CN100582081C - 一种c10叔碳酸的合成方法 - Google Patents
一种c10叔碳酸的合成方法 Download PDFInfo
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- CN100582081C CN100582081C CN200710011863A CN200710011863A CN100582081C CN 100582081 C CN100582081 C CN 100582081C CN 200710011863 A CN200710011863 A CN 200710011863A CN 200710011863 A CN200710011863 A CN 200710011863A CN 100582081 C CN100582081 C CN 100582081C
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- solution
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- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000002253 acid Substances 0.000 title claims abstract description 14
- 230000002194 synthesizing effect Effects 0.000 title abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title description 7
- 229910052799 carbon Inorganic materials 0.000 title description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 66
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 239000003208 petroleum Substances 0.000 claims abstract description 18
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000007599 discharging Methods 0.000 claims abstract description 16
- 238000005406 washing Methods 0.000 claims abstract description 16
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003054 catalyst Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims abstract description 4
- 239000010949 copper Substances 0.000 claims description 37
- 238000000605 extraction Methods 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 30
- 238000006396 nitration reaction Methods 0.000 claims description 24
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 claims description 14
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 238000010189 synthetic method Methods 0.000 claims description 3
- 238000005829 trimerization reaction Methods 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 230000009466 transformation Effects 0.000 claims description 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 2
- 238000003756 stirring Methods 0.000 abstract description 27
- 125000005586 carbonic acid group Chemical group 0.000 abstract description 4
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 abstract description 3
- 238000000926 separation method Methods 0.000 abstract description 3
- 229940112669 cuprous oxide Drugs 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 150000002763 monocarboxylic acids Chemical group 0.000 description 36
- 239000003921 oil Substances 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 5
- 238000004064 recycling Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 238000005810 carbonylation reaction Methods 0.000 description 3
- -1 monocarboxylic acid peroxide lipid Chemical group 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000006315 carbonylation Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 230000003335 steric effect Effects 0.000 description 2
- 239000002887 superconductor Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 229910052761 rare earth metal Chemical group 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200710011863A CN100582081C (zh) | 2007-06-26 | 2007-06-26 | 一种c10叔碳酸的合成方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200710011863A CN100582081C (zh) | 2007-06-26 | 2007-06-26 | 一种c10叔碳酸的合成方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101081811A CN101081811A (zh) | 2007-12-05 |
CN100582081C true CN100582081C (zh) | 2010-01-20 |
Family
ID=38911635
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200710011863A Expired - Fee Related CN100582081C (zh) | 2007-06-26 | 2007-06-26 | 一种c10叔碳酸的合成方法 |
Country Status (1)
Country | Link |
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CN (1) | CN100582081C (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102947264B (zh) * | 2010-06-04 | 2015-10-21 | 埃克森美孚化学专利公司 | 萃取塔和使用其的方法 |
CN102718646B (zh) * | 2011-11-23 | 2014-06-25 | 西南化工研究设计院有限公司 | 一种叔碳酸的生产方法 |
CN105218354B (zh) * | 2015-09-24 | 2017-05-10 | 万华化学集团股份有限公司 | 一种合成叔碳酸的方法 |
CN105688759B (zh) * | 2016-03-14 | 2019-01-29 | 万华化学集团股份有限公司 | 一种离心内旋流式多相喷射反应器及其用于制备叔碳酸的方法 |
CN110551017B (zh) * | 2019-09-25 | 2021-02-26 | 西南化工研究设计院有限公司 | 一种液液传质催化合成叔羧酸的工艺与系统 |
-
2007
- 2007-06-26 CN CN200710011863A patent/CN100582081C/zh not_active Expired - Fee Related
Non-Patent Citations (2)
Title |
---|
叔碳酸合成工艺条件优化. 张进等.化学试剂,第23卷第5期. 2001 |
叔碳酸合成工艺条件优化. 张进等.化学试剂,第23卷第5期. 2001 * |
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Publication number | Publication date |
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CN101081811A (zh) | 2007-12-05 |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: SHENYANG WANFANG CONSTRUCTION TECHNOLOGY DEVELOPME Free format text: FORMER OWNER: SUN JING Effective date: 20130717 |
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C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 110004 SHENYANG, LIAONING PROVINCE TO: 110166 SHENYANG, LIAONING PROVINCE |
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TR01 | Transfer of patent right |
Effective date of registration: 20130717 Address after: 110166, 27, Miyoshi street, Heping District, Liaoning, Shenyang Patentee after: Shenyang Wanfang Construction Technology Development Co., Ltd. Address before: 61, B, building 3-27-1, Changxin Plaza, five Li River Street, Heping District, Liaoning, Shenyang, 110004 Patentee before: Sun Jing |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100120 Termination date: 20160626 |