CN100593562C - Biomass synthetic fuel - Google Patents
Biomass synthetic fuel Download PDFInfo
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- CN100593562C CN100593562C CN200710078507A CN200710078507A CN100593562C CN 100593562 C CN100593562 C CN 100593562C CN 200710078507 A CN200710078507 A CN 200710078507A CN 200710078507 A CN200710078507 A CN 200710078507A CN 100593562 C CN100593562 C CN 100593562C
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Abstract
The invention discloses a kind of biological synthetic fuel. The comprised component and weight proportion are as follows: monohydric alcohol with 1- 11 carbons 20- 80%, one or many of benzin naphtha,solvent naphtha, dimethyl ether and gasoline 10- 50%, one or many of ether, acetone, butanol and petrohol 4.5- 10%, one or many of hydrogen dioxide, petroleum ether, tertiary-butyl-p-cresol 0.5- 2%,one or many of cyclopentadiene iron, toluene and dimethylbenzene 5- 18%. The main material is industrial waste liquid or side product or agricultural waste, the heat value is high and the dynamic effect is pretty good when used in generator. The invention is characterized by environment- friendly fuel discharge material, wide source of raw material, low production cost and direct utilization of generator. The invention aslo discloses the method for preparing biological synthetic fuel.
Description
Technical field
The present invention relates to a kind of synthol, particularly a kind of biomass synthetic fuel.
Background technology
Energy conservation and protection environment are the long-range strategy and policy of economy and social development.Along with the high speed development of Modern Traffic, the Motor vehicles cumulative year after year not only causes energy dilemma, and the pollution of physical environment is on the rise.In the prior art, the fuel that the vehicles such as motor vehicle, boats and ships use substantially all is gasoline or diesel oil.Though, played immeasurable effect in people's life and industrial production PetroChina Company Limited.,, the excessive utilization of petroleum-based energies such as gasoline or diesel oil causes the arch-criminal of energy dilemma and environmental pollution just.Simultaneously, produce a large amount of industry or agricultural waste in worker, agriculture production and the people's life, these materials are discharged in the Nature and also pollute the environment.Country pays much attention to and has issued " People's Republic of China's renewable energy source method " to above problem, classifies the development and use of renewable resources the pioneer field of development in science and technology as, encourages exploitation, research, uses renewable resources.
Based on above problem, need utilize industrial effluent and byproduct or agricultural wastes and invent a kind of bioenergy fuel come fuel such as gasoline replacing and be applied to motor vehicle or boats and ships on.Not only can save petroleum resources, reduce pollutant emission, protection and improve environment, and reduce manufacturing cost and use cost significantly.
Summary of the invention
In view of this, the purpose of this invention is to provide a kind of biomass synthetic fuel, this fuel value height, the discharge feature of environmental protection are good, raw material sources do not need the transformation apparatus motor vehicle engine in industrial effluent and byproduct and agricultural wastes, low cost of manufacture and when using, and be very easy to use.
Biomass synthetic fuel of the present invention, this fuel comprises following component by weight percentage:
The monohydroxy-alcohol 20-80% that contains 1 to 11 C
One or more 10-50% in petroleum naphtha, solvent oil, dme, the gasoline
One or more 4.5-10% in ether, acetone, propyl carbinol, the Virahol
One or more 0.5-2% in hydrogen peroxide, sherwood oil, the ditertbutylparacresol
One or more 5-18% in cyclopentadiene iron, toluene, the dimethylbenzene.
Further, biomass synthetic fuel of the present invention, this fuel comprises following component by weight percentage:
The monohydroxy-alcohol 52% that contains 1 to 11 C
In petroleum naphtha, solvent oil, dme, the gasoline one or more 30%
In ether, acetone, propyl carbinol, the Virahol one or more 7%
In hydrogen peroxide, sherwood oil, the ditertbutylparacresol one or more 1%
In cyclopentadiene iron, toluene, the dimethylbenzene one or more 10%.
Further, biomass synthetic fuel of the present invention, described monohydroxy-alcohol is selected from one or more in methyl alcohol, ethanol, propyl alcohol or the butanols.
