CN100532518C - Lubricating oil composition - Google Patents
Lubricating oil composition Download PDFInfo
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- CN100532518C CN100532518C CNB028210719A CN02821071A CN100532518C CN 100532518 C CN100532518 C CN 100532518C CN B028210719 A CNB028210719 A CN B028210719A CN 02821071 A CN02821071 A CN 02821071A CN 100532518 C CN100532518 C CN 100532518C
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- agent
- water
- vegetable oil
- animal grease
- fatty acid
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/041—Mixtures of base-materials and additives the additives being macromolecular compounds only
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/38—Treating surfaces of moulds, cores, or mandrels to prevent sticking
- B28B7/384—Treating agents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/401—Fatty vegetable or animal oils used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/09—Characteristics associated with water
- C10N2020/091—Water solubility
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/24—Emulsion properties
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/36—Release agents or mold release agents
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Lubricants (AREA)
Abstract
The water-soluble lubricating oil composition of this invention contains animal fats and oils and/or plant fats and oils, and the nonionic surfactant of polyoxyethylene sorbitol fatty acid ester. The water-soluble lubricating oil composition of this invention is excellent in emulsion stability, and it can reduce environmental pollution. It is suitably as metal processing oils such as cutting oil and plastic working oils, and release agent such as asphalt mixture adhesion prevention agent and concrete release agent.
Description
Technical field
The present invention relates to a kind of water-soluble lubricating oil compositions, relate to a kind of machining oil and plastic working wet goods metalworking fluid, asphalt mixture of being applicable in more detail and adhere to the water-soluble lubricating oil compositions that prevents mold oils such as agent and concrete parting agent.
Background technology
As in the processing of metal and pottery, can be used as the lubricating oil of machining oil and plastic working wet goods metalworking fluid, can use mineral oil or synthetic oil as the lubricated wet goods of emulsion-type straigth type or that make these oily moisture formation (emulsion type) of base oil (base oil).In recent years, in the processing of metal or pottery, consider because the high speed of processing and high conveyingization etc. can produce danger on fire etc., more use water-soluble metal processing wet goods.Because this water-soluble metal treated oil uses behind dilute with water usually, so the emulsifying stability during dilution is very important.If emulsifying stability is poor, then can make working accuracy produce skew, perhaps around machinery, pollute etc.Therefore wish metalworking fluid (lubricating oil) that well emulsify stability occurs having.
In addition, when using with above-mentioned mineral oil or synthetic oil as the lubricating oil of base oil, thereby mineral oil or synthetic oil can leak in the soil etc. the danger of causing environmental pollution is arranged.
On the other hand as the technology of broad surface such as laying road or playground, what extensively carry out at present is to lay the asphalt mixture that heat with site formation after comprehensively, and then the utilization rolling device such as roller of mating formation makes the construction work of the even laying of asphalt mixture that is in heated condition.In this pitch engineering, when utilizing above-mentioned rolling devices such as roller to carry out compacting, can produce adhesive power, asphalt mixture is sticked on the roller, produce concavo-convexly, make the downgrade of mating formation thereby make on the face of finishing of mating formation at roller and bituminous contact site.
The asphalt mixture that uses in above-mentioned pitch engineering is loaded in the lorry compartment usually and transports in addition.Therefore asphalt mixture also can often stick on the truck railway carriage when transportation.
In the past, for prevent asphalt mixture stick to roller etc. above, widely used is mineral oil such as heavy oil or light oil, used oil and water etc.
But when only making water, can not prevent the adhesion of asphalt mixture sometimes with the difference of the character of asphalt mixture and execution conditions (meteorological conditions etc.).When using mineral oils such as heavy oil or light oil,, finally make pitch rotten in addition, become the reason that forms stepping-stone etc. because mineral oils uprises the solvability of pitch composition.Further, neither be fine for the effect of its anti-asphalt adhesives of ferrous products such as truck and street roller.
Particularly, in recent years along with the surge of consumption, exist the asphalt mixture viscosity of waste water type to uprise, adhesive power grow, the anti-adhesion effect problem then on the low side of mineral oils comparatively speaking.Mineral oils is seeped in ground and the ground when bitumen construction in addition, is a big problem from the environment aspect.In addition when using mineral oils because the solvability of asphalt mixture is uprised, might cause the damage of variable color of application face and viscosity degradation etc.
In order to solve above problem, use to add used water-soluble machining oil in man-hour at metal, perhaps research and develop for addressing the above problem.For example specially permit the asphalt adhesive that discloses the nonionogenic tenside that contains sorbitan-fatty acid ester class or polyoxyethylene sorbitan fatty acid ester class in No. 2736606 communique and prevent agent.Open the spy in addition and disclose the heated bitumen matrix material that contains sodium alkyl sulfate, sodium alkylether sulphate, water and Oleum Cocois in the flat 10-121028 communique and adhere to and to prevent agent.Adopt that disclosed asphalt adhesive prevents agent in the above-mentioned communique, though have the effect that prevents asphalt adhesive to a certain degree, it prevents that the effect of asphalt adhesive from being not fine.
