CN100463956C - Fabric care compositions having reduced fabric abrasion - Google Patents

Fabric care compositions having reduced fabric abrasion Download PDF

Info

Publication number
CN100463956C
CN100463956C CNB998127973A CN99812797A CN100463956C CN 100463956 C CN100463956 C CN 100463956C CN B998127973 A CNB998127973 A CN B998127973A CN 99812797 A CN99812797 A CN 99812797A CN 100463956 C CN100463956 C CN 100463956C
Authority
CN
China
Prior art keywords
composition
weight
fabric
polymkeric substance
preferred
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB998127973A
Other languages
Chinese (zh)
Other versions
CN1325433A (en
Inventor
S·G·P·R·考夫贝尔格斯
R·A·A·瑟勒曼斯
N·J·戈尔顿
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Ltd
Procter and Gamble Co
Original Assignee
Procter and Gamble Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Ltd filed Critical Procter and Gamble Ltd
Publication of CN1325433A publication Critical patent/CN1325433A/en
Application granted granted Critical
Publication of CN100463956C publication Critical patent/CN100463956C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/365—Organic compounds containing phosphorus containing carboxyl groups

Abstract

The present invention relates to fabric enhancement compositions which provide reduced fabric abrasion damage. The compositions of the present invention comprise: a)one or more fabric abrasion polymers, said polymers comprising the following units: i)at least one monomeric unit comprising an amide moiety; ii)at least one monomeric unit comprising an N-oxide moiety; or iii)a polymer which contains at least one monomeric unit comprising an amide moiety and at least one monomeric unit comprising an N-oxide moiety; and b)the balance carriers and fabric conditioning or fabric enhancement ingredients.

