. the method for claim 11, wherein second etch step adopts the etching gas that produces polymer in etching process.
13. the method for claim 12, wherein the etching gas of second etch step comprises CF 4, CHF 3, CF 8Or CH 2F 2
14. the method for claim 13, wherein the etching gas of second etch step comprises and is selected from CF 4, CHF 3, CF 8And CH 2F 2Combination.
CNB2006100988276A 2006-02-07 2006-07-13 The manufacture method of flash memory Expired - Fee Related CN100552922C (en)

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KR1020060011549A KR100854875B1 (en) 2006-02-07 2006-02-07 Method of manufacturing a flash memeory device

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Cited By (4)

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CN101894804A (en) * 2009-05-21 2010-11-24 海力士半导体有限公司 Method of manufacturing nonvolatile memory device
CN102768979A (en) * 2011-05-04 2012-11-07 海力士半导体有限公司 Method for fabricating nonvolatile memory device
CN104952806A (en) * 2014-03-26 2015-09-30 华邦电子股份有限公司 Memory element and method for manufacturing the same
CN107623002A (en) * 2016-07-13 2018-01-23 新加坡商格罗方德半导体私人有限公司 Integrated circuit and its manufacture method with programmable storage

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KR101034950B1 (en) * 2007-09-10 2011-05-17 주식회사 하이닉스반도체 Method of fabricating the trench isolation layer for semiconductor device
KR100960449B1 (en) * 2008-01-10 2010-05-28 주식회사 하이닉스반도체 Method of forming an isolation layer in semiconductor device

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JPH11163304A (en) 1997-11-28 1999-06-18 Toshiba Corp Nonvolatile semiconductor storage device and manufacture thereof
KR100297736B1 (en) * 1999-08-13 2001-11-01 윤종용 Trench isolation method
KR100537276B1 (en) * 2002-11-18 2005-12-19 주식회사 하이닉스반도체 Method of manufacturing a semiconductor device
KR20040054146A (en) * 2002-12-17 2004-06-25 주식회사 하이닉스반도체 Method for forming a tunnel oxide and method for forming floating gate in flash memory device using the same

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CN101894804A (en) * 2009-05-21 2010-11-24 海力士半导体有限公司 Method of manufacturing nonvolatile memory device
CN102768979A (en) * 2011-05-04 2012-11-07 海力士半导体有限公司 Method for fabricating nonvolatile memory device
CN102768979B (en) * 2011-05-04 2016-04-20 海力士半导体有限公司 Manufacture the method for nonvolatile semiconductor memory member
CN104952806A (en) * 2014-03-26 2015-09-30 华邦电子股份有限公司 Memory element and method for manufacturing the same
CN104952806B (en) * 2014-03-26 2018-01-05 华邦电子股份有限公司 Memory element and method for manufacturing the same
CN107623002A (en) * 2016-07-13 2018-01-23 新加坡商格罗方德半导体私人有限公司 Integrated circuit and its manufacture method with programmable storage
CN107623002B (en) * 2016-07-13 2019-06-11 新加坡商格罗方德半导体私人有限公司 Integrated circuit and its manufacturing method with programmable storage

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