Block-shaped soft magnetic alloy lamination element and manufacture method thereof
Technical field
The present invention relates to a kind of soft magnetic alloy lamination element, especially a kind of soft magnetic alloy lamination element and manufacture method of forming by multilayer magnetically soft alloy thin slice and binding agent thereof.
Background technology
Magnetically soft alloy is widely used in electromagnetism transform fields such as transformer core, inductor iron core, yoke.When magnetically soft alloy was applied to yoke, it mainly acts on was the conducting magnetic circuit.If yoke is operated in the stationary magnetic field, can make with the bulk magnetically soft alloy; If be operated in the alternating magnetic field, then need to use the lamination of sheet magnetically soft alloy, to reduce the eddy current of yoke inside.
Since yoke in magnetic circuit, play the control magnetic flux flow to, increase local magnetic flux density, prevent or reduce multiple effect such as leakage field, in recent years, the fast development of industries such as electric power, electronics, electromechanics has proposed more and more stricter requirement to yoke with magnetically soft alloy.For example, the design work rotating speed of many specific type of electric machines is up to tens thousand of rev/mins, and the changes of magnetic field frequency of stator and internal rotor reaches hundreds of hertz-tens thousand of hertz.Again for example, in MR imaging apparatus, use a large amount of magnetically soft alloys as yoke up and down between two magnetic poles, and yoke is operated in stationary magnetic field and the formed stack of the high-frequency alternating magnetic field magnetic field, the eddy current of yoke is one of key factor that influences image quality.In addition, electric meter, relay, electron detector, charged particle deflection system etc. also need high-quality yoke.
The traditional soft magnetic alloy of making yoke is silicon steel sheet and permalloy sheet.At first these alloy rollings are become the thin slice below 1 millimeter, show coating then, again large amount of thin sheets is piled up, welding or bonding, cutting and form big block element.But under the high-frequency work environment of mentioning in the above, the ordinary silicon steel disc is limit owing to rolling thickness, and eddy current loss is big, high can not the continuation of iron loss used, and must adopt ultra-thin silicon strip.But, on the one hand its magnetic property and imperfection, cost is very high on the other hand, against in the developing direction that reduces device cost.Permalloy is because the initial permeability height, coercive force is little, resistivity is bigger, and its processing thickness can be less than 0.01mm, therefore become one of candidate's magnetically soft alloy of yoke manufacturing, but because high magnetic conductance permalloy counter stress is very responsive, shear or traditional yoke manufacturing process such as punching press can influence very greatly to magnetism of material, permalloy makes by its yoke of making and does not have the price competitive advantage because of containing the mass expensive metallic nickel in addition.
Non-crystaline amorphous metal is the magnetically soft alloy of new generation of 20th century the eighties realization industrialization.This material is because of possessing processing thickness (about 0.03mm) and high resistivity (about 130 μ Ω cm as thin as a wafer, be more than the twice of silicon steel sheet and permalloy) and have good high frequency characteristics, especially high permeability and low eddy current loss have been widely used in iron cores such as range transformer, instrument transformer at present.20th century late nineteen eighties, nanometer crystal alloy has appearred again in the way by the non-crystaline amorphous metal heating crystallization, it has comprehensive magnetic characteristic almost best in all magnetically soft alloys, is used widely rapidly in fields such as high frequency transformers.
In the prior art, the amorphous nano peritectic alloy generally all uses in the mode of Wound core.Though also be cured in some cases and cut, only require the magnetic characteristic of element usually, and special machinery and electromagnetic propertys such as intensity, toughness, layer insulation are not explicitly called for.But,,, the mechanical strength and the toughness of element is had specific (special) requirements because yoke need fix through assembly process mostly if the amorphous nano peritectic alloy is applied to yoke.In addition, if yoke is operated in the high frequency magnetic field, also require element to have good layer insulation characteristic, with further inhibition eddy current.