Description

Has the Fabrid care composition that reduces fabric abrasion
The cross reference of related application
The rights and interests of the U.S. Provisional Application that the application requires to submit on November 2nd, 1998 U.S. Provisional Application is submitted to number on November 30th, 60/106,759 and 1998 number 60/110,310.
Invention field
The present invention relates to provide fabric to strengthen the Fabrid care composition that benefit can reduce fabric abrasion simultaneously again.Composition of the present invention comprises one or more polymkeric substance that can reduce fabric abrasion and can provide benefit for the human consumer, particularly other composition of fabric-softening, antistatic, fixation etc.
Background of invention
The home treated of fabric prescription teacher to laundry composition in present technique is known problem.Therefore, well-known, change fabric and textiles as the use of articles for use such as the clothes worn and clothes and wash(ing)cycle producing detrimentally affect to the fabric that so uses and wash and the outward appearance and the integrity of textiles.Fabric and textiles are along with time and use can wear away.In order to remove in the normal use in the fabric and textiles or the dirt and the stain of accumulation on it must wash it.Yet washing operation itself can damage and increase the weight of to damage the integrity and the outward appearance of this fabric and textiles through many all after dates.
The damage of fabric integrity and outward appearance can show as some kinds of modes.Mechanical effect during laundry can make the staple fibre on weaving or the knitting fabric/textile works split away off.These fibers that split away off may form observable velveteen, fine hair or " bobbles " on fabric face, thereby reduce the new outward appearance of fabric.Problem through fabric abrasion after wash(ing)cycle repeatedly can be even more serious.
All feeling for a long time to need to provide provide protection to prevent the composition of fabric abrasion to fabric.In addition, also feel for a long time the composition that can compensate fabric abrasion need be provided.
Summary of the invention
The present invention has satisfied the demand, and its reason is now to be surprised to find some high-molecular weight polymer that contains amide units, N-oxide unit or its mixture and can be used for providing fabric abrasion minimizing effect, i.e. fabric anti-attrition effect.Polymkeric substance of the present invention is described as " fabric anti-attrition polymkeric substance " here, can reduce the loss amount that fabric is subjected in the time of on being applied to fabric.Surprisingly, fabric anti-attrition polymkeric substance of the present invention contains one or more unit, and these unit can also provide the benefit that suppresses dye transfer except fabric anti-attrition benefit can be provided.Therefore, polymkeric substance of the present invention mainly has fabric anti-attrition benefit, preferably also has the benefit that suppresses dye transfer simultaneously.
First aspect of the present invention relates to Fabrid care composition, wherein comprises:
A) from about 0.01%, preferably from about 0.1% to about 20%, preferably to the fabric anti-attrition polymkeric substance of about 10% weight, described fabric anti-attrition polymkeric substance comprises:
I) at least a monomeric unit that contains amide moieties;
The ii) at least a monomeric unit that contains N-oxide compound part;
Iii) and their mixture; With
B) carrier of remaining sum and supplementary component;
Condition is that the molecular weight of described fabric anti-attrition polymkeric substance is greater than 100,000 dalton.
The invention further relates to Fabrid care composition, said composition comprises:
A) from about 0.01%, preferably from about 0.1% to about 20%, preferably to the fabric anti-attrition polymkeric substance of about 10% weight, described fabric anti-attrition polymkeric substance comprises:
I) at least a monomeric unit that contains amide moieties;
The ii) at least a monomeric unit that contains N-oxide compound part;
Iii) and their mixture;
B) randomly, preferred about 10% from about 1%, more preferably from about 20% to about 80%, preferably to about 60%, more preferably to the fabric softener of about 45% weight;
C) randomly, be less than the basic solvent of about 15% weight, the ClogP of preferred described solvent is about 0.15～about 1;
D) randomly, one or more laking agent of about 0.001%～about 90% weight;
E) randomly, one or more cellulose reactive laking agent of about 0.01%～about 50% weight;
F) randomly, the chlorine scavenger of about 0.01%～about 15% weight;
G) randomly, one or more crystal growth inhibitors of about 0.005%～about 1% weight;
H) randomly, one or more liquid vehicles of about 1%～about 12% weight;
I) randomly, the enzyme of about 0.001%～about 5% weight;
J) randomly, the polyolefin emulsion or the suspension of about 0.01～about 8% weight;
K) randomly, a kind of stablizer of about 0.01～about 0.2% weight;
L) randomly, a kind of cats product of about 0.5%～about 5% weight;
M) randomly, one or more of about 0.01%～about 50% weight can provide the line style or the cyclic polyamine of bleaching provide protection; With
O) carrier of remaining sum and supplementary component;
Condition is that the molecular weight of described fabric anti-attrition polymkeric substance is greater than 100,000 dalton.
The present invention relates to belong to the fabric-conditioning compositions of laundry detergent composition, drip washing adding and the composition of the dry fabric-conditioning compositions that adds.
The present invention also relates to fabric provides the method that reduces fabric abrasion, described method comprises the step that the composition that makes the described fabric fabric anti-attrition polymkeric substance described here with containing 0.01% weight of having an appointment contacts.
To those skilled in the art, below having read be described in detail with appending claims after, these purposes and some other purpose, characteristics and advantage will become very clear.
All percentage ratios, ratio and ratio all refer to weight at this except as otherwise herein provided.Unless otherwise prescribed, otherwise all temperature all refer to degree centigrade (℃).The equal symbolic animal of the birth year of all documents of quoting is closed part, incorporates this paper into as a reference.
Detailed Description Of The Invention
The present invention relates to some and can reduce fabric abrasion and composition that can the reinforced fabric outward appearance on being applied to fabric the time.These benefits are provided by wonderful discovery, and described discovery is that some polymkeric substance that contains acid amides or N-oxide compound functional unit has the benefit of fabric anti-attrition.Surprisingly, find yet that these unit can also provide additional benefit, promptly suppress dye transfer.Therefore, composition of the present invention can not only provide fabric to damage the benefit that reduces and the fabric color fidelity can also be provided.
Fabrid care composition of the present invention comprises one or more fabric anti-attrition polymkeric substance described here.For the present invention, the term " fabric " care composition " be defined as " a kind of composition that nursing role can be provided for fabric, its non-limitative example comprises laundry detergent composition, independence (stand-alone) composition, detergent additives, fabric softening compositions, particularly the softening compositio of drip washing adding, the dry softening compositio that adds ".Composition of the present invention provides effective fabric anti-attrition effect.Term " effectively fabric anti-attrition effect " is defined as " fabric of crossing with compositions-treated described here has the outward appearance of improvement for the fabric of compositions-treated described here of no use " here.Narrate key element required for the present invention below.
Fabric anti-attrition polymkeric substance
It is about 0.01% that composition of the present invention comprises, and preferred about 0.1% to about 20%, the fabric anti-attrition polymkeric substance of preferred about 10% weight.
Preferred anti-attrition polymkeric substance of the present invention is a water-soluble polymers.For the present invention, term " water-soluble " is defined as " at 25 ℃ of a kind of transparent isotropic liquids of polymer formation that are dissolved in the water with 0.2% weight or level still less ".
Can be used for fabric anti-attrition polymkeric substance of the present invention and have following general formula:
[-P(D) m-] n
Wherein unit P is the polymer backbone that contains homopolymer unit or copolymer unit.The D unit defines hereinafter.For the present invention, term " homopolymer " is defined as " the polymkeric substance bone Ke that is made of the unit with same unit composition, the i.e. polymer backbone that is formed by the same monomer polymerization ".For the present invention, term " multipolymer " is defined as " polymer backbone that is made of the unit with different units composition, the i.e. polymer backbone that is formed by two or more monomer polymerizations ".
The P skeleton preferably comprises the unit with following general formula:
-[CR 2-CR 2]-or-[(CR 2) x-L]-
Wherein each R unit is hydrogen, C independently 1-C 12Alkyl, C 6-C 12Aryl, and D unit as described below, preferred C 1-C 4Alkyl.
Each L unit is independently selected from and contains heteroatomic part, and its nonrestrictive example is selected from one group that is made up of following:
Figure C99812797D00071
Polysiloxane with following formula:
Figure C99812797D00081
Wherein index p is 1～about 6; Have dye transfer and suppress active unit:
Figure C99812797D00082
And their mixture, wherein R 1Be hydrogen, C 1-C 12Alkyl, C 6-C 12Aryl, and composition thereof.R 2Be C 1-C 12Alkyl, C 1-C 12Alkoxyl group, C 6-C 12Aryloxy, and composition thereof, preferable methyl and methoxyl group.R 3Be hydrogen, C 1-C 12Alkyl, C 6-C 12Aryl, and composition thereof, preferred hydrogen or C 1-C 4Alkyl, more preferably hydrogen.R 4Be C 1-C 12Alkyl, C 6-C 12Aryl, and composition thereof.
Fabric anti-attrition polymer backbone of the present invention comprises one or more and contains the unitary D unit that one or more can provide inhibition dye transfer benefit.This D unit can be the part of the skeleton represented as following general formula itself:
[-P(D) m-] n
Perhaps this D unit can be incorporated in the skeleton as having for example side group of the skeleton unit of following formula:
Figure C99812797D00083
Or
Figure C99812797D00084
But the unitary number of D depends on this prescription.For example, the unitary number of D should be regulated to such an extent that can make polymkeric substance have water-soluble and any optional dye transfer inhibition effect, the polymkeric substance that can obtain having fabric anti-attrition performance again simultaneously.The molecular weight of fabric anti-attrition polymkeric substance of the present invention is from about 500, and is preferred about 1000, more preferably from about 100,000, most preferably from about 160,000 to about 6,000,000, preferably to about 2,000,000, more preferably to about 1,000,000, more more preferably to about 500,000, most preferably to about 360,000 dalton.Therefore the value of index n should be selected to such an extent that pointed molecular weight can be provided, and can be provided under the room temperature that is defined as 25 ℃ here simultaneously, and the water solubility in water is 100ppm at least, preferably at least about 300ppm, and more preferably at least about 1,000ppm.
The unitary polymkeric substance of amide containing
The preferred unitary non-limitative example of D is the D unit that contains amide moieties.Wherein amide units comprises by the example that side group is incorporated into the polymkeric substance in the polymkeric substance:
Polyvinylpyrolidone (PVP) shown in the following formula:
Ju Yi Xi oxazolidinone shown in the following formula:
Figure C99812797D00092
Ju vinyl methyl oxazolidinone shown in the following formula:
Figure C99812797D00093
The polyacrylamide that polyacrylamide shown in the following formula and N-replace:
Figure C99812797D00101
Wherein each R ' is hydrogen, C independently 1-C 6Alkyl, perhaps 2 R ' unit can lump together and form 1 ring that contains 4-6 carbon atom;
The PMAm that PMAm shown in the following formula and N-replace:
Figure C99812797D00102
Wherein each R ' is hydrogen, C independently 1-C 6Alkyl, perhaps 2 R ' unit can lump together and form 1 ring that contains 4-6 carbon atom;
Poly-(N-acryl G-NH2) shown in the following formula:
Figure C99812797D00103
Wherein each R ' is hydrogen, C independently 1-C 6Alkyl, perhaps 2 R ' unit can lump together and form 1 ring that contains 4-6 carbon atom;
Poly-(N-methacryloyl G-NH2) shown in the following formula:
Figure C99812797D00104
Wherein each R ' is hydrogen, C independently 1-C 6Alkyl, perhaps 2 R ' unit can lump together and form 1 ring that contains 4-6 carbon atom;
Polyurethane vinyl acetate shown in the following formula:
Figure C99812797D00111
Wherein each R ' is hydrogen, C independently 1-C 6Alkyl, perhaps 2 R ' unit can lump together and form 1 ring that contains 4-6 carbon atom.
The unitary example of D that nitrogen-atoms during wherein dye transfer suppresses partly is incorporated into polymer backbone is poly-(the 2-ethyl-2-oxazoline) shown in the following formula:
Figure C99812797D00112
Wherein index n represents the number of existing monomer residue.
Fabric anti-attrition polymkeric substance of the present invention can contain can provide any dye transfer with suitable performance product to suppress unitary mixture.The preferred polymers that contains the D unit and be amide moieties be the nitrogen-atoms height of its amide units be substituted so that these nitrogen-atoms by around non-polar group effectively be shielded in various degree those compounds.This just provides the polymkeric substance with amphiphilic nature.Its non-limitative example comprises Polyvinylpyrolidone (PVP), Ju Yi Xi oxazolidinone, N, and N-two replaces polyacrylamide and N, and N-two replaces PMAm.About the details of physicochemical property of this base polymer of a part can be consulted " water-soluble synthetic polymer: character and behavior ", Philop Molyneux, volume I, CRC press (1983) incorporates this paper into as a reference.
The polymkeric substance of amide containing can exist with partial hydrolysis and/or cross-linked form.Can be used for preferred polymers of the present invention is Polyvinylpyrolidone (PVP) (PVP).This polymkeric substance has amphiphilic nature, contains the high polarity amide group of giving its wetting ability and polar attraction, also contains on skeleton and/or in the ring and gives its hydrophobic nonpolar methylene radical and methyne.These rings also can be provided at the planar alignment that has aromatic nucleus in the dye molecule.PVP is soluble in water-based system and organic solvent system.PVP can be available from ISP company, Wayne, and New Jersey, and BASF AG, Parsippany, the New Jersey is Powdered, or aqueous solution form has several viscosity grades, and the trade mark is for example K-12, K-15, K-25 and K-30.The viscosity-average molecular weight that the K-value representation is as follows:
Figure C99812797D00121
PVP K-12, K-15 and K-30 also can be available from Polyscience companies, Warrington, and the Pennsylvania, PVP K-15, K-25 and K-30 and poly-(2-ethyl-2-oxazoline) can be available from Aldrich chemical company, Milwaukee, Wisconsin.PVP K30 (40,000) also can be available from BASF AG to K90 (360,000), and its commodity are called Luviskol, or available from ISP company, high-molecular weight PVP more, and as available from Aldrich company, PVP 1.3MM also is applicable to the present invention.Be applicable to that other PVP section bar material of the present invention is the multipolymer of vinyl pyrrolidone/dimethylaminoethyl methacrylate, can be quaternary ammonium form available from ISP company, commodity are by name
Figure C99812797D00122
Or available from Aldrich chemical company, molecular weight is about 1.0MM; The multipolymer of vinyl pyrrolidone/vinyl-acetic ester can be available from BASF AG, and commodity are by name Vinyl pyrrolidone: vinyl-acetic ester is 3:7～7:3.
The polymkeric substance that contains the N-oxide unit
The another kind of D unit that can provide dye transfer to suppress booster action for fabric anti-attrition polymkeric substance described here is the N-oxide unit shown in the following formula:
Figure C99812797D00124
R wherein 1, R 2And R 3It can be any alkyl unit (for the present invention, term " alkyl " does not comprise independent hydrogen atom).This N-oxide unit can be a polymkeric substance, as polyamine, i.e. and the part of polyalkylene amine skeleton, perhaps this N-oxide compound can be the part that is connected to the side group on the polymer backbone.Containing the N-oxide unit is polyethylene imine based N-oxide compound as an example of the polymkeric substance of the part of polymer backbone.The non-limitative example that can contain the group of N-oxide compound part comprises some heterocycle, particularly pyridine, pyrroles, imidazoles, pyrazoles, pyrazine, pyrimidine, pyridazine, piperidines, tetramethyleneimine, pyrrolidone, tetramethyleneimine (azolidine) and morpholine.Preferred polymkeric substance be poly-(4-vinylpridine N-oxide compound, PVNO).In addition, the N-oxide unit can be the side group of ring, for example aniline N-oxide compound.
The amine nitrogen of N-oxidation and the preferably about 1:0 of ratio of non-oxide amine nitrogen be to about 1:2 in the polymkeric substance that contains the N-oxide compound of the present invention, and preferred about 1:1 extremely is more preferably to 3:1.The amount of N-oxidation unit can design adjusting by the prescription teacher.For example, formulator can make the monomer that contains the N-oxide compound and the monomer copolymerization that contains non-N-oxide compound to reach the unitary ratio of desired N-oxide compound and non-N-oxide compound amino, perhaps formulator can be in preparation process the oxidation level of controlling polymers.The unitary Pk of amine oxide in the polyamine N-oxide of the present invention aValue is less than or equal to 10, preferably is less than or equal to 7, is more preferably less than or equals 6.The molecular-weight average of the polymkeric substance that contains the N-oxide compound of dye transfer inhibitor benefit is provided can for fabric anti-attrition polymkeric substance is about 500 dalton, preferred about 100,000 dalton, more preferably from about 160,000 dalton is to about 6,000,000 dalton is preferably to about 2,000,000 dalton is more preferably to about 360,000 dalton.
The polymkeric substance of amide containing unit and N-oxide unit
