CN100528958C - ABS hardening flame-proof modified formulation - Google Patents
ABS hardening flame-proof modified formulation Download PDFInfo
- Publication number
- CN100528958C CN100528958C CNB2006100344067A CN200610034406A CN100528958C CN 100528958 C CN100528958 C CN 100528958C CN B2006100344067 A CNB2006100344067 A CN B2006100344067A CN 200610034406 A CN200610034406 A CN 200610034406A CN 100528958 C CN100528958 C CN 100528958C
- Authority
- CN
- China
- Prior art keywords
- component
- abs
- following content
- brominated polycarbonate
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an ABS hardening flame-proof modifying formula, which comprises the following parts: 60-85% acrylonitrile-butadiene-phenylethene, 1-5% chlorinated polyethylene, 1-5% acrylonitrile-phenylethene copolymer grafted maleic anhydride, 1-5% methyl acrylate-butadiene-phenylethene copolymer, 8-25% phenylethene-acrylonitrile copolymer, 3-9% bromopolycarbonate and 1-5% antimony trioxide.
Description
Technical field
The present invention relates to a kind of ABS improved composition, relate in particular to a kind of improved composition that can improve ABS resin surface hardness and flame retardant properties.
Background technology
ABS (vinyl cyanide--divinyl--vinylbenzene) resin is a kind of good comprehensive properties engineering plastics, has good electrical property, cold tolerance, oil resistance and chemical mediator stability, and surface hardness and flame retardant properties are inferior slightly.Raising along with scientific-technical progress and quality of life, people's awareness of safety is more and more stronger, the plastic material that uses for aspects such as automobile, building, household electrical appliance, office appliances has proposed strict fire protection flame retarding requirement both at home and abroad, has formulated corresponding technical standard and standard.In addition, ABS is widely used in the panel of electric equipment products, in order to keep permanent aesthetic appearance, its surface hardness has been proposed new requirement, and therefore researching and developing ABS stiffened flame-retarded technology has seemed very important.
Summary of the invention
The object of the present invention is to provide a kind of ABS hardening flame-proof modified composition that improves ABS resin surface hardness and flame retardant properties.
For achieving the above object, the invention provides a kind of ABS hardening flame-proof modified composition, it comprises the component of following content: vinyl cyanide--divinyl--styrol copolymer 60-85%; Chlorinatedpolyethylene 1-5%; Acrylonitritrile-styrene resin grafted maleic anhydride 1-5%; MBS 1-5%; Styrene-acrylonitrile copolymer 8-25%; Brominated polycarbonate 3-9%; Antimonous oxide 1-5%; More than the percentage ratio of each component all be weight percent.
The present invention has following beneficial effect: in improved composition, added toughener styrene-acrylonitrile copolymer and flame retardant brominated polycarbonate and antimonous oxide, improved surface hardness and flame retardant properties.
Embodiment
A kind of ABS hardening flame-proof modified composition, it comprises the component of following content:
ABS (vinyl cyanide--divinyl--styrol copolymer) 60-85%;
SAN (styrene-acrylonitrile copolymer) 8-25%;
CPE (chlorinatedpolyethylene) 1-5%;
AS-G-MAH (acrylonitritrile-styrene resin grafted maleic anhydride) 1-5%;
MBS (MBS) 1-5%;
Brominated polycarbonate 3-9%;
Antimonous oxide (Sb2O3) 1-5%;
More than the percentage ratio of each component all be weight percent, the bromine content of brominated polycarbonate is 58%.
In the above-mentioned composition, SAN is a toughener, can improve the surface hardness of ABS resin.Brominated polycarbonate and antimonous oxide are fire retardants, can improve the flame retardant properties of ABS resin.
Embodiment one
This ABS hardening flame-proof modified composition comprises the component of following content:
ABS 61.8％；
SAN 23.2％；
CPE 3％；
AS-G-MAH 2％；
MBS 3％；
Brominated polycarbonate 5%;
Antimonous oxide 2%;
More than the percentage ratio of each component all be weight percent, the bromine content of brominated polycarbonate is 58%.
