CN100429277C - Agricultural stalk base wood and plastic composite material and combination processing method - Google Patents
Agricultural stalk base wood and plastic composite material and combination processing method Download PDFInfo
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- CN100429277C CN100429277C CNB200610086350XA CN200610086350A CN100429277C CN 100429277 C CN100429277 C CN 100429277C CN B200610086350X A CNB200610086350X A CN B200610086350XA CN 200610086350 A CN200610086350 A CN 200610086350A CN 100429277 C CN100429277 C CN 100429277C
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- agricultural stalk
- plastic composite
- composite materials
- section bar
- base wood
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Abstract
The present invention relates to an agricultural stalk-base wood-plastic composite material and a combined processing method. Raw materials comprise plasticized agriculture straw powder and thermoplastic plastics, lubricant comprises dimethyl silicon oil, stearic acid and polyester wax, a solubilizing agent is acrylic acid-phenylethene-maleic anhydride alternating copolymer, a plasticizing agent is dimethyl phthalate, and a fire retarding agent is iron oxide red. The processing method has the steps that the raw materials are uniformly mixed and agitated and then conveyed in a molding mechanism to obtain sections. A natural polymer compound namely agricultural stalk plant fiber and an artificially synthesized high molecular compound have favorable compatibility via the present invention, and thus, interface compound can be really realized to obtain products which have excellent performance and are made of wood-plastic composite materials.
Description
Technical field
The present invention relates to a kind of agricultural stalk base wood plastic composite materials and preparation method.
Background technology
Traditional wood plastic composite mainly be with plant fiber powder as packing material, very difficult realization " polymer chemistry is compound " truly.It is the natural high molecular composite material of main body that vegetable fibre is actually a kind of Mierocrystalline cellulose, hemicellulose, lignin three class natural macromolecular materials.This macromole life compound substance is a complex system.The vegetable fibre surface is the poly-hydroxy structure, it is the polarity hydrophilic substance, and general artificial synthetic macromolecular compound (plastics) is nonpolar oleophilic substance, both are difficult to compatible, and affinity is poor, as simply with the two direct blend, interior outward appearance is coarse, goods become fragile, and machinery, mechanical property is very poor, thereby have limited the use range of product.
Summary of the invention
The objective of the invention is: provide a kind of section bar that is exactly like timber in appearance that utilizes raw material production such as vegetable fibre and plastics, but performance is better than the agricultural stalk base wood plastic composite materials and the preparation method of timber.
Realize that the object of the invention technical scheme is as follows:
The agricultural stalk base wood plastic composite materials comprises the raw material of following weight part
Plasticizing agricultural stalk powder particles material 60-80 part
Thermoplastics 15-25 part
Lubricant 2.5-8 part
Expanding material 3-5 part
Softening agent 1-3 part
Fire retardant 0.1-0.5 part,
800-1250 order superfine talcum powder 3-5 part,
Described lubricant comprises that dimethyl silicone oil, stearic acid and polyester are cured, and described expanding material is vinylformic acid-alternate styrene-maleic anhydride copolymer, and described softening agent is a dioctyl phthalate (DOP), and described fire retardant is a red iron oxide.
The lubricant parts by weight of raw materials is as follows:
Dimethyl silicone oil 1-5 part
1 part of stearic acid
The cured 0.5-2 part of polyester.
Described plasticizing agricultural stalk powder particles material be with agricultural stalk pulverize, activation plasticizing, granulation obtain, described agricultural stalk is the wheat straw stalk, for straw, for cotton stalk, for wood chip, for rice chaff, be bagasse.
Described thermoplastics is a polyethylene, polypropylene, polyvinyl chloride, polystyrene etc.