Has further example that dye transfer suppresses the fabric anti-attrition polymkeric substance of benefit and is the polymkeric substance that not only contains above-mentioned amide units but also contain above-mentioned N-oxide unit.Its non-limitative example comprises 2 kinds of monomeric multipolymers, and wherein first kind of monomer contains amide units, and second kind of monomer contains the N-oxide unit.In addition, contain these unitary oligopolymer or block polymer and can lump together formation mixing acid amides/N-oxide polymer.But formed polymkeric substance must can keep above-mentioned water-soluble requirement.
Molecular weight
For above-mentioned all polymkeric substance of the present invention, most preferably, its molecular weight should be in above-mentioned scope.This scope typically is higher than only gives the molecular weight ranges that dye transfer suppresses the polymkeric substance of benefit separately.In fact, the fabric anti-attrition polymkeric substance of higher molecular weight can provide fabric anti-attrition effect, and this effect typically produces after handling, and for example in the clothes use, produces in the washing process especially in the back.Bound by theory unintentionally, can think that high molecular can make polymer deposition on fabric face, and enough stabilityes are provided so that polymkeric substance subsequently fabric use and washing process in can be retained on the fabric.In addition, can think,, increase molecular weight and just can increase the stability of polymer deposition on fabric face for given electric density.The desirable balance of electric density and molecular weight in cycles of washing process subsequently, can provide enough be deposited on the fabric face speed and to enough magnetisms of fabric.Increase molecular weight and be considered to more desirable than increasing electric density, because it allows the bigger selection in the material ranges that required benefit can be provided, and can avoid dirt and resistates can be attracted to this negative impact on the fabric of handling especially owing to increase electric density.Yet, it should be noted, can predict similar benefit from increasing this approach of electric density, can keep the material of lower molecular weight simultaneously again.
Fabrid care composition
The present invention relates to Fabrid care composition, said composition comprises:
A) from about 0.01%, preferably from about 0.1% to about 20%, preferably to the fabric anti-attrition polymkeric substance of about 10% weight, described fabric anti-attrition polymkeric substance comprises:
I) at least a monomeric unit that contains amide moieties;
The ii) at least a monomeric unit that contains N-oxide compound part;
Iii) and their mixture;
B) randomly, preferred about 10% from about 1%, more preferably from about 20% to about 80%, preferably to about 60%, more preferably to the fabric softener of about 45% weight;
C) randomly, be less than the basic solvent of about 15% weight, the ClogP of preferred described solvent is about 0.15～about 1;
D) randomly, one or more laking agent of about 0.001%～about 90% weight;
E) randomly, one or more cellulose reactive laking agent of about 0.01%～about 50% weight;
F) randomly, the chlorine scavenger of about 0.01%～about 15% weight;
G) randomly, one or more crystal growth inhibitors of about 0.005%～about 1% weight;
H) randomly, one or more liquid vehicles of about 1%～about 12% weight;
I) randomly, the enzyme of about 0.001%～about 5% weight;
J) randomly, the polyolefin emulsion or the suspension of about 0.01～about 8% weight;
K) randomly, a kind of stablizer of about 0.01～about 0.2% weight;
L) randomly, a kind of cats product of about 0.5%～about 5% weight;
M) can provide the line style or the cyclic polyamines of bleaching provide protection from one or more of about 0.01% weight; With
O) carrier of remaining sum and supplementary component;
Condition is that the molecular weight of described fabric anti-attrition polymkeric substance is greater than 100,000 dalton.
Being below can be with amide containing of the present invention, contain the non-limitative example of each composition of N-oxide compound and combination of polymers thereof combination.
Laking agent
Composition of the present invention randomly contains from about 0.001%, preferably from about 0.5% to about 90%, preferably to about 50%, more preferably to about 10%, most preferably to one or more laking agent of about 5% weight.
Dye-fixing agent, or claim " laking agent ", be the well-known material that is commercially available, designing this material is in order to improve the outward appearance of DYED FABRICS by the loss that reduces dyestuff on the fabric that causes owing to cleaning function.Be not included in this range of definition is in some embodiments as the component of fabric softener.
Many laking agent are cationic, and based on season nitrogenous compound or based on the nitrogenous compound of band strong cation electric charge, this electric charge forms under working conditions on the spot.Cationic fixing agent can obtain with the extensive stock name from a few suppliers of family.Representational example comprises: CROSCOLOR PMF (in July, 1981, article No. No.7894) and CROSCOLOR NOFF (in January, 1988, article No. No.8544), and Crosfield company produces; INDOSOL E-50 (on February 27th, 1984, reference number No.6008.35.84; Based on polyvinylamine), Sandoz company produces; SANDOFIX TPS, Sandoz company produces, and is a kind of preferred laking agent used herein.Other limiting examples comprise SANDOFIX SWE (a kind of cation type resin shape compound), and Sandoz company produces, REWIN SRF, REWIN SRF-O and REWIN DWR, and CHT-Beitlich GMBH company produces;
Figure C99812797D00151
ECO,
Figure C99812797D00152
FRD and Ciba-Geigy company produces.A kind of preferred laking agent that uses in the present composition is
Figure C99812797D00154
Clariant company produces.
Other cationic laking agent can be consulted " improving the aftertreatment of dyestuff firmness on the fabric fibre ", ChristopherC.Cook, Rev.Prog.Coloration, volume XII, (1982).Be applicable to that laking agent of the present invention is an ammonium compound, for example lipid acid diamines condenses, the particularly hydrochloride of diamines ester, acetate, Methylsulfate (metosulphate) and benzyl hydrochloride.Non-limitative example comprises the amino trimethyl ammonium Methylsulfate of oil base diethylamino buserelin, oil base methyl diethylenediamine Methylsulfate (methosulphate) and single stearyl ethylene.In addition, tertiary amine, polymeric alkyl diamine derivative, polyamines-cyanuryl chloride condenses and amination DCH all are suitable as the laking agent of the present composition.
The cellulose reactive laking agent
Another kind is applicable to that laking agent of the present invention is the cellulose reactive laking agent.Composition of the present invention randomly contains from about 0.01%, preferably from about 0.05%, more preferably from about 0.5% to about 50%, preferably to about 25%, more preferably to about 10%, most preferably to one or more cellulose reactive laking agent of about 5% weight.One or more laking agent combinations that the cellulose reactive laking agent is can be suitably above-mentioned with this paper are so that form a kind of " laking agent system ".
Term " cellulose reactive laking agent " here be defined as " a kind of when otherwise at the scene, or by formulator heat or during thermal treatment can with the laking agent of cellulosic fibre reaction ".Be applicable to that cellulose reactive laking agent of the present invention can be definite by following testing sequence.
Cellulose reactive test (CRT)
The cloth specimen (fabric) (for example 10 * 10cm has dyed direct red 80 knitted cotton) of selected 4 fritter dyestuffs meeting bleeding.Use 2 swatch in the same old way respectively as first and second pairs.All the other 2 swatch soaked 20 minutes in the aqueous solution that contains the cellulose reactive laking agent that 1% (w/w) will test.Take out cloth specimen and thorough drying then.Wherein a cloth specimen of handling is behind finish-drying, is set in the electric iron 10 times of " linen " shelves by temperature.The first contrast cloth specimen is the electric iron by same temperature 10 times also.
All 4 cloth specimens (2 contrast cloth specimens and 2 processing cloth specimens, all handled for every with electric iron) in the Launder-O-Meter pond, under representative condition, washed 0.5 hour at 60 ℃ with recommended dose separately with commercially available washing composition, use the abundant drip washing of 200ml cold water 4 times then, last straight line drying.
By the newer untreated cloth specimen and the DE value of 4 tried cloth specimens, measure dyefastness then.In ASTM D2244,, promptly calculate aberration and done definition the DE value.Generally speaking, the DE value relates to the size and the aspect of 2 kinds of difference between the psychological physic colour stimulus, determine by tristimulus value, or definite by the chromaticity coordinates and the illumination factor, calculate with one group that defines in CIE 1976CIELAB inverse space, inverse space, Hunter (Hunter), the Friele-MacAdam-Chickering color space or any equivalent color space special color difference equation.For the present invention, the DE value of sample is low more, and this sample is approaching more untested sample just, thereby colour fastness is just high more.
Because this test relates to the selection problem of cellulose reactive laking agent, so if the cloth specimen of handling in the flatiron step contrasts the better DE values of cloth specimen than 2, then for purposes of the invention, candidate is exactly the cellulose reactive laking agent.
Typical cellulose reactive laking agent is the compound that contains the cellulose reactive part, the non-limitative example of these compounds comprises halo triazine, vinyl sulphone, epichlorohydrin derived thing, hydroxy ethylene urea derivatives, formaldehyde condensation products, many carboxylates, oxalic dialdehyde and glutaraldehyde derivative, and their mixture.Further example can be consulted " fabric processing and performance " (Textile Processing and Properties) book, author tyrone L.Vigo, 120-121 page or leaf, Elsevier (1997), this book disclose concrete electrophilic group and corresponding cellulose affinity thereof.
Preferred hydroxy ethylene urea derivatives comprises dihydroxymethyl dihydroxyl ethylidene-urea and dimethyl urea oxalic dialdehyde.Preferred formaldehyde condensation products comprises from formaldehyde and the group deutero-condensation product that is selected from amino, imino-, phenolic group, urea groups, cyano group amide group and aryl.There are the Sandofix WE 56 of Clariant company production, the Zetex E of Zeneca company production and the Levogen BF that Bayer AG produces in the commercial goods in this compounds.Preferred many carboxylates derivative comprises butane tetracarboxylic acid derivative, citric acid derivant, many acrylate and derivative thereof.Particularly preferred cellulose reactive laking agent is a kind of in the hydroxy ethylene urea derivatives class, is that Clariant company produces, and commodity are called Indosol CR.Some other most preferred cellulose reactive laking agent is that CHTR Beitlich company produces, commodity RewinDWR by name and Rewin WBS.
Chlorine scavenger
Composition of the present invention randomly contains from about 0.01%, preferably from about 0.02%, more preferably from about 0.25% to about 15%, preferably to about 10%, more preferably to the chlorine scavenger of about 5% weight.Cationic moiety in the non-polymer scavenging agent and anionicsite separately can both with the situation of chlorine reaction under, can regulate the consumption of scavenging agent according to the requirement of formulator.
The chlorine scavenger that is suitable for comprises the ammonium salt shown in the following formula:
[(R) 3R 1N] +X -
Wherein each R is hydrogen, C independently 1-C 4Alkyl, the C of replacement is arranged 1-C 4Alkyl and their mixture, preferred R is hydrogen or methyl, more preferably hydrogen.R 1Be hydrogen, C 1-C 9Alkyl, the C of replacement is arranged 1-C 9Alkyl and their mixture, preferred R 1Be hydrogen.X is the compatibility negatively charged ion, and its non-limitative example comprises chlorine root, bromine root, citrate, sulfate radical; Preferred X is the chlorine root.
The non-limitative example of preferred chlorine scavenger comprises ammonium chloride, ammonium sulfate and their mixture; Preferred ammonium chloride.
Crystal growth inhibitor
Composition of the present invention randomly contains from about 0.005%, preferably from about 0.5%, more preferably from about 0.1% to about 1%, preferably to about 0.5%, more preferably to about 0.25%, most preferably to one or more crystal growth inhibitors of about 0.2% weight.Following " crystalline growth inhibition test " is used for measuring the suitability of certain material as crystal growth inhibitor.
Crystalline growth inhibition test (CGIT)
The suitability that is used as the material of crystal growth inhibitor of the present invention can be determined in external growth velocity by assessing some inorganic crystallites.People such as Nancollas are at " nucleation and growth of calcium phosphate in the solution ", Prog.Crystal Growth Charact., volume 3, the program described in 77-102 page or leaf (1980) one literary compositions are a kind of inhibiting methods of crystalline growth that is applicable to the assessment compound, and the document is incorporated this paper into as a reference.Below figure with an example that explains in crystallization forms by a kind of time lag that crystal growth inhibitor provided (t-hysteresis) of hypothesis.
Figure C99812797D00181
Observed t-lags behind provides compound delay calcium phosphate crystal growth a kind of of usefulness to measure.T-lags behind big more, and crystal growth inhibitor is just effective more.
Exemplary operation steps
With 2.1M KCl (35ml), 0.0175M CaCl 2(50ml), 0.01M KH 2PO 4(50ml) and deionized water (350ml) be incorporated in the proper container.Insert a standard pH electrode that the standard calomel reference electrode is housed,, remove the oxygen in the solution simultaneously temperature regulation to 37 ℃.In case temperature and pH reach stable, just add the crystal growth inhibitor solution that to test.Typical inhibitor experimental concentration is 1 * 10 -6M.This solution uses 0.05M KOH titration to pH 7.4.Mixture 5ml hydroxyapatite slurry treatment.The hydroxyapatite slurry can prepare by following method: with Bio-
Figure C99812797D00182
HTP, promptly hydroxyapatite powder (100g) places 1 liter of distilled water, and the 6N HCl that adds capacity is adjusted to 2.5 with its pH value, carries out boiling, this solution is heated till whole hydroxyapatites dissolvings (may need to heat a couple of days) then.The temperature maintenance that makes this solution then adds the 50% KOH aqueous solution with pH regulator to 12 simultaneously at about 22 ℃.Heat this solution once more, allow formed slurry standing sedimentation 2 days, isolate supernatant liquor then.Add 1.5 liters of distilled water, stir this solution, allow its once more sedimentation tell supernatant liquor after 2 days.This rinsing operation steps repeats more than 6 times, and is with 2NHCl that the pH regulator of solution is extremely neutral then.Resulting slurry can be stored 11 months at 37 ℃.
Be applicable to that crystal growth inhibitor of the present invention is 1 * 10 in concentration -6Its t-lags behind and was at least 10 minutes during M, preferably is at least 20 minutes, more preferably is at least 50 minutes.Crystal growth inhibitor is multi-form sequestrant, and it is true according to being, crystal growth inhibitor is to heavy metal ion, and promptly copper has low avidity.For example, crystal growth inhibitor avidity to copper in the solution of 0.1 ionic strength is less than 15 when measuring for 25 ℃, preferably less than 12.
Preferred crystal growth inhibitor of the present invention is selected from by carboxylic acid cpd, organic diphosphonic acid and their mixture.Be the non-limitative example of preferred crystal growth inhibitor below.
Carboxylic acid cpd
The non-limitative example that can be used as the carboxylic acid cpd of crystal growth inhibitor comprises oxyacetic acid, phytinic acid, poly carboxylic acid, carboxylic acid and polycarboxylic polymkeric substance and multipolymer, and their mixture.This inhibitor can be the form of acid or salt.Preferred poly carboxylic acid comprises and has at least 2 quilts and be no more than the hydroxy-acid group that 2 carbon atoms (for example MU (methylene unit)) separate.Preferred salt form comprises basic metal, as the salt of lithium, sodium and potassium, and alkylammonium salt.Be applicable to that many carboxylates of the present invention also can consult U.S.3,128,287, U.S.3,635,830, U.S.4,663,071, U.S.3,923,679; U.S.3,835,163; U.S.4,158,635; U.S.4,120,874 and U.S.4,102,903, all these patent documentations are all listed this paper in as a reference.
Further the many carboxylates that are suitable for comprise the multipolymer of the many carboxylates of ether hydroxyl, many acrylic ester polymers, maleic anhydride and acrylic acid methoxy ethylene or Vinyl Ether.1,3,5-trihydroxybenzene, 2,4, the multipolymer of 6-trisulfonic acid and carboxy methoxy-succinic acid also are useful.An alkali metal salt of polyacetic acid, for example ethylenediamine tetraacetic acid (EDTA) and nitrilotriacetic acid(NTA), and an alkali metal salt of many carboxylates, for example mellitic acid, succsinic acid, oxygen di-succsinic acid, polymaleic acid, 1,3, an alkali metal salt of 5-benzenetricarboxylic acid, carboxy methoxy-succinic acid also is suitable for use as crystal growth inhibitor of the present invention.
Can be used as the polymkeric substance of crystal growth inhibitor and the molecular weight of multipolymer and be preferably greater than about 500 dalton, more preferably to about 50,000 dalton to about 100,000 dalton.
The example that is used as the commercially available material of crystal growth inhibitor comprises many acrylic ester polymers, the Rohm ﹠amp that BF Goodrich company produces; Haas company produces
Figure C99812797D00191
BASF AG produces
Figure C99812797D00192
Produce with Norso Haas company Preferably Many acrylic ester polymers, more preferably
Figure C99812797D00195
And 410N (MW 10,000) and
Figure C99812797D00201
440N (MW 4000), it is a kind of many acrylic ester polymers of aminophosphonic acid modification, also more preferably Norso-Haas company produce with
Figure C99812797D00202
This polymer-modified sour form that QR784 (MW4000) sells.
