CN100457243C - Superfine air bubble generation method and device and sterilization device using same - Google Patents

Superfine air bubble generation method and device and sterilization device using same Download PDF

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Publication number
CN100457243C
CN100457243C CNB2006100086525A CN200610008652A CN100457243C CN 100457243 C CN100457243 C CN 100457243C CN B2006100086525 A CNB2006100086525 A CN B2006100086525A CN 200610008652 A CN200610008652 A CN 200610008652A CN 100457243 C CN100457243 C CN 100457243C
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air bubble
sterilization
water
superfine
micro air
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CN1840231A (en
Inventor
日高政隆
隅仓岬
阴山晃治
横井浩人
武本刚
渡边昭二
圆佛伊智朗
原直树
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Hitachi Ltd
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Hitachi Ltd
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Abstract

The present invention provides a method and a device forming superfine bubbles retainable for a long period of time and a water treating device applying it for sterilizing and disinfecting facilities for sewage treating water. A water sterilizing and disinfecting vessel 1, a low-pressure container 2 and a superfine bubble forming device 3 are provided. The sewage treating water is charged to the water sterilizing and disinfecting vessel 1 and the treated water is discharged from a sewage re-generating water discharge pipe. Fine bubbles are formed by a fine bubble forming device 3 to be charged to the low pressure container 2. The fine bubbles charged to the low-pressure container 2 are pressurized and compressed by a booster pump 4 to become superfine bubbles, by rapidly reducing their volume, retainable for a long period of time. The superfine bubbles are charged to the sterilizing and disinfecting vessel 1 to perform sterilization by an oxidation reaction by an pressure wave accompanying disintegration of the superfine bubbles 15 and a hydroxyl free radical. The sterilizing effect is enhanced by gradually destroying of the superfine bubbles of which parts are retained for a long period of time.

Description

Generation method, the generating apparatus of superfine air bubble and utilize its sterilization or sterilizing equipment decontaminating apparatus
Technical field
The present invention relates to the device of purification, sterilization, sterilization of running water, Xia Shui, rivers and creeks water, lake water, industrial wastewater etc. and sterilization, sterilizing equipment decontaminating apparatus.
Background technology
As the utilization of the micro air bubble that purification, sterilization, sterilization are shown and the document of effect, has non-patent literature 1.In addition, the document as illustrating with the Ozone Water sterilization effects has non-patent literature 2.
At first, according to the record of non-patent literature 1, the micro air bubble that illustrates in this specification and the definition of superfine air bubble are shown.Micro air bubble is for being called as the about bubble below 50 microns of diameter of microvesicle (マ イ Network ロ バ Block Le).The bubble of general this size is added to surrounding fluid by gas in the bubble and dwindles in liquid, the finally dissolving fully at about 2 minutes.On the other hand, superfine air bubble is to be called as nanometer bubbles bubble, diameter 100 nanometers~200 nanometers.Nanometer bubble dwindles at microvesicle, exist in the consoluet process, but continue usually to dwindle, dissolving fully.
As shown in the non-patent literature 1, by micro air bubble (microvesicle) is applied hydromechanical stimulation, bubble diameter is dwindled rapidly, do not dissolve the ground bubble that exists steady in a long-term, promptly have the superfine air bubble (nanometer bubble) of long-term retentivity thereby can generate.To micro air bubble (microvesicle) apply physical stimulation, process that bubble diameter is dwindled rapidly is called as and damages by pressure.
In addition, according to non-patent literature 1, along with micro air bubble is added to surrounding liquid, diameter reduces, so, make inside become high pressure, high temperature by capillary effect, produce pressure wave during elimination.But by this pressure wave decomposing bacteria, organic matter, so, purification, sterilization, Disinfection Effect can be obtained.In addition, in the dissolving of bubble, the surface area ratio of relative volume is bigger, so micro air bubble has the effect of raising in the dissolution velocity of liquid.
According to non-patent literature 2, dissolved in the oxidation-reduction potential height of the Ozone Water of ozone gas, have the strong disinfecting effect.As in the manufacturing of Ozone Water, using micro air bubble, dissolution velocity height then, so the bubble of not running away from liquid level reduces with not dissolving, the utilization ratio of ozone improves.Yet the ozone in the liquid decomposes easily, so, the problem that exists short time concentration to descend.
