CN1007731B - "authracene oil-based" paint and its preparation - Google Patents
"authracene oil-based" paint and its preparationInfo
- Publication number
- CN1007731B CN1007731B CN 85105330 CN85105330A CN1007731B CN 1007731 B CN1007731 B CN 1007731B CN 85105330 CN85105330 CN 85105330 CN 85105330 A CN85105330 A CN 85105330A CN 1007731 B CN1007731 B CN 1007731B
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- CN
- China
- Prior art keywords
- paint
- oil
- agent
- carbolineum
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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Abstract
The present invention belongs to chemical industry paint (C09D). A method for producing 'anthracene oil base' paint by replacing tung oil and vegetable oil with anthracene oil has the production processes that (1), an anthracene oil base agent containing anthracene oil is first produced; (2), a formula is designed according to needed paint, and the 'anthracene oil base' paint is processed under normal temperature. Produced black paint of anthracene oil bases, broken color paint, pure color paint, anti-rust paint, etc. are all multifunctional paint. The present invention has a construction method of coating, or spraying, or waterlogging or roasting. Raw materials of the present invention come from byproducts at the time of refining coal oil, and have the advantages of low price and easy obtain. Thus, the profit of the paint is 3 to 10 times of cost.
Description
At present, produces paint kind more than 2,000 on the known world, be divided into priming paint and finish paint two big classes, generally adopt tung oil, plant wet goods raw material to boil and form, and majority is specialized paint that applicable surface is narrow.
The present invention seeks to: make a kind of many performances oil-based paints, enlarge the scope of application, do not use vegetables oil simultaneously, solve the contradiction of paint industry and human contention vegetables oil.
The present invention was divided into for two steps:
The first step: make six kinds of carbolineum bases that contain carbolineum earlier.These six kinds of carbolineum bases are meant rust-preventive agent, reinforcer, wedding agent, anti-aging electuary, the stiffening agent that adds lustre to, solvation, and its method for making is:
Solvation: prescription: toluene 85%, chloroprene rubber powder 5%, carbolineum 10%.Technology: these three kinds of compositions are packed in the hybrid reaction jar, stir, make the chloroprene rubber powder off-bottom be glue after, packing is sealed up for safekeeping stand-by.Performance: adjust paint viscosity, play the solvent or diluent effect.
Rust-preventive agent: prescription: electrode pitch 50%, the cotton powder 10% of carbolineum 10%, 325 order barite, solvation 30%, technology: electrodeposition pitch is added the fusing of reactor internal heating, be warmed up to 300-360 ℃, add the cotton powder of barite, be incubated 0.5-2 hour, lower the temperature 190-215 ℃ the time, add carbolineum insulation 0.5-1 hour, cool to 110-125 ℃, add solvation and stir, be cooled to normal temperature and seal up for safekeeping stand-by.Performance: rise antirust, protection against corrosion, waterproof, the effect of band rust brushing.
Reinforcer: prescription: polyvinyl chloride 8%, cyclohexanone 20%, solvation 47%, acetone 15%, 605 Resins, epoxy 5%, 325 order barite cotton 5%.Technology: preceding four kinds of raw materials are added in the retort, placed 20-50 hour, used the stirrer high-speed stirring then 20 minutes-1 hour, add after 605 Resins, epoxy 5 parts (weight) stir, add the cotton powder of the heavy crystalline substance of 325 orders 5 parts (weight) again and stir well, normal temperature is sealed up for safekeeping stand-by.Performance, acid-and base-resisting, salt and solvent have preservative property.
Wedding agent: prescription: rosin 45%, calcium oxide 3%, the cotton powder 10% of carbolineum 10%, 605 Resins, epoxy 5%, 325 order barite, solvation 27%.Technology: rosin is added in the reactor, heat fused 1-2 hour, when temperature is raised to 200-250 ℃, slowly add calcium oxide again, stirred one to two hour, temperature is raised to 250-275 ℃, be incubated ten minutes to one hour, add carbolineum then and stir, when temperature drops to 200-215 ℃, be incubated 15 minutes to one hour, add asbestos powder again, stir, take the dish out of the pot, when temperature arrives 110-125 ℃, add Resins, epoxy, add solvation again and stir, be cooled to normal temperature, packing is sealed up for safekeeping stand-by.Performance: play bonding, heat stable resin.
Stiffening agent adds lustre to: prescription: carbolineum 10%, the cotton powder 10% of water glass 50%, the 325 order barite of modulus 3.3, acetone 30%.Technology: these four kinds of raw materials are packed into to mix in the retort, and normal temperature is sealed up for safekeeping stand-by.Performance improves gloss of film degree and hardness, quickens paint from the speed of doing.