Many carboxylates crystal growth inhibitor comprises Citrate trianion, for example citric acid and soluble salt thereof (especially sodium salt), 3,3-dicarboxyl-4-oxa--1, the 6-adipate, and further be disclosed in the United States Patent (USP) 4,566 of classifying this paper reference as, allied compound in 984, C 5-C 20Alkyl, C 5-C 20Alkenyl succinic and salt thereof, its non-limitative example are dodecenyl succinic succsinic acid, lauryl succsinic acid, myristyl succsinic acid, palmityl succsinic acid, 2-dodecenyl succinic succsinic acid, 2-15 carbene base succsinic acids and these sour salt.Other many carboxylates that are suitable for are disclosed in United States Patent (USP) 4,144, and in 226,3,308,067 and 3,723,322, all these patents are all listed this paper in as a reference.
Organic phospho acid
Organic diphosphonic acid also is suitable for use as crystal growth inhibitor.For the present invention, term " organic diphosphonic acid " is defined as " organic diphosphonic acid or its salt that do not comprise nitrogen-atoms ".Preferred organic diphosphonic acid comprises C 1-C 4Di 2 ethylhexyl phosphonic acid preferably is selected from following one group C 2Di 2 ethylhexyl phosphonic acid: ethylidene diphosphonic acid, alpha-hydroxy-2-phenylethyl bisphosphate, methylenediphosphonate (MDP), vinylidene-1,1-di 2 ethylhexyl phosphonic acid, 1,2-dihydroxyl ethane-1,1-di 2 ethylhexyl phosphonic acid, hydroxyl ethane-1,1-di 2 ethylhexyl phosphonic acid, these sour salt and their mixture.Hydroxyl ethane-1 most preferably, 1-di 2 ethylhexyl phosphonic acid (HEDP).Preferred phosphonic acids is that the trade mark that Bayer AG produces is BAYHIBIT
Figure C99812797D00203
2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid.
Fabric softener
Composition of the present invention can randomly contain at least about 1%, preferably from about 10%, more preferably from about 20% to about 80%, preferably to about 60%, more preferably to one or more fabric softeners of about 45% weight.
According to the preferred fabric softener of the present invention is the aminated compounds shown in the following formula:
Figure C99812797D00204
Quaternary ammonium compound shown in the following formula:
Figure C99812797D00211
And their mixture, wherein each R is C independently 1-C 6Alkyl, C 1-C 6Hydroxyalkyl, benzyl and composition thereof; R 1C preferably 11-C 22Straight chained alkyl, C 11-C 22Branched-chain alkyl, C 11-C 22Straight alkenyl, C 11-C 22Branched alkenyl, and their mixture; Q is a carbonyl moiety, is independently selected from following unit shown in various:
Figure C99812797D00212
R wherein 2Be hydrogen, C 1-C 4Alkyl, preferred hydrogen; R 3Be C 1-C 4Alkyl, preferred hydrogen or methyl; Preferred Q has following formula:
Figure C99812797D00213
Or
Figure C99812797D00214
X is a tenderizer compatibility negatively charged ion, the negatively charged ion of preferred strong acid, for example chlorine root, bromine root, methylsulfate, ethyl sulphate, sulfate radical, nitrate radical and these mixture, more preferably chlorine root and methylsulfate.Negatively charged ion also can, but not preferred, the band double charge, in this case, X (-)Represent group half.The value of exponent m is 1～3; The value of index n is 1～4, preferred 2 or 3, more preferably 2.
A specific embodiments of the present invention provides the amine of the index n that 2 or more a plurality of different numerical value are arranged in each molecule and the aminated compounds of seasonization, for example, from raw material amine, i.e. the tenderizer of methyl (3-aminopropyl) (2-hydroxyethyl) amine preparation.
The tenderizer preferred according to the present invention has following formula:
Following formula wherein
Figure C99812797D00222
Shown unit is the fatty acyl group part.The fatty acyl group that is applicable to tenderizer of the present invention partly is the Witepsol W-S 55 source deutero-from following oil plant; described oil plant comprises: butter, vegetables oil and/or partially hydrogenated vegetables oil, and particularly including Tower rape oil, Thistle oil, peanut oil, Oleum Helianthi, Semen Maydis oil, soya-bean oil, Yatall MA, Rice pollard oil.Diester quat (DEQA) more preferably again, wherein exponent m equals 2.
Formulator can select above-mentioned any fatty acyl group partly to originate according to the physics and the chemical property of desired final fabric softener, and perhaps, formulator also can mix formation a kind of " blend of customization " with various Witepsol W-S 55s source.But the technician in the grease field knows that as under the plant oil condition, the composition of fatty acyl group can change, from the crops to the crops, perhaps from each vegetable oil source to each vegetable oil source.With the DEQA from the preparation of natural origin derived fatty acid is preferred.
A preferred embodiment of the present invention provides and has contained R 1Unitary tenderizer, wherein R 1The unit contains at least about 3%, preferably at least about 5%, more preferably at least about 10%, most preferably at least about 15% C 1-C 22Alkenyl comprises polyalkenyl (how unsaturated) unit, particularly oil base, inferior oil base and flax oil base.
For the present invention; term " mixing-in fat acyl group unit " is defined as " comprise 10～22 carbon atoms; comprise the alkyl of carbonylic carbon atom and the unitary mixture of fatty acyl group of alkenyl chain, and contain 1～3 two key under the situation of alkenyl chain, preferably all two keys are in cis-configuration ".With regard to R of the present invention 1The unit, preferably the fatty acyl group group of most of at least percentage ratio is undersaturated, for example from about 25%, preferably from about 50% to about 70%, preferably to about 65%.The aggregate level that contains the fabric softener of polyunsaturated fat carboxyl groups can be from about 3%, preferably from about 5%, more preferably from about 10% to about 30%, preferably to about 25%, more preferably to about 18%.As mentioned above, cis-trans-isomer all can use, and preferably suitable/inverse ratio is from 1:1, preferred 3:1 at least, and more preferably from about 4:1 to about 50:1, more preferably from about 20:1 is 1:1 at least still.
Contained undersaturated level can be measured by the iodine number (IV) of corresponding lipid acid in butter, Tower rape oil or other fatty acyl group cellular chain; under situation of the present invention; this value preferably should be in the scope of 5-100, and two compounds differences, and its IV value is below or above 25.
In fact from the tallow fatty acid compound shown in the following formula that comes of deriving
Figure C99812797D00231
When iodine number is 5-25, during preferred 15-20, finds suitable/trans isomer weight ratio greater than about 30/70, be preferably greater than about 50/50, more preferably greater than about 70/30 concentration (concentrability) that the best just can be provided.
For this compounds that the tallow fatty acid that is higher than 25 from iodine number makes, find that the ratio of cis-trans-isomer is so not strict, unless need very high concentration.Further preferred embodiment of the present invention comprises DEQA, wherein R 1Average iodine number be about 45.
Be suitable for being used in the R in the isotropic liquid of the present invention 1The unitary iodine number (IV) that is further characterized in that maternal fatty acid is preferably from about 10, more preferably from about 50, most preferably from about 70 to about 140, preferably to about 130, more preferably to about 115.But formulators according to the specific embodiments of the present invention that their selection will be implemented, can add the fatty acyl group unit of iodine number outside above-mentioned scope of a certain quantity.For example, " hardening raw material " (IV is less than or equal to about 10) and fatty acid mixt source can be merged, in order to regulate the performance of final tenderizer.
Preferred source, fatty acyl group unit, branching especially, for example, and " Guerbet branching ", the source, fatty acyl group unit and the source, synthetic fatty acyl group unit that have unit such as methyl, ethyl to replace along main alkyl chain also be suitable for.For example, formulator can add one or more on a certain " non-natural produces " position, for example at C 17The fatty acyl group unit that methyl-branched is arranged on the 3rd carbon atom of chain.Term " non-natural produces " refers to " the acyl group unit of not finding significant quantity (greater than about 0.1%) in the common grease of the raw material that is used as Witepsol W-S 55 source described here " in this article.Therefore, if required branched chain fatty acyl group unit can not obtain in the calm facile natural matter, then can carry out suitable blending with synthetic fatty acid and other synthetic materials or with other unitary source of natural triglycerides deutero-acyl group.
Be example below according to preferred tenderizer of the present invention.
Chlorination N, N-two (tallow acyl-oxygen-ethyl)-N, N-Dimethyl Ammonium;
Chlorination N, N-two (canola oleoyl-oxygen-ethyl)-N, N-Dimethyl Ammonium;
Methylsulfuric acid N, N-two (tallow acyl-oxygen-ethyl)-N-methyl-N-(2-hydroxyethyl) ammonium;
Methylsulfuric acid N, N-two (canola oleoyl-oxygen-ethyl)-N-methyl-N-(2-hydroxyethyl) ammonium;
Methylsulfuric acid N, N-two (tallow amido ethyl)-N-methyl-N-(2-hydroxyethyl) ammonium;
Chlorination N, N-two (2-tallow acyl-oxygen-2-oxo-ethyl)-N, N-Dimethyl Ammonium;
Chlorination N, N-two (2-Tower rape oil acyl-oxygen-2-oxo-ethyl)-N, N-Dimethyl Ammonium;
Chlorination N, N-two (2-tallow acyl-oxygen ethyl carbonyl oxygen ethyl)-N, N-Dimethyl Ammonium;
Chlorination N, N-two (2-Tower rape oil acyl-oxygen ethyl carbonyl oxygen ethyl)-N, N-Dimethyl Ammonium;
Chlorination N-(2-tallow acyl-oxygen-2-ethyl)-N-(2-tallow acyl-oxygen-2-oxo-ethyl)-N, the N-Dimethyl Ammonium;
Chlorination N-(2-Tower rape oil acyl-oxygen-2-ethyl)-N-(2-canola oleoyl-2-oxo-ethyl)-N, the N-Dimethyl Ammonium;
Chlorination N, N, N-three (tallow acyl-oxygen ethyl)-N-ammonium methyl;
Chlorination N, N, N-three (Tower rape oil acyl-oxygen ethyl)-N-ammonium methyl;
Chlorination N-(2-tallow acyl-oxygen-2-oxoethyl)-N-(tallow acyl)-N, the N-Dimethyl Ammonium;
Chlorination N-(2-Tower rape oil acyl-oxygen-2-oxoethyl)-N-(canola oleoyl)-N, the N-Dimethyl Ammonium;
Chlorination 1,2-two tallow acyloxy-3-N, N, N-trimethyl ammonium propane; With
Chlorination 1,2-Tower rape oil acyloxy-3-N, N, N-trimethyl ammonium propane; And the mixture of above-mentioned tenderizer.
Particularly preferably be chlorination N, N-two (tallow acyl-oxygen-ethyl)-N, the N-Dimethyl Ammonium, wherein the tallow chain is undersaturated and chlorination N to small part, N-two (canola oleoyl-oxygen-ethyl)-N, N-Dimethyl Ammonium, methylsulfuric acid N, N-two (tallow acyl-oxygen-ethyl)-N-methyl-N-(2-hydroxyethyl) ammonium and methylsulfuric acid N, N-two (canola oleoyl-oxygen-ethyl)-N-methyl-N-(2-hydroxyethyl) ammonium, and their mixture.
Other can be used for the United States Patent (USP) 5,643,865 that fabric softener of the present invention is disclosed in the people such as Mermelstein of promulgation on July 1st, 1997; The people's such as Buzzaccarini of promulgation on April 22nd, 1997 United States Patent (USP) 5,622,925; The people's such as Baker of promulgation on August 23rd, 1996 United States Patent (USP) 5,545,350; The people's such as Wahl of promulgation on December 12 nineteen ninety-five United States Patent (USP) 5,474,690; The people's such as Turner of promulgation on January 27th, 1994 United States Patent (USP) 5,417,868; The people's such as Trinh of promulgation on April 28th, 1987 United States Patent (USP) 4,661,269; The United States Patent (USP) 4,439,335 of the Burns of promulgation on March 27th, 1984; The United States Patent (USP) 4,401,578 of the Verbruggen of promulgation on August 30 nineteen eighty-three; The United States Patent (USP) 4,308,151 of the Cambre of promulgation on December 29th, 1981; The people's such as Rudkin of promulgation on October 27th, 1978 United States Patent (USP) 4,237,016; The United States Patent (USP) 4,233,164 of the Davis of promulgation on November 11st, 1980; The people's such as Watt of promulgation on August 30th, 1977 United States Patent (USP) 4,045,361; The people's such as Wiersema of promulgation on August 10th, 1976 United States Patent (USP) 3,974,076; The United States Patent (USP) 3,886,075 of the Bernadino of promulgation on May 6th, 1975; The people's such as Edwards of on January 21st, 1975 promulgation United States Patent (USP) 3,861,870, and people's such as Yamamura European patent application publication No. 472,178, above-mentioned all documents are all incorporated this paper into as a reference.
Primary solvent
Composition of the present invention, preferably its isotropy liquid embodiment also can randomly contain solvent.The content that is present in the primary solvent in the present composition is typically less than about 95%, preferably less than about 50%, be more preferably less than about 25%, most preferably less than about 15% weight.Some scheme in the isotropic liquid embodiment of the present invention can not comprise primary solvent, but can for a kind of suitable nonionogenic tenside of usefulness.
Primary solvent of the present invention is mainly used to obtain to have the liquid composition of enough transparency viscosity.Primary solvent also must be selected, to significantly reduce the stimulation of the solvent stink in the composition.For example, Virahol is not a kind of effective primary solvent just, and its reason is that it can not be used for preparing a kind of composition with proper viscosity.Virahol can not be as the primary solvent that is fit to, because it has stronger stink.
Will consider that it generates the ability of stable composition at low temperatures when selecting primary solvent, preferably, the composition that contains suitable primary solvent is still transparent when temperature drops to about 4 ℃, and still can recover its transparency fully after being low to moderate about 7 ℃ of storages.
To select according to its octanol/water partition ratio (P) according to primary solvent of the present invention.The octanol/water partition ratio is a kind of tolerance of the concentration ratio of a kind of concrete primary solvent when reaching balance in hot alcohol and water.Partition ratio can be easily is that logP represents and reports with its denary logarithm.
The existing report of the logP of many primary solvent species, for example data of just having collected many this respects the citing document of Ponmona 92 databases that can obtain from daylight Chemical Information System company (Daylight CIS) and this original.
But log P value is easy to calculate with " CLOGP " program, and this program also can obtain from DaylightCIS company.This program also is listed in the log P experimental value that obtains in Pomona 92 databases." the log P of calculating " is (reference of measuring with the disintegrating method (fragmentapproach) of Hansch and Leo: A.Leo (ClogP), Comprehensive Medicinal Chemistry (comprehensive medical chemistry), the 4th volume, C.Hansch, P.G.Sammens, J.B.Taylor and C.A.Ransden, the chief editor, the 295th page, Pergamon press, 1990, incorporate this paper into as a reference).Disintegrating method is based on the chemical structure of each HR chemical combination species, and considers number and type, atom connectivity and the chemical bond of atom.The ClogP value is the most reliable, is widely used in to calculate the octanol water dispenser.Those of skill in the art will be understood that also can adopt experiment log P value.The more not preferred embodiment of the present invention of experiment log P value representative.Adopt when testing log P value, preferably 1 hour log P value.Other method that can be used to calculate ClogP comprises, for example be disclosed in J.Chem.Inf.Comput.Sci. (chemical information computational science magazine), 27a, the fragmentation method of Crippen in 21 (1987) (fragmentation method), be disclosed in J.Chem.Inf.Comput.Sci., 29, the fragmentation method of Viswanadhan in 163 (1989) and be disclosed in Eur.J.Med.Chem.-Chim.Theor (European medical chemistry magazine-chemical theory), the Broto method in 19,71 (1984).
Be applicable to primary solvent of the present invention be selected from ClogP be about 0.15～about 1, preferred about 0.15～about 0.64, more preferably from about 0.25～about 0.62, those solvents of 0.4～about 0.6 most preferably from about.Preferred primary solvent has chiral molecular at least to a certain degree, and preferably its fusing point or solidification point are in room temperature or below near room temperature, so that make primary solvent be liquid status near room temperature or room temperature.For some embodiment, the lower molecular weight primary solvent may be wished.Preferred molecule is highly asymmetrical.
Relevantly be applicable to that the further describing of primary solvent of isotropic liquid composition of the present invention see WO 97/03169 " fabric softener composition of concentrated, stable " for details, on January 30th, 1997 is open, has transferred P﹠G; The WO 97/03170 stable fabric softener composition of water-dispersion " spissated, ", on January 30th, 1997 is open, transferred P﹠G, with WO 97/34972 " fabric softening compound/composition ", on September 25th, 1997, transferred P﹠G, all these documents are all incorporated this paper into as a reference.
The hydrophobicity dispersion agent
A kind of preferred composition of the present invention comprises from about 0.1%, preferably from about 5%, more preferably from about 10% to about 80%, preferably to about 50%, more preferably to the hydrophobicity polyamine dispersant shown in the following formula of about 25% weight:
Figure C99812797D00271
Wherein R, R 1With B suitable can be referring to people's such as Watson United States Patent (USP), on October 15th, 1996 promulgation is incorporated this paper into as a reference, the value of w, x and y should be able to make this skeleton have before replacement preferably at least about 1200 dalton, more preferably 1800 daltonian molecular weight.
R 1The unit is the alkylidene group oxygen unit shown in the following formula preferably:
-(CH 2CHR′O) m(CH 2CH 2O) nH
Wherein R ' is methyl or ethyl, m and n be preferably about 0～and about 50, condition is that the alkoxylate mean value that is provided by m+n is at least about 0.5.
Relevantly be applicable to that further describing of polyamine dispersant of the present invention can be referring to the United States Patent (USP) 4,891,160 of the Vander Meer of January 2 nineteen ninety promulgation; The United States Patent (USP) 4,597,898 of the Vander Meer of promulgation on July 1st, 1986; On June 27th, 1984 disclosed Oh and Gosselink european patent application 111,965; June in 1984 disclosed Gosselink on the 27th european patent application 111,984; July in 1984 disclosed Gosselink on the 4th european patent application 112,592; The United States Patent (USP) 4,548,744 of the Connor of promulgation on October 22nd, 1985; With the people's such as Watson that issued on October 15th, 1996 United States Patent (USP) 5,565,145, all these documents are all incorporated this paper into as a reference.But any suitable clay/soil dispersing agent or anti-redeposition agent all can be used in the laundry composition of the present invention.