Superfine air bubble shown in the non-patent literature 1 (nanometer bubble: diameter is about below 1 micron) is because buoyancy is little, so, be difficult for running away from liquid level.In addition, common micro air bubble is added to liquid gradually and eliminates under the state that compares balance, but the superfine air bubble that damages by pressure has long-term retentivity.By in liquid, damaging the generation superfine air bubble in large quantities by pressure, thereby for example can keep the concentration of higher Ozone Water for a long time.In addition, because diameter is little, so the pressure wave during elimination is big, purification, sterilization, Disinfection Effect are also high.Like this, can obtain can the long term maintenance sterilization, the effect of sterilizing function.
Shown in non-patent literature 1, like that, in order to generate superfine air bubble with long preservation period, need in being added to the process of liquid, micro air bubble apply the stimulation that is called as the equation of damaging by pressure.
[non-patent literature 1] " characteristic of water and newly utilize technology ", the LTS of Co., Ltd. (エ ヌ テ イ one エ ス), 142-146 page or leaf, 2004.
[non-patent literature 2] " new technology that new edition ozone utilizes ", three excellent (サ Application ユ one) study, 74-83 page or leaf, 1988.
In the prior art of non-patent literature 1, though recorded and narrated the effect of superfine air bubble and the possibility of long preservation, not shown applying is used to generate the method that damaging by pressure of superfine air bubble with long preservation period is hydromechanical stimulation.
In the prior art of non-patent literature 2 records, consider the decomposition of ozone, need to increase place capacity, the economy of equipment construction descends.In addition, when equipment moved, the sterilizing of following water treatment water used the high ozone of manufacturing cost, and the ozone in the liquid decomposes easily, and concentration descended in the short time.For this reason, for sterilization, sterilization, need long-term a large amount of ozone of supplying with, the problem that exists economy to reduce.
In addition, in the sterilizing equipment that uses micro air bubble, superfine air bubble, when the processing discharge of controlling inflow inadequately and bubble quantity delivered, mistake or not enough situation according to the bubble supply, in the occasion of surplus, economy descends, in the occasion of deficiency, bactericidal property descends, and has the problem of the reliability decrease of sterilizing equipment.
Summary of the invention
In order to achieve the above object, the present invention is at the low liquid in container of pressure ratio atmosphere pressures, be under the reduced pressure atmosphere, the generation diameter is about the micro air bubble below 50 microns, liquid in container pressurization to above-mentioned low pressure, the compression micro air bubble, generating diameter is the superfine air bubble of 100 nanometers~200 nanometers.In addition, have such feature: the liquid that will have above-mentioned superfine air bubble is pressurized to atmosphere pressures, is discharged in the atmosphere.
According to the present invention, has the effect that the function that makes the sterilization that utilizes superfine air bubble with long preservation period or sterilizing equipment decontaminating apparatus enlarges.
Description of drawings
Fig. 1 is the pie graph of the sterilizing equipment that utilizes superfine air bubble of the embodiment of the invention 1.
Fig. 2 is the pressure-plotting in sterilizing loop.
Fig. 3 is the pie graph that uses the occasion of ozone at the sterilizing equipment of embodiment 1.
Fig. 4 is the pie graph of sterilizing equipment that the variation of embodiment 1 is shown.
Fig. 5 is the pie graph of the sterilizing equipment that utilizes superfine air bubble of the embodiment of the invention 2.
Fig. 6 is the flow-control flow chart of the sterilizing equipment of the embodiment of the invention 2.
Fig. 7 is the pie graph of the sterilizing equipment that utilizes superfine air bubble of the embodiment of the invention 3.
Fig. 8 is the pie graph of the sterilizing equipment that utilizes superfine air bubble of the embodiment of the invention 4.
Fig. 9 is the procedure chart that the superfine air bubble of the embodiment of the invention 4 is blown into.
