CN101002567B - Insecticide composition - Google Patents
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- CN101002567B CN101002567B CN2007100024190A CN200710002419A CN101002567B CN 101002567 B CN101002567 B CN 101002567B CN 2007100024190 A CN2007100024190 A CN 2007100024190A CN 200710002419 A CN200710002419 A CN 200710002419A CN 101002567 B CN101002567 B CN 101002567B
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Abstract
An insecticide compound includes 2, 3, 5, 6-tetrafluoro-4-methoxy methylbenzyl2, 2-dimethyl-3-(2-methyl-1-propenyl) cyclopropane carboxylate, alpha-[2-(2-butoxyethoxy) ethoxy]-4, 5-mthylenedioxo-2-propyltoluene, 2-methyl-4-oxygen-3-(2-propymyl)cyclopent-2-alkenyl2, 2-dimethyl-3-(2-methyl-1-propeny) cyclopropane carboxylate, and can effectively dominante the insect pest.
Description
Technical field
The present invention relates to the method for new type disinsection composition and control worm.
Background technology
In JP2001-11022A, by general formula (1) provide 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound:
Be called as active insecticidal components.
Known α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4,5-methylene dioxy-2-propyltoluene (hereinafter being called " PBO ") is used to strengthen the insecticidal activity of a pyrethrum ester compound analogy.And, by 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2 that general formula (2) provides, 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound:
Be also referred to as Pesticidal compound.
Summary of the invention
The invention provides Pesticidal combination, described Pesticidal combination comprises 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound (hereinafter being called " compound (1) "), PBO and 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound (hereinafter being called " compound (2) "), the amount of PBO 2～20 times of weight of compound (1) normally wherein, preferred 2.5～10 times, and the amount of compound (2) 1～5 times of weight of compound (1) normally, preferred 1～3 times.
Pesticidal combination of the present invention provides the excellent insecticidal effect by synergy, therefore, can reduce the total amount of the active component that is used to control worm.This helps saving cost in worm control and causes seldom environmental influence.And, the present invention also provides the method for control worm, described method comprises administered compound (1), PBO and compound (2), the wherein amount of PBO 2～20 times, preferred 2.5～10 times of weight of compound (1) normally, and the amount of compound (2) are 1～5 times, preferred 1～3 times of weight of compound (1) normally.
Disclose compound (1) among the JP2001-11022A and can obtain described compound (1) according to its description.Compound (1) and compound (2) have the optical isomer based on asymmetric carbon atom, and the present invention includes all active isomers and its mixture.PBO is compound known and can buys from the market.And compound (2) also is that compound known and its isomer can be used as d-prallethrin and buy from the market.
Pesticidal combination of the present invention can pass through mixing cpd (1), PBO and compound (2) preparation.
Pesticidal combination of the present invention can be used to prepare pesticide tablet.Pesticide tablet is fiber carrier or the porous carrier that holds compound (1), PBO and compound (2).
The example of fiber carrier comprises native fiber for example paper pulp, cellulose and cotton; Synthetic fibers are polyester and polyacrylate for example; And inorfil for example glass fibre and asbestos.The inorganic substances that the example of porous carrier comprises porous are diatomite for example; Porous ceramics is pottery for example; And porous resin for example polyurethane foam and polypropylene foam.
The size of pesticide tablet is 2.0～2.5cm normally
3, for example, the apparent volume before holding Pesticidal combination of the present invention is 2.2cm * 3.5cm * 0.28cm (about 2.2cm
3).The common every 2.2cm of pesticide tablet
3The compound (1), PBO and the compound (2) that contain 1～320mg total amount.
In order on fiber carrier or porous carrier, to hold Pesticidal combination of the present invention, usually Pesticidal combination and organic solvent are mixed and prepare insecticide solution and dipping.Insecticide solution comprises the organic solvent of 50～95wt% usually.And the total amount of compound in the insecticide solution (1), PBO and compound (2) is 5～40wt% normally.The common every 2.2cm of pesticide tablet
3The insecticide solution that contains 20～800mg.