Ionogen
The fabric-softening embodiment of the present composition, especially transparent isotropic liquid fabric softener can be randomly, but preferably comprise one or more ionogen, is used to control phase stability, clay and/or transparency.For example, the existence of some ionogen, particularly calcium chloride, magnesium chloride may be to guarantee initial product transparency and low viscous key, perhaps may influence the liquid embodiment, especially the diluted viscosity of isotropic liquid embodiment.Do not want to be limited by theory, but only be desirable to provide the example that formulator must be guaranteed the situation of suitable diluted viscosity, comprise following Example.Anisotropy or non-anisotropic liquid fabric softener composition can disperse the manufacturing article of the described composition of a certain measured quantity to be incorporated into drip washing stage in the laundry operations process by a kind of design.Typically, these manufacturing article are a kind of dividers of just just carrying tenderizer during the drip washing cycle.The water yield that these dividers typically are designed to allow to equal the softener composition volume enters into divider to guarantee the conveying fully of softener composition.Can in composition of the present invention, add ionogen with the softener composition of guaranteeing phase stability and avoid diluting " gelling is come out ", or undesirable or unacceptable viscosity increase takes place.Avoided gelling or formation " swollen ", high viscosity solution just can be guaranteed the conveying fully of softener composition.
But the people that are proficient in the fabric softener technology can know that electrolytical level also is subjected to the other factors particularly type, consumption and the level of nonionogenic tenside and the influence of type of primary solvent of fabric softener.For example, the trolamine deutero-ester type quaternary ammonium that is suitable for use as tenderizer of the present invention is made in the mode of a kind of distribution of producing list, two and three esterquat and amine precursor typically.Therefore, as in this example, the mutability during list, two and three esters and aminated compounds distribute can be concluded electrolytical different levels.Therefore, before selecting electrolytical type and/or level, formulator must be considered all the components, i.e. tenderizer, nonionogenic tenside, under the situation of isotropic liquid, also must consider the type and the level of primary solvent, and the level of supplementary component and kind.
Can use multiple ionizable salt.The example of the salt that is fit to is the halogenide of IA and IIA family metal in the periodic table of elements, for example, and calcium chloride, sodium-chlor, Potassium Bromide and lithium chloride.Ionizable salt is mixing each composition making composition of the present invention, and to obtain in the process of desired viscosity subsequently be useful especially.The consumption of ionizable salt depends on absorption of active ingredient in the composition, and can be adjusted according to the wish of formulator.The levels typical that is used for the salt of control combination thing viscosity be composition about 20～about 10,000ppm, preferred about 20～about 5,000ppm.
Except above-mentioned water-soluble ionizable salt, perhaps replace above-mentioned water-soluble ionizable salt, also can add the many ammonium salts of alkylidene group in the composition to realize viscosity controller.In addition, these compounds can also play scavenging agent, main wash, in the drip washing and carrying out forming the process of ion pair on the fabric with negatively charged ion always, these compounds can improve softness.Compare with inorganic electrolyte, these compounds can especially make stable viscosity at low temperature a wide temperature range.The object lesson of the many ammonium salts of alkylidene group comprises L-Methionin mono-hydrochloric salts and 1,5-two ammoniums-2-methylpentane dihydrochloride.
Enzyme
The compositions and methods of the invention can randomly use one or more enzymes, particularly lipase, proteolytic enzyme, cellulase, amylase, mannase, wood sugar type dextranase and peroxidase.Can be used for preferred enzyme of the present invention is cellulase.The cellulase that can be used for fabric enhancing compositions of the present invention comprises preferably and demonstrates the bacterium of optimum performance and the enzyme of fungi type at pH 5～9.5.The United States Patent (USP) 4 of incorporating the Barbesgaard of this paper promulgation in 6 days March in 1984 as a reference into, 435,307 disclose plain enzyme of the fungi fiber type that is suitable for that obtains from humicola lanuginosa (Humicola insolens) or humicola lanuginosa strain DSM 1800 or the fungi that can produce cellulase 212 that belongs to single gas vacuole Pseudomonas, and belong to the cellulase that extracts the liver pancreas of (Dolabella Auricula Solander) from sea mollusk ear shape truncation sea hare.The plain enzyme of useful fiber also is disclosed in GB-A-2, and in 075,028, GB-A-2,095,275 and DE-OS-2,247,832, all these documents are all listed this paper in as a reference.Useful especiallyly be
Figure C99812797D00291
With (Novo company product).The plain enzyme of other useful fiber also is disclosed in WO 91/17243 (Novo company), WO 96/34092, WO96/34945 and EP-A-0, in 739,982.Every gram composition can comprise the highest 5mg, the organized enzyme of more typical 0.01mg～3mg weight.Alternatively say, typically comprise in the composition from 0.001%, preferably from 0.01% to 5%, preferably to the commercially available zymin of 1% weight.Can be in another way as under the particular case with the cellulase definition in the activity of zymin, corresponding activity unit is preferred (for example, CEVU or cellulase equivalent viscosity unit).For example, composition of the present invention can contain the cellulase that equals 0.5～1000CEVU/ gram composition activity level.Its activity was generally 1,000～10 when the cellulase preparation that is used to prepare the present composition was liquid form, 000CEVU/g, and its activity is generally 1 when being solid form, about 000CEVU/g.
The cationic charge toughener
Composition of the present invention can randomly comprise one or more cationic charge tougheners, the fabric-softening embodiment that adds during especially for drip washing of the present invention.Typically, prepare following multiple composition with ethanol, therefore, ethanol is the solvent source that joins in the finished product preparation.Formulator is not limited to use ethanol, and generation also can add other solvent, particularly hexylene glycol, be beneficial to the final composition preparation.This point is especially true in transparent, translucent, isotropy composition.
Preferred cation charge enhancers of the present invention is described below.
I) Quaternary ammonium compound
A kind of optional combination thing of the present invention comprises at least about 0.2%, preferred about 0.2%～about 10%, the cationic charge toughener shown in the following formula of 0.2%～about 5% weight more preferably from about:
Figure C99812797D00301
R wherein 1, R 2, R 3And R 4Be C independently of one another 1-C 22Alkyl, C 3-C 22Alkenyl, R 5-Q-(CH 2) m-, R wherein 5Be C 1-C 22Alkyl, and composition thereof, m is 1～about 6; X is a negatively charged ion.
Preferred R 1Be C 6-C 22Alkyl, C 6-C 22Alkenyl, and composition thereof, more preferably C 11-C 18Alkyl, C 11-C 18Alkenyl, and composition thereof; R 2, R 3And R 4C preferably separately 1-C 4Alkyl, more preferably R 2, R 3And R 4It respectively is methyl.
Formulator can be selected R similarly 1Be R 5-Q-(CH 2) m-part, wherein R 5Be alkyl or the alkenyl part that contains 1～22 carbon atom; preferred this alkyl or alkenyl partly are an acyl group unit when lumping together with the Q unit; preferably derive from being selected from following one group Witepsol W-S 55 source in this acyl group unit: tallow, partial hydrogenation tallow, lard, partial hydrogenation lard, vegetables oil and/or partially hydrogenated vegetable oil be low erucic acid rape oil, Thistle oil, peanut oil, Oleum Helianthi, Semen Maydis oil, soya-bean oil, Yatall MA, rice bran wet goods for example, and composition thereof.
Contain R 5-Q-(CH 2) mAn example of the fabric softener cationic charge toughener of-part has following structural formula:
Figure C99812797D00311
R wherein 5-Q-is an oleoyl unit, and m equals 2.
X is a tenderizer compatibility negatively charged ion, the negatively charged ion of preferred strong acid, for example chlorine root, bromine root, methylsulfate, ethyl sulphate, sulfate radical, nitrate radical and these mixture, more preferably chlorine root and methylsulfate.
Ii) Polyvinylamine
An embodiment preferred of the present invention contains at least about 0.2%, preferred about 0.2%～about 5%, the polyvinylamine shown in one or more following formulas of 0.2%～about 2% weight more preferably from about:
Figure C99812797D00312
Wherein y be about 3～about 10,000, preferred about 10～about 5,000, more preferably from about 20～about 500.Be applicable to that polyvinylamine of the present invention can obtain from BASF AG.
Randomly, in one or more polyvinylamine skeletons-NH 2Unitary hydrogen can be replaced by the alkylidene group oxygen unit of following formula:
—(R 1O) xR 2
R wherein 1Be C 2-C 4Alkylidene group, R 2Be hydrogen, C 1-C 4Alkyl, and composition thereof; X is 1～50.Implement in the kenel at one of the present invention, polyvinylamine directly has been connected the unitary substrate reaction of the inferior propoxy-of 1 2-earlier with on the nitrogen, then with one or more ethylene oxide molecule reactions, to form the unit shown in the following formula:
Wherein the value of x is 1～about 50.Above the so available abbreviation formula of replacement PO-EO x-expression, but also can be incorporated in the alkylidene group oxygen substituting group more than 1 inferior propoxy-unit.
Polyvinylamine is especially preferred as the cationic charge toughener of liquid fabric softening composition, because the amine moiety that greater number is arranged of every unit weight, this has just improved electric density greatly.In addition, cationic charge is that original position produces, and its level can be regulated by formulator.
Iii) Many quaternary ammonium compounds
A kind of preferred composition of the present invention comprises at least about 0.2%, preferred about 0.2～about 10%, the cationic charge toughener shown in the following formula of 0.2～about 5% weight more preferably from about:
Figure C99812797D00321
Wherein R replaces or unsubstituted C 2-C 12Alkylidene group, replacement or unsubstituted C 2-C 12Hydroxy alkylidene; R 1Be C independently of one another 1-C 4Alkyl, R 2Be C independently of one another 1-C 22Alkyl, C 3-C 22Alkenyl, R 5-Q-(CH 2) m-, R wherein 5Be C 1-C 22Alkyl, C 3-C 22Alkenyl, and composition thereof; M is 1～about 6; Q is as defined carbonyl unit, front; And composition thereof; X is a negatively charged ion.
Preferred R is an ethylidene; R 1Be methyl or ethyl, more preferably methyl; At least 1 R 2C preferably 1-C 4Alkyl, more preferably methyl.Preferred at least 1 R 2Be C 11-C 22Alkyl, C 11-C 22Alkenyl, and composition thereof.
Formulator can be selected R similarly 2Be R 5-Q-(CH 2) m-part, wherein R 5It is the moieties that contains 1～22 carbon atom; preferred this moieties is an acyl group unit when lumping together with the Q unit; preferably derive from being selected from following one group Witepsol W-S 55 source in this acyl group unit: tallow, partial hydrogenation tallow, lard, partial hydrogenation lard, vegetables oil and/or partially hydrogenated vegetable oil be low erucic acid rape oil, Thistle oil, peanut oil, Oleum Helianthi, Semen Maydis oil, soya-bean oil, Yatall MA, rice bran wet goods for example, and composition thereof.
Contain R 5-Q-(CH 2) mAn example of the fabric softener cationic charge toughener of-part has following structural formula:
Figure C99812797D00331
R wherein 1Be methyl, 1 R 2The unit is a methyl, and 1 R in addition 2The unit is R 5-Q-(CH 2) m-, R wherein 5-Q-is 1 oleoyl unit, and m equals 2.
X is a tenderizer compatibility negatively charged ion, the negatively charged ion of preferred strong acid, for example chlorine root, bromine root, methylsulfate, ethyl sulphate, sulfate radical, nitrate radical and these mixture, more preferably chlorine root and methylsulfate.
Dispersed auxiliary agent
Not only contained saturated but also contain undersaturated diester quat do not add the concentration auxiliary agent and just can prepare by stable denseer composition.But composition of the present invention can require organic and/or inorganic concentration auxiliary agent to reach greater concn and/or to meet the advantages of higher stability standard, and this depends on other composition.When using special tenderizer level is the stability of guaranteeing under extreme conditions, and this concentration auxiliary agent may need, or preferably, the concentration auxiliary agent typically can be a viscosity modifier.The surfactant concentration auxiliary agent typically is selected from one group that is made up of following: (1) single-long-chain alkyl cats product; (2) nonionogenic tenside; (3) amine oxide; (4) lipid acid; (5) their mixture.These auxiliary agents are disclosed in the common pending application number 08/461,207 of P﹠G, and submit to June 5 nineteen ninety-five, and people such as Wahl specifically are stated from and walk to the 20th page of 12 row for the 14th page 12, and this application is incorporated this paper into as a reference.
Preferred dispersed auxiliary agent derives from Clariant company With
Figure C99812797D00333
When containing PVP in the composition of the present invention, embodiment preferred not only comprises the coco group ethoxylated amine but also comprises the coco group ethoxylated alcohol, and wherein ethoxylation degree is about 10, and every kind can trade(brand)name
Figure C99812797D00334
With
Figure C99812797D00335
Obtain.The preferred example of using this blend is for example to comprise 0.2%
Figure C99812797D00336
With 0.1%
Figure C99812797D00337
Composition.
When having described dispersed auxiliary agent, its aggregate level be composition weight from 0.1%, preferably from 0.3%, more preferably from 3%, more more preferably from 4%, most preferably from 5% to 25%, preferably to 17%, more preferably to 15%, most preferably to 13% weight.These materials both can be used as the active softening agent starting material, example is used to generate the reactant single-long-chain alkyl cats product of fabric softener activeconstituents as previously discussed and/or the part of lipid acid adds, and also can be used as independently, component adds.The aggregate level of dispersed auxiliary agent comprises any amount of the part existence that can be used as the tenderizer activeconstituents.
Stain remover
Embodiment specific to the fabric softener that adds according to drip washing of the present invention, some stain remover not only provides following detergency ability, and the purpose that adds stain remover is in order suitably to keep suitable viscosity, especially to keep the suitable viscosity in the non-isotropy composition disperse phase.
Any polymkeric substance stain remover known to the those of skill in the art all can randomly be used for the compositions and methods of the invention.The feature of polymkeric substance stain remover is both to have contained hydrophilic segment, so that make the surface hydrophilic of hydrophobic fibre such as polyester and nylon, contain hydrophobic segment again, be deposited on the hydrophobic fibre by finishing the drip washing cycle, and keep adhesion thereon, thereby can be used as the wedding agent of hydrophilic segment.This just can make this detergent-treatment of stain that produces subsequently, easier cleaning in the washing step of back.
If you are using, stain remover account for usually detergent composition weight about 0.01%～about 10.0%, typically account for about 0.1%～about 5%, preferred about 0.2%～about 3.0%.
Following document is incorporated this paper into as a reference.These documents have been narrated and have been applicable to stain remover polymkeric substance of the present invention.These documents are: the people's such as Rohrbaugh of promulgation on March 17th, 1998 United States Patent (USP) 5,728,671; The people's such as Gosselink of promulgation on November 25th, 1997 United States Patent (USP) 5,691,289; The people's such as Pan of promulgation on February 4th, 1997 United States Patent (USP) 5,599,782; The people's such as Gosselink of promulgation on May 16 nineteen ninety-five United States Patent (USP) 5,415,807; The people's such as Morrall of promulgation on January 26th, 1993 United States Patent (USP) 5,182,043; The people's such as Gosselink of promulgation on September 11 nineteen ninety United States Patent (USP) 4,956,447; The people's such as Maldonado of promulgation on December 11 nineteen ninety United States Patent (USP) 4,976,879; The people's such as Scheibel of promulgation on November 6 nineteen ninety United States Patent (USP) 4,968,451; The Borcher of promulgation on May 15 nineteen ninety, people's such as Sr United States Patent (USP) 4,925,577; The United States Patent (USP) 4,861,512 of the Gosselink of promulgation on August 29th, 1989; The people's such as Maldonado of promulgation on October 31st, 1989 United States Patent (USP) 4,877,896; The United States Patent (USP) 4,721,580 of the Gosselink of promulgation on January 26th, 1988; The United States Patent (USP) 4,702,857 of the Gosselink of promulgation on October 27th, 1987; The people's such as Gosselink of promulgation on December 8th, 1987 United States Patent (USP) 4,711,730; The people's such as Nicol of promulgation on December 28th, 1976 United States Patent (USP) 4,000,093; The United States Patent (USP) 3,959,230 of the Hayes of promulgation on May 25th, 1976; The United States Patent (USP) 3,893,929 of the Basadur of promulgation on July 8th, 1975; European patent application 0 219 048 with people such as disclosed Kud on the 22nd April in 1987.
Further the stain remover that is suitable for is disclosed in people's such as Voilland United States Patent (USP) 4,201,824; People's such as Lagasse United States Patent (USP) 4,240,918; People's such as Tung United States Patent (USP) 4,525,524; People's such as Ruppert United States Patent (USP) 4,579,681; United States Patent (USP) 4,220,918; United States Patent (USP) 4,787,989; Authorized the EP279 of Rhone-PoulencChemie company, 134A in 1988; The EP 457,205 of BASF AG (1991); With the DE 2,335,044 that authorized UnileverN.V. company in 1974, all these documents all are incorporated herein by reference.