In addition, when making concrete product, most be to use molding box that concrete setting is become target shape and make.Can take off molding box with comparalive ease for molding box and concrete are sticked together this moment and use releasing agent in order to protect molding box.Concrete parting agent generally is before concreting, is coated in advance on the internal surface of molding box to use.Used all the time concrete parting agent, be with light oil or mechanical wet goods mineral oil as base oil, correspondingly add various additives such as wax, metallic soaps, rust-preventive agent as required and make.Also can be divided into oil type, emulsion-type, solvable type etc. according to using method in addition.
As such concrete parting agent, for example open in the flat 5-69428 communique the spy, the concrete parting agent of being made by the mineral oils solvent that contains phosphatide and sorbitan-fatty acid ester or its ethylene oxide adduct is disclosed.Disclosed concrete parting agent in this communique though can reduce the pollution of molding box and realize rust-proof effect, owing to used the mineral oils solvent, is not fine from environment and secure context therefore.As mentioned above, even in the concrete parting agent field, reality is still not develop the product of aspects such as taking into account function and environment.
Therefore, wish to develop a kind of well emulsify stability that has, simultaneously environmental pollution be can reduce, machining oil and plastic working wet goods metalworking fluid are suitable as, asphalt mixture adheres to the water-soluble lubricating oil compositions that prevents mold oils such as agent and concrete parting agent.
Summary of the invention
Therefore, purpose of the present invention just is, provide have good emulsifying stability, can reduce simultaneously environmental pollution, be suitable as machining oil and plastic working wet goods metalworking fluid, asphalt mixture adheres to the water-soluble lubricating oil compositions that prevents mold oils such as agent and concrete parting agent.
The inventor attentively studies, and found that the water-soluble lubricating oil compositions that contains animal grease and/or Vegetable oil lipoprotein and specific surfactant can realize above-mentioned purpose.
On the basis of above-mentioned discovery, the invention provides a kind of water-soluble lubricating oil compositions that contains animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant.
In addition, in this specification sheets " water-soluble lubricating oil ", be the notion that comprises mold oil and metalworking fluid, metalworking fluid comprises machining oil and plastic working oil, prevents agent and concrete parting agent and comprise the asphalt mixture adhesion in the mold oil.
In addition, the invention provides a kind of water-soluble metal treated oil composition that contains animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant.
In addition, the invention provides a kind of mold oil that contains animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant.
In addition, the invention provides a kind of asphalt mixture adhesion that contains animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant and prevent the agent composition.
In addition, the invention provides a kind of concrete parting agent composition that contains animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant.
Implement optimal morphology of the present invention
At first water-soluble lubricating oil compositions of the present invention is described below.
In addition, " water-soluble " is meant in this manual, situation about using down with emulsion state behind the dilute with water during use.That is, water-soluble lubricating oil compositions of the present invention is to form the emulsion form to use behind dilute with water.Such water-soluble lubricating oil compositions was compared with the former water-insoluble lubricating oil as machining oil, calendering wet goods metalworking fluid and flame retardant resistance work oil, had the low feature that waits of flash point.
Water-soluble lubricating oil compositions of the present invention contains animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant.Water-soluble lubricating oil compositions of the present invention is made as base oil with animal grease and/or Vegetable oil lipoprotein.
As above-mentioned animal grease, butter are for example arranged, lard and fish oil etc.As above-mentioned Vegetable oil lipoprotein, soybean oil is arranged in addition in addition, rape seed oil, Semen Maydis oil, Thistle oil, sunflower oil, continuous seed oil, Rice pollard oil, sesame oil, sweet oil, peanut oil, plam oil, palm-kernel oil, Oleum Cocois and linseed oil wet goods.In water-soluble lubricating oil compositions of the present invention, above-mentioned animal grease and Vegetable oil lipoprotein can use separately, also can two or more mixing use.Can only use animal grease also can only use Vegetable oil lipoprotein in addition, also animal grease and Vegetable oil lipoprotein can be mixed use in addition.In addition, the animal grease and the Vegetable oil lipoprotein that use in the water-soluble lubricating oil compositions of the present invention, the grease that preferably is in a liquid state at normal temperatures.By the grease that uses normal temperature to be in a liquid state, easy to manufacture and can not solidify when preserving, so be easy to use.In addition, even above-mentioned animal grease and Vegetable oil lipoprotein are not in a liquid state separately at normal temperatures, and if be in a liquid state when being use mixing two or more desirable at normal temperatures yet.Also can use waste edible oil as above-mentioned animal grease and Vegetable oil lipoprotein in addition.
The content of above-mentioned animal grease and/or Vegetable oil lipoprotein in the oeverall quality of water-soluble lubricating oil compositions, preferably contains more than the 65 quality %, more preferably contains more than the 75 quality %.The content of animal grease and/or Vegetable oil lipoprotein is during less than 65 quality %, and its effect that reduces environmental pollution is relatively poor, therefore preferably in above-mentioned scope.
