CN100575594C - A kind of flax fibre craft - Google Patents

A kind of flax fibre craft Download PDF

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Publication number
CN100575594C
CN100575594C CN200710301223A CN200710301223A CN100575594C CN 100575594 C CN100575594 C CN 100575594C CN 200710301223 A CN200710301223 A CN 200710301223A CN 200710301223 A CN200710301223 A CN 200710301223A CN 100575594 C CN100575594 C CN 100575594C
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China
Prior art keywords
flax fibre
health
flax
storehouse
fibre
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CN200710301223A
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CN101177913A (en
Inventor
刘国忠
张振华
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Jiangsu Redbud Textile Technology Co Ltd
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Jiangsu Redbud Textile Technology Co Ltd
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Priority to CN200710301223A priority Critical patent/CN100575594C/en
Publication of CN101177913A publication Critical patent/CN101177913A/en
Priority to CA2709414A priority patent/CA2709414A1/en
Priority to JP2010537236A priority patent/JP5384516B2/en
Priority to PCT/CN2008/001967 priority patent/WO2009076795A1/en
Priority to EP08861378A priority patent/EP2236661A4/en
Priority to KR1020107013292A priority patent/KR20100095448A/en
Priority to US12/808,343 priority patent/US20110185510A1/en
Priority to MX2010006706A priority patent/MX2010006706A/en
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Abstract

The invention discloses a kind of flax fibre craft, it comprises the steps: that (1) is sprayed onto the auxiliary agent that configures on the flax fibre, and the weight ratio of wherein said auxiliary agent and flax fibre is 0.4~0.5; (2) will put into the first health storehouse through the flax fibre after step (1) is handled, place 2~3 days; (3) will in the first health storehouse, take out through the flax fibre after step (2) health, the second health storehouse put in the upset of described flax fibre, heat promptly stop to heat to 50~60 ℃ after, health storehouse health 5~6 days; (4) will take out through the flax fibre after step (3) health, can carry out follow-up spinning process.This craft can make the flax fibre health preserving adjuvant fully enter the inside of whole flax fibre, guarantees that flax fibre obtains abundant health, can solve the problem that flax fibre is crisp, easily broken, difficulty is spun.