The specific embodiment
The object of the present invention is to provide a kind of nonequilibrium Pressure stimulation above its dissolution velocity, method and apparatus of generation superfine air bubble with long preservation period of when bubble is added in the liquid, applying.
The present invention promptly under the reduced pressure atmosphere, generates micro air bubble at the low liquid in container of pressure ratio atmosphere pressures, and to the liquid in container pressurization of above-mentioned low pressure, the compression micro air bubble generates superfine air bubble.In addition, have such feature: the liquid that will have above-mentioned superfine air bubble is pressurized to atmosphere pressures, is discharged in the atmosphere.
Specifically, the container of low pressure keeps low-pressure state by pump or suction device, from the micro air bubble generating apparatus gas is injected into the low liquid in container of pressure ratio atmosphere pressures, generate micro air bubble, by pump this liquid in container is pressurizeed, the compression micro air bubble generates superfine air bubble, in the process of being compressed by pump, the liquid that will have superfine air bubble from low pressure vessel is discharged to the atmosphere.As the pump that the fluid under the above-mentioned reduced pressure atmosphere is pressurizeed, is discharged in the atmosphere, use booster effective, particularly preferably use vortex flow type pump, scroll type pump, high-pressure plunger type pump etc.
In the present invention, the movement of dwindling of the balance when being added to liquid with micro air bubble is compared, can rapid and non-equilibrium ground compressed air bubble, so, can apply the hydromechanical stimulation that is used to form superfine air bubble with long preservation period and promptly damage stimulation by pressure.
Like this, can generate can long preservation superfine air bubble, the effect of sustainable maintenance sterilization, sterilizing function.For example, generate the ozone superfine air bubble, be applicable to the water treatment of running water, Xia Shui, rivers and creeks water, lake water, industrial wastewater, thereby but the water of high water quality is supplied with in the breeding of long term inhibition bacterium by using this method and device.
Particularly, be provided with and drop into the processing tank of handling water, in handling water, inject superfine air bubble about sterilization, the sterilization of water treatment water down.Adjust the flow of handling water evenly with the rate of climb of superfine air bubble, in tank, form the belt-like zone of superfine air bubble.
Handle water when passing through the belt-like zone of superfine air bubble, carry out sterilization, sterilization by above-mentioned effect.In order to keep sterilization, disinfective action, measure the position of the above-mentioned belt-like zone of acquisition according to using differential pressure measurement optics or waterpower etc., prevent from the disengaging of the liquid level of above-mentioned belt-like zone or with handle water discharge together etc., it is effective that the flow of water is handled in control.
According to the present invention, but has the effect of the function of the sterilization of expansion long preservation superfine air bubble or sterilizing equipment decontaminating apparatus.
In addition, owing in having utilized the sterilizing equipment of superfine air bubble, do not utilize bubble can descend the sterilization or the sterilization of water treatment water, so, can make the place capacity optimization, have the effect of raising about the economy of the making of descending water treatment facilities.
In addition, owing in utilizing the sterilizing equipment of superfine air bubble, can reduce the bubble use amount, so, have the effect of raising about the economy of the operation funds of following water treatment facilities.
In addition, owing to can control the growing amount of superfine air bubble by good precision, so, have the reliability of water treatment facilities under improving and the effect of economy.
Below, form of implementation of the present invention is described with reference to the accompanying drawings.Fig. 1 is the pie graph of the sterilizing equipment that utilizes superfine air bubble of embodiment 1, and Fig. 2 is the schematic diagram of pressure distribution, and Fig. 3 is the pie graph that utilizes the sterilizing equipment of ozone superfine air bubble.
In Fig. 1, be provided with down sterilizing groove 1, low pressure vessel 2, the micro air bubble generating apparatus 3 of water treatment water.In sterilizing groove 1, inject water treatment water down from following water treatment water ascending pipe 21, the water after handling is discharged from water reuse (treatment water discharge pipe 22 down.