Nonionic surfactant as above-mentioned polyoxyethylene sorbitol fatty acid ester for example has the polyoxyethylene sorbitol tetrastearate, polyoxyethylene sorbitol four oleic acid esters and polyoxyethylene sorbitol mono-laurate etc.In the lubricating oil composition of the present invention, above-mentioned nonionogenic tenside can use separately also and can two or more mixing use.
The content of above-mentioned polyoxyethylene sorbitol fatty acid ester nonionic surfactant, animal grease and/or Vegetable oil lipoprotein total amount with respect to 100 mass parts preferably contain 1～50 mass parts, more preferably contain 5～30 mass parts.Above-mentioned animal grease and/or Vegetable oil lipoprotein with respect to 100 mass parts, the content of above-mentioned nonionic surfactant is during less than 1 mass parts, emulsifying stability is insufficient, in addition when content surpasses 50 mass parts, the interpolation of tensio-active agent also promotes effect as can not expecting, and cost is raise, so content is preferably in above-mentioned scope.
In the water-soluble lubricating oil compositions of the present invention, also can contain any composition commonly used that is contained in the lubricating oil all the time.As this any composition, antioxidant is for example arranged, yield point inhibitor, extreme pressure agent, viscosity index improver, rust-preventive agent, defoamer, sanitas and dispersion agent etc.When containing above-mentioned any composition, its content accounts in the total mass of water-soluble lubricating oil compositions about 0.1～10 quality %.
Water-soluble lubricating oil compositions of the present invention uses behind the dilute with water.Weaker concn is preferably 1～50 times when dilute with water, further preferably 3～30 times.
Water-soluble lubricating oil compositions of the present invention can utilize following method manufacturing.
That is, animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant are heated to proper temperature separately, the limit mixed dissolution is fully stirred on the limit, obtains water-soluble lubricating oil compositions of the present invention.The water-soluble lubricating oil compositions that obtains can use behind the dilute with water as required.The interpolation of above-mentioned any composition can also can be carried out after obtaining the water-soluble lubricating oil compositions before heating.
Then, water-soluble metal treated oil composition of the present invention is described.
Water-soluble metal treated oil composition of the present invention contains animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant.Water-soluble metal treated oil composition of the present invention is made as base oil with animal grease and/or Vegetable oil lipoprotein.
As above-mentioned animal grease and Vegetable oil lipoprotein, can use in the above-mentioned water-soluble lubricating oil compositions employedly, its content is also the same.In addition, above-mentioned polyoxyethylene sorbitol fatty acid ester nonionic surfactant also can use in the above-mentioned water-soluble lubricating oil compositions employedly, and its content is also the same.
The content of above-mentioned animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant, any one-tenth grade, can be the same with the situation in the above-mentioned water-soluble lubricating oil compositions.
Water-soluble metal treated oil composition of the present invention, the same with water-soluble lubricating oil compositions of the present invention, utilize water dilution back to use preferably 1～50 times of its extension rate, further preferably 3～30 times.
Water-soluble metal treated oil composition of the present invention can be used as machining oil or plastic working oil.Using method as machining oil or plastic working oil is not particularly limited, and can with traditional machining oil or plastic working oil is the same uses.
In addition, the manufacture method of water-soluble metal treated oil composition of the present invention can adopt the method same with the manufacture method of above-mentioned water-soluble lubricating oil compositions.
Then mold oil of the present invention is described.
Mold oil of the present invention contains animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant.Mold oil of the present invention is made as base oil with animal grease and/or Vegetable oil lipoprotein.
As above-mentioned animal grease and Vegetable oil lipoprotein, can use in the above-mentioned water-soluble lubricating oil compositions employedly, its content is also the same.In addition, above-mentioned polyoxyethylene sorbitol fatty acid ester nonionic surfactant can use in above-mentioned water-soluble lubricating oil compositions employedly, and its content is also the same.
The content of above-mentioned animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant, any one-tenth grade, can be the same with the situation in the above-mentioned water-soluble lubricating oil compositions.Mold oil of the present invention can adhere to as asphalt mixture and prevent agent and concrete parting agent.
In addition, the manufacture method of mold oil of the present invention also can adopt the manufacture method same with the manufacture method of above-mentioned water-soluble lubricating oil compositions.
Then, asphalt mixture adhesion of the present invention is prevented that the agent composition from describing.
Asphalt mixture of the present invention adheres to and prevents the agent composition, contains animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant.Asphalt mixture of the present invention adheres to and prevents that the agent composition from making as base oil with animal grease and/or Vegetable oil lipoprotein.
As above-mentioned animal grease and Vegetable oil lipoprotein, can use in above-mentioned water-soluble lubricating oil compositions employedly, its content is also the same.In addition, above-mentioned polyoxyethylene sorbitol fatty acid ester nonionic surfactant can use in the above-mentioned water-soluble lubricating oil compositions employedly, and its content is also the same.