Further, biomass synthetic fuel of the present invention, this fuel comprises following component by weight percentage:
Methyl alcohol 20-80%
Gasoline 10-50%
Acetone 4.5-10%
Ditertbutylparacresol 0.5-2%
Toluene 5-18%.
Further, biomass synthetic fuel of the present invention, this fuel comprises following component by weight percentage:
Methyl alcohol 52%
Gasoline 30%
Acetone 7%
Ditertbutylparacresol 1%
Toluene 10%.
The invention also discloses the production method of described biomass synthetic fuel, this method may further comprise the steps:
(1) select the following raw material of desired number:
The monohydroxy-alcohol 20-80% that contains 1 to 11 C
One or more 10-50% in petroleum naphtha, solvent oil, dme, the gasoline
One or more 4.5-10% in ether, acetone, propyl carbinol, the Virahol
One or more 0.5-2% in hydrogen peroxide, sherwood oil, the ditertbutylparacresol
One or more 5-18% in cyclopentadiene iron, toluene, the dimethylbenzene
(2) in reactor, add the following material of above-mentioned quantitative proportion successively:
The monohydroxy-alcohol that contains 1 to 11 C
In petroleum naphtha, solvent oil, dme, the gasoline one or more
In ether, acetone, propyl carbinol, the Virahol one or more
With the mixture pressurization 0.5MPa-1MPa of above material, normal-temperature reaction 25-35 minute;
(3) the following material of the above-mentioned quantitative proportion of adding in post reaction mixture:
In hydrogen peroxide, sherwood oil, the ditertbutylparacresol one or more
In cyclopentadiene iron, toluene, the dimethylbenzene one or more
Above mixture is stirred under normal temperature, normal pressure;
(4) mixture that stirs is put into homogeneous jar homogeneous more than 30 hours, be finished product.
The invention has the beneficial effects as follows: biomass synthetic fuel of the present invention is a raw material with industrial effluent and byproduct and agricultural wastes, processing extracts effective constituent, further synthesize high-grade fuel, product is water white transparency or colored liquid, the calorific value height, be applied to and have good power effect in the motor car engine, also can be used for domestic fuel; This fuel draining thing feature of environmental protection is good, the raw material sources channel is wide, production cost is low and when using do not need the transformation apparatus motor vehicle engine and directly application, and is very convenient.The present invention can use with any mixed with gasoline, and is not stratified, increase dynamic property and do not have any unusually, saves the fuel for motor vehicle cost greatly.
Embodiment
Main physical characteristic and engine below in conjunction with biomass synthetic fuel of the present invention use the performance test of propellant combination to further specify beneficial effect of the present invention.In following examples, biomass synthetic fuel gross weight of the present invention is 10 kilograms, and petroleum naphtha, solvent oil, dme, gasoline are ignition dope; Ether, acetone, propyl carbinol, Virahol are solubility promoter; Hydrogen peroxide, sherwood oil, ditertbutylparacresol are catalyzer; Cyclopentadiene iron, toluene, dimethylbenzene are synergistic agent.
Embodiment one
Produce biomass synthetic fuel of the present invention, may further comprise the steps:
(1) select the following raw material of desired number, this fuel comprises following component by weight percentage:
The mixture 20% of first, second, third, butanols arbitrary proportion
The mixture 50% of petroleum naphtha, solvent oil, dme, gasoline arbitrary proportion
The mixture 10% of ether, acetone, propyl carbinol, Virahol arbitrary proportion
The mixture 2% of hydrogen peroxide, sherwood oil, ditertbutylparacresol arbitrary proportion
The mixture 18% of cyclopentadiene iron, toluene, dimethylbenzene arbitrary proportion.