From the water of micro air bubble device circulation stream 8 taking-up low pressure vessels 2, in gas phase blender 12 with from gas phase pipe 17, mix by the gas phase that flow rate regulating valve 13 flows into, deliver to micro air bubble generating apparatus 3.In by the micro air bubble generating apparatus 3 shown in the present embodiment, generate micro air bubble according to gas-liquid two-phase cut mode by high-pressure pump 11, be injected into low pressure vessel 2 from nozzle 19.The generation of micro air bubble is adjusted by flow rate regulating valve 17 and flow rate regulating valve 18.
The micro air bubble that is injected into low pressure vessel 2 by rapid volume-diminished, forms superfine air bubble with long preservation period by booster 4 pressurizations, compression.This superfine air bubble is injected into the sterilizing tank 1 near atmosphere pressures.Pressurization does not make all micro air bubbles be varied to superfine air bubble, is discharged to the atmosphere by gas phase pipe 14 from low pressure vessel 2 with the state that mixes with a part of micro air bubble sometimes.
The superfine air bubble 15 that injects destroys the oxidation reaction that the pressure wave that produces and hydroxyl free radical produce by it and carries out sterilization processing, long-term maintenance of a part and little by little destroying, thus have Disinfection Effect.The water (recycled water) that is subjected to the sterilizing processing is from water reuse (treatment water discharge pipe 22 taking-ups down.
The flow that is injected into the superfine air bubble of sterilizing groove 1 from low pressure vessel 2 is adjusted by flow rate regulating valve 9.Because the suction pressure of pump 4 is a negative pressure,, in the time will becoming lower pressure, use vavuum pump 5, the gas phase of discarded low pressure vessel gas phase portion 16 so the pressure ratio atmosphere pressures of low pressure vessel 2 is low.In addition, the pressure of low pressure vessel 2 also can be adjusted by flow rate regulating valve 6.
Fig. 2 illustrates from low pressure vessel 2 along sterilizing groove 1, an example of the pressure distribution of the system in the loop of processing water circulation stream 7.In being adjusted to 0.4 atmospheric low pressure vessel 2, generate micro air bubble by micro air bubble generating apparatus 3.Micro air bubble in the low pressure vessel 2 is attracted by booster 4, is discharged to sterilizing groove 1.At this moment, the pressure loss of flow rate regulating valve 9 descends pressure slightly.The pressure ratio of the outlet of booster 4 and atmospheric pressure exceed and the suitable amount of dynamic pressure amount that flows, but are released to the sterilizing groove 1 of atmosphere opening, and static determinacy is an atmospheric pressure.After this, the processing water that comprises superfine air bubble is by handling water circulation stream 7, and the pressure by after pressure loss amount atmospheric pressure and head and that deduct pipeline by flow rate regulating valve 6, turns back to low pressure vessel 2.In flow rate regulating valve 6, produce the pressure loss corresponding with the aperture of valve.
Handle in the water loop at this, owing to being connected to sterilizing groove 1 by the lower pressure loss, so the superfine air bubble after the pressurization compression is delivered to not decompression, expansion sterilizing groove 1 basically from booster 4.
Booster 4 has flow rate regulating valve 9 in its suction portion, owing to produce the pressure loss, so, be easy to generate cavitation.For this reason, use anti-cavitation (the キ ヤ PVC テ one シ ヨ Application) vortex flow type pump that performance is high, scroll type pump, high-pressure plunger type pump etc.In addition, do not produce the aperture that flow rate regulating valve 9 is adjusted on cavitation ground.
Fig. 3 illustrates the sterilizing equipment that uses ozone.Occasion using ozone as the gas phase of using in the sterilizing equipment at present embodiment needs ozone generating apparatus 23 and useless ozone treatment apparatus 24, and sterilizing groove 1 also needs airtight.Yet ozone has the effect that obtains high sterilizing power according to the dissolved efficiency of its powerful oxidation and micro air bubbleization.
Occasion using oxygen as the gas phase of using in the sterilizing equipment at present embodiment though oxidizing force is lower than ozone, can obtain enough sterilizing powers.In addition, do not need to be provided with airtight, ozone generating apparatus 23, and the useless ozone treatment apparatus 24 of sterilizing groove 1.In addition, even in the occasion of using air, the pressure wave in the time of also can destroying by superfine air bubble and the oxidation reaction of hydrogen-oxygen free radical obtain bactericidal action.