Anti-aging towards grinding agent: prescription: carbolineum 10%, 325 order red lead powder 3%, 325 order yellow lead powder 3%, 325 order iron mica powder 12%, 325 orders " silver " powder or aluminium powder 2%, 325 order silicon carbide 8%, 325 order lapis amiridis 7%, the cotton powder 10% of 616 Resins, epoxy, 5%, 325 order barite, solvation 40%.Technology: needed raw material packed into to mix in the retort, and barrelling is sealed up for safekeeping stand-by.Performance: uvioresistant, insulation, anti-aging.
Second step: according to required paint kind component design, with needed various carbolineum bases at normal temperatures, the reaction in-tank mixing of packing into, after adding the mixing of mill base or stopping composition again, adjust this lacquer viscosity to 25-35 second (coating-4 viscosity meter) with solvation, mesh-of-grind is promptly made required paint to 20-30 ° again.
Embodiment is as follows:
Example one: prepare Authracene oil-based black paint rust-preventive agent 45%, reinforcer 20%, wedding agent 25%, anti-aging towards grinding agent 10%.Technology: with these four kinds of carbolineum bases reaction in-tank mixing of packing into, adjust this lacquer viscosity to 25-35 second (coating-4 viscosity meter), to 20-30 °, can seal up for safekeeping stand-by through mesh-of-grind with solvation.
Illustrate: this paint adds special-purpose performance stopping composition (subsidiary material), just can be made into the specialized paint of special purpose, as: the colored cement 20-50%(weight that in this paint, adds this paint weight), just can be made into colored floor board paint, the wooden carbon dust that adds the 20-50% of this paint weight for another example in this paint just can be made into antirust flatting.
Example two: prepare Authracene oil-based secondary color paint.
Rust-preventive agent 30%, reinforcer 20%, wedding agent 30%, anti-aging towards grinding agent 20%.Technology: with these four kinds of carbolineum bases reaction in-tank mixing of packing into, then needed mill base (its amount is the 20-50% of these four kinds of carbolineum base gross weights) is added, continue to mix, adjust this lacquer viscosity to 25-35 second (coating-4 viscosity meter) with solvation again, to 20-30 °, can seal up for safekeeping stand-by through mesh-of-grind.
Illustrate: color matching can add pigment according to the oil absorption of pigment and the required pigment degree of depth, if prepare special-purpose colored paint, will have the stopping composition of special-purpose performance and pigment and join in the Authracene oil-based solvation and stir, in order to stand-by.As prepare marine antifouling paint, when the preparation mill base, add the phenyl-hexachloride powder in this mill base, or red precipitate, or highly toxic substance such as zinc oxide, its weight is coated with lacquer 10～30% of gross weight for this, mix.And for example prepare bike, electric fan, refrigerator, washing machine, the needed baking vanish of car product, be exactly in Authracene oil-based secondary color paint mill base, to add the chloroprene rubber powder of its amount, will add its weight again and mix for the carbolineum of the 2-5% of this lacquer gross weight for the 2-5% of this gross weight.Adjust this lacquer viscosity to 25-35 second (coating-4 viscosity meter) with solvation again, to 20-30 °, can seal up for safekeeping stand-by through mesh-of-grind.
Example three: prepare Authracene oil-based pure color paint.
Prescription: reinforcer 20%, wedding agent 50%, anti-aging towards grinding agent 30%.Technology: mix in the retort of under the normal temperature reinforcer, wedding agent being packed into, add and ageing-resistantly mix towards grinding agent, adjust this lacquer viscosity to 25-35 second (coating-4 viscosity meter) with solvation again, mesh-of-grind can be sealed up for safekeeping stand-by to 20-30 ° then.
Illustrate: if require made varnished insulation performance good, then add 325 order cloud powder in this lacquer and get final product, and adjust this lacquer viscosity to 25-35 second (coating-4 viscosity meter) with solvation again, mesh-of-grind can be sealed up for safekeeping stand-by to 20-30 ° then.If the water glass of the 30-50% of this lacquer amount of adding or the unslaked lime of 30-50% mix in this paint, can be made into the be full of cracks lacquer through grinding, add the high calcium resin (rosin calcium fat) of the 30-50% of this lacquer weight, can be made into wrinkle paint; Add the naphthalene of 10-30% of this lacquer weight or phosphorus benzene bis-acid potassium acid anhydride or urea and mix, after grinding, can be made into crystallization paint; If be incorporated as the 10-30% cobalt chloride of this lacquer weight, mix, can be made into variable color paint through grinding.
Example four: prepare Authracene oil-based anticorrosive paint.
Prescription: rust-preventive agent 50%, reinforcer 20%, the hardening capacity of adding lustre to 15%, ageing-resistant towards grinding agent 15%.Technology: will mix in rust-preventive agent, reinforcer, the retort of packing under the normal temperature, add optical brightener and mix, add again and ageing-resistantly mix, adjust to 25-35 second (coating-4 viscosity meter) with solvation towards grinding agent, mesh-of-grind can be sealed up for safekeeping stand-by to 20-30 ° then.