Bleaching protection polyamines
Composition of the present invention can randomly comprise from about 0.01%; preferably from about 0.75%; more preferably from 10%; most preferably from about 15% to about 50%; preferably to about 35%; more preferably to about 30%, most preferably can provide the line style or the cyclic polyamine of bleaching provide protection to one or more of about 5% weight.
The line style polyamines
Bleaching protection polyamines of the present invention has following general formula:
Figure C99812797D00351
Wherein R is propylene, trimethylene and composition thereof; Preferred trimethylene.Each R 1Be the alkylidene group oxygen unit shown in hydrogen, methyl, ethyl or the following formula independently:
—(R 3O)—R 4
R wherein 3Be ethylidene, propylene, 1,2-butylidene or its mixture; Preferred R 3Be ethylidene or propylene, more preferably propylene.R 4Be hydrogen, C 1-C 4Alkyl, and composition thereof; Preferred hydrogen.R 1Can comprise the unitary any mixture of alkylidene group oxygen.R 2Be hydrogen, R 1,-RN (R 1) 2, and composition thereof; Preferred at least 1 R when n equals 2 2Be hydrogen.N is integer 1 or 2.For " all alkylization " amine, each R 1And R 2Be independently selected from methyl or ethyl.
Preferred bleaching protection line style polyamines has such skeleton, and wherein, R is a trimethylene, R 2Be hydrogen or alkoxyl group, n equals 2, and this polyamines is N, N '-two (3-aminopropyl)-trimethylene diamines (TPTA).For some prescription, the polyamines that comprises alkylate polyamine is preferred.For example, tetramethyl-dipropylenetriamine, permethylated dipropylenetriamine, monomethyl dipropylenetriamine.
Cyclic amine
Bleaching protection cyclic polyamine of the present invention comprises the polyamine backbone shown in the following formula:
R—L—R
Wherein L is 1 connector element, and described connector element comprises the ring with at least 2 nitrogen-atoms; R be hydrogen atom ,-(CH 2) kN (R 1) 2, and composition thereof; Wherein the value of index k is 2～4, preferred 3.Preferred this comprises that the molecular weight of the unitary cyclammonium skeleton of R is 200 dalton or still less.
Each R 1Be hydrogen, C independently 1-C 2Alkylidene group oxygen unit shown in alkyl or the following formula:
—(R 3O)—R 4
R wherein 3Be ethylidene, propylene, 1,2-butylidene or its mixture; Preferred R 3Be ethylidene or propylene, more preferably propylene.R 4Be hydrogen, C 1-C 4Alkyl, and composition thereof; Preferred hydrogen.R 1Can comprise the unitary any mixture of alkylidene group oxygen.
The general formula of preferred polyamines of the present invention is as follows:
(R 1) 2N-(CH 2) k-L-(CH 2) k-N(R 1) 2
Wherein index k respectively has identical value, and each R 1It is identical unit.
The skeleton of preferred cyclic amine of the present invention comprises the N shown in the following formula, and N '-dibasic 1, the 4-piperazine ring:
Each R wherein 5Be hydrogen, C independently 1-C 4Alkyl, C 1-C 4Hydroxyalkyl, C 1-C 4Aminoalkyl, 2 R on the perhaps same carbon atom 5Thereby unit and oxygen bonding form a carbonyl (C=O), and wherein carbon atom is an annular atoms, and their mixture.Comprising the unitary example that contains the ring of carbonyl of L is 1,4-diketopiperazine compounds (diketopiperizines).
A preferred skeleton of chlorine scavenger polyamines of the present invention had the following formula structure before modification:
Figure C99812797D00371
Wherein each R unit is-(CH 2) 3NH 2, each R 5The unit is a hydrogen.
But this ring element can only have replacement on 1 theheterocyclic nitrogen atom, is hydrogen as 1 R unit wherein, and another R unit is-(CH 2) kNH 2Situation the same, the piperazine shown in the following formula for example:
Figure C99812797D00372
Ring-type of the present invention is pressed skeleton more and is preferably comprised at least 1 trimethylene unit, more preferably comprises at least 2 trimethylene unit.
Cats product
Fabric enhancing compositions of the present invention can randomly comprise from about 0.5%, preferably from about 1% to about 10%, and preferably to one or more positively charged ion nitrogenous compounds of about 5% weight, the cats product shown in the preferred following formula:
Wherein R is C 10-C 18Alkyl, each R 1Be C independently 1-C 4Alkyl, X are water soluble anions; Preferred R is C 12-C 14Alkyl, preferred R 1It is methyl.Preferred X is a halogen, more preferably chlorine.
The preferred non-limitative example that is applicable to the cationic nitrogen compound of Fabrid care composition of the present invention is bromination N, N-dimethyl-(2-hydroxyethyl)-N-dodecyl ammonium, bromination N, N-dimethyl-(2-hydroxyethyl)-N-tetradecyl ammonium.The cationic nitrogen compound that is suitable for can obtain from Akzo company, and its trade(brand)name has Ethomeen
Figure C99812797D00381
Secomine
Figure C99812797D00382
With
Figure C99812797D00383
Using method
The invention further relates to a kind of protection and enhanced method that fabric is provided, described method comprises the step that fabric is contacted with the composition that contains following component:
A) from about 0.01%, preferably from about 0.1% to about 20%, preferably to the fabric anti-attrition polymkeric substance of about 10% weight, described fabric anti-attrition polymkeric substance comprises:
I) at least a monomeric unit that contains amide moieties;
The ii) at least a monomeric unit that contains N-oxide compound part;
Iii) and their mixture;
B) one or more fabric enhancing ingredients randomly; With
C) carrier of remaining sum;
Condition is that the molecular weight of described fabric anti-attrition polymkeric substance is greater than 100,000 dalton.
With regard to meaning of the present invention, term " contact " is defined as " fabric fully contacts with the above-mentioned aqueous solution that contains the composition of fabric anti-attrition polymkeric substance ".Contact typically by immersion, washing, drip washing, on fabric, spray means generation such as said composition, but also can comprise matrix, particularly absorbed the material of said composition and contacting of fabric on it.Laundry is a kind of preferable methods.Laundry can be carried out at various temperatures, but typical laundry temperature is to be lower than about 30 ℃, preferred about 5 ℃～about 25 ℃.
Table I
Weight %
Composition 1 2 3 4 5 6 7
Polymkeric substance 1 10.0 7.5 15.0 10.0 7.5 5.0 5.0
Solidifying agent 2 -- 5.0 2.5 2.5 2.5 -- 1.0
The polyalkylene imines 3 -- -- 15.0 -- -- -- 10.0
The polyalkylene imines 4 -- -- -- 10.0 -- -- --
Polyamines 5 -- -- -- -- 25.0 -- --
Fabric softener 6 -- -- -- -- -- 15.0 --
Bayhibit?AM 7 1.0 1.0 0.2 1.0 1.0 -- 1.0
NH 4Cl -- -- -- 0.2 0.2 -- 0.5
MgCl 2 -- -- -- -- -- -- 4.0
SRP-2 8 -- -- -- -- 0.5 -- 1.0
White dyes 9 -- -- -- -- -- -- 0.2
Water and trace ingredients Equal amount Equal amount Equal amount Equal amount Equal amount Equal amount Equal amount
1. fabric anti-attrition polymer poly vinyl pyrrolidone K90, BASF AG produces, trade(brand)name Luviskol
Figure C99812797D00391
2. laking agent, Clariant company produces, trade(brand)name Cartafix
Figure C99812797D00392
3. according to PEI 1200 E4 of the people's such as Watson of on October 15th, 1996 promulgation United States Patent (USP) 5,565,145.
4. according to PEI 1200 E1 of the people's such as Watson of on October 15th, 1996 promulgation United States Patent (USP) 5,565,145.
5. N, N-two (3-aminopropyl)-1,3-propylene diamine.
6. chlorination two (tallow acyl-oxygen ethyl) Dimethyl Ammonium.
7. 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid, Bayer AG produces.
8. diethoxyization is gathered (terephthalic acid 1,2-propylene glycol ester) short block polymer.
9. 4,4 '-two (2-sulfonated phenylethylene base) biphenyl.
Table II
Weight %
Composition 8 9 10 11 12 13 14
Polymkeric substance 1 10.0 7.5 15.0 10.0 7.5 5.0 5.0
Solidifying agent 2 -- 5.0 2.5 2.5 2.5 2.5 2.5
The polyalkylene imines 3 -- -- 15.0 -- 10.0 -- --
The polyalkylene imines 4 -- -- -- 5.0 -- -- --
Polyamines 5 -- -- -- -- 15.0 10.0 20.0
Bayhibit?AM 6 1.0 1.0 0.2 1.0 1.0 0.5 1.0
NH 4Cl -- -- -- 0.2 0.2 -- 0.2
Water and trace ingredients Equal amount Equal amount Equal amount Equal amount Equal amount Equal amount Equal amount
1. fabric anti-attrition polymer poly vinyl pyrrolidone K60, BASF AG produces, trade(brand)name Luviskol
Figure C99812797D00393
2. laking agent, Clariant company produces, trade(brand)name Cartafix
3. according to PEI 1200 E4 of the people's such as Watson of on October 15th, 1996 promulgation United States Patent (USP) 5,565,145.
4. according to PEI 1200 E1 of the people's such as Watson of on October 15th, 1996 promulgation United States Patent (USP) 5,565,145.
5. N, N-two (3-aminopropyl)-1,3-propylene diamine.
6. 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid, Bayer AG produces.
Table III
Weight %
Composition 15 16 17 18 19 20 21
Polymkeric substance 1 10.0 7.5 5.0 10.0 7.5 5.0 5.0
Solidifying agent 2 -- 5.0 2.5 2.5 2.5 -- 2.5
The polyalkylene imines 3 -- -- 15.0 -- -- -- --
Polyamines 4 -- -- -- 15.0 -- -- --
Polyamines 5 -- -- -- -- 15.0 10.0 25.0
Bayhibit?AM 6 1.0 1.0 0.5 1.0 1.0 -- 1.0
NH 4Cl -- -- -- 0.2 0.2 -- 0.2
Water and trace ingredients Equal amount Equal amount Equal amount Equal amount Equal amount Equal amount Equal amount
1. fabric anti-attrition polymer poly vinyl pyrrolidone copolymerization dimethylaminoethyl methacrylate, Aldrich company produces.
2. laking agent, Clariant company produces, trade(brand)name Cartafix
Figure C99812797D00401
3. according to PEI 1200 E4 of the people's such as Watson of on October 15th, 1996 promulgation United States Patent (USP) 5,565,145.
4. N, N-two (3-aminopropyl)-1,3-propylene diamine.
5. 1,4-two (3-aminopropyl) piperazine.
6.2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid, Bayer AG produces.
Table IV
Weight %
Composition 22 23 24 25 26
Polymkeric substance 1 5.0 1.0 -- -- --
Polymkeric substance 2 -- -- 0.5 2.0 --
Polymkeric substance 3 -- -- -- -- 2.5
Tenderizer 4 2.6 18.0 19.0 -- --
Tallow alcohol E25 -- 1.0 -- -- --
Lipid acid 5 0.3 1.0 -- -- --
Hydrochloric acid 0.02 0.02 0.02 -- --
PEG?4000 -- 0.6 0.6 -- --
Flavouring agent 1.0 1.0 1.0 0.1 0.1
The siloxanes foam preventer 0.01 0.01 0.01 -- --
Polyalkyleneamines 6 3.0 3.0 -- 15.0 --
Polyamines 7 -- -- 5.0 -- 10.0
Laking agent 8 1.0 -- 5.0 -- 10.0
Laking agent 9 -- 3.0 -- 5.0 --
HEDP 10 0.2 -- -- 0.4 --
CaCl 2(ppm) -- 600 1200 -- --
Dyestuff (ppm) 10 50 50 -- --
Water and trace ingredients Equal amount Equal amount Equal amount Equal amount Equal amount
1. fabric anti-attrition polymer poly vinyl pyrrolidone K90, BASF AG produces, trade(brand)name Luviskol
Figure C99812797D00411
2. fabric anti-attrition polymer poly vinyl pyrrolidone K60, BASF AG produces, trade(brand)name Luviskol
Figure C99812797D00412
3. fabric anti-attrition polymer poly vinyl pyrrolidone copolymerization dimethylaminoethyl methacrylate, Aldrich company produces.
4. chlorination two (tallow acyl-oxygen ethyl) Dimethyl Ammonium.
5. iodine number is 18 tallow fatty acids.
6. according to PEI 1200 E4 of the people's such as Watson of on October 15th, 1996 promulgation United States Patent (USP) 5,565,145.
7. N, N-two (3-aminopropyl)-1,3-propylene diamine.
8. cellulose reactive laking agent, Clariant company produces, trade(brand)name Indosol
Figure C99812797D00413
9. cellulose reactive laking agent, CHTR.Beitlich company produces, trade(brand)name Rewin
Figure C99812797D00414
10. 1,1-hydroxyl ethane di 2 ethylhexyl phosphonic acid.
Table V
Weight %
Composition 27 28 29 30
Polymkeric substance 1 5.0 1.0 2.0 1.0
Tenderizer 2 -- -- -- 15.0
Tenderizer 3 2.6 19.0 -- --
Tallow alcohol E25 0.3 -- -- --
Lipid acid 4 0.3 -- -- --
Hydrochloric acid 0.02 0.02 -- 0.02
PEG?4000 -- 0.6 -- 0.6
Flavouring agent 1.0 1.0 0.1 1.0
The siloxanes foam preventer 0.01 0.01 -- 0.01
Polyalkyleneamines 5 3.0 3.0 10.0 3.0
Laking agent 6 1.0 3.0 10.0 1.0
Laking agent 7 2.0 -- -- 2.0
CaCl 2(ppm) -- 600 -- 600
Dyestuff (ppm) 10 50 -- 50
Water and trace ingredients Equal amount Equal amount Equal amount Equal amount
1. fabric anti-attrition polymer poly vinyl pyrrolidone K90, BASF AG produces, trade(brand)name Luviskol
Figure C99812797D00421
2. chlorination two tallow Dimethyl Ammonium.
3. chlorination two (tallow acyl-oxygen ethyl) Dimethyl Ammonium.
4. iodine number is 18 tallow fatty acids.
5. according to PEI 1200 E4 of the people's such as Watson of on October 15th, 1996 promulgation United States Patent (USP) 5,565,145.
6. cellulose reactive laking agent, Clariant company produces, trade(brand)name Indosol
Figure C99812797D00422
7. cellulose reactive laking agent, CHTR.Beitlich company produces, trade(brand)name Rewin
Figure C99812797D00423
Be the non-limitative example that is applicable to the present composition of supplying with through the matrix drying sheet below.
Table VI
Weight %
Composition 31 32 33 34 35 36
Polymkeric substance 1 20.0 30.0 10.0 5.0 7.5 15.0
Tenderizer 2 40.0 25.0 -- -- -- --
Tenderizer 3 -- -- 20.0 -- -- --
Tenderizer 4 -- -- -- 20.0 12.0 60.0
Tenderizer 5 30.0 30.0 20.0 30.0 20.0 --
Glycosperse?S-20 6 -- -- 10.0 -- -- --
Zerol -- -- 20.0 10.0 --
Carclazyte 4.0 4.0 3.0 4.0 4.0 --
Flavouring agent 0.7 1.1 0.7 1.6 2.6 1.4
The polyalkylene imines 7 -- 5.0 -- -- -- --
The polyalkylene imines 8 -- -- 4.0 2.2 -- --
The polyalkylene imines 9 2.0 -- -- -- 5.0 7.0
Laking agent 10 2.0 5.0 4.0 2.2 5.0 3.0
HEDP 11 0.2 -- 0.5 -- -- 0.7
Oxyacetic acid -- 0.2 -- 0.2 -- --
Many carboxylations compound 12 -- 0.2 - -- 0.4 --
Stearic acid Equal amount Equal amount Equal amount Equal amount Equal amount Equal amount
1. fabric anti-attrition polymer poly vinyl pyrrolidone K60, BASF AG produces, trade(brand)name Luviskol
Figure C99812797D00431
2. methylsulfuric acid two (oleoyl oxygen ethyl) Dimethyl Ammonium.
3. methylsulfuric acid two (palmitin acyl-oxygen ethyl) hydroxyethyl ammonium methyl.
4. methylsulfuric acid two tallow base Dimethyl Ammonium.
5. the stearyl dimethyl amine of 1:2: three squeezing stearic acid.
6. many ethoxylation dehydrated sorbitols monostearate, Lonza company produces.
7. according to PEI 1800 E1 of the people's such as Watson of on October 15th, 1996 promulgation United States Patent (USP) 5,565,145.
8. according to PEI 1200 E4 of the people's such as Watson of on October 15th, 1996 promulgation United States Patent (USP) 5,565,145.
9. according to PEI 1800 E4 of the people's such as Watson of on October 15th, 1996 promulgation United States Patent (USP) 5,565,145.
10. cellulose reactive laking agent, Clariant company produces, trade(brand)name Indosol
Figure C99812797D00441
11. 1,1-hydroxyl ethane di 2 ethylhexyl phosphonic acid.
12. many carboxylations compound, BASF AG produces, trade(brand)name Sokalan CP
Figure C99812797D00442
Be below also applicable to the laundry drip washing cycle the limiting examples according to preliminary wetting fabric-conditioning of the present invention and/or fabric enhancing compositions.Following example provides the effect of fabric abrasionproof for the fabric of crossing with described compositions-treated.
Table VII
Weight %
Composition 37 38 39
Polymkeric substance 1 3.5 3.5 3.5
Laking agent 2 2.3 2.4 2.5
Polyamines 3 15.0 17.5 20.0
Bayhibit?AM 4 1.0 1.0 1.0
Water and trace ingredients Equal amount Equal amount Equal amount
1. fabric anti-attrition polymer poly vinyl pyrrolidone K90, BASF AG produces, trade(brand)name Luviskol
Figure C99812797D00443
2. laking agent, Clariant company produces, trade(brand)name Cartafix
Figure C99812797D00444
3. 1,4-two (3-aminopropyl) piperazine.
4. 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid, Bayer AG produces.
Table VIII
Weight %
Composition 40 41 42
Polymkeric substance 1 3.5 3.5 3.5
Laking agent 2 2.3 2.4 2.5
Polyamines 3 15.0 17.5 20.0
Bayhibit?AM 4 1.0 1.0 1.0
Chlorination C 12-C 14The dimethyl ethoxyl quaternary ammonium salt 5.0 5.0 5.0
Fabric softener 5 2.5 2.5 2.5
Genamine?C?100 0.33 0.33 0.33
Water and trace ingredients Equal amount Equal amount Equal amount
1. fabric anti-attrition polymer poly vinyl pyrrolidone K90, BASF AG produces, trade(brand)name Luviskol
Figure C99812797D00451
2. laking agent, Clariant company produces, trade(brand)name Cartafix
Figure C99812797D00452
3. 1,4-two (3-aminopropyl) piperazine.
4. 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid, Bayer AG produces.
5. methylsulfuric acid two (Tower rape oil acyl-oxygen ethyl) hydroxyethyl ammonium methyl.
Table I X
Weight %
Composition 43 44 45 46
Polymkeric substance 1 -- 7.5 3.5 3.5
Laking agent 2 2.5 5.0 2.4 2.4
Polyamines 3 -- 5.0 10.0 --
Polyamines 4 -- -- -- 10.0
Bayhibit 5 1.0 1.0 1.0 1.0
Water Equal amount Equal amount Equal amount Equal amount
1. Polyvinylpyrolidone (PVP) K85 is available from BASF's
Figure C99812797D00453
2. laking agent, Clariant company produces, trade(brand)name Cartafix
Figure C99812797D00454
3. 1,1-N-dimethyl-9,9-N " dimethyl dipropylenetriamine.
4. 1,1-N-dimethyl-5-N '-methyl-9,9-N " dimethyl dipropylenetriamine.
5. 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid, Bayer AG produces.
Table X
Weight %
Composition 47 48 49 50
Polymkeric substance 1 3.5 3.5 2.0 --
Laking agent 2 2.4 2.4 1.0 2.5
Polyamines 3 15.0 17.0 5.0 7.0
Fabric softener 4 -- -- 10.0 --
Bayhibit 5 1.0 1.0 0.2 1.0
Water Equal amount Equal amount Equal amount Equal amount
1. Polyvinylpyrolidone (PVP) K85 is available from BASF's
Figure C99812797D00461
2. laking agent, Clariant company produces, trade(brand)name Cartafix
Figure C99812797D00462
3.N, N '-two (3-aminopropyl)-1,4-piperazine.
4. chlorination two (tallow acyl-oxygen ethyl) Dimethyl Ammonium.
5. 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid, Bayer AG produces.
Table X I
Weight %
Composition 51 52 53 54
Polymkeric substance 1 4.5 4.5 3.5 3.5
Laking agent 2 2.4 2.4 2.4 2.4
Polyamines 3 7.0 8.0 -- --
Polyamines 4 -- -- 15.0 --
Polyamines 5 -- -- -- 15.0
Bayhibit 5 1.0 1.0 1.0 1.0
Water Equal amount Equal amount Equal amount Equal amount
1. Polyvinylpyrolidone (PVP) K85 is available from BASF's
Figure C99812797D00463
2. laking agent, Clariant company produces, trade(brand)name Cartafix
Figure C99812797D00464
3. 1,1-N-dimethyl-9,9-N " dimethyl dipropylenetriamine.
4. 1,1-N-dimethyl-5-N '-methyl-9,9-N " dimethyl dipropylenetriamine.
5. N, N '-two (3-aminopropyl)-1,4-piperazine.
6. 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid, Bayer AG produces.
Table X II
Weight %
Composition 55 56 57 58
Polymkeric substance 1 4.5 4.5 3.5 3.5
Laking agent 2 2.4 2.4 2.4 2.0
Polyamines 3 -- -- 17.0 25.0
Polyamines 4 20.0 25.0 -- --
Bayhibit 5 1.0 1.0 1.0 0.2
Water Equal amount Equal amount Equal amount Equal amount
1. Polyvinylpyrolidone (PVP) K85 is available from BASF's
Figure C99812797D00471
2. laking agent, Clariant company produces, trade(brand)name Cartafix
Figure C99812797D00472
3. N, N '-two (3-aminopropyl)-1,4-piperazine.
4. 1,1-N-dimethyl-5-N '-methyl-9,9-N " dimethyl dipropylenetriamine.
5. 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid, Bayer AG produces.