According to the sterilizing equipment that utilizes superfine air bubble of present embodiment, seldom can carry out sterilizing to following water treatment water with chlorine, so, have and improve the effect and the effect that improves the sterilizing performance of the economy of water treatment facilities down.
The following describes the modified example of present embodiment.Fig. 4 is the pie graph of sterilizing equipment of the modified example of embodiment 1.Sterilizing equipment shown in Figure 1 has relatively been cancelled the micro air bubble generating apparatus based on centrifugal separation and dissolved under pressure method, and the micro air bubble generating apparatus that utilizes ultrasonic cavitation is set.
The device that utilizes ultrasonic cavitation by ultrasonic oscillator 31, cable 32, and the ultrasonic wave machine 33 of delivering letters constitute.By using ultrasonic oscillator 31, thereby can produce the bubble of homogeneous diameter.In addition,, can control the generation of micro air bubble, adjust bubbles volume easily by electricity output to ultrasonic oscillator 31.
According to the sterilizing equipment of the variation of present embodiment, can be by the growing amount of good precision control superfine air bubble, so, have and improve the effect of the reliability of water treatment facilities down.
Below, embodiments of the invention 2 are described.Fig. 5 is the pie graph of the sterilizing equipment that utilizes superfine air bubble of embodiment 2, and Fig. 6 be the flow-control flow chart based on the sterilizing equipment of voidage detection of embodiment 2.
In by the sterilizing equipment shown in the embodiment 1, controller 44 is set, at following water treatment water ascending pipe 21 flow rate regulating valve 42 and flowmeters 47 are installed, at following water reuse (treatment water discharge pipe 22 flow rate regulating valve 43 and flowmeters 48 are installed.In addition, at the central portion fixing clearance rate meter 35 of sterilizing groove 1, fixing clearance rate meter 73 up, fixing clearance rate meter 74 below voidage meter 35 is connected to controller 44 with the detection of these voidage meters with line.In addition, the detection with flowmeter 47 and flowmeter 48 is connected to controller 44 with line.Adjust valve 42, flow rate regulating valve 43 at controller 44 usefulness control line connection traffics, carry out the straighforward operation of valve according to control signal.
In controller 44, measure the voidage of sterilizing groove 1 with voidage meter 35, the zone that superfine air bubble is existed is as input signal, superfine air bubble towards above the occasion that moves, the measuring-signal of one side monitor traffic meter 47, increase the aperture of flow rate regulating valve 42 on one side, make and handle the control that the water influx increases.Equally, on one side the measuring-signal of monitor traffic meter 48, the aperture of flow rate regulating valve 43, the control that the recycled water discharge rate is increased increased on one side.On the other hand, superfine air bubble with handle water towards below the occasion that moves, reduce the aperture of flow rate regulating valve 42 and flow rate regulating valve 43, reduce the control of handling water influx and recycled water discharge rate.
Below, the flow chart of flow-control of the measured value of relative voidage meter is described according to Fig. 6.Concentrate belt-like zone 41 to be in the occasion of the common depth of water at micro air bubble, voidage meter 35 detects the existence of bubble.
Voidage meter 35, voidage meter 73, and voidage meter 74 all detect the occasion of bubble, bubble is for being that the center is present in the state from the top to the below with the common depth of water.Therefore, slave controller 44 is sent the signal that flow rate regulating valve 42, flow rate regulating valve 43 all keep present aperture.
Detect at voidage meter 35 and voidage meter 73, voidage meter 74 undetected occasions, bubble with the common depth of water be the center be in the top.Therefore, slave controller 44 is sent the signal of flow rate regulating valve 42, all little increase degree of flow rate regulating valve 43.Like this, the decline flow velocity of handling water increases slightly, and micro air bubble concentrates belt-like zone 41 to descend gradually, is stagnating near the depth of water usually.
Detect at voidage meter 35 and voidage meter 74, voidage meter 73 undetected occasions, bubble with the common depth of water be the center be in the below.Therefore, slave controller 44 is sent all the shade signal of aperture of flow rate regulating valve 42, flow rate regulating valve 43.Like this, the upflow velocity of handling water increases slightly, and micro air bubble concentrates belt-like zone 41 to rise gradually, is stagnating near the depth of water usually.