The content of above-mentioned animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant and grade for any one-tenth can be the same with the situation in the above-mentioned water-soluble lubricating oil compositions.
In addition, asphalt mixture of the present invention adheres to and prevents that the manufacture method of agent composition from can adopt the method same with the manufacture method of above-mentioned water-soluble lubricating oil compositions.
Asphalt mixture of the present invention adheres to and prevents the agent composition, and is the same with water-soluble lubricating oil compositions of the present invention, utilizing water dilution back to use preferably 1～50 times of its extension rate, further preferably 3～30 times.When extension rate surpassed 50 times, the content ratio of animal grease or Vegetable oil lipoprotein reduced, and can not get well preventing the adherent effect of asphalt mixture sometimes, so extension rate is preferably below 50 times.In order to improve emulsifying stability, adhere to the water that prevents from also can mix in the agent composition about 0.1～10 quality % at asphalt mixture of the present invention.
In addition, " asphalt mixture " is meant tackiness agents such as containing pitch or resene tackiness agent, further contains other materials such as supporting by the arm material in this manual, the mixture that uses when the road of mating formation etc.
Then, asphalt mixture adhesion of the present invention is prevented that agent from describing.
Asphalt mixture of the present invention adheres to and prevents agent, the asphalt mixture of the invention described above is adhered to prevent that agent composition dilute with water from obtaining.Preferably 1～50 times of its extension rate, further preferably 3～30 times.
Asphalt mixture of the present invention adheres to and prevents agent, can directly take a walk on for example truck railway carriage or road and uses.In addition, also can on construction machineries such as rubber tyred roller or street roller, scatter with suitable distributing method such as coating or spraying.In the time of on spreading to truck railway carriage or road, be not particularly limited for dispersion volume, but general be 100～1000mL/m
2About.In addition, its glue spread also is not particularly limited in the time of on being applied to construction machinery etc., but general be 50～200mL/m
2About.
Then, concrete parting agent composition of the present invention is described.
Concrete parting agent composition of the present invention contains animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant.Concrete parting agent composition of the present invention is made as base oil with animal grease and/or Vegetable oil lipoprotein.
As above-mentioned animal grease and Vegetable oil lipoprotein, can use in the above-mentioned water-soluble lubricating oil compositions employedly, its content is also the same.In addition, above-mentioned polyoxyethylene sorbitol fatty acid ester nonionic surfactant also can use in the above-mentioned water-soluble lubricating oil compositions employedly, and its content is also the same.
The content of above-mentioned animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester nonionic surfactant and grade for any one-tenth can be the same with the situation in the above-mentioned water-soluble lubricating oil compositions.
In addition, the manufacture method of concrete parting agent composition of the present invention adopts the same method of manufacture method with above-mentioned water-soluble lubricating oil compositions.
Concrete parting agent composition of the present invention, the same with water-soluble lubricating oil compositions of the present invention, utilizing water dilution back to use preferably 1～50 times of its extension rate, further preferably 3～30 times.When extension rate surpassed 50 times, the content ratio of animal grease or Vegetable oil lipoprotein reduced, and can not get good concrete stripping result, so extension rate is preferably below 50 times.In order to improve emulsifying stability, in concrete parting agent of the present invention, also can mix the water about 0.1～10 quality %.
Then, concrete parting agent of the present invention is described.
Concrete parting agent of the present invention is to obtain after above-mentioned concrete parting agent composition is utilized the water dilution.Preferably 1～50 times of extension rate, further preferably 3～30 times.
Concrete parting agent of the present invention can solidify concrete using molding box, when making concrete product, directly is coated on the internal surface of molding box and uses.Be not particularly limited for coating process, can use suitable coating process to implement.In the time of on being applied to molding box, its glue spread also is not particularly limited, and that general is 20～100mL/m
2About.
In addition, at water-soluble lubricating oil compositions of the present invention, water-soluble metal treated oil composition, mold oil, asphalt mixture adheres to and prevents the agent composition, asphalt mixture adheres to and prevents agent, in concrete parting agent composition and the concrete parting agent, except adding animal grease and/or Vegetable oil lipoprotein, and outside the polyoxyethylene sorbitol fatty acid ester nonionic surfactant, in the scope of not damaging performance, also can with former water-soluble lubricating oil compositions, water-soluble metal treated oil composition, asphalt mixture adheres to and to prevent that agent composition and asphalt mixture from adhering to and prevent mineral wet goods used in the agent etc. and use.In addition, when containing mineral oil, its content lacks than the total amount of animal grease and/or Vegetable oil lipoprotein.
Embodiment
Further the present invention is described in detail to utilize embodiment below.In addition, scope of the present invention is not restricted to these embodiment.In addition, in the record below, if not otherwise specified, " part " is meant " mass parts ", and " % " is meant " quality % ".