Chinese patent application 99815455,01806129,01810721 and 01811986 has disclosed the method for making motor stator and MR imaging apparatus yoke with Fe-based amorphous alloy.Wherein, the application No.99815455 described have laminated construction, key component is Fe
80Si
11B
9The amorphous bulk element, its manufacture method comprises operations such as amorphous thin ribbon cutting, stacked, annealing, epoxy resin cure, shearings.Application No.01806129 and 01810721 has further proposed the claim of the core loss of the non-crystal cell of the block lamination of FeSiB under characteristic frequency and magnetic field.Application No.01811986 then attempts making lamination non-crystaline amorphous metal rod with the new technology of punching press, and drift and die tool adopt the carbide material of high rigidity during enforcement, has reduced the degree of wear of stamped workpieces well.
Yet,, unavoidably can cause the wearing and tearing of cutter and mould when shearing or punching because non-crystaline amorphous metal has high shear strength.Simultaneously, use common epoxy resin cure element after because the fragility of epoxy resin is bigger, cause whole element toughness deficiency, easily cracking even broken in cutting, assembling and use.Common in addition epoxy resin paint-dipping process can not effectively guarantee epoxy resin even coating between each lamella in element, can make element inner heat in alternating magnetic field thus, produces eddy current loss.
Summary of the invention
The purpose of this invention is to provide a kind of amorphous nano peritectic alloy lamination element and manufacture method thereof that has good magnetic characteristic and mechanical performance simultaneously.
Another object of the present invention provides a kind of dipping paint method and device thereof of block-shaped soft magnetic alloy lamination element, can realize the paint-dipping process of multiple function.
To achieve these goals, the invention provides following technical scheme:
A first aspect of the present invention has provided a kind of block-shaped soft magnetic alloy lamination element, by the soft magnetic alloy sheet-band and the adhesive mutually folded polyhedron formed of thickness less than 0.05 millimeter.The chemical composition of soft magnetic alloy sheet-band wherein (atomic percent) is: Fe
100-a-b-c-dSi
aB
bM
cM '
d, wherein, M is Co and/or Ni, M ' is at least a among C, Cu, V, Cr, Mn, Nb, Mo, Ta, W, the Au, wherein, 0≤a≤18,5≤b≤20,0≤c≤10,0≤d≤6.
The three-dimensional shape of this element is polygon cylinder, cylinder, curved surface cylinder, adhesive is epoxy resin and additive, additive is at least a in curing agent, flexibilizer, modifier, crosslinking agent, fire retardant, catalyst, the diluent, each soft magnetic alloy sheet-band lamination has at least a surface that area rubber cover stick more than 70% is arranged in the element, element along perpendicular to the tensile strength of lamination in-plane at least at 5.1kg/cm
2More than.
Another aspect of the present invention has provided a kind of manufacture method of block-shaped soft magnetic alloy lamination element, comprises the steps:
(a) utilize flash set technology to make the continuous strip of described alloy;
(b) alloy thin band is wound into the ring of preliminary dimension;
(c) alloy hoop with preliminary dimension is squeezed into piece with anchor clamps;
(d) alloy block is carried out the heat treatment of predetermined temperature and time;
(e) will be dipped in through heat treated alloy block and be optimized dipping lacquer in the adhesive solvent;
(f) will solidify 1~100 hour at 50~120 ℃ through the alloy block of adhesive dipping lacquer;
(g) alloy block that solidifies is cut into the lamination element of required form and size.
The chemical composition of wherein said alloy material (atomic percent) is: Fe
100-a-b-c-dSi
aB
bM
cM '
d, wherein, M is Co and/or Ni, M ' is at least a of C, Cu, V, Cr, Mn, Nb, Mo, Ta, W, Au, 0≤a≤18,5≤b≤20,0≤c≤10,0≤d≤6.
A third aspect of the present invention has provided a kind of dipping paint method of block-shaped soft magnetic alloy lamination element, adopts the insulation processing technology, comprises the steps:
(i) after the workpiece annealing that will be through being extruded to shape, be placed in the airtight impregnating vessel and prepare dipping lacquer;
(ii) the adhesive in the pressure volume pot is delivered to and finishes dipping lacquer in the impregnating vessel with gases at high pressure.
Dipping paint method adopts at least a in antivacuum dipping lacquer, vacuum paint dipping and the vacuum pressure impregnation.When described vacuum paint dipping, vacuum ranges is absolute pressure 5Torr~5 * 10
-2Torr.