Detect at voidage meter 35, voidage meter 73 and voidage meter 74 undetected occasions, bubble is present in the common depth of water.Therefore, slave controller 44 is sent the signal that flow rate regulating valve 42, flow rate regulating valve 43 all keep present aperture.
Do not detect at voidage meter 35, voidage meter 73 and voidage meter 74 detected occasions, bubble is clamped the common depth of water and is present in 2 positions, above and below.In this occasion, concentrate belt-like zone 41 to transfer to the common depth of water micro air bubble of below and carry out sterilizing.Therefore, slave controller 44 is sent the signal that flow rate regulating valve 42, flow rate regulating valve 43 all reduce aperture.Like this, the decline flow velocity of handling water reduces, and micro air bubble concentrates belt-like zone 41 to rise, and is stagnating near the depth of water usually.
Detect at voidage meter 73, voidage meter 35 and voidage meter 74 undetected occasions, bubble is present in the top of the common depth of water.Therefore, slave controller 44 is sent the signal that flow rate regulating valve 42, flow rate regulating valve 43 all increase aperture.Like this, the decline flow velocity of handling water increases, and micro air bubble concentrates belt-like zone 41 to descend, and is stagnating near the depth of water usually.
Detect at voidage meter 74, voidage meter 35 and voidage meter 73 undetected occasions, bubble is present in the below of the common depth of water.Therefore, slave controller 44 is sent the signal that flow rate regulating valve 42, flow rate regulating valve 43 all reduce aperture.Like this, the decline flow velocity of handling water reduces, and micro air bubble concentrates belt-like zone 41 to rise, and is stagnating near the depth of water usually.
Voidage meter 35, voidage meter 73, and voidage meter 74 all do not detect the occasions of bubble, bubble is not present in the measurement category of voidage meter.Therefore, put aside the common depth of water in order to make bubble, slave controller 44 transmitted traffics are adjusted the signal that valve 42, flow rate regulating valve 43 all keep present aperture.
Above control increase by the occasion that is combined in water level and descends flow rate regulating valve 42 aperture operation and implemented in the operation that the occasion that water level rises increases the aperture of flow rate regulating valve 43.
By above control, superfine air bubble can be focused on the central portion of sterilizing groove 1, be concentrated into band shape and be configured.Concentrate in the belt-like zone 41 at this micro air bubble, the interval of superfine air bubble dwindles, and superfine air bubble can not run out of from the top basically, but concentrates belt-like zone 41 to destroy at micro air bubble.Like this, the density of the oxidation reaction that pressure wave in the time of can increasing micro air bubble destruction and hydrogen-oxygen free radical produce, so the sterilizing performance improves, simultaneously, the utilization ratio of bubble improves, and can reduce to produce bubbles volume.
According to the sterilizing equipment of the superfine air bubble that utilizes present embodiment, except the effect of embodiment 1, also have the economy of water treatment facilities under can improving and the effect of sterilizing performance.
Below, embodiments of the invention 3 are described.Fig. 7 is the pie graph of the sterilizing equipment that utilizes superfine air bubble of embodiment 3.
In sterilizing equipment shown in the embodiment 2, tabular ultrasonic oscillator 45 is located in the sterilizing groove 1, by ultrasonic wave sender 46 drive vibrator 45.Ultrasonic wave sender 46 usefulness control lines are connected to controller 44, make ultrasonic oscillator 45 by low-frequency vibration according to the control signal of controller 44.Here, apply vibration, make bubble destruction and be dissolved as purpose with 45 pairs of bubbles of ultrasonic oscillator.The frequency of ultrasonic wave sender 46 is used about 20kHz~100kHz.