Embodiment 1
With A) 90 parts rape seed oil and B) 10 parts polyoxyethylene sorbitol four oleic acid esters (30 moles of EO of addition) are heated to 70 ℃ separately, and the limit is fully stirred the limit and is made its mixed dissolution, obtains water-soluble lubricating oil compositions of the present invention.To this water-soluble lubricating oil compositions that obtains, carry out various evaluations according to following " judgement criteria of water-soluble lubricating oil compositions ".Its evaluation result sees Table 1 (experiment (1)～(5)) and table 2 (experiment (6)～(8)).
(judgement criteria of water-soluble lubricating oil compositions)
(1) frictional coefficient
Water dilutes 10 times with the water-soluble lubricating oil compositions that obtains, and utilizes the frictional coefficient of vibration frictional dissipation trier (オ プ チ モ-Le society system) this diluent of diluent determining.Condition determination is as follows.
Load: 200N
Vibrational frequency: 50Hz
Amplitude: 2mm
Time: 10 minutes
(2) emulsifying stability
Water dilutes 10 times with the water-soluble lubricating oil compositions that obtains, and places 8 hours after fully stirring, and estimates its emulsified state, estimates according to following judgement criteria.
◎: emulsified state is stable, does not separate fully
Zero: only have a bit and separate
*: separate
(3) bituminous solvability
In order to confirm that water-soluble lubricating oil compositions of the present invention adhering to the effect that prevents agent as asphalt mixture, carries out following evaluation.
Under 170 ℃, 5 parts of drainages to be mated formation with modifying asphalt (" エ コ Off ァ Le ト TA " Nippon Mitsubishi Oil's (strain) system) and 95 parts of No. 6 rubbles mixing, modulation obtains asphalt mixture.Then will be by the above-mentioned asphalt mixture 20g that obtains, be immersed among 10 times of water diluents (asphalt mixture of the present invention adheres to and prevents agent) 50mL of the water-soluble lubricating oil compositions that obtains, after at room temperature placing 3 days, the state of range estimation asphalt mixture is estimated according to following standard.
◎: asphalt mixture does not change
*: the asphalt mixture dissolving
(4) prevent the adherent effect of asphalt mixture
On the iron plate of 60cm * 45cm, 5 times of diluents of the water-soluble lubricating oil compositions that coating 100mL obtains (asphalt mixture of the present invention adheres to and prevents agent), same asphalt mixture (temperature: the 170 ℃) 1kg that in lift-launch on the above-mentioned iron plate and pitch solvability, uses then in above-mentioned (2).After 30 minutes, from horizontal direction about 30 ° of angles that tilt, whether the range estimation asphalt mixture sticks on the iron plate, estimates according to following standard with iron plate.
◎: asphalt mixture does not stick on the iron plate fully
Zero: asphalt mixture sticks on the iron plate a little
*: asphalt mixture sticks on the iron plate in a large number
(5) environmental safety
(5)-1 biological degradability
Utilization is assert the test method of standard OECD301C based on Eco mark, measures through the biological degradability after 28 days.Result when using rapeseed oil is 87% in addition.
Result shown in the table 1, whether that is remembered assert that at Eco mark standard is more than 60%.
(5)-2 organism influence experiment
Utilization is assert the test method of standard OECD203 (scarlet Medaka acute toxicity test) based on Eco mark, measures through the LC50 after 96 hours.
In addition, the identification standard of Eco mark is more than 60% through its biological degradability after 28 days in the experiment of above-mentioned (5)-1, and the LC50 in the experiment of (5)-2 after 96 hours is more than 100mg/L.
Organism influence experiment is to use the composition of 1000mg/L to carry out, even whether investigation utilizes the composition scarlet Medaka of 1000mg/L all to survive.
(6) machinability
Use seven Application -60 ° of HSS of De リ Le A type (point diameter 4) of イ ワ Star-Le society system, on mild steel, carry out perforate processing (1000rpm), estimate as water-soluble machining oil.In addition, use, measure angle precision, estimate behind 30 times of the water-soluble lubricating oil compositions dilute with waters that obtain.
(7) estimate press formability
Use piercing and shaping die evaluation cylinder drift oil pressure forming test machine, estimate press formability.Condition determination is as follows.Use electrogalvanizing steel plate evaluation in addition.
Drift: 40mm φ * 4mm rpm
Punch die: 40mm φ * 4mm rpm
Blank holder: 1 ton
Use behind 10 times of the water-soluble lubricating oil compositions dilute with waters that obtain, range estimation sidewall outward appearance is according to its stickness of following standard evaluation.
Zero: can be shaped, be the state that surface of steel plate does not have defective
△: can be shaped, be the state that the defective of a bit adhering is only arranged at surface of steel plate
*: can be shaped, be the state that wire adhesion defective is arranged at surface of steel plate.
(8) estimate concrete demoulding
Use injector, the solution 4ml that after the iron molding box of long 10cm * wide 10cm * high 30cm is coated with 5 times of the water-soluble lubricating oil compositions dilute with waters that will obtain, obtains.In molding box, build by the mixing concrete of following prescription.When building, the limit uses 30 seconds limits of desk-top vibrator vibration of 3000vpm to carry out.Place the demoulding after 2 days, according to its release property of following standard evaluation.