Before the modification and the performance index of the ABS resin material after the modification can be referring to following table:
| Before the modification | After the modification | |
| Impact property (KJ/M2) | 23.75 | 5.91 |
| Tensile property (Mpa) | 42 | 42.32 |
| Bending property (Mpa) | 60 | 64.01 |
| Surface hardness | B | HB |
| UL94(3.0mm) | V-2 | V-0 |
As can be seen from the above table, in improved composition, added toughener SAN, made surface hardness be increased to HB, added flame retardant brominated polycarbonate and antimonous oxide, made flame retardant properties bring up to the V-0 level from the V-2 level of UL94 from B.
Embodiment two
This ABS hardening flame-proof modified composition comprises the component of following content:
ABS 72.8％；
SAN 18.2％；
CPE 1％；
AS-G-MAH 2％；
MBS 2％；
Brominated polycarbonate 3%;
Antimonous oxide 1%;
More than the percentage ratio of each component all be weight percent, the bromine content of brominated polycarbonate is 58%.
Before the modification and the performance index of the ABS resin material after the modification can be referring to following table:
| Before the modification | After the modification | |
| Impact property (KJ/M2) | 23.75 | 8.35 |
| Tensile property (Mpa) | 42 | 42.13 |
| Bending property (Mpa) | 60 | 64.38 |
| Surface hardness | B | HB |
| UL94(3.0mm) | V-2 | V-0 |
As can be seen from the above table, in improved composition, added toughener SAN, made surface hardness be increased to HB, added flame retardant brominated polycarbonate and antimonous oxide, made flame retardant properties bring up to the V-0 level from the V-2 level of UL94 from B.
Embodiment three
This ABS hardening flame-proof modified composition comprises the component of following content:
ABS 80％；
SAN 9％；
CPE 3％；
AS-G-MAH 1％；
MBS 2％；
Brominated polycarbonate 4%;
Antimonous oxide 1%;
More than the percentage ratio of each component all be weight percent, the bromine content of brominated polycarbonate is 58%.
Before the modification and the performance index of the ABS resin material after the modification can be referring to following table:
| Before the modification | After the modification | |
| Impact property (KJ/M2) | 23.75 | 8.14 |
| Tensile property (Mpa) | 42 | 42.65 |
| Bending property (Mpa) | 60 | 66.31 |
| Surface hardness | B | HB |
| UL94(3.0mm) | V-2 | V-0 |
As can be seen from the above table, in improved composition, added toughener SAN, made surface hardness be increased to HB, added flame retardant brominated polycarbonate and antimonous oxide, made flame retardant properties bring up to the V-0 level from the V-2 level of UL94 from B.
Claims (5)
1, a kind of ABS hardening flame-proof modified composition, it comprises the component of following content:
Vinyl cyanide--divinyl--styrol copolymer 60-85%;
Chlorinatedpolyethylene 1-5%;
Acrylonitritrile-styrene resin grafted maleic anhydride 1-5%;
MBS 1-5%;
It is characterized in that: the component that also comprises following content in the said composition:
Styrene-acrylonitrile copolymer 8-25%;
Brominated polycarbonate 3-9%;
Antimonous oxide 1-5%;
More than the percentage ratio of each component all be weight percent.
2, ABS hardening flame-proof modified composition according to claim 1 comprises the component of following content:
Vinyl cyanide--divinyl--styrol copolymer 61.8%;
Chlorinatedpolyethylene 3%;
Acrylonitritrile-styrene resin grafted maleic anhydride 2%;
MBS 3%;
It is characterized in that: the component that also comprises following content in the said composition:
Styrene-acrylonitrile copolymer 23.2%;
Brominated polycarbonate 5%;
Antimonous oxide 2%;
More than the percentage ratio of each component all be weight percent.
3, ABS hardening flame-proof modified composition according to claim 1 comprises the component of following content:
Vinyl cyanide--divinyl--styrol copolymer 72.8%;
Chlorinatedpolyethylene 1%;
Acrylonitritrile-styrene resin grafted maleic anhydride 2%;
MBS 2%;
It is characterized in that: the component that also comprises following content in the said composition:
Styrene-acrylonitrile copolymer 18.2%;
Brominated polycarbonate 3%;
Antimonous oxide 1%;
More than the percentage ratio of each component all be weight percent.