During described pressure dipping lacquer, pressure limit is 760Torr~6 * 10
3Torr, the gas of employing are N
2, CO
2, in Ar, dry air and other the nontoxic gas any one, the time of keeping pressure is 10 minutes~10 hours with the size of workpiece and what.
A fourth aspect of the present invention has provided a kind of dipping lacquer device of block-shaped soft magnetic alloy lamination element, adopts the insulation processing technology, comprises with the lower part:
Pressure volume pot: be used to store adhesive;
High-pressure air source: pressure volume pot links to each other, and is used for by gases at high pressure adhesive being delivered to the workpiece impregnating vessel;
Impregnating vessel: pressure volume pot links to each other, and the dipping lacquer that is used to place the workpiece of preparation dipping lacquer processing and finish workpiece is handled.
In addition, this device also comprises the pumped vacuum systems that links to each other with the workpiece impregnating vessel, is used to control the vacuum degree of impregnating vessel inside.Described pressure volume pot links to each other with the import of the below of impregnating vessel.
Like this, according to the needs of practical application, alloy lamination of the present invention can present multiple three-dimensional shape, such as polygon cylinder, cylinder, curved surface cylinder etc.Be different from the employed preparation method of above prior art, the present invention has presented a kind of manufacture method of novelty, when alloy lamination bar that the method makes is keeping good dynamic magnetic characteristic, embody its tensile strength emphatically and can reach 5.1kg/cm at least
2(0.5Mpa).
In an embodiment of the present invention, block-shaped soft magnetic alloy lamination element forms the three-dimensional structure that multiple three-dimensional shape is polygon cylinder, cylinder, curved surface cylinder etc. by the neat stacking of the amorphous thin ribbon that is about 0.025mm, forms with composite adhesive solidifications of other additive such as modified epoxy and crosslinking agent, fire retardant, catalyst, diluents between the lamination.Described preparation technology can also comprise multiple autotelic high-temperature annealing process, reaching amorphous bulk nano-crystallization and to improve multiple purposes such as element magnetic characteristic, the element magnetic characteristic that wherein is enhanced comprises the dynamic magnetic characteristic of direct current magnetic characteristics such as high magnetic permeability and high saturation flux density and low core loss.
Compared with prior art, the technical scheme that obtains of the present invention has the following advantages: manufacturing process is more reasonable; The area on surface 70%~90% is coated with adhesive between lamination, and element stretch-proof ability is strong; Get final product completion of cure under the condition low behind the element dipping lacquer, that the time is short in curing temperature.
Brief Description Of Drawings
Figure 1A is to be the lamination element of cuboid according to the three-dimensional shape that manufacture method of the present invention is made;
Figure 1B is to be cylindrical lamination element according to the three-dimensional shape that manufacture method of the present invention is made;
Fig. 1 C is to be the lamination element of octahedra cylinder according to the three-dimensional shape that manufacture method of the present invention is made;
Fig. 1 D is to be the lamination element of anchor ring otch cylinder according to the three-dimensional shape that manufacture method of the present invention is made;
Fig. 1 E is to be the lamination element of curved surface cylinder according to the three-dimensional shape that manufacture method of the present invention is made;
Fig. 2 is the iron core alloy hoop of winding is extruded to shape into reservation shape with anchor clamps a schematic diagram;
Fig. 3 is the multi-functional paint-dipping process system that uses among the present invention.
Embodiment
The invention will be further described below in conjunction with drawings and Examples, but this explanation does not limit the scope of application of the present invention.