Zero: on molding box, almost do not have the concrete bur
△: being scattered on molding box has concrete thin bur
*: thick concrete bur is arranged on molding box
In addition, calculate the number of bubbles of size more than existing 3mm ф on the rectangular-shaped concrete single side face that obtains.
Concrete formulation
Ordinary Portland cement 1.0kg
Fine aggregate 2.4kg
Coarse aggregate (overall dimension: 15mm) 2.4kg
Water reducer (パ リ Star Network #1: rattan pool medicine (strain) system) 0.002kg
Water 0.5kg
In addition, in above-mentioned concrete prescription, the mass ratio of water/cement is 50%, and with respect to the amount of cement, the consumption of water reducer is 0.2 quality.
Embodiment 2
With A) 80 parts soybean oil and 10 parts plam oil and B) 10 parts polyoxyethylene sorbitol four oleic acid esters (30 moles of E0 of addition) are heated to 70 ℃ separately, and the limit is fully stirred the limit and is made its mixed dissolution, obtains water-soluble lubricating oil compositions of the present invention.To this water-soluble lubricating oil compositions that obtains, carry out same evaluation with embodiment 1.Evaluation result sees Table 1 (experiment (1)～(5)) and table 2 (experiment (6)～(8)).
Embodiment 3
With A) 90 parts rapeseed oil and B) 8 parts polyoxyethylene sorbitol four oleic acid esters (30 moles of E0 of addition) and 2 parts of polyoxyethylene sorbitol four oleic acid esters (60 moles of E0 of addition) are heated to 70 ℃ separately, the limit is fully stirred the limit and is made its mixed dissolution, obtains water-soluble lubricating oil compositions of the present invention.To this water-soluble lubricating oil compositions that obtains, carry out same evaluation with embodiment 1.Evaluation result sees Table 1 (experiment (1)～(5)) and table 2 (experiment (6)～(8)).
Embodiment 4
In the water-soluble lubricating oil compositions that embodiment 1 obtains, the water that the limit adds relative composition gross weight 1% amount is fully stirred on the limit, obtains water-soluble lubricating oil compositions of the present invention.The water-soluble lubricating oil compositions that obtains is carried out the same evaluation of embodiment 1.Evaluation result sees Table 1 (experiment (1)～(5)) and table 2 (experiment (6)～(8)).
Comparative example 1～3
As a comparative example 1～3, use following material to carry out the same evaluation with embodiment 1.Its evaluation result sees Table 1 (experiment (1)～(5)) and table 2 (experiment (6)～(8)).
Comparative example 1: commercially available light oil
Comparative example 2: water
Comparative example 3: water-soluble machining oil ス ギ カ Star ト CE-11N (ス ギ system ラ chemical industry (strain) is with the machining oil of mineral oil as base oil)
Comparative example 4
The polyoxyethylene sorbitan trioleate (20 moles of E0 of addition) of 80 parts rapeseed oils and 20 parts is heated to 70 ℃ separately, and the limit is fully stirred the limit and is made its mixed dissolution, obtains lubricating oil composition.To this lubricating oil composition that obtains, carry out same evaluation with embodiment 1.Evaluation result sees Table 1 (experiment (1)～(5)) and table 2 (experiment (6)～(8)).
Table 1
| (1) | (2) | (3) | (4) | (5)—1 | (5)—2 | |
| Embodiment 1 | 0.11 | ○ | ◎ | ◎ | More than 60% | More than the 1000mg/L |
| Embodiment 2 | 0.12 | ◎ | ◎ | ◎ | More than 60% | More than the 1000mg/L |
| Embodiment 3 | 0.12 | ◎ | ◎ | ◎ | More than 60% | More than the 1000mg/L |
| Embodiment 4 | 0.11 | ◎ | ◎ | ◎ | More than 60% | More than the 1000mg/L |
| Comparative example 1 | 0.40 | — | × | ◎ | — | — |
| Comparative example 2 | — | — | ◎ | × | — | — |
| Comparative example 3 | 0.13 | — | × | ○ | — | — |
| Comparative example 4 | 0.13 | × | ◎ | ○ | — | — |
In table 1 "-" this experiment is not carried out in expression." more than the 1000mg/L " do not have-bar scarlet Medaka fish dies even be meant the 1000mg/L of 10 times of amounts using normality 100mg/L yet in experiment (5)-2 in addition.
Table 2
This experiment is not carried out in "-" expression in the table 2.
Can know from table 1 and find out that water-soluble lubricating oil compositions of the present invention has good emulsifying stability, the bituminous solvability is low when preventing agent as the asphalt mixture adhesion, has the good adherent effect that prevents asphalt mixture.In addition, water-soluble lubricating oil compositions of the present invention as can be known has good environmental safety.