Claims (11)

1. an energy provides the fabric softening compositions isotropy liquid of fabric anti-attrition effect and color fidelity benefit, that drip washing adds in the drip washing cycle, and described composition comprises:
A) from a kind of fabric anti-attrition polymkeric substance of 0.01%-20% weight, described fabric anti-attrition polymkeric substance is that molecular weight is 160,000～360,000 daltonian a kind of Polyvinylpyrolidone (PVP);
B) from a kind of fabric softener of 1%～80% weight;
C) randomly, be less than the basic solvent of 15% weight, the ClogP of described solvent is 0.15～1;
G) one or more crystal growth inhibitors of 0.005%～1% weight;
1) can provide the line style or the cyclic polyamine of bleaching provide protection from one or more of 0.01%-5% weight; With
M) carrier of remaining sum and supplementary component.
2. according to the composition of claim 1, it further comprises one or more laking agent of 0.001%～90% weight.
3. according to the composition of claim 1, it further comprises one or more cellulose reactive laking agent of 0.01%～50% weight.
4. according to the composition of claim 1, it further comprises the chlorine scavenger of 0.01%～15% weight.
5. according to the composition of claim 1, it further comprises one or more liquid vehicles of 1%～12% weight.
6. according to the composition of claim 1, it further comprises the enzyme of 0.001%～1% weight.
7. according to the composition of claim 1, it further comprises the polyolefin emulsion or the suspension of 0.01～8% weight.
8. according to the composition of claim 1, it further comprises a kind of stablizer of 0.01～0.2% weight.
9. according to the composition of claim 1, the water solubility of wherein said Polyvinylpyrolidone (PVP) is 1000ppm at least.
10. according to the composition of claim 1, it further comprises the laking agent of 0.001%～50% weight.
11. composition according to claim 1; wherein said polyamines is selected from following one group bleaching protection polyamines: 1; 4-two (3-aminopropyl) piperazine, 1; 1-N-dimethyl-5-N '-methyl-9,9-N " dimethyl dipropylenetriamine, 1,1-N-dimethyl-9; 9-N " dimethyl dipropylenetriamine, N; N '-two (3-aminopropyl)-1, the 3-propylene diamine, and composition thereof.
CNB998127973A 1998-11-02 1999-10-22 Fabric care compositions having reduced fabric abrasion Expired - Fee Related CN100463956C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10675998P 1998-11-02 1998-11-02
US11031098P 1998-11-30 1998-11-30
US60/106,759 1998-11-30
US60/110,310 1998-11-30