(2) in reactor, add the following material of above-mentioned quantitative proportion successively:
First, second, third, butanols mixture
Petroleum naphtha, solvent oil, dme, gasoline mixture
Ether, acetone, propyl carbinol, isopropanol mixture
With the mixture pressurization 0.5MPa of above material, normal-temperature reaction 25 minutes;
(3) the following material of the above-mentioned quantitative proportion of adding in post reaction mixture:
Hydrogen peroxide, sherwood oil, ditertbutylparacresol mixture
Cyclopentadiene iron, toluene, xylene mixture
Above mixture stirrer with 600 rev/mins under normal temperature, normal pressure is stirred;
(4) mixture that stirs is put into homogeneous jar homogeneous 30 hours, be finished product.
Embodiment two
Produce biomass synthetic fuel of the present invention, may further comprise the steps:
(1) select the following raw material of desired number, this fuel comprises following component by weight percentage:
The mixture 52% of first, second, third, butanols arbitrary proportion
The mixture 30% of petroleum naphtha, solvent oil, dme, gasoline arbitrary proportion
The mixture 7% of ether, acetone, propyl carbinol, Virahol arbitrary proportion
The mixture 1% of hydrogen peroxide, sherwood oil, ditertbutylparacresol arbitrary proportion
The mixture 10% of cyclopentadiene iron, toluene, dimethylbenzene arbitrary proportion.
(2) in reactor, add the following material of above-mentioned quantitative proportion successively:
First, second, third, butanols mixture
Petroleum naphtha, solvent oil, dme, gasoline mixture
Ether, acetone, propyl carbinol, isopropanol mixture
With the mixture pressurization 0.8MPa of above material, normal-temperature reaction 30 minutes;
(3) the following material of the above-mentioned quantitative proportion of adding in post reaction mixture:
Hydrogen peroxide, sherwood oil, ditertbutylparacresol mixture
Cyclopentadiene iron, toluene, xylene mixture
Above mixture stirrer with 600 rev/mins under normal temperature, normal pressure is stirred;
(4) mixture that stirs is put into homogeneous jar homogeneous 30 hours, be finished product.
Carry out the every index of biomass synthetic fuel that proportioning produces according to present embodiment and reach best.
Embodiment three
Produce biomass synthetic fuel of the present invention, may further comprise the steps:
(1) select the following raw material of desired number, this fuel comprises following component by weight percentage:
The mixture 80% of first, second, third, butanols arbitrary proportion
The mixture 10% of petroleum naphtha, solvent oil, dme, gasoline arbitrary proportion
The mixture 4.5% of ether, acetone, propyl carbinol, Virahol arbitrary proportion
The mixture 0.5% of hydrogen peroxide, sherwood oil, ditertbutylparacresol arbitrary proportion
The mixture 5% of cyclopentadiene iron, toluene, dimethylbenzene arbitrary proportion.
(2) in reactor, add the following material of above-mentioned quantitative proportion successively:
First, second, third, butanols mixture
Petroleum naphtha, solvent oil, dme, gasoline mixture
Ether, acetone, propyl carbinol, isopropanol mixture
With the mixture pressurization 1MPa of above material, normal-temperature reaction 35 minutes;
(3) the following material of the above-mentioned quantitative proportion of adding in post reaction mixture:
Hydrogen peroxide, sherwood oil, ditertbutylparacresol mixture
Cyclopentadiene iron, toluene, xylene mixture
Above mixture stirrer with 600 rev/mins under normal temperature, normal pressure is stirred;
(4) mixture that stirs is put into homogeneous jar homogeneous 30 hours, be finished product.
Embodiment four
Produce biomass synthetic fuel of the present invention, may further comprise the steps:
(1) select the following raw material of desired number, this fuel comprises following component by weight percentage:
Methyl alcohol 80%
Gasoline 10%
Acetone 4.5%
Ditertbutylparacresol 0.5%
Toluene 5%.
(2) in reactor, add the following material of above-mentioned quantitative proportion successively:
Methyl alcohol
Gasoline
Acetone
With the mixture pressurization 0.5MPa of above material, normal-temperature reaction 25 minutes;
(3) the following material of the above-mentioned quantitative proportion of adding in post reaction mixture:
Ditertbutylparacresol
Toluene
Above mixture stirrer with 600 rev/mins under normal temperature, normal pressure is stirred;
(4) mixture that stirs is put into homogeneous jar homogeneous 30 hours, be finished product.