Description

A kind of flax fibre craft
Technical field
The present invention relates to a kind of craft of flax fibre.
Background technology
Raising along with the human substance life horizontal, originally people more from having transferred in the requirement to its comfortableness the concern of dress ornament durability, because flax fibre has sucting wet air permeability, low static behaviour and good antibacterial characteristics preferably, crudefiber crop fabric clothing lining more and more is subjected to people's favor.The lining of existing crudefiber crop fabric clothing is meant that mainly flax, ramie raw materials or this type of raw material and other fiber carry out blending/interweave as cotton, wool, chemical fibre, silk etc. and make, but, make that the crudefiber crop textiles does not have to be more widely used because flax, ramie price are higher.And jute is the second-biggest-in-the-world cellulose fibre that is only second to cotton, and it is cheap, and compares with flax, ramie and to have the moist and drapability of better loosing, comfortable and easy to wear, be difficult for sticking body summer, and antibacterial ability is only second to hemp, has huge using value and potentiality to be exploited.But because the content of lignin higher (can reach 10-13%) in the jute, than high several times of flax, fiber is very thick, hard, and spinnability is very poor, and this has restricted the application of jute aspect garment material greatly.In the prior art,, at first must come unstuck and the refinement fiber to above-mentioned natural fabric in order to improve the spinnability of above-mentioned material, even if but having carried out coming unstuck and refinement, its flax fibre that obtains still is in crisp, hard state, is difficult to spin.So must to through come unstuck and refinement after flax fibre carry out the improvement and the upgrading of fiber trait (flexibility, smoothness, bulkiness and spinnability), can spin high yarn count, high performance ramie yarn.
Above-mentioned health preserving adjuvant to the improvement of flax fibre proterties and the needs use flax fibre of upgrading carries out health to flax fibre to be realized.In the prior art, the health-preserving method of Chinese patent CN1292435A and the disclosed flax fibre of CN1086273A then is with flax fibre humidification heap storage health 18~30 hours, directly delivers from godown afterwards and manually closes bundle, to numb Shu Jinhang combing.Similarly, Chinese patent CN1796622A discloses the dual processing method of modifying of a kind of second hards fiber, described second hards fiber is being carried out in the process of modification, need carry out health to it equally, the same employing of this method carried out the dewing health 36~48 hours to flax fibre in the room of 18~25 ℃ of room temperatures, but the regain of flax fibre only is 15~18% after its health.In above-mentioned prior art, adopt the method for room temperature humidification health that flax fibre is carried out health, and conditioned time was controlled in 48 hours, this technology is on the one hand owing to adopt the room temperature health auxiliary agent fully can not be infiltrated through flax fibre inside; Can't promote a small amount of enzyme residual in flax fibre pre-treatment degumming tech on the other hand in the health process, play a role once more; The third aspect, the flax fibre that is positioned at bottom, health storehouse is for the flax fibre on its top, because it is positioned at the bottom all the time and can't fully contacts with air, cause " breathing " of fiber not smooth, thereby " hole " that causes " chamber " at flax fibre center and be attached thereto is obstructed, health preserving adjuvant can't fully enter fibrous inside, has influenced the health effect of health preserving adjuvant to flax fibre.Cause a small amount of health preserving adjuvant to enter in the fiber and practice shows the health poor effect of bottom fiber.
Summary of the invention
Technical problem to be solved by this invention is the sufficient inadequately problem of flax fibre health in the prior art; And then by improving the craft of flax fibre, overcome above-mentioned technical problem, and provide a kind of flax fibre health preserving adjuvant that can make fully to enter the inside of whole flax fibre, guarantee that flax fibre obtains abundant health, and can make full use of the enzyme in the flax fibre pre-treatment process carries out further health to flax fibre flax fibre craft.
For solving the problems of the technologies described above, flax fibre craft provided by the invention comprises the steps:
(1) auxiliary agent behind the interpolation water is sprayed onto on the flax fibre, the weight ratio of wherein said auxiliary agent and flax fibre is 0.4~0.5;
(2) will put into the first health storehouse through the flax fibre after step (1) is handled, place 2~3 days;
(3) will in the first health storehouse, take out through the flax fibre after step (2) health, the second health storehouse put in the upset of described flax fibre, heat promptly stop to heat to 50~60 ℃ after, health storehouse health 5~6 days.
As the craft that can select, can after above-mentioned steps (3), will take out through the flax fibre after step (3) health, place naturally and can carry out follow-up spinning process in 2~6 hours.
Wherein, described flax fibre is preferably hemp or jute.