Publications (2)

Publication Number Publication Date
CN1325433A CN1325433A (en) 2001-12-05
CN100463956C true CN100463956C (en) 2009-02-25

Family

ID=26804003

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998127973A Expired - Fee Related CN100463956C (en) 1998-11-02 1999-10-22 Fabric care compositions having reduced fabric abrasion

Country Status (10)

Country Link
EP (1) EP1124927B1 (en)
JP (1) JP4509384B2 (en)
CN (1) CN100463956C (en)
AT (1) ATE352605T1 (en)
AU (1) AU1228300A (en)
BR (1) BR9914980B1 (en)
CA (1) CA2347809C (en)
DE (1) DE69935001T2 (en)
ES (1) ES2281208T3 (en)
WO (1) WO2000026331A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5670815B2 (en) * 2011-04-21 2015-02-18 花王株式会社 Treatment agent composition for clothing

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4126563A (en) * 1974-07-08 1978-11-21 Graham Barker Composition for treating fabrics, method for making and using the same
CN1066878A (en) * 1991-04-12 1992-12-09 普罗格特-甘布尔公司 Laundry detergent composition
WO1995006098A1 (en) * 1993-08-27 1995-03-02 Cussons (International) Limited Laundry detergent composition

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE785653A (en) * 1971-07-02 1973-01-02 Procter & Gamble Europ
US5451341A (en) * 1993-09-10 1995-09-19 The Procter & Gamble Company Soil release polymer in detergent compositions containing dye transfer inhibiting agents to improve cleaning performance
EP0778342A1 (en) * 1995-12-06 1997-06-11 The Procter & Gamble Company Detergent compositions
ZA974226B (en) * 1996-05-17 1998-12-28 Procter & Gamble Detergent composition
EP0919610B1 (en) * 1997-10-31 2005-03-16 The Procter & Gamble Company Liquid acidic limescale removal compositions packaged in a spray-type dispenser
ATE293673T1 (en) * 1998-05-15 2005-05-15 Procter & Gamble LIQUID, ACIDIC CLEANING COMPOSITION FOR HARD SURFACES
US6627590B1 (en) * 1998-05-22 2003-09-30 The Procter & Gamble Company Acidic cleaning compositions with C10 alkyl sulfate detergent surfactant
EP0982394A1 (en) * 1998-08-27 2000-03-01 The Procter & Gamble Company Liquid neutral or alkaline hard-surface cleaning composition
EP1114134B1 (en) * 1998-09-15 2006-10-25 The Procter & Gamble Company Rinse-added fabric care compositions comprising low molecular weight linear polyamines

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4126563A (en) * 1974-07-08 1978-11-21 Graham Barker Composition for treating fabrics, method for making and using the same
CN1066878A (en) * 1991-04-12 1992-12-09 普罗格特-甘布尔公司 Laundry detergent composition
WO1995006098A1 (en) * 1993-08-27 1995-03-02 Cussons (International) Limited Laundry detergent composition

Also Published As

Publication number Publication date
AU1228300A (en) 2000-05-22
CA2347809C (en) 2007-04-24
BR9914980B1 (en) 2009-01-13
JP4509384B2 (en) 2010-07-21
WO2000026331A1 (en) 2000-05-11
CN1325433A (en) 2001-12-05
CA2347809A1 (en) 2000-05-11
ATE352605T1 (en) 2007-02-15
DE69935001T2 (en) 2007-08-30
BR9914980A (en) 2001-08-14
EP1124927A1 (en) 2001-08-22
EP1124927B1 (en) 2007-01-24
JP2002528663A (en) 2002-09-03
ES2281208T3 (en) 2007-09-16
DE69935001D1 (en) 2007-03-15

Similar Documents

Publication Publication Date Title
EP1163319B1 (en) Fabric maintenance compositions comprising certain cationically charged fabric maintenance polymers
US6642200B1 (en) Fabric maintenance compositions comprising certain cationically charged fabric maintenance polymers
CA3011431C (en) Fabric treatment compositions, their manufacture and use
CN106536697B (en) Fabric and home care treatment compositions
US20060252669A1 (en) Fabric care composition comprising polymer encapsulated fabric or skin beneficiating ingredient
CN1882678B (en) Laundry compositions having copolymers containing polyalkylene oxide groups and quaternary nitrogen atoms and a surfactant system
EP0966513B1 (en) Fabric laundry treatment composition
CA2745628A1 (en) Improvements relating to fabric conditioners
KR100336148B1 (en) Color care compositions
JPH09509455A (en) Cellulase fabric conditioning composition
US6020302A (en) Color care compositions
US6531438B1 (en) Rinse-added fabric care compositions comprising low molecular weight linear and cyclic polyamines
CN100463956C (en) Fabric care compositions having reduced fabric abrasion
US6143712A (en) Fabric softening compositions
JP2002522651A (en) Fabric protection composition
US6794355B1 (en) Fabric care composition having reduced fabric abrasion
CA2359438A1 (en) Fabric enhancement compositions
US6410503B1 (en) Fabric care compositions
JP2002537492A (en) Fabric improving composition
JP2001524618A (en) Stabilized fabric softener composition
JP2003515007A (en) Fabric strengthening agent

Legal Events

Date Code Title Description
C06 Publication
C10 Entry into substantive examination
PB01 Publication
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20090225

Termination date: 20111022