From above-mentioned four kinds of embodiment of six kinds of carbolineum bases, they had all both had outstanding performance and effect, possessed the performance and the effect of general paint again simultaneously.From facts have proved, this paint can be with rust brushing, spray, stain and acid-and base-resisting simultaneously, salt, also has the dual performance of priming paint, finish paint simultaneously.
The outstanding properties of this lacquer mainly is carbolineum and two kinds of unified results of raw material contradictory of electrode pitch.Go out residuum behind light oil, middle oil, heavy oil, the carbolineum because electrode pitch is a coal tar fractional distillation, have superb anticorrosion, antirust, water resistance.But its weathering resistance is very poor, and cold short heat is soft.Carbolineum is that coal tar fractionation from 300-360 ℃ is come out, be a kind of heavy-gravity liquid, non-volatile at normal temperatures, chemical property itself is stable, and counter electrode pitch dissolving power can reach 95-97%, so enough carbolineum molecules are placed around the electrode pitch molecule, form firm barrier film, make between the asphaltene molecule and can't directly contact, asphaltene molecule also can't contact with air, so can reach the aging-resistant purpose.Improve the weathering resistance of electrode pitch, the adding of carbolineum simultaneously also can make the bituminous uncombined carbon produce plasticity and cohesive force, and this has just improved the sticking power of Authracene oil-based paint, snappiness, impact resistance.It can be rapidly by the zone of oxidation of steel surface, in the immersion ferric oxide, with ferric oxide be one thoroughly, form a bonding zone of transition, gather and join together, combine with the metal carrier body parent securely, this is that Authracene oil-based paint can be with the reason of rust brushing, carbolineum and electrode pitch all have good antiseptic property, and they are all water insoluble again.Add in design and during this paint formulation, adopted silicon carbide, neutral substances such as the cotton powder of barite, so with it take as the leading factor raw material production paint acid-and base-resisting, salt, anticorrosion, antirust, moistureproof, water resistance is good.
Implement meaning of the present invention
One, makes to produce the raw material of paint with carbolineum, can replace using in the paint industry conventional practice of tung oil, edible vegetable oil, relax the contradiction of paint industry and human contention vegetables oil.
Two, do to produce the paint that the base of paint is produced with carbolineum, it is many to have performance, and purposes is wide, price is low, technology is simple, social benefit and the tangible characteristics of economic benefit.
Claims (15)
1, a kind of paint that constitutes by mineral oil, filmogen, pigment, solvent and stopping composition, it is characterized in that taking raw material as the leading factor, make six kinds of carbolineum bases: solvation, rust-preventive agent, reinforcer, wedding agent, the stiffening agent that adds lustre to, anti-aging towards grinding agent with carbolineum and electrode pitch; Make Authracene oil-based black paint, Authracene oil-based secondary color paint, Authracene oil-based pure color paint, Authracene oil-based anticorrosive paint by these six kinds of carbolineum base appropriate combination.
2, paint according to claim 1, it is characterized in that its preparation method is the prescription according to design, with needed carbolineum base and paint batch materials with specialized performance, be contained in the retort and mix, adjust viscosity to 25-35 second (coating-4 viscosity meter) with solvation again, mesh-of-grind promptly can be made into needed paint to 20-30 °.
3,, it is characterized in that described solvation prescription is a toluene 85%, chloroprene rubber powder 5%, carbolineum 10% according to the paint of claim 1 or 2.
4, paint according to claim 1 and 2 is characterized in that described rust inhibitor formulation is an electrode pitch 50%, the cotton powder 10% of carbolineum 10%, 325 order barite, solvation 30%.
5,, it is characterized in that described reinforcer prescription is a polyvinyl chloride 8%, pimelinketone 20%, solvation 47%, acetone 15%, 605 Resins, epoxy 5%, 325 order barite cotton 5% according to the paint of claim 1 or 2.
6, paint according to claim 1 and 2 is characterized in that described wedding agent prescription is a rosin 45%, calcium oxide 3%, the cotton powder 10% of carbolineum 10%, 605 Resins, epoxy 5%, 325 order barite, solvation 27%.
7, paint according to claim 1 and 2 is characterized in that the described stiffening agent prescription that adds lustre to is a carbolineum 10%, the cotton powder 10% of water glass 50%, the 325 order barite of modulus 3.3, acetone 80%.
8, paint according to claim 1 and 2, it is characterized in that described anti-aging: prescription: carbolineum 10% towards grinding agent, 325 order red lead powders, 3%, 325 order yellow lead powder, 3%, 325 order iron mica powder 12%, 325 orders " silver " powder or aluminium powder 2%, 325 order silicon carbide, 8%, 325 order lapis amiridis, 7%, 616 Resins, epoxy 5%, the cotton powder 10% of 325 order barites, solvation 40%.