The example of organic solvent comprises for example diisooctyl phthalate of ester, di-2-ethylhexyl phthalate, diisodecyl adipate (DIDA), di-n-octyl sebacate, diisononyl adipate, Diisooctyl Sebacate, di 2-ethylhexyl azelate, dihexyl azelate, dodecoic acid two-2-Octyl Nitrite, di butoxyethoxyethyl adipate, isopropyl palmitate, dioctyl adipate, dibutyl sebacate, citric acid O-acetyl group tributyl, di-2-ethylhexyl maleate and isopropyl myristate; With hydrocarbon for example dodecane, tridecane, the tetradecane and pentadecane, isoparaffin, cycloalkane and kerosene of normal paraffin hydrocarbons for example.The representative instance of the normal paraffin hydrocarbons solvent that can buy from the market comprise Norpar-13 (Exxon Mobil Corp production), Norpar-15 (Exxon Mobil Corp. production), normal paraffin hydrocarbons M level (NipponOil Corp.), normal paraffin hydrocarbons H level (Nippon Oil Corp.) and Neochiozol (Chuokasei Co., Ltd.).The representative instance of the isoparaffic solvent that can buy from the market comprises Isopar M (Exxon Mobil Corp. production), Isopar V (Exxon MobilCorp. production), IP solvent 2028 (Idemitsu Kosan Co., Ltd.), IP solvent 2835 (Idemitsu Kosan Co., Ltd.) and Shelsol TM (Shell Chemicals Japan), the representative instance of the cycloalkane solvent that can buy from the market comprises Exxsol D80 (ExxonMobil Corp. production), Exxsol D110 (Exxon Mobil Corp. production) and ExxsolD130 (Exxon Mobil Corp. production).Organic solvent can be the mixture of above-mentioned solvent.
Insecticide solution can also comprise other solvent, colouring agent, antioxidant, synergist, stabilizing agent, spices or the like.
The example of colouring agent comprises anthraquinone (anthraquinine) type blue colorant for example 1,4-dibutylamino anthraquinone, 1,4-diisopropylaminoethyl anthraquinone, 1,4-two (2,6-diethyl-4-aminomethyl phenyl amino) anthraquinone, 1-methylamino-4-o-tolyl amino anthraquinones, 1-methylamino-4-m-tolyl amino anthraquinones, 1-methylamino-4-p-tolyl amino anthraquinones.These colouring agents can use or use two kinds or more of mixtures separately.And these can use by mixing with different colours.
The example of antioxidant comprises phenolic compound for example dibutyl hydroxy toluene, butylated hydroxyanisole (BHA), 2,2-methylene two (4-methyl-6-tert butyl phenol) and 2,6-di-t-butyl-4-cresols.The example of synergist comprises two (2,3,3,3-tetrachloro propyl group) ether and N-(2-ethylhexyl) two rings [2.2.1] heptan-5-alkene-2,3-dicarboximide (dicarboximide), the example of stabilizing agent comprise ultraviolet (UV) absorbent for example benzotriazole UV absorbers and benzophenone UV absorbent.
And insecticide solution can comprise another kind of Pesticidal compound or insect-repelling compound.
The example of other Pesticidal compound comprises for example allethrin of pyrethroid compound, tetramethrin, phenothrin, resmethrin, cyphenothrin, permethrin, cypermethrin, decis, tralomethrin, cyfloxylate, PH, alkynes miaow chrysanthemum ester (imiprothrin), ether chrysanthemum ester, sumicidin, fenpropathrin, silicon hydrocarbon chrysanthemum ester (silafluofen), transfluthrin, terallethrin (terallethrin), Biphenthrin, Prallethrin and 2-methyl-4-oxygen-3-(2-acrylic) ring hept-2-ene" base 3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester; Organophosphorus compound is dichlorvos, sumithion, Ravap, fenthion, chlopyrifos and basudin for example; Carbamate compounds for example unden, sevin,
Worm ketone and Bassa; Chitin is synthetic suppress compound for example the octafluoro urea, decide worm urea, fluorine bell urea, diflubenzuron, cyromazine and 1-(2, the 6-difluoro benzoyl)-3-[2-fluoro-4-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl] urea; The juvenile hormone compound is pyriproxyfen, Entocon ZR 515, illiteracy 512 and Fenoxycarb 25WG for example; New class nicotine (neonicotinoid) compound and N-phenyl pyrazole compounds.
The example of insect-repelling compound comprises N, N-diethyl-m-toluamide, limonene, linalool, citronellal, menthol, menthones, hinokitol, geraniol, cineole, indenes worm prestige (indoxacarb), carane-3,4-glycol, MGK-R-326, MGK-R-874 and BAYKBR-3023.
Pesticidal combination of the present invention can be used to control worm by the method for routine.Insecticide solution can also be used to control worm by the method for routine; And it is applicable to the preparation pesticide tablet.
Pesticide tablet can be used to control worm by heating.For example, be placed on the hot plate, local or its adjacent domain (for example indoor) that described hot plate places worm to haunt, and in about 140～200 ℃ of heating down.