Wherein, described preferred promoter is to comprise that 1~2 part of emulsifying agent, ammonia value are that 0.3~0.4 molecular weight is 300~30000 1~3 part of 0.8~2 part of 4~8 parts of amido silicon oils, humectant, hygroscopic agent, 85~93.5 parts in water.
Wherein, described auxiliary agent also comprises 5~7 parts of quaternary softeners.The ammonia value of described amido silicon oil is 0.35.The portion rate of described humectant and hygroscopic agent is 2/3~4/5.Described emulsifying agent is a nonionic emulsifier.Preferred described humectant is that glycerine, described hygroscopic agent are urea in the auxiliary agent.
The present invention has advantage as described below:
(1) flax fibre craft of the present invention divides the flax fibre health for two main stages, phase I is at room temperature carried out health 2~3 days with flax fibre, make auxiliary agent to enter in the fiber lentamente fully, thereby make auxiliary agent fully infiltration lentamente in flax fibre; But in view of its health temperature is a room temperature, auxiliary agent can not fully be penetrated into fiber inner core place, so health storehouse temperature is heated up, thereby make flax fibre inside " chamber " and " cavity " heat the effect under, further open, thereby enlarged " passage " that health preserving adjuvant penetrates into fibrous inside, made the described health preserving adjuvant can to penetrate into fiber inner core place better, further improved the spinnability of flax fibre.
When (2) changing the storehouse, the flax fibre that will be positioned at bottom, the first health storehouse integrally overturns by flax fibre, make it after entering the second health storehouse, be positioned at top, thereby make and be positioned at of the change of the flax fibre of bottom by the position, it is fully contacted with air, " chamber " that makes the flax fibre inside center be " breathing " fully, thereby makes health preserving adjuvant fully enter in " chamber " and " cavity " of flax fibre inside, and flax fibre is further contacted health.
(3) in the health process of second stage of the present invention, the temperature in the second health storehouse is heated to 50~60 ℃, on the one hand can be so that flax fibre comes unstuck residual a small amount of enzyme in the pre-treatment process, excite its activity once more, inside come unstuck handle inadequately uniformly that the glue of flax fibre inside is hydrolyzed, flax fibre is further separated, improved the bulkiness of flax fibre; On the other hand, heating helps enlarging " chamber " and " cavity " size of flax fibre inside center, thereby acceleration auxiliary agent and moisture penetration enter flax fibre inside.
(4) flax fibre after health being carried out nature places, can with in the health process owing to the temperature a large amount of steam be attached to the flax fibre surface that raise vapor away, thereby avoid because the flax fibre surface water yield is excessive, in follow-up weaving process, cause flax fibre and weave winding between the roller on the machine; Thereby can improve spinning efficiency and quality.
(5) use above-mentioned preferred promoter, select the ammonia value at 0.3~0.4 amido silicon oil, and the ratio of control adjuvant component umber, because the amido silicon oil of small-molecular weight can enter fibrous inside effectively, thereby improved the flexibility of tossa effectively, and guaranteed that the tossa surface has suitable smoothness, thereby being enough to make have between the tossa to form the necessary cohesive force of yarn, thereby improve the spinnability of fiber; On the other hand, the selection of above-mentioned auxiliary agent and component number thereof makes this health preserving adjuvant offer to reach an amount of amido silicon oil of the required flexibility of fiber, can not increase owing to the excessive oxidation probability of auxiliary agent that makes of amido silicon oil, thereby avoided the yellowing of tossa, guaranteed the suitable fibre whiteness of tossa.In addition, hygroscopic agent and humectant have been added simultaneously in this preferred health preserving adjuvant, wherein said humectant is pinned the moisture of fibrous inside effectively, but have only humectant can have scattering and disappearing of fibrous inside moisture in the weaving process unavoidably, hygroscopic agent in the auxiliary agent then can be in time absorbs moisture once more by the external world and replenishes fibrous inside weaving the moisture that is scattered and disappeared by fibrous inside in the environment so, and by controlling the umber ratio of hygroscopic agent and humectant, thereby the wetting balance that the assurance fiber is inside and outside, the regain of required fiber in the maintenance tossa weaving process.In addition, in above-mentioned health preserving adjuvant, add the quaternary softener, can further improve the flexibility of fiber.
The specific embodiment
The preparation of auxiliary agent
Embodiment 1
Flax fibre health preserving adjuvant (one) comprises following component:
The ammonia value is that 0.35 molecular weight is 6 parts of arbitrary amido silicon oils of 300~500
6 parts of two alkyl-dimethyl based quaternary ammonium salts
1.5 parts of paregal Os (emulsifying agent)
3 parts in urea (hygroscopic agent)
2 parts of glycerine (humectant)