9,, it is characterized in that prescription is: rust-preventive agent 45%, reinforcer 20%, wedding agent 25%, anti-aging towards grinding agent 10% according to claim 1 and 2 described a kind of Authracene oil-based black paints.
10, paint according to claim 9 is characterized in that in the described paint adding the stopping composition of an amount of special-purpose performance, just can be made into the specialized paint of special purpose; The colored cement that adds the 20-50% of this paint weight in this paint just can be made into colored floor board paint, and the wooden carbon dust that adds the 20-50% of this paint weight for another example in this paint just can be made into antirust flatting.
11, a kind of Authracene oil-based secondary color paint according to claim 1 and 2, the rust-preventive agent 30% that it is characterized in that filling a prescription, reinforcer 20%, wedding agent 30%, anti-aging towards grinding agent 20% add an amount of pigment in addition as required.
12, paint according to claim 11 is characterized in that in the described paint adding the material of an amount of special-purpose performance, just can be made into the specialized paint of special purpose; The phenyl-hexachloride powder that adds the 10-30% of this lacquer in this lacquer, or red precipitate, or highly toxic substance such as zinc oxide mix, and make marine antifouling paint; The chloroprene rubber powder that in this paint, adds the 2-5% of this lacquer, the carbolineum that will add the 2-5% of this lacquer again mixes, adjust this viscosity to 25-35 second (coating-4 viscosity meter) with solvation again, to 20-30 °, promptly can be made into bike, electric fan, refrigerator, washing machine, the special-purpose baking vanish of car through mesh-of-grind.
13, paint according to claim 1 and 2 is characterized in that described Authracene oil-based pure color paint formulation is reinforcer 20%, wedding agent 50%, ageing-resistant towards grinding agent 30%.
14, paint according to claim 13, it is characterized in that adding in the described paint material of an amount of special-purpose performance, just can be made into the specialized paint of special purpose, the water glass of the 30-50% of this lacquer amount of adding or the unslaked lime of 30-50% in this paint, mix, can be made into the be full of cracks lacquer through grinding; The high calcium resin (rosin calcium fat) that adds the 30-50% of this lacquer weight can be made into wrinkle paint; Add the naphthalene of 10-30% of this lacquer weight or phosphorus benzene bis-acid potassium acid anhydride or urea and mix, after grinding, can be made into crystallization paint; Its blending process all is required raw material to be contained in the retort mix, and adjusts viscosity to 25-35 second (coating-4 viscosity meter) with the fusing agent again, to 20-30 °, can seal up for safekeeping stand-by through mesh-of-grind.
15, paint according to claim 1 and 2 is characterized in that described Authracene oil-based anticorrosive paint, fills a prescription to be rust-preventive agent 50%, reinforcer 20%, the stiffening agent 15% that adds lustre to, ageing-resistant towards grinding agent 15%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 85105330 CN1007731B (en) | 1985-07-10 | 1985-07-10 | "authracene oil-based" paint and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 85105330 CN1007731B (en) | 1985-07-10 | 1985-07-10 | "authracene oil-based" paint and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN85105330A CN85105330A (en) | 1987-03-04 |
| CN1007731B true CN1007731B (en) | 1990-04-25 |
Family
ID=4794407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 85105330 Expired CN1007731B (en) | 1985-07-10 | 1985-07-10 | "authracene oil-based" paint and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1007731B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103721915B (en) * | 2014-01-14 | 2015-06-17 | 杭州三晶工艺塑料有限公司 | Bottom material surface processing technology enabling surface to have crystal flower lines |
| CN103773015A (en) * | 2014-01-20 | 2014-05-07 | 南通东南公路工程有限公司 | Rosin soap emulsified asphalt water-proof material |
| CN104387972A (en) * | 2014-11-14 | 2015-03-04 | 无锡伊佩克科技有限公司 | Multicolor hard film rust preventive oil applied to boat bottom and preparation method of oil |
| CN105802458B (en) * | 2014-12-30 | 2018-05-04 | 天津天女化工集团股份有限公司 | A kind of bloom offset printing gloss oil |
| CN105907254A (en) * | 2016-06-24 | 2016-08-31 | 无锡伊佩克科技有限公司 | Epoxy resin anti-rust paint with rust for steel and preparation method thereof |
| CN112552818B (en) * | 2020-11-09 | 2022-05-13 | 钟宏云 | Bright oil, preparation method thereof and application of limestone land |
-
1985
- 1985-07-10 CN CN 85105330 patent/CN1007731B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CN85105330A (en) | 1987-03-04 |
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