Pesticidal combination of the present invention is effective to control winged insect (for example diptera worm) especially.The example of this worm comprises tame uranotaenia (Culex spp.), for example Culex pipiens pallens (Culex pipienspallens), three spots man mosquito (Culex tritaeniorhynchus), tropical tame mosquito (Culex pipiensquinquefaciatus) and ground player whose turn comes next mosquito (Culex pipiens molestus); Aedes (Aedesspp.), for example Aedes aegypti (Aedes aegypti) and aedes albopictus (Aedes albopitus); Anopheles (Anopheles spp.) is Anopheles sinensis (Anopheles sinensis) for example; Chironomidae (Chironimidae); Nuscidae (Muscidae) is Musca domeatica, nonbiting stable fly (Muscina stabulans) and Fannia canicularis (Fannia canicularis) for example; Calliphoridae (Calliphoridae); Flesh flies (Sarcophagidae); Drosophilidae (Drosophilidae); Moth Simulidae (Psychodidae); Phoridae (Phoridae); Tabanidae (Tabanidae); Simulidae (Simuliidae); Stomoxyidae and Heleidae (Ceratopogonidae).
Embodiment
Below explain in detail the present invention; Right rather than be defined in following embodiment.In the following embodiments, umber is meant parts by weight.
Preparation embodiment 1
With 4 parts of compounds (1), 10 parts of PBO, 4 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone and 71.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 2
With 1 part of compound (1), 20 parts of PBO, 5 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone and 63.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 3
With 4 parts of compounds (1), 8 parts of PBO, 4 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone and 73.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 4
With 4 parts of compounds (1), 8 parts of PBO, 4 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1; 4-diisopropylaminoethyl anthraquinone, 20 parts of tributyl O-acetyl group citrates and 53.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 5
With 4 parts of compounds (1), 8 parts of PBO, 4 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone, 20 parts of diisononyl adipates and 53.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 6
With 4 parts of compounds (1), 8 parts of PBO, 4 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1; 4-diisopropylaminoethyl anthraquinone, 10 parts of tributyl O-acetyl group citrates, 10 parts of diisononyl adipates and 53.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 7
With 4 parts of compounds (1), 10 parts of PBO, 4 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1; 4-diisopropylaminoethyl anthraquinone, 20 parts of tributyl O-acetyl group citrates and 51.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 8
With 4 parts of compounds (1), 10 parts of PBO, 4 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone, 20 parts of diisononyl adipates and 51.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 9
With 4 parts of compounds (1), 10 parts of PBO, 4 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1; 4-diisopropylaminoethyl anthraquinone, 10 parts of tributyl O-acetyl group citrates, 10 parts of diisononyl adipates and 51.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 10
With 1 part of compound (1), 20 parts of PBO, 5 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1; 4-diisopropylaminoethyl anthraquinone, 10 parts of tributyl O-acetyl group citrates and 53.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 11
With 1 part of compound (1), 20 parts of PBO, 5 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone, 10 parts of diisononyl adipates and 53.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 12
With 1.5 parts of compounds (1), 30 parts of PBO, 1.5 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone and 56.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix the formation insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 13
With 1 part of compound (1), 2 parts of PBO, 5 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1; 4-diisopropylaminoethyl anthraquinone, 30 parts of tributyl O-acetyl group citrates and 51.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 14
With 1 part of compound (1), 2 parts of PBO, 5 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone, 30 parts of diisononyl adipates and 51.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Preparation embodiment 15
With 1 part of compound (1), 2 parts of PBO, 5 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1; 4-diisopropylaminoethyl anthraquinone, 15 parts of tributyl O-acetyl group citrates, 15 parts of diisononyl adipates and 51.5 parts of Shelsol TM (isoparaffic solvent, Shell Chemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) forms pesticide tablet, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Be with reference to embodiment below, be provided for the pesticide tablet of reference.
With reference to embodiment 1
With 4 parts of compounds (1), 5 parts of PBO, 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone and 80.5 parts of Shelsol TM (isoparaffic solvent, ShellChemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) is formed for the pesticide tablet of reference, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
With reference to embodiment 2
With 5 parts of PBO, 4 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone and 80.5 parts of Shelsol TM (isoparaffic solvent, ShellChemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) is formed for the pesticide tablet of reference, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
With reference to embodiment 3
With 1 part of compound (1), 10 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone and 78.5 parts of Shelsol TM (isoparaffic solvent, ShellChemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) is formed for the pesticide tablet of reference, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
With reference to embodiment 4
With 10 parts of PBO, 5 parts of compounds (2), 10 parts of dibutyl hydroxy toluenes, 0.5 part 1,4-diisopropylaminoethyl anthraquinone and 74.5 parts of Shelsol TM (isoparaffic solvent, ShellChemicals Japan) mix and form insecticide solution.(2.2cm * 3.5cm * 0.28cm) dipping insecticide solution (100mg) is formed for the pesticide tablet of reference, and described fiber carrier is made up of paper pulp and velveteen with fiber carrier.