The preparation method of agricultural stalk base wood plastic composite materials comprises following operation steps
A, with the raw material mixing and stirring in the above-mentioned prescription, churning time 15-30 minute;
B, the raw material of mixing and stirring is sent into shaper make section bar;
The section bar of C, moulding is cooled to room temperature;
D, section bar surface sanded, sand milling surplus 0.2-0.5 millimeter, the section bar surfaceness is 12-100 after the surface treatment;
Described shaper is the SZSJ80/156 conical double screw extruder, is the single screw rod Wood-plastic profiles of DMS65/30 forcing machine, and its processing condition are: driving screw rotating speed 80-160 changes, and barrel zone temperature 120-190 ℃, extrusion pressure is 15-35Mpa.
After the surface treatment, adopt heat transfer printing, or the water trans-printing, print wood grain on the section bar surface.
The agricultural stalk base wood plastic composite materials is mainly to utilize vegetable fibre (as straw, straw, rice husk, cotton stalk, waste of flax, bagasse, bamboo powder, wood powder) and waste or used plastics to be exactly like timber in appearance by what the molecule aggregation novel process was made, but performance is better than the novel material of timber, it is different from fully with resin glue and wood chip, " fiberboard " high-density plate that fiber is bonded, woodwork plate etc., it is by plastic working method such as expressing technique, and injection molding process is produced various sheet materials, section bar and special-shaped material.
Processing method of the present invention, making the natural polymer mixture is that agricultural stalk vegetable fibre and synthetic macromolecular compound have good consistency, thereby can realize truly " interface is compound ", obtain the Wood Plastics Composite Product of excellent performance.
Its physicals is as follows:
| Project | Unit | Testing standard | Numerical value |
| Proportion | g/cm 3 | GB1033 | 0.96-1.1 |
| Coefficient of linear expansion (20 ℃) | mm/mm/℃ | GB1036 | 3.5×10 -5 |
| Moisture absorption | ％ | 0.1 | |
| Water-absorbent (in 24 hours water) (light face) | ％ | 0.2 | |
| The Wood-plastic material surface resistivity | GB1410-89 | ≈8×10 13 | |
| The ultraviolet ray ageing rate | Micron/year | 50-56 |
Its mechanical property is as follows:
Embodiment
Below in conjunction with embodiment, the present invention is further described.
Embodiment 1:
Take off the raw material of row weight part
80 parts in plasticizing agricultural stalk powder particles material
15 parts in polythene thermoplastic plastics
1 part of dimethyl silicone oil
1 part of stearic acid
3 parts of vinylformic acid-alternate styrene-maleic anhydride copolymers
Cured 0.5 part of polyester
0.1 part of red iron oxide
1 part of dioctyl phthalate (DOP)
5 parts of 800-1250 order superfine talcum powders,
Wherein plastifying agricultural stalk powder particles material is to use agricultural stalk, as wheat straw stalk, straw, cotton stalk, wood chip, rice chaff, bagasse, with traditional plant fiber plasticizing process, be about to agricultural stalk and make through segment, pulverizing, plasticizing, the organic cladding of talcum powder, granulation etc.
Wherein thermoplastics also can be a polystyrene etc.
Wherein dimethyl silicone oil, stearic acid, polyester is cured is lubricant, plays and improves material fluidity, reduces the internal cohesive energy effect, vinylformic acid-alternate styrene-maleic anhydride copolymer is an expanding material, dioctyl phthalate (DOP) is a softening agent, red iron oxide is a fire retardant.
Concrete preparation manipulation follows these steps to carry out:
A, the raw material in the above-mentioned prescription is put into the height/cold mixing stirring of kneader device 15-30 minute, mixing and stirring of stirring;
B, the raw material of mixing and stirring is sent into the SZSJ80/156 conical double screw extruder, this machine is with 4 venting holes, and driving screw rotating speed 80-160 changes, and built-in temperature 120-190 ℃, built-in pressures of machine section pressure 30-35Mpa makes multi-cavity wall profiled material; Because of extrusion machinery all has a plurality of gas barrier, material must not dewater in advance can realize drying and devolatilization.