The amorphous nano peritectic alloy lamination element that the present invention spoke of, needs according to practical application, can present multiple three-dimensional shape, such as polygon cylinder, cylinder, curved surface cylinder etc., by the yoke that these amorphous nano peritectic alloy lamination elements are made, can be used as control magnetic flux flow in the systems such as two magnetic poles up and down in the stator of many pot motors and rotor, the MR imaging apparatus and electric meter, relay, electron detector, charged particle deflector to, increase the soft iron of the formation magnetic circuit of local magnetic flux density.Yoke usually is operated in the internal magnetic field change frequency and reaches hundreds of hertz in tens thousand of hertz magnetic field, and this applying working condition requires element to have good layer insulation characteristic, to reduce eddy current loss.Simultaneously since the preparation of traditional yoke mostly need through assembly operations such as extruding, fixing, welding or bonding, punching press or shearings, the mechanical strength of yoke and the quality of toughness also can be to very big to its magnetic property influence, thereby have a strong impact on the work quality of use equipment, therefore must be to the processing and preparing of yoke, particularly the dipping lacquer of lamination element being handled to have specific (special) requirements, to reduce the stress sensitivity of element as far as possible.The present invention for seeking the overall target of high-insulativity and high mechanical properties between element layer, has designed new block-shaped soft magnetic alloy lamination element preparation method just.
Figure 1A-Fig. 1 E is the block lamination example that utilizes prepared of the present invention to go out.According to actual needs, the polygon lamination can also through different annealing (as be lower than Curie temperature or be higher than Curie temperature, under the transverse magnetic or under vertical magnetic field) make the amorphous or the nanocrystalline lamination of different magnetic properties.The present invention can also utilize accurate cutting and grinding technology to be cut into anchor ring otch cylinder as Fig. 1 D, also can utilize the curved surface typified form to add accurate cutting and grinding technology and make curved surface cylinder as Fig. 1 E.Need to prove that the various laminations of Fig. 1 demonstration do not limit coverage of the present invention.
Lamination element in the previous patent prepares the square lamination of attitude amorphous thin ribbon cut growth of normally will quenching earlier, these preliminary working laminations neatly pile block stereochemical structure then, make female lamination element through annealing and dipping lacquer curing process again, after various cutting technique is made difform block lamination yoke element.But, there are a lot of flaws in the traditional preparation process technology, for example, the lamination preparation needs the cutting preliminary working, has increased a cutting action and has equaled to increase the influence of surface stress to lamination magnetic; Have, common epoxy resin paint-dipping process can not effectively guarantee epoxy resin even coating between each lamella in element, can make element inner heat in alternating magnetic field thus again, produces eddy current loss; After using common epoxy resin cure element in addition,, cause whole element toughness deficiency, easily cracking even broken in cutting, assembling and use subsequently because the fragility of epoxy resin is bigger.The present invention tries hard to abandoning tradition preparation technology's drawback, adopts more reasonable method to prepare each class component shown in Figure 1.Fig. 2 is the present invention and prepares one of unique distinction of lamination element, promptly directly the iron core alloy hoop 10 usefulness anchor clamps 20 of the suitable dimension of winding are extruded to shape into reservation shape, use a plurality of bolt 30 symmetries fastening then, anchor clamps 20 are plane high-strength panels among Fig. 2, but this explanation does not limit the shape of employed anchor clamps 20 among the present invention, according to the appearance requirement of the curved surface cylinder of Fig. 1 E, anchor clamps 20 can also present the different curve shape.Described typing workpiece can carry out various annealing processs by actual demand to be handled, so that improving the magnetic property of element.
The present invention also provides a kind of multi-functional workpiece dipping lacquer processing method, specifically, is after the workpiece annealing that is extruded to shape shown in Figure 2, can carry out different dipping lacquer process operations according to actual needs in identical dipping lacquer processing unit.Figure 3 shows that the multi-functional dipping lacquer processing unit that uses among the present invention, this device is made of four parts generally, i.e. high-pressure air source 40, pressure volume pot 50 (being used for adhesive stores), workpiece impregnating vessel 60 and pumped vacuum systems 70.Handle if carry out common normal pressure dipping lacquer, then close pumped vacuum systems 70, with high-pressure air source 40 mesohigh gases the adhesive liquid in the pressure volume pot 50 is headed in the impregnating vessel 60, till workpiece 65 is soaked in submergence.Gases at high pressure can be N
2, CO
2, a kind of in any nontoxic gas such as Ar or dry air.Handle if carry out vacuum paint dipping, then impregnating vessel 60 will be closed overhead-valve 62 after being soaked workpiece putting into, and opens pumped vacuum systems 70 before the dipping lacquer earlier, and impregnating vessel 60 is evacuated to absolute pressure in 5Torr~5 * 10
-2In the Torr scope, be placed on workpiece on the carriage and both can before vacuumizing, have soaked, also can by outside transmission facility 63 workpiece be put into lacquer liquid 66 times vacuumizing the back adhesive liquid level 66 times.