Provide the effect of Pesticidal combination of the present invention by the following examples.
Experimental example 1
5 female adult mosquitoes (Culex pipiens pallens) are released in 2 glass tubes (height: 12cm, internal diameter: 4cm), with two openings of 16 purpose nets sealing respectively.
Plate is (wide: as 7.8cm) to place trial circle cylinder (height: 80cm, diameter: 20cm).Described plate has 2 holes that diameter is 4cm.Two Kong Jun are positioned at the place from cylinder upper opening center 4cm.
2 above-mentioned glass tubes are placed on the hole of described plate and and cover with transparent cylinder (height: 30cm, diameter 20cm).
Heat the pesticide tablet 12h of the present invention that obtains by preparation embodiment 1 with heater (heater of buying on the market that is used for pesticide tablet) down at 160～170 ℃, and move on to the cylindrical bottom of test.After 5 minutes, calculate the mosquito number of knocking down.And, carry out identical step by using the pesticide tablet that obtains with reference to embodiment 1 and 2.
Table 1 provides the result.
Table 1
Experimental example 2
Use the step identical, except with tropical tame mosquito replacement Culex pipiens pallens, carry out by preparing pesticide tablet of the present invention that embodiment 2 obtains and the test that obtains by reference embodiment 3 and 4 with reference to pesticide tablet with experimental example 1.
Table 2 provides the result.
Table 2
Claims (9)
1. Pesticidal combination, it comprises 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound, α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4,5-methylene dioxy-2-propyltoluene and 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound
α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4 wherein, the amount of 5-methylene dioxy-2-propyltoluene is 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2～20 times of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound weight, and 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2, the amount of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound is 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,1～5 times of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound weight.
2. the Pesticidal combination of claim 1, α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4 wherein, the amount of 5-methylene dioxy-2-propyltoluene is 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2.5～10 times of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound weight, and 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2, the amount of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound is 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,1～3 times of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound weight.
3. pesticide tablet, it is fiber carrier or the porous carrier that holds claim 1 or 2 described Pesticidal combinations.
4. insecticide solution, it comprises 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound, α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4,5-methylene dioxy-2-propyltoluene, 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound and organic solvent
α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4 wherein, the amount of 5-methylene dioxy-2-propyltoluene is 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2～20 times of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound weight, and 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2, the amount of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound is 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,1～5 times of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound weight.
5. the insecticide solution of claim 4, wherein 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound, α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4,5-methylene dioxy-2-propyltoluene and 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2, the total amount of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound is 5～40% of an insecticide solution weight.
6. claim 4 or 5 insecticide solution, wherein organic solvent is ester or hydrocarbon.
7. method of controlling worm, comprise to the place that described worm or described worm haunt and use 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound, α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4,5-methylene dioxy-2-propyltoluene and 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound
α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4 wherein, the amount of 5-methylene dioxy-2-propyltoluene is 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2～20 times of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound weight, and 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2, the amount of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound is 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,1～5 times of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound weight.
8. the method for the control worm of claim 7, α-[2-(2-butoxy ethyoxyl) ethyoxyl]-4 wherein, the amount of 5-methylene dioxy-2-propyltoluene is 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,2.5～10 times of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound weight, and 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 2, the amount of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound is 2,3,5,6-tetrafluoro-4-methoxy benzyl 2,1～3 times of 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropanecarboxylcompound weight.
9. a method of controlling worm comprises the described pesticide tablet of heating claim 3.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006010828A JP2007191422A (en) | 2006-01-19 | 2006-01-19 | Insecticidal mat and insect pest control liquid for thermal transpiration |
| JP2006010828 | 2006-01-19 | ||
| JP2006-010828 | 2006-01-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101002567A CN101002567A (en) | 2007-07-25 |
| CN101002567B true CN101002567B (en) | 2011-02-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100024190A Active CN101002567B (en) | 2006-01-19 | 2007-01-17 | Insecticide composition |
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| JP (1) | JP2007191422A (en) |
| CN (1) | CN101002567B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1423942A (en) * | 2001-12-10 | 2003-06-18 | 成都彩虹电器（集团）股份有限公司 | Bactericidal mosquito killing tablets |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1423942A (en) * | 2001-12-10 | 2003-06-18 | 成都彩虹电器（集团）股份有限公司 | Bactericidal mosquito killing tablets |
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| CN101002567A (en) | 2007-07-25 |
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