In this embodiment, selecting the ammonia value is that 0.35 molecular weight is arbitrary amido silicon oil of 300~500, and this amido silicon oil molecular weight is very little, its easier fibrous inside that enters, and improved the compliance of fiber well.Select two alkyl-dimethyl based quaternary ammonium salts, paregal O, urea, glycerine can realize respectively well fiber is carried out flexibility, emulsification that further health improves fiber, preserves moisture and moisture absorbing, and cost is low; Described paregal O is a nonionic emulsifier, claims average oiling again, is the condensation product of oxirane and higher aliphatic, and this emulsifying agent does not have binding ability to various fibers, uses back flush away easily.
In addition, the auxiliary agent with said components value can keep suitable smoothness of fiber and suitable tossa whiteness when effectively improving the tossa compliance, and can keep the suitable regain of tossa.
Embodiment 2
Jute fiber life preservation auxiliary agent of the present invention (two) comprises following component:
The ammonia value is that 0.35 molecular weight is 6 parts of arbitrary amido silicon oils of 1000~3000
1 part of paregal O (emulsifying agent)
1 part in urea (hygroscopic agent)
0.8 part of glycerine (humectant)
Auxiliary agent with said components value can keep suitable smoothness of fiber and suitable tossa whiteness when effectively improving the tossa compliance, and can keep the suitable regain of tossa.
Embodiment 3
Jute fiber life preservation auxiliary agent three of the present invention comprises following component:
The ammonia value is that 0.3 molecular weight is 4 parts of arbitrary amido silicon oils of 10000~13000
1 part of polyoxyethylene nonylphenol ether
2 parts in urea (hygroscopic agent)
1.4 parts of glycerine (humectant)
In this embodiment, selecting the ammonia value is that 0.3 molecular weight is arbitrary amido silicon oil of 10000~15000, and this amido silicon oil belongs to the less amido silicon oil of molecular weight equally, and it enters fibrous inside equally easily, and has improved the compliance of fiber well.Wherein, described polyoxyethylene nonylphenol ether, urea, glycerine can be realized its emulsification well respectively, preserve moisture and moisture absorbing, and cost is low; Described mulser OP is a nonionic emulsifier, is the condensation product of oxirane and alkylphenol.Auxiliary agent with said components value can keep suitable smoothness of fiber and suitable tossa whiteness when effectively improving the tossa compliance, and can keep the suitable regain of tossa.
As the embodiment that can select, the molecular weight of above-mentioned amido silicon oil can also be chosen in 13000~15000,15000~18000, between 18000~20000.The special health preserving adjuvant of selecting the amido silicon oil in this molecular weight ranges to constitute can improve the flexibility of tossa equally, and keep the suitable smoothness (slippery) of its fiber surface and the suitable whiteness of fiber, particularly importantly can keep fiber regain required in the tossa weaving process.
Craft
Embodiment 1
Flax fibre health preserving adjuvant behind the interpolation water is sprayed onto on the tossa, and preferred one deck flax fibre of laying just sprays health preserving adjuvant one time in the process of spraying flax fibre, and the flax fibre of the capacity in will being pre-configured in the health storehouse is laid and finished; The weight ratio of wherein said auxiliary agent and flax fibre is 0.4.The effect of setting the weight ratio of described health preserving adjuvant and flax fibre in the present invention is, gives the flax fibre health enough adjuvant components.
Afterwards, the flax fibre that above-mentioned laying finishes is put into the first health storehouse, placed 2 days.In this stage, guaranteed that auxiliary agent can enter in the fiber fully lentamente, thereby made auxiliary agent fully infiltration lentamente in flax fibre.
Flax fibre after the above-mentioned health is taken out in the first health storehouse, and the flax fibre that takes out spun upside down inversion, described flax fibre after upset is put into the second health storehouse, is superposed thereby assurance will be positioned at the flax fibre of the first health storehouse inner bottom part when putting into the second health storehouse; And heat to 60 ℃, after stopping to heat, health 5 days.In this health stage, (1) at first flax fibre is overturn, be to be positioned at of the change of the flax fibre of bottom by the position in order to make, it is fully contacted with air, " chamber " that makes the flax fibre inside center be " breathing " fully, thereby make health preserving adjuvant fully enter in " chamber " and " cavity " of flax fibre inside, flax fibre is further contacted health; (2) the second health storehouse temperature is heated up, can so that " chamber " of flax fibre inside and " cavity " heat the effect under, further open, thereby enlarged " passage " that health preserving adjuvant penetrates into fibrous inside, made the described health preserving adjuvant can to penetrate into fiber inner core place better; (3) heated up in the second health storehouse, purpose is in order to make the flax fibre residual a small amount of enzyme in the pre-treatment process that comes unstuck, to excite its activity once more, is come unstuck in inside and handles inadequately uniformly that the glue of flax fibre inside is hydrolyzed, flax fibre is further separated, improved the bulkiness of flax fibre.