In controller 44, measure the voidage of sterilizing grooves 1 with voidage meter 35, reach moment of predetermined value in voidage, concentrate belt-like zone 41 to apply ultrasonic vibration to micro air bubble.Destroy at chien shih superfine air bubble in short-term by the action of ultrasonic waves of low frequency, can be to handling the oxidation reaction that water applies a large amount of pressure waves and produced by the hydrogen-oxygen free radical.In the present embodiment, focus pressure ripple and oxidation reaction act on bacterium, so, can kill the higher bacterium of patience.In case after bubble is eliminated,, form next micro air bubble and concentrate belt-like zone 41 by the control shown in the 2nd embodiment.
The sterilizing equipment that utilizes superfine air bubble according to present embodiment except the effect of the 2nd embodiment, also has the effect that can improve the sterilizing performance.
Below, embodiments of the invention 4 are described.Fig. 8 is the schematic diagram of the superfine air bubble generating apparatus of embodiment 4.
Replace the low pressure vessel of Fig. 1, Fig. 3~sterilizing equipment shown in Figure 7 by the booster 51 of plunger piston type, generate superfine air bubble.Flow into the processing water at sterilizing tank 51 by following water treatment water ascending pipe 61, flow out recycled waters by following water reuse (treatment water discharge pipe 62.The processing water of sterilizing tank 51 enters into the cylinder 53 of booster 52 from handling water circulation stream 57 by flow rate regulating valve 56, check valve 58.
In booster 52, make piston 65 move back and forth the pressure in the master cylinder 53 by piston actuated bar 66, piston drive mechanism 67.When being negative pressure in the cylinder 53, micro air bubble is blown in the cylinder 53 from micro air bubble generating apparatus 63.Drive flow rate regulating valve 56, flow rate regulating valve 59, flow rate regulating valve 64 by measuring-signal by controller 73 according to pressure gauge 74, thus the pressure in the cylinder 53 of control booster 52.
In the present embodiment, be blown into form performance micro air bubble generating apparatus 63, but also can use other micro air bubble producing methods such as pressure reducing mode of gas-liquid two-phase cut mode or dissolved under pressure liquid by the gas phase of nozzle.
Below, according to Fig. 9 the process that superfine air bubble is blown into is described.In Fig. 9 (a), draw piston 65 by piston actuated bar 66 towards the direction of arrow among the figure, become negative pressure by the pressure loss of flow rate regulating valve 56 in the cylinder 53.At this moment, decompression makes the part gasification of dissolving in the gas phase in the water, and gas phase portion is formed at the top in cylinder 53.
In the moment of piston arrives minimum point (pulling out fully), open flow rate regulating valve 64 ground are controlled, and from micro air bubble generating apparatus 63 micro air bubble are blown in the cylinder 53 of negative pressure.
Behind the predetermined small effluxion, or after piston 65 is pressed into predetermined micro-stroke amount, shown in Fig. 9 (b), like that, close the control of flow rate regulating valve 64.Continue by piston actuated bar 66 that the direction of arrow is pressed into piston 65 in the figure,, deliver to the sterilizing tank by check valve 60 to the pressurization of the micro air bubbles in the cylinder 53.Pressurization in the time of is thus compressed micro air bubble non-equilibriumly, generates superfine air bubble.
Fig. 9 (c) illustrates the state that piston 65 is pressed into fully.After this, draw piston 65 towards the direction of arrow among Fig. 9 (a), turn back to the state of Fig. 9 (a), a series of repeatedly action by piston actuated bar 66.In the present embodiment, the low pressure vessel that booster self can be generated as superfine air bubble, so, but have the advantage of simplified apparatus.
According to the sterilizing equipment that utilizes superfine air bubble of present embodiment, except the effect of the 1st~the 3rd embodiment, also has the effect of the economy that improves equipment making.
Superfine air bubble according to the generation method of the present embodiment of above explanation not only can be used for water treatment down, and can be used for the purification of water quality of water sterilizing, moisture film processing up and down, health medical treatment instrument field, lake or plant, the various wastewater treatments of factory livestock products etc., and the function water manufacturing etc.

Claims (11)

1. the generation method of a superfine air bubble, it is characterized in that: the generation diameter is about the micro air bubble below 50 microns in the liquid in the low low pressure vessel of pressure ratio external pressure, to described liquid pressurization, the compression micro air bubble, generating diameter is the superfine air bubble of 100 nanometers~200 nanometers, and the described pressurized liquid with superfine air bubble is discharged to the outer space of described low pressure vessel.