For further strengthening the dipping lacquer treatment effect, the multi-functional paint-dipping process system that the present invention uses can also carry out vacuum pressure impregnation and handle, as shown in Figure 3, after impregnating vessel 60 vacuum degrees meet the demands, when closing pumped vacuum systems 70, open pressure volume pot 50 and related valve, utilize the high pressure dry gas that adhesive solvent is headed into impregnating vessel 60 from bottom to top until the submergence workpiece, the pressurization scope of the present invention's control is in 760Torr~6 * 10
3Between the Torr, the time of keeping pressure can be 10 minutes to 10 hours with the size of workpiece and what.The data of embodiment 1 show that vacuum pressure impregnation further promotes adhesive to clamp-on between the lamination of workpiece, has improved laminate surface adhesive coverage rate.
Dipping lacquer lamination element normal pressure in impregnating vessel drips lacquer a period of time, ooze unnecessary adhesive liquid on the workpiece, be placed in the curing oven then, because the adhesive that uses among the present invention comprises a small amount of special curing catalysts composition, so the dipping lacquer lamination element can solidify under 50~120 ℃ relatively lower temp and both can dry in 1~100 hour among the present invention.The alloy block that is cured cuts into as shown in Figure 1 various lamination elements by required form and size.
Dipping lacquer lamination element among the present invention presents outstanding mechanical performance through optimizing paint-dipping process, and according to GB GB/T4944-1996 examination criteria regulation, the tensile strength of lamination element can reach 5.1kg/cm at least
2(0.5Mpa), the break surface that draws back has the area rubber cover stick more than 70~90%.
In order further to understand the invention process effect, adopt the amorphous and the nanocrystalline lamination element of the present invention's preparation below, according to the different paint-dipping process of similar elements composition, different elements composition but same paint-dipping process, different annealing conditions etc. are specifically introduced two embodiment, wherein the chemical composition of selected soft magnetic alloy sheet-band (atomic percent) is: Fe
100-a-b-c-dSi
aB
bM
cM '
d, wherein, M is Co and/or Ni, M ' is at least a among C, Cu, V, Cr, Mn, Nb, Mo, Ta, W, the Au, 0≤a≤18,5≤b≤20,0≤c≤10,0≤d≤6.Only as understanding the effect that this patent is implemented, these statements do not constitute the restriction to invention scope in the statement that material, technical conditions and data gather among the embodiment.
The preparation and the performance test of the lamination element of the different paint-dipping process of embodiment 1 identical component
The Fe that approximately 100mm is wide, 0.025mm is thick
80Si
9B
11Amorphous alloy ribbon makes with traditional fast quenching solidifying process (single roller quench), will prepare attitude strip coiled internal diameter 63.66mm, external diameter 119.56mm, twine about 800 the circle annular core, temperature is a room temperature, pressure is 1-2kg/cm
2The annular core of winding is extruded to shape into flat pattern with anchor clamps 20 as shown in Figure 2, is extruded to shape and at room temperature finishes, and pressure is 1-2kg/cm
2Use a plurality of bolt 30 symmetries fastening then, fastening good iron core carrying jig is heat-treated, and 360~380 ℃ of treatment temperatures are incubated 1.5 hours, to eliminate the influence of machining stress to element function, also does the preliminary drying dehumidifying preparation of workpiece simultaneously for paint-dipping process.Cooling back workpiece is placed into shown in Figure 3 multi-functional paint-dipping process system immediately after laying down fastening clips, selected workpiece is divided into three parts, carries out antivacuum dipping lacquer, vacuum paint dipping and vacuum pressure impregnation PROCESS FOR TREATMENT respectively.