Embodiment five
Produce biomass synthetic fuel of the present invention, may further comprise the steps:
(1) select the following raw material of desired number, this fuel comprises following component by weight percentage:
Methyl alcohol 52%
Gasoline 30%
Acetone 7%
Ditertbutylparacresol 1%
Toluene 10%.
(2) in reactor, add the following material of above-mentioned quantitative proportion successively:
Methyl alcohol
Gasoline
Acetone
With the mixture pressurization 0.5MPa of above material, normal-temperature reaction 30 minutes;
(3) the following material of the above-mentioned quantitative proportion of adding in post reaction mixture:
Ditertbutylparacresol
Toluene
Above mixture stirrer with 600 rev/mins under normal temperature, normal pressure is stirred;
(4) mixture that stirs is put into homogeneous jar homogeneous 30 hours, be finished product.
Select each component cost of employing minimum in the present embodiment, and every index all reach the automotive fuel standard.
Embodiment six
Produce biomass synthetic fuel of the present invention, may further comprise the steps:
(1) select the following raw material of desired number, this fuel comprises following component by weight percentage:
Methyl alcohol 20%
Gasoline 50%
Acetone 10%
Ditertbutylparacresol 2%
Toluene 18%.
(2) in reactor, add the following material of above-mentioned quantitative proportion successively:
Methyl alcohol
Gasoline
Acetone
With the mixture pressurization 1MPa of above material, normal-temperature reaction 35 minutes;
(3) the following material of the above-mentioned quantitative proportion of adding in post reaction mixture:
Ditertbutylparacresol
Toluene
Above mixture stirrer with 600 rev/mins under normal temperature, normal pressure is stirred;
(4) mixture that stirs is put into homogeneous jar homogeneous 30 hours, be finished product.
Biomass synthetic fuel of the present invention described in the above embodiment, through check, every index meets the requirement of engine to fuel, and concrete outcome is as follows:
1, the Main physical characteristic of biomass synthetic fuel of the present invention
Close flash point, proportion, octane value and burning-point to the fuel of above embodiment different substances set of dispense ratio are tested, concrete numerical value such as following table:
| Sequence number | Embodiment one | Embodiment two | Embodiment three | Embodiment four | Embodiment five | Embodiment six |
| Octane value | ＞98 | ＞98 | ＞98 | ＞98 | ＞98 | ＞98 |
| Proportion (g/cm 3) | 0.78 | 0.77 | 0.76 | 0.78 | 0.74 | 0.78 |
| Close flash point/℃ | -26 | -23 | -24 | -26 | -23 | -26 |
| Burning-point/℃ | 485 | 484 | 488 | 488 | 484 | 486 |
| Benzene content | ＜0.4 | ＜0.4 | ＜0.4 | ＜0.4 | ＜0.4 | ＜0.4 |
The physical parameter that detects after the above different substances proportioning meets the requirement of engine to fuel fully.
2, engine uses the performance test of biomass synthetic fuel of the present invention
(1) engine power performance
Use biomass synthetic fuel of the present invention, no matter be to use separately or mix use with gasoline, can both make dynamic property, accelerating ability, anti-knocking property and the stationarity of petrol engine vehicle reach the every index of petrol engine with fuel, average fuel consumption is compared with gasoline and is maintained an equal level or the about 5%-10% of reduction.Under the situation that equal fuel consumes, aspect dynamic property, still all be significantly improved from the speed per hour aspect.
(2) discharging experiment
Biomass synthetic fuel of the present invention, detect exhaust emission discharging actual measurement through national passenger vehicle quality inspection center: CO is 3.36 gram/km, and HC is 0.64 gram/km, NO
X0.09 gram/km all reaches country and carries out emission standard, and is better than the exhaust gas emission of prior art fuel, reaches environmental requirement.
Various materials all can reach the purpose that the present invention will reach by the permutation and combination in proportional range among the above embodiment, and index all reaches the numerical value in the previous list, and other combinations are not enumerated here one by one.