From table 2, can know in addition and find out that water-soluble lubricating oil compositions of the present invention has good machinability, press formability and concrete demoulding, can be used as machining oil (machining oil), punch process oil, concrete parting agent.
As above explanation, water-soluble lubricating oil compositions of the present invention can alleviate the pollution to environment when having well emulsify stability.
In addition, asphalt mixture of the present invention adheres to and prevents agent, when having good emulsifying stability, low pitch solvability and alleviating environmental pollution, also has the good adherent effect of asphalt mixture that prevents.
In addition, concrete parting agent composition of the present invention when having good emulsifying stability and can alleviating environmental pollution, also has good concrete demoulding effect.
Claims (16)
1, a kind of mold oil is characterized in that: the nonionic surfactant by animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester constitutes.
2. mold oil, by animal grease and/or Vegetable oil lipoprotein, the nonionic surfactant of polyoxyethylene sorbitol fatty acid ester, and be selected from mineral oil, antioxidant, the yield point inhibitor, extreme pressure agent, viscosity index improver, rust-preventive agent, defoamer, at least a formation of sanitas and dispersion agent, and the content of described animal grease and/or Vegetable oil lipoprotein is more than the 65 quality % of oeverall quality.
3, mold oil as claimed in claim 1 or 2 is characterized in that: with respect to the animal grease and/or the Vegetable oil lipoprotein total amount of 100 weight parts, the content of the nonionic surfactant of polyoxyethylene sorbitol fatty acid ester is 1～50 weight part.
4, as claim 1 or 2 described mold oils, it is characterized in that: above-mentioned animal grease and/or Vegetable oil lipoprotein are the grease that is in a liquid state under the normal temperature.
5, a kind of asphalt mixture adheres to and prevents the agent composition, and it is characterized in that: the nonionic surfactant by animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester constitutes.
6, a kind of asphalt mixture adheres to and prevents the agent composition, by animal grease and/or Vegetable oil lipoprotein, the nonionic surfactant of polyoxyethylene sorbitol fatty acid ester, and be selected from mineral oil, antioxidant, the yield point inhibitor, extreme pressure agent, viscosity index improver, rust-preventive agent, defoamer, at least a formation of sanitas and dispersion agent, and the content of described animal grease and/or Vegetable oil lipoprotein is more than the 65 quality % of oeverall quality.
7, prevent the agent composition as claim 5 or 6 described asphalt mixtures adhesions, it is characterized in that: the animal grease of relative 100 weight parts and/or Vegetable oil lipoprotein total amount, the content of the nonionic surfactant of polyoxyethylene sorbitol fatty acid ester are 1～50 weight part.
8, prevent the agent composition as claim 5 or 6 described asphalt mixtures adhesions, it is characterized in that: above-mentioned animal grease and/or Vegetable oil lipoprotein are the grease that is in a liquid state under the normal temperature.
9, each described asphalt mixture in the claim 5～8 is adhered to prevent the agent composition, dilute with water and the asphalt mixture that obtains adhere to and prevent agent.
10, each described asphalt mixture in the claim 5～8 is adhered to prevent the agent composition, 1～50 times of dilute with water and the asphalt mixture that obtains adhere to and prevent agent.
11, a kind of concrete parting agent composition is characterized in that: the nonionic surfactant by animal grease and/or Vegetable oil lipoprotein and polyoxyethylene sorbitol fatty acid ester constitutes.
12. concrete parting agent composition, by animal grease and/or Vegetable oil lipoprotein, the nonionic surfactant of polyoxyethylene sorbitol fatty acid ester, and be selected from mineral oil, antioxidant, the yield point inhibitor, extreme pressure agent, viscosity index improver, rust-preventive agent, defoamer, at least a formation of sanitas and dispersion agent, and the content of described animal grease and/or Vegetable oil lipoprotein is more than the 65 quality % of oeverall quality.
13, as claim 11 or 12 described concrete parting agent compositions, it is characterized in that: the animal grease of relative 100 weight parts and/or Vegetable oil lipoprotein total amount, the content of the nonionic surfactant of polyoxyethylene sorbitol fatty acid ester are 1～50 weight part.
14, as claim 11 or 12 described concrete parting agent compositions, it is characterized in that: above-mentioned animal grease and/or Vegetable oil lipoprotein are the grease that is in a liquid state under the normal temperature.
15, the concrete parting agent that each described concrete parting agent composition obtains in the dilute with water claim 11～14.