Before just vacuumizing, done present embodiment the dipping lacquer experiment of different vacuum respectively with the method that vacuumizes back submergence workpiece, also under different vacuum and pressure, carried out simultaneously the vacuum pressure impregnation experiment respectively, the lamination element that finally machines is according to GB GB/T4944-1996 tensile strength examination criteria, carried out the tensile strength test, test result is in conjunction with the maximum coverage rate of laminate surface with in room temperature, 1000Hertz, the core loss value under the 0.1Tesla condition is summarised in the table 1.As described in Table 1, can reach optimum mechanical strength and dynamic magnetic performance through the element of vacuum pressure impregnation technology gained.
Table 1 Fe
80Si
9B
11Lamination element is through finished product tensile strength, surface coverage and the iron loss contrast table of different paint-dipping process
Sequence number |
Paint-dipping process |
Tensile strength Kg/cm
2 |
Laminate surface coverage rate (%) |
Iron loss P
10kHz/0.1T(W/kg)
|
1 |
The normal pressure dipping lacquer |
5.25 |
70 |
5.95 |
2 |
Vacuum paint dipping (workpiece is immersed in the lacquer liquid and vacuumizes) vacuum degree: 2 * 10
-1Torr
|
6.37 |
75 |
5.48 |
3 |
Vacuum paint dipping (workpiece is immersed in the lacquer liquid and vacuumizes) vacuum degree: 4.2 * 10
-1Torr
|
6.69 |
75 |
4.9 |
4 |
Vacuum paint dipping (workpiece vacuumizes before being immersed in lacquer liquid) vacuum degree: 2 * 10
-2Torr
|
7.78 |
80 |
4.9 |
5 |
Vacuum paint dipping (workpiece vacuumizes before being immersed in lacquer liquid) vacuum degree: 4.5 * 10
-2Torr
|
8.45 |
82 |
4.696 |
6 |
Vacuum pressure impregnation (vacuum degree: 4.4 * 10
-2Torr, pressure 1.5 * 10
3Torr)
|
9.12 |
85 |
4.37 |
7 |
Vacuum pressure impregnation (vacuum degree: 4.6 * 10
-2Torr, pressure 2 * 10
3Torr)
|
9.27 |
88 |
4.229 |
8 |
Vacuum pressure impregnation (vacuum degree: 4.8 * 10
-2Torr, pressure 3 * 10
3Torr)
|
9.96 |
88 |
4.25 |
9 |
Vacuum pressure impregnation (vacuum degree: 4.8 * 10
-2Torr, pressure 4 * 10
3Torr)
|
10.1 |
90 |
4.106 |
10 |
Vacuum pressure impregnation (vacuum degree: 4.8 * 10
-2Torr, pressure 4.5 * 10
3Torr)
|
10.2 |
91 |
4.12 |
Embodiment 2 heterogeneities but lamination element performance test that same paint-dipping process is prepared
With fast solidification technology (single roller quench) the preparation amorphous band that about 100mm is wide, 0.025mm is thick.Amorphous band is Fe
100-a-b-c-dSi
aB
bM
cM '
d, wherein, M is Co and/or Ni, M ' is at least a among C, Cu, V, Cr, Mn, Nb, Mo, Ta, W, the Au, 0≤a≤18,5≤b≤20,0≤c≤10,0≤d≤6., with the heterogeneity strip coiled internal diameter 63.66mm of preparation attitude, external diameter 119.56mm twines about 800 annular cores that enclose, and the heat treatment under different annealing conditions as required of anchor clamps typing each workpiece of back is to form amorphous and nanocrystalline semi-finished product.Last under identical vacuum pressure impregnation condition (vacuum degree: 4.8 * 10
-2Torr, pressure 4.5 * 10
3Torr) the workpiece dipping lacquer in multi-functional paint-dipping process system after all annealing, after curing is finished, lamination element is according to GB GB/T4944-1996 tensile strength examination criteria, carried out the tensile strength test, as embodiment 1, test result is in conjunction with the maximum coverage rate of laminate surface with in room temperature, and the core loss when 1000Hertz, the magnetic induction of 0.1Tesla magnetic field is summarised in the table 2.