The section bar of C, moulding is cooled to room temperature;
D, section bar surface sanded, sand milling surplus 0.2-0.5 millimeter, the section bar surfaceness is 12-100 after the surface treatment;
Owing in shaper, handle through excessive temperature, wood plastic composite surface plastic molecules is heaped, make that the outward appearance woodiness touch is poor, need to carry out the sand milling grinding process with its surface of wood grain processor pair, can grind deeply and shallow mill as required, vertically carry out several roads, laterally carry out several roads sand milling Fuzzy Processing.Goods have wood grain and skidproof effect concurrently.Can be through the material that wood grain is handled nondiscoloration in outdoor ten years.
If goods are indoor floor, can adopt heat transfer printing to handle, print grain pattern on the section bar surface; If goods are decoration bar section, can adopt the water trans-printing, print grain pattern on the section bar surface.
Embodiment 2:
Take off the raw material of row weight part
60 parts in plasticizing agricultural stalk powder particles material
25 parts of polyvinyl chloride thermoplasticss
5 parts of dimethyl silicone oils
1 part of stearic acid
Chlorinated polyvinyl chloride 3-5
Cured 2 parts of polyester
0.5 part of red iron oxide
3 parts of dioctyl phthalate (DOP)s
3 parts of 800-1250 order superfine talcum powders,
The raw material of mixing and stirring is sent into the single screw rod Wood-plastic profiles of DMS65/30 forcing machine, and driving screw rotating speed 80-160 changes, and barrel zone temperature 120-190 ℃, build and press section pressure 15-18Mpa, obtain the wood plastic composite section bar after the material per os mould typing cooling.Be suitable for the preparation of industrial pallet, shop version.
Other preparation manipulation method is with embodiment 1.
Embodiment 3:
Take off the raw material of row weight part
70 parts in plasticizing agricultural stalk powder particles material
20 parts of polypropylene thermoplastics
3 parts of dimethyl silicone oils
1 part of stearic acid
4 parts of vinylformic acid-alternate styrene-maleic anhydride copolymers
Cured 1.25 parts of polyester
0.3 part of red iron oxide
2 parts of dioctyl phthalate (DOP)s
4 parts of 800-1250 order superfine talcum powders,
Concrete preparation manipulation method is with embodiment 1, or with embodiment 2.
Claims (6)
1, agricultural stalk base wood plastic composite materials is characterized in that: the raw material that comprises following weight part
Plasticizing agricultural stalk powder particles material 60-80 part
Thermoplastics 15-25 part
Lubricant 2.5-8 part
Expanding material 3-5 part
Softening agent 1-3 part
Fire retardant 0.1-0.5 part,
800-1250 order superfine talcum powder 3-5 part,
Described lubricant is dimethyl silicone oil, stearic acid and polyester wax, and described expanding material is vinylformic acid-alternate styrene-maleic anhydride copolymer, and described softening agent is a dioctyl phthalate (DOP), and described fire retardant is a red iron oxide.
2, agricultural stalk base wood plastic composite materials according to claim 1 is characterized in that: lubricant is the raw material of following weight part:
Dimethyl silicone oil 1-5 part
1 part of stearic acid
Polyester wax 0.5-2 part.
3, agricultural stalk base wood plastic composite materials according to claim 1, it is characterized in that: described plasticizing agricultural stalk powder particles material is that agricultural stalk pulverizing, activation plasticizing, granulation are obtained, and described agricultural stalk is selected from wheat straw stalk, straw, cotton stalk, wood chip, rice chaff or bagasse.
4, agricultural stalk base wood plastic composite materials according to claim 1, it is characterized in that: described thermoplastics is selected from polyethylene, polypropylene, polyvinyl chloride or polystyrene.
5, the preparation method of agricultural stalk base wood plastic composite materials according to claim 1 and 2 is characterized in that: comprise following operation steps
A, with the raw material mixing and stirring in the above-mentioned prescription, churning time 15-30 minute;
B, the raw material of mixing and stirring is sent into shaper make section bar;
The section bar of C, moulding is cooled to room temperature;
D, section bar surface sanded, sand milling surplus 0.2-0.5 millimeter, the section bar surfaceness is 12-100 after the surface treatment;
Described shaper is SZSJ80/156 conical double screw extruder or the single screw rod Wood-plastic profiles of DMS65/30 forcing machine, and its processing condition are: driving screw rotating speed 80-160 changes, and barrel zone temperature 120-190 ℃, extrusion pressure is 15-35MPa.