16, with each described concrete parting agent composition in the claim 11～14,1～50 times of dilute with water and the concrete parting agent that obtains.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001329601 | 2001-10-26 | ||
| JP329601/2001 | 2001-10-26 |
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| CN100532518C true CN100532518C (en) | 2009-08-26 |
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| CNB028210719A Expired - Fee Related CN100532518C (en) | 2001-10-26 | 2002-10-24 | Lubricating oil composition |
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|---|---|
| JP (1) | JP4205585B2 (en) |
| CN (1) | CN100532518C (en) |
| TW (1) | TW583309B (en) |
| WO (1) | WO2003035809A1 (en) |
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| EP1743753A1 (en) * | 2005-06-20 | 2007-01-17 | Heraeus Kulzer GmbH | Shaping paste, its use and method of production of ceramic bodies |
| JP5034068B2 (en) * | 2006-02-28 | 2012-09-26 | 酒井重工業株式会社 | Asphalt adhesion inhibitor |
| CN102046343A (en) * | 2008-05-30 | 2011-05-04 | 建筑研究和技术有限公司 | Formwork release composition and use thereof |
| JP5515981B2 (en) * | 2009-08-20 | 2014-06-11 | 日油株式会社 | Asphalt adhesion inhibitor composition |
| JP5654229B2 (en) * | 2009-11-30 | 2015-01-14 | 出光興産株式会社 | Water-soluble metalworking fluid and method of using the same |
| JP5253454B2 (en) * | 2010-05-27 | 2013-07-31 | 田中鉄工株式会社 | Anti-adhesive agent supply device, anti-adhesive agent supply method, and anti-adhesive agent |
| CN102205390B (en) * | 2011-04-28 | 2013-05-08 | 苏州兴业材料科技股份有限公司 | Environmentally-friendly casting mold-releasing agent and preparation method thereof |
| JP5866963B2 (en) * | 2011-10-24 | 2016-02-24 | 日油株式会社 | Asphalt mixture adhesion inhibitor composition |
| TWI467002B (en) * | 2012-02-24 | 2015-01-01 | Univ Nat Formosa | Straw biolubricant |
| CN102816557A (en) * | 2012-08-01 | 2012-12-12 | 新疆蛛蛛网科技股份有限公司 | Environment-friendly drilling fluid (EFD) |
| KR102083699B1 (en) | 2012-08-10 | 2020-03-02 | 니치유 가부시키가이샤 | Adhesion inhibitor for asphalt |
| CN102851006A (en) * | 2012-09-30 | 2013-01-02 | 中国石油集团西部钻探工程有限公司 | Bio-oil lubricant for drilling wells and preparation method of bio-oil lubricant |
| CN102942499A (en) * | 2012-10-12 | 2013-02-27 | 陕西师范大学 | Preparation method of asphalt release agent |
| MY175118A (en) * | 2013-05-20 | 2020-06-09 | Malaysian Palm Oil Board | A mould release lubricant |
| JP6206076B2 (en) * | 2013-10-16 | 2017-10-04 | 日油株式会社 | Asphalt mixture adhesion inhibitor |
| CN103992861B (en) * | 2014-04-25 | 2016-02-10 | 蚌埠市鸿安精密机械有限公司 | A kind of thin-layer rust-preventative oil |
| CN104479842A (en) * | 2014-12-18 | 2015-04-01 | 蒙城县科技创业服务中心 | Green and environment-friendly concrete release agent and preparation method thereof |
| CN104479835A (en) * | 2014-12-18 | 2015-04-01 | 蒙城县科技创业服务中心 | Concrete releasing agent prepared from rapeseed oil and preparation method of concrete releasing agent |
| CN104531309A (en) * | 2014-12-18 | 2015-04-22 | 蒙城县科技创业服务中心 | Waterborne polyurethane concrete de-molding agent and preparation method thereof |
| CN104498160A (en) * | 2014-12-18 | 2015-04-08 | 蒙城县科技创业服务中心 | Concrete releasing agent prepared from rosin and preparation method thereof |
| CN104498161A (en) * | 2014-12-18 | 2015-04-08 | 蒙城县科技创业服务中心 | Concrete release agent prepared from animal fat |
| KR101635457B1 (en) * | 2016-01-11 | 2016-07-01 | 주식회사 누보켐 | Asphalt release agent and manufacturing method thereof |
| WO2018018423A1 (en) * | 2016-07-26 | 2018-02-01 | 顾湘 | Fair-faced concrete release agent and preparation method therefor |
| CN107088648B (en) * | 2017-04-18 | 2019-07-02 | 奎克化学（中国）有限公司 | A kind of casting grid of lead-acid accumulator oil-based release agent |
| CN111378519A (en) * | 2018-12-27 | 2020-07-07 | 膳魔师（江苏）家庭制品有限公司 | Preparation method of water swelling liquid |
| JP7193064B2 (en) * | 2019-02-14 | 2022-12-20 | ボーソー油脂株式会社 | Concrete formwork remover |
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| KR102144960B1 (en) * | 2020-04-01 | 2020-08-14 | (주)씨엔루브 | Method for manufacturing a concrete oily release agent using waste oil |
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- 2002-10-24 JP JP2003538311A patent/JP4205585B2/en not_active Expired - Fee Related
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| WO2003035809A1 (en) | 2003-05-01 |
| JPWO2003035809A1 (en) | 2005-02-10 |
| JP4205585B2 (en) | 2009-01-07 |
| TW583309B (en) | 2004-04-11 |
| CN1575330A (en) | 2005-02-02 |
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