Explanation is at last, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, although the present invention is had been described in detail with reference to preferred embodiment, those of ordinary skill in the art is to be understood that, can in described scope, make amendment or be equal to replacement technical scheme of the present invention, and not breaking away from the aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of the claim scope of the present invention.
Claims (1)
1. biomass synthetic fuel, it is characterized in that: the production method of biomass synthetic fuel may further comprise the steps:
(1) by following weight percent batching:
The monohydroxy-alcohol 20-80% that contains 1 to 11 C
One or more 10-50% in petroleum naphtha, solvent oil, dme, the gasoline
One or more 4.5-10% in ether, acetone, propyl carbinol, the Virahol
One or more 0.5-2% in hydrogen peroxide, sherwood oil, the ditertbutylparacresol
One or more 5-18% in cyclopentadiene iron, toluene, the dimethylbenzene
(2) in reactor, add the following material of above-mentioned quantitative proportion successively:
The monohydroxy-alcohol that contains 1 to 11 C
In petroleum naphtha, solvent oil, dme, the gasoline one or more
In ether, acetone, propyl carbinol, the Virahol one or more
With the mixture pressurization 0.5MPa-1MPa of above material, normal-temperature reaction 25-35 minute;
(3) the following material of the above-mentioned quantitative proportion of adding in post reaction mixture:
In hydrogen peroxide, sherwood oil, the ditertbutylparacresol one or more
In cyclopentadiene iron, toluene, the dimethylbenzene one or more
Above mixture is stirred under normal temperature, normal pressure;
(4) mixture that stirs is put into homogeneous jar homogeneous more than 30 hours, be finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710078507A CN100593562C (en) | 2007-05-25 | 2007-05-25 | Biomass synthetic fuel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710078507A CN100593562C (en) | 2007-05-25 | 2007-05-25 | Biomass synthetic fuel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101085938A CN101085938A (en) | 2007-12-12 |
| CN100593562C true CN100593562C (en) | 2010-03-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200710078507A Expired - Fee Related CN100593562C (en) | 2007-05-25 | 2007-05-25 | Biomass synthetic fuel |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101875869A (en) * | 2010-07-22 | 2010-11-03 | 国润金华（北京）国际能源投资有限公司 | Biological alcohol-based liquid fuel and preparation method thereof |
| CN101928610B (en) * | 2010-09-01 | 2013-03-13 | 桂林腾翔新能源科技有限公司 | Synthetic fuel for vehicles |
| CN102676246B (en) * | 2012-05-22 | 2014-07-30 | 方文盛 | Fuel additive |
| CN103695044A (en) * | 2013-12-31 | 2014-04-02 | 张锦碧 | Environmental-protection alcohol-based biofuel |
| CN104119968B (en) * | 2014-08-14 | 2015-08-05 | 蒙呈星 | A kind of Novel vehicle fuel |
| CN104119966A (en) * | 2014-08-14 | 2014-10-29 | 蒙呈星 | Novel vehicular fuel |
| CN106147914A (en) * | 2015-04-02 | 2016-11-23 | 天津市澍丰农业科技有限公司 | A kind of clean type bio-fuel |
| CN105176602A (en) * | 2015-10-12 | 2015-12-23 | 张青贵 | Alcohol mixed-type vehicle-used fuel and preparation method thereof |
| CN106118791A (en) * | 2016-08-25 | 2016-11-16 | 桂林九马新动力科技有限公司 | A kind of energy saving biomass fuel and preparation method thereof |
| CN107858180B (en) * | 2017-10-13 | 2019-09-24 | 河南省科学院能源研究所有限公司 | A kind of biomass-based γ valerolactone-gasoline reconciles fuel and preparation method thereof |
| CN115678623A (en) * | 2022-08-18 | 2023-02-03 | 杨洪波 | Biomass liquid fuel |
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2007
- 2007-05-25 CN CN200710078507A patent/CN100593562C/en not_active Expired - Fee Related
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| CN101085938A (en) | 2007-12-12 |
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