To take out through the flax fibre after the above-mentioned second health storehouse health, placement got final product in 6 hours naturally.This placement stage also is unusual important step in the flax fibre craft, this step can with in the health process owing to the temperature a large amount of steam be attached to the flax fibre surface that raise vapor away, thereby make the flax fibre surface be unlikely to very wet, fiber just can not cause flax fibre and weave winding between the roller part on the machine in follow-up weaving process so; Thereby raising weaving efficiency.As the embodiment that can select, this step also can be saved, but as the craft of flax fibre nature placement health step is set preferably still.
Embodiment 2
Flax fibre health preserving adjuvant behind the interpolation water is sprayed onto on the tossa, and preferred one deck flax fibre of laying just sprays health preserving adjuvant one time in the process of spraying flax fibre, and the flax fibre of the capacity in will being pre-configured in the health storehouse is laid and finished; The weight ratio of wherein said auxiliary agent and flax fibre is 0.45; The weight ratio of above-mentioned health preserving adjuvant and flax fibre has guaranteed to give the flax fibre health enough adjuvant components.
Afterwards, the flax fibre that above-mentioned laying finishes is put into the first health storehouse, placed 2.5 days; Guaranteed that equally auxiliary agent can enter in the fiber fully lentamente.
Flax fibre after the above-mentioned health is taken out in the first health storehouse, and the flax fibre that takes out is spun upside down inversion, described flax fibre after upset is put into the second health storehouse, and heat to 55 ℃, after stopping to heat, health 5.5 days; Intensification in this step can so that " chamber " of flax fibre inside and " cavity " further open during than low temperature, thereby enlarged " passage " that health preserving adjuvant penetrates into fibrous inside, made the described health preserving adjuvant can to penetrate into fiber inner core place better; In addition, when this temperature, can the stimulating activity temperature spot be lower than this temperature, in fiber comes unstuck pre-treatment process the activity of residual a small amount of enzyme, inside come unstuck handles inadequately uniformly that the glue of flax fibre inside is hydrolyzed, flax fibre is further separated, improved the bulkiness of flax fibre.
To take out through the flax fibre after the above-mentioned second health storehouse health, placement got final product in 5 hours naturally.
Embodiment 3
Flax fibre health preserving adjuvant behind the interpolation water is sprayed onto on the hemp, and preferred one deck flax fibre of laying just sprays health preserving adjuvant one time in the process of spraying flax fibre, and the flax fibre of the capacity in will being pre-configured in the health storehouse is laid and finished; The weight ratio of wherein said auxiliary agent and flax fibre is 0.5; The weight ratio of above-mentioned health preserving adjuvant and flax fibre has guaranteed to give the flax fibre health enough adjuvant components.
Afterwards, the flax fibre that above-mentioned laying finishes is put into the first health storehouse, placed 3 days; Give auxiliary agent and can infiltrate through time enough in the fiber fully lentamente.
Flax fibre after the above-mentioned health is taken out in the first health storehouse, and the flax fibre that takes out is spun upside down inversion, described flax fibre after upset is put into the second health storehouse, and heat to 50 ℃, after stopping to heat, health 6 days; Intensification in this step equally can so that " chamber " of flax fibre inside and " cavity " further open during than low temperature, thereby enlarged " passage " that health preserving adjuvant penetrates into fibrous inside, made the described health preserving adjuvant can to penetrate into fiber inner core place better; In addition, when this temperature, can the stimulating activity temperature spot be lower than this temperature, in fiber comes unstuck pre-treatment process the activity of residual a small amount of enzyme, inside come unstuck handles inadequately uniformly that the glue of flax fibre inside is hydrolyzed, flax fibre is further separated, improved the bulkiness of flax fibre.
To take out through the flax fibre after the above-mentioned second health storehouse health, placement got final product in 2 hours naturally.
Flax fibre after above-mentioned craft health is detected discovery, and the regain of flax fibre is not 12~16% before the health, and then to raise be 32~38% to the regain of flax fibre after the health.As seen, craft of the present invention can improve the regain of flax fibre effectively, and then improves the spinnability of flax fibre.
Though the present invention elaborates it by the specific embodiment; but; those skilled in the art should be understood that; the any form of being made on this basis that does not exceed the claim protection domain and the variation of details; any conversion such as being applicable to all emulsifying agents of the present invention and hygroscopic agent and humectant all belongs to invention which is intended to be protected.