6, the preparation method of agricultural stalk base wood plastic composite materials according to claim 5 is characterized in that: after the surface treatment, adopt heat transfer printing, or the water trans-printing, print wood grain on the section bar surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610086350XA CN100429277C (en) | 2006-07-03 | 2006-07-03 | Agricultural stalk base wood and plastic composite material and combination processing method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610086350XA CN100429277C (en) | 2006-07-03 | 2006-07-03 | Agricultural stalk base wood and plastic composite material and combination processing method |
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| Publication Number | Publication Date |
|---|---|
| CN1876724A CN1876724A (en) | 2006-12-13 |
| CN100429277C true CN100429277C (en) | 2008-10-29 |
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| CNB200610086350XA Expired - Fee Related CN100429277C (en) | 2006-07-03 | 2006-07-03 | Agricultural stalk base wood and plastic composite material and combination processing method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101081934B (en) * | 2007-07-10 | 2011-06-08 | 广州华工百川科技股份有限公司 | Preparation method of anesthesia stem and plastic composite material |
| CN101215420B (en) * | 2007-12-30 | 2013-01-02 | 东北林业大学 | Wood-plastic composite material prepared from waste and old plastic mixer and preparation method thereof |
| CN101733808B (en) * | 2008-11-07 | 2014-11-26 | 北京环能海臣科技有限公司 | Straw section with waterproof skin compounded on surface |
| CN101735396B (en) * | 2009-12-31 | 2011-10-26 | 陕西科技大学 | Method for preparing super absorbent resin by using wheat straw |
| CN101864118B (en) * | 2010-05-28 | 2013-07-03 | 金发科技股份有限公司 | Styrene-based non-halogen flame-retardant injection-grade wood-plastic composite material and preparation method thereof |
| CN102250477A (en) * | 2011-07-05 | 2011-11-23 | 衢州伊梦特实业有限公司 | Wood-plastic composite panel and preparation method thereof |
| CN102702763A (en) * | 2012-05-22 | 2012-10-03 | 宁国惠云塑木新材料有限公司 | Method for producing wood-plastic material by processing rice straws |
| CN103360775A (en) * | 2013-07-26 | 2013-10-23 | 广东晨宝复合材料有限公司 | PE wood plastic composite and processing and forming methods thereof |
| CN105315688A (en) * | 2014-07-31 | 2016-02-10 | 南京工业大学 | Modification of straw biomass and use method thereof |
| CN105086484A (en) * | 2015-08-13 | 2015-11-25 | 许超群 | High-intensity wood-plastic composite and preparing method thereof |
| CN105348836A (en) * | 2015-11-10 | 2016-02-24 | 江苏科技大学 | Composite material based on biomass and preparation method therefor |
| CN105368086A (en) * | 2015-11-10 | 2016-03-02 | 江苏科技大学 | Biomass composite material composition and preparation method thereof |
| CN106280514B (en) * | 2016-08-08 | 2018-12-04 | 江苏省农业科学院 | A kind of preparation method of plant fiber-based foaming thermoplastic masterbatch |
| CN106751330A (en) * | 2016-12-28 | 2017-05-31 | 童道庆 | A kind of heat resistance composite decorating board preparation method high |
| CN110358196B (en) * | 2019-06-27 | 2022-02-18 | 武汉金发科技有限公司 | Flame retardant and polypropylene composite material |
| CN113004699B (en) * | 2019-12-20 | 2022-11-29 | 洛阳尖端技术研究院 | Silicon rubber and product thereof |
| CN114316425B (en) * | 2021-11-25 | 2023-11-10 | 南通荣荟新材料科技有限公司 | Plant source multifunctional master batch capable of being thermoplastically processed and preparation method thereof |
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| CN1876724A (en) | 2006-12-13 |
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Granted publication date: 20081029 Termination date: 20120703 |