4, ABS hardening flame-proof modified composition according to claim 1 comprises the component of following content:
Vinyl cyanide--divinyl--styrol copolymer 80%;
Chlorinatedpolyethylene 3%;
Acrylonitritrile-styrene resin grafted maleic anhydride 1%;
MBS 2%;
It is characterized in that: the component that also comprises following content in the said composition:
Styrene-acrylonitrile copolymer 9%;
Brominated polycarbonate 4%;
Antimonous oxide 1%;
More than the percentage ratio of each component all be weight percent.
5, according to claim 1,2,3 or 4 described ABS hardening flame-proof modified compositions, it is characterized in that: the bromine content of brominated polycarbonate is 58%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100344067A CN100528958C (en) | 2006-03-20 | 2006-03-20 | ABS hardening flame-proof modified formulation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100344067A CN100528958C (en) | 2006-03-20 | 2006-03-20 | ABS hardening flame-proof modified formulation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101041736A CN101041736A (en) | 2007-09-26 |
| CN100528958C true CN100528958C (en) | 2009-08-19 |
Family
ID=38807544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100344067A Expired - Fee Related CN100528958C (en) | 2006-03-20 | 2006-03-20 | ABS hardening flame-proof modified formulation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100528958C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8735490B2 (en) * | 2009-12-30 | 2014-05-27 | Cheil Industries Inc. | Thermoplastic resin composition having improved impact strength and melt flow properties |
-
2006
- 2006-03-20 CN CNB2006100344067A patent/CN100528958C/en not_active Expired - Fee Related
Non-Patent Citations (2)
| Title |
|---|
| ABS树脂的共混改性. 曾威.合成树脂及塑料，第16卷第6期. 1999 |
| ABS树脂的共混改性. 曾威.合成树脂及塑料，第16卷第6期. 1999 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101041736A (en) | 2007-09-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103421240B (en) | The square single-wall corrugated pipe material of a kind of electric power | |
| WO2008078406A1 (en) | Flame-retardant thermoplastic resin composition | |
| CN101313027A (en) | Use of a blend of phthalate plasticizers in poly(vinyl halide) compounds | |
| CN109265902B (en) | Flame-retardant ABS material and preparation method and application thereof | |
| CN101230188A (en) | Polycarbonate/acrylonitrile-butadiene-phenylethene copolymer alloy | |
| EP1917306A1 (en) | Flame retardant polymer compositions | |
| WO2000069961A1 (en) | Flame retardant resin composition | |
| TW200528545A (en) | Flame-retarded polystyrene resin compositions | |
| CN104086918A (en) | High-strength electric protecting tube | |
| CN103483690B (en) | A kind of modified polypropylene composite material | |
| JPS6127410B2 (en) | ||
| KR100932759B1 (en) | Flame retardant thermoplastic resin composition excellent in detergent resistance | |
| CN100528958C (en) | ABS hardening flame-proof modified formulation | |
| CN100471909C (en) | ABS hardening flame-proof modified composition | |
| CN105440503A (en) | Flame-retardant PVC waterproof coiled material | |
| CN101440212A (en) | Thermoplastic environment-protecting flame-retardant reinforced nylon 6 and nylon 66 alloy | |
| CN103319862A (en) | Halogen-free flame-retardant PBT/ASA (Polybutylece Terephthalate/Acrylonitrile-Styrene-Acrylate) alloy | |
| CN101096449B (en) | PC/ABS alloy material | |
| CN103059427A (en) | Flame-retardant polystyrene resin | |
| CN1479803A (en) | Flame retardant polypropylene resin composition | |
| CN102030966A (en) | Mineral filled flame-retardant ABS composite material and preparation method thereof | |
| CN111372991A (en) | Flame retardant poly (vinyl chloride) compounds | |
| JPH07122014B2 (en) | Flame-retardant rubber-modified styrene resin composition | |
| CN101519562B (en) | Flame-retardant protective coating for bromocarbon acrylic acid printed circuit and preparation method thereof | |
| KR100782701B1 (en) | Rubber modified styrenic flame retardant resin composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090819 Termination date: 20120320 |