Finished product tensile strength, surface coverage and the iron loss contrast table of table 2 heterogeneity lamination element behind vacuum pressure impregnation
Sequence number |
Chemical composition |
Annealing conditions |
Microstructure (℃/h) |
Hot strength Kg/cm
2 |
Surface coverage (%) |
Iron loss P
10kHz/0.1T(W/kg)
|
1 |
Fe
80Si
9B
11 |
370℃/1.5h |
Amorphous |
10.1 |
88 |
4.12 |
2 |
Fe
80Si
9B
10C
|
370℃/1h |
Amorphous |
10.1 |
90 |
4.755 |
3 |
Fe
73.5Cu
1Ta
2Si
14.5B
9 |
375℃/1.5h |
Amorphous |
9.8 |
86 |
4.71 |
4 |
Fe
72Cu
1V
6Si
14B
7 |
375℃/1.5h |
Amorphous |
9.75 |
88 |
4.455 |
5 |
Fe
72Cu
1.5Mo
6Si
14B
6.5 |
375℃/1.5h |
Amorphous |
10 |
90 |
4.914 |
6 |
Fe
72Cu
4Nb
2Cr
2Si
14B
6 |
375℃/1.5h |
Amorphous |
9.54 |
85 |
4.725 |
7 |
Fe
72Cu
4W
3Si
14B
7 |
375℃/1.5h |
Amorphous |
9.82 |
90 |
5.01 |
8 |
Fe
72Cu
4Nb
2Mn
2Si
14B
6 |
375℃/1.5h |
Amorphous |
9.98 |
90 |
4.26 |
9 |
(Fe
0.8Ni
0.2)
78Cu
1Nb
3Si
9B
9 |
380℃/1h |
Amorphous |
9.65 |
86 |
4.72 |
10 |
(Fe
0.8Co
0.2)
73.7Cu
0.8Nb
3Si
13.5B
9 |
380℃/1h |
Amorphous |
9.69 |
86 |
4.91 |
11 |
Fe
72.3Au
0.7Nb
2.5Mo
0.5Si
16B
8 |
380℃/1h |
Amorphous |
10 |
90 |
4.416 |
12 |
(Fe
0.8Co
0.1Ni
0.1)
73.5Cu
1Nb
3Si
13.5B
9 |
380℃/1h |
Amorphous |
9.57 |
86 |
4.91 |
13 |
Fe
80Si
9B
11 |
550℃/0.5h |
Nanocrystalline |
6.68 |
90 |
2.231 |
14 |
Fe
73.5Cu
1Ta
2Si
14.5B
9 |
545℃/0.5h |
Nanocrystalline |
7.32 |
86 |
2.534 |
15 |
Fe
72Cu
1.5Mo
6Si
14B
6.5 |
545℃/0.5h |
Nanocrystalline |
7.58 |
86 |
2.496 |
16 |
Fe
72Cu
4W
3Si
14B
7 |
545℃/0.5h |
Nanocrystalline |
7.33 |
88 |
2.390 |
17 |
Fe
72Cu
4Nb
2Mn
2Si
14B
6 |
545℃/0.5h |
Nanocrystalline |
6.52 |
90 |
2.912 |
18 |
(Fe
0.8Ni
0.2)
78Cu
1Nb
3Si
9B
9 |
540℃/0.5h |
Nanocrystalline |
6.57 |
90 |
2.011 |
19 |
(Fe
0.8Co
0.2)
73.7Cu
0.8Nb
3Si
13.5B
9 |
540℃/0.5h |
Nanocrystalline |
7.05 |
88 |
2.892 |
20 |
Fe
72.3Au
0.7Nb
2.5Mo
0.5Si
16B
8 |
540℃/0.5h |
Nanocrystalline |
7.40 |
85 |
2.266 |
Comparative example |
Fe
73.5Si
13.5Nb
3B
9Cu
1 |
540℃/0.5h |
Nanocrystalline |
7.32 |
86 |
2.530 |
Must emphasize that the concrete enforcement of this patent need not to be subjected to the specification specified of above embodiment to limit, can in claims limited range of the present invention, make various changes and improvements when association area research staff specifically implements.