Claims (9)

1. flax fibre craft, it comprises the steps:
(1) auxiliary agent that configures is sprayed onto on the flax fibre, the weight ratio of wherein said auxiliary agent and flax fibre is 0.4~0.5;
(2) will put into the first health storehouse through the flax fibre after step (1) is handled, place 2~3 days;
(3) will in the first health storehouse, take out through the flax fibre after step (2) health, the second health storehouse put in the upset of described flax fibre, heat promptly stop to heat to 50~60 ℃ after, health storehouse health 5~6 days.
2. flax fibre craft according to claim 1 is characterized in that: will take out through the flax fibre after step (3) health, placement got final product in 2~6 hours naturally.
3. flax fibre craft according to claim 1 is characterized in that: described flax fibre is hemp or jute.
4. flax fibre craft according to claim 1 is characterized in that: described auxiliary agent comprises that 1~2 part of emulsifying agent, ammonia value are that 0.3~0.4 molecular weight is 300~30000 0.8~2 part of 4~8 parts of amido silicon oils, humectant, 1~3 part of hygroscopic agent.
5. flax fibre craft according to claim 4 is characterized in that: described auxiliary agent also comprises 5~7 parts of quaternary softeners.
6. flax fibre craft according to claim 4 is characterized in that, the ammonia value of described amido silicon oil is 0.35.
7. flax fibre craft according to claim 4 is characterized in that, the portion rate of described humectant and hygroscopic agent is 2/3~4/5.
8. flax fibre craft according to claim 4 is characterized in that, described emulsifying agent is a nonionic emulsifier.
9. flax fibre craft according to claim 4 is characterized in that, described humectant is that glycerine, described hygroscopic agent are urea.
CN200710301223A 2007-12-17 2007-12-17 A kind of flax fibre craft Active CN100575594C (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
CN200710301223A CN100575594C (en) 2007-12-17 2007-12-17 A kind of flax fibre craft
EP08861378A EP2236661A4 (en) 2007-12-17 2008-12-04 Process for health-preserving hemp fiber and special health-preserving additive for jute fiber used therein
JP2010537236A JP5384516B2 (en) 2007-12-17 2008-12-04 Hemp fiber curing method and burlap fiber curing additive
PCT/CN2008/001967 WO2009076795A1 (en) 2007-12-17 2008-12-04 Process for health-preserving hemp fiber and special health-preserving additive for jute fiber used therein
CA2709414A CA2709414A1 (en) 2007-12-17 2008-12-04 The process for health preserving bast fibres and the jute fibre specific health preserving assistant used in the same
KR1020107013292A KR20100095448A (en) 2007-12-17 2008-12-04 Process for health-preserving hemp fiber and special health-preserving additive for jute fiber used therein
US12/808,343 US20110185510A1 (en) 2007-12-17 2008-12-04 Process for health preserving bast fibres and the jute fibre specific health preservation assistant used in the same
MX2010006706A MX2010006706A (en) 2007-12-17 2008-12-04 Process for health-preserving hemp fiber and special health-preserving additive for jute fiber used therein.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200710301223A CN100575594C (en) 2007-12-17 2007-12-17 A kind of flax fibre craft

Publications (2)

Publication Number Publication Date
CN101177913A CN101177913A (en) 2008-05-14
CN100575594C true CN100575594C (en) 2009-12-30

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009024023A1 (en) * 2007-08-20 2009-02-26 Jiangsu Redbud Textile Technology Co., Ltd. Hemp yarn and mix-spinning method of hemp and other fibre, and yarn thereof
EP2236661A4 (en) * 2007-12-17 2012-12-19 Jiangsu Redbud Textile Tech Co Process for health-preserving hemp fiber and special health-preserving additive for jute fiber used therein
CN102174721A (en) * 2011-03-21 2011-09-07 盐城悦弘织造有限公司 Curing pretreatment method for improving spinnability of hemp fibrils
CN109322154B (en) * 2018-11-07 2021-12-07 青岛奥洛思新材料有限公司 Lubricant for processing hemp roving and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
织物整理剂改性氨基硅油. 李俊英等.应用化工,第30卷第6期. 2001
织物整理剂改性氨基硅油. 李俊英等.应用化工,第30卷第6期. 2001 *

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