2. the generating apparatus of a superfine air bubble, it is characterized in that: the low pressure vessel that is provided for the stowing pressure liquid lower than external pressure, diameter is about the micro air bubble feedway that micro air bubble below 50 microns is injected into described low pressure vessel, and the pump of described low pressure vessel of connection and space outerpace, constitute: described micro air bubble feedway produces micro air bubble in the liquid of described low pressure vessel, described pump is to the liquid pressurization of described low pressure, compress described micro air bubble, generating diameter is the superfine air bubble of 100 nanometers~200 nanometers, and the described liquid with superfine air bubble that is pressurizeed is discharged to space outerpace from the discharge side of described pump.
3. the generating apparatus of superfine air bubble according to claim 2 is characterized in that: will remain low-pressure state in the described low pressure vessel by described pump.
4. the generating apparatus of superfine air bubble according to claim 2 is characterized in that: will remain low-pressure state in the described low pressure vessel by the vavuum pump that is connected with described low pressure vessel.
5. the generating apparatus of superfine air bubble according to claim 2 is characterized in that: described micro air bubble feedway is for shearing the gas-liquid two-phase flow mode.
6. the generating apparatus of superfine air bubble according to claim 2 is characterized in that: described micro air bubble feedway is to utilize frequency for the hyperacoustic mode below the above 100kHz of 20kHz.
7. the generating apparatus of superfine air bubble according to claim 2, it is characterized in that: the raw-gas of described micro air bubble is ozone, oxygen or air.
8. the sterilization of a following water treatment water or sterilizing equipment decontaminating apparatus have and are taken into down sterilization or the sterilization tank that water treatment water carries out sterilization or sterilization; It is characterized in that:
Generating apparatus with the described superfine air bubble of claim 2, this low pressure vessel is communicated with described sterilization or sterilization tank by described pump, the micro air bubble that is injected into described low pressure vessel is pressurizeed, is compressed by described pump, and formed diameter is that the superfine air bubble of 100 nanometers~200 nanometers is injected into described sterilization or sterilization tank.
9. the sterilization or the sterilizing equipment decontaminating apparatus of water treatment water down according to claim 8, it is characterized in that: the sinking of water treatment water under in described sterilization or sterilization tank, forming, by with the rate of climb balance of described superfine air bubble, thereby the belt-like zone that superfine air bubble has been concentrated is set, the processing water by belt-like zone is implemented sterilization, disinfective action at this belt-like zone.
10. the sterilization or the sterilizing equipment decontaminating apparatus of water treatment water down according to claim 9, it is characterized in that: the central portion, top of the described belt-like zone of described sterilization or sterilization tank, and the bottom voidage meter is set, the inlet portion of water treatment water is provided with flow rate regulating valve respectively with the export department that discharges water treatment water under the regeneration under being taken into of described sterilization or sterilization tank, and the control device of controlling described flow rate regulating valve according to the indication of these voidage meters is set.
11. the sterilization of a following water treatment water or sterilizing equipment decontaminating apparatus, have be taken into down water treatment water carry out sterilization or sterilization sterilization or the sterilization tank; It is characterized in that:
The booster, the 1st that is provided with plunger piston type is handled water circulation stream, piston drive mechanism, micro air bubble feedway, and the 2nd handles water circulation stream;
Described booster has piston and is used as the cylinder of low pressure vessel;
The described the 1st handles water circulation stream is communicated with described cylinder, has the 1st check valve that the processing water that is used to make described sterilization or sterilize tank is back to the cylinder of described booster;
Described piston drive mechanism drives described reciprocating motion of the pistons;
Described micro air bubble feedway, the micro air bubble that when pulling out described piston diameter is about below 50 microns injects described cylinder;
The described the 2nd handles water circulation stream is communicated with described cylinder, have when being used to described piston is pressed into described micro air bubble pressurization and the diameter of generation to be the superfine air bubble of 100 nanometers~200 nanometers be forced into described sterilization or the 2nd check valve of the tank of sterilizing.
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