CN100408605C - Graft copolymer of chlorinated polyethylene-alkyl-acrylates, and preparing method and use - Google Patents
Graft copolymer of chlorinated polyethylene-alkyl-acrylates, and preparing method and use Download PDFInfo
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- CN100408605C CN100408605C CNB2006100018956A CN200610001895A CN100408605C CN 100408605 C CN100408605 C CN 100408605C CN B2006100018956 A CNB2006100018956 A CN B2006100018956A CN 200610001895 A CN200610001895 A CN 200610001895A CN 100408605 C CN100408605 C CN 100408605C
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- CN
- China
- Prior art keywords
- alkyl
- chlorinatedpolyethylene
- raw material
- graft copolymerization
- acrylates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000034 method Methods 0.000 title claims abstract description 19
- 229920000578 graft copolymer Polymers 0.000 title abstract description 46
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 56
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 29
- 239000002994 raw material Substances 0.000 claims abstract description 24
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 15
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- -1 acrylic acid alkyl ester compound Chemical class 0.000 claims description 23
- 239000003607 modifier Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 4
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 4
- SPTHWAJJMLCAQF-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene;hydrogen peroxide Chemical compound OO.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-N 0.000 claims description 3
- 239000004160 Ammonium persulphate Substances 0.000 claims description 3
- 239000004159 Potassium persulphate Substances 0.000 claims description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 3
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 3
- 235000019394 potassium persulphate Nutrition 0.000 claims description 3
- 229940114930 potassium stearate Drugs 0.000 claims description 3
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 2
- 229940080350 sodium stearate Drugs 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 64
- 239000011347 resin Substances 0.000 abstract description 30
- 229920005989 resin Polymers 0.000 abstract description 30
- 125000005250 alkyl acrylate group Chemical group 0.000 abstract description 17
- 239000000843 powder Substances 0.000 abstract description 7
- 238000002360 preparation method Methods 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000035939 shock Effects 0.000 description 31
- 239000000203 mixture Substances 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 14
- 239000004609 Impact Modifier Substances 0.000 description 13
- 239000000126 substance Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 9
- 230000004048 modification Effects 0.000 description 9
- 238000012986 modification Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 5
- 230000007704 transition Effects 0.000 description 5
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- 239000004135 Bone phosphate Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
- 235000013539 calcium stearate Nutrition 0.000 description 3
- 239000008116 calcium stearate Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920005601 base polymer Polymers 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229920013716 polyethylene resin Polymers 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- SCFQUKBBGYTJNC-UHFFFAOYSA-N heptyl prop-2-enoate Chemical compound CCCCCCCOC(=O)C=C SCFQUKBBGYTJNC-UHFFFAOYSA-N 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2006100018956A CN100408605C (en) | 2006-01-25 | 2006-01-25 | Graft copolymer of chlorinated polyethylene-alkyl-acrylates, and preparing method and use |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006100018956A CN100408605C (en) | 2006-01-25 | 2006-01-25 | Graft copolymer of chlorinated polyethylene-alkyl-acrylates, and preparing method and use |
Publications (2)
Publication Number | Publication Date |
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CN1814642A CN1814642A (en) | 2006-08-09 |
CN100408605C true CN100408605C (en) | 2008-08-06 |
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CNB2006100018956A Active CN100408605C (en) | 2006-01-25 | 2006-01-25 | Graft copolymer of chlorinated polyethylene-alkyl-acrylates, and preparing method and use |
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CN (1) | CN100408605C (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103113687B (en) * | 2012-05-02 | 2013-12-04 | 江苏天腾化工有限公司 | PVC (Polyvinyl Chloride) impact modifier and preparation method thereof |
CN103130962B (en) * | 2013-03-06 | 2016-12-28 | 曹广文 | Chlorinated polyethylene rubber, butyl acrylate, acrylonitrile, N phenyl maleimide graft copolymer and preparation method thereof |
CN103755877B (en) * | 2013-12-21 | 2015-12-09 | 山东日科橡塑科技有限公司 | A kind of ACM production technique with high maximum elongation |
KR101754470B1 (en) * | 2015-06-26 | 2017-07-06 | 주식회사 케이씨씨 | Copolymer of acrylate modified chlorinated polyolefin and primer coat composition for plastic substrate comprising the same |
CN105504172B (en) * | 2015-12-23 | 2020-08-07 | 河北雄发新材料科技发展有限公司 | Preparation process of modified chlorinated polyethylene for rubber and plastic material |
CN105693891A (en) * | 2016-04-23 | 2016-06-22 | 山东日科橡塑科技有限公司 | Polyvinyl chloride low temperature toughening modifier and polyvinyl chloride mixture containing same |
CN112920413B (en) * | 2021-01-29 | 2022-02-22 | 常州爱特恩新材料科技有限公司 | Ionomer type grafted multifunctional material, preparation method thereof and application thereof in PVC (polyvinyl chloride) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5338803A (en) * | 1992-04-16 | 1994-08-16 | The Dow Chemical Company | Modified CPE for PVC impact modification |
CN1469892A (en) * | 2000-09-11 | 2004-01-21 | ��ʡ��ѧԺ | Graft copolymers, methods for grafting hydrophilic chains onto hydrophobic polymers, and articles thereof |
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2006
- 2006-01-25 CN CNB2006100018956A patent/CN100408605C/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5338803A (en) * | 1992-04-16 | 1994-08-16 | The Dow Chemical Company | Modified CPE for PVC impact modification |
CN1469892A (en) * | 2000-09-11 | 2004-01-21 | ��ʡ��ѧԺ | Graft copolymers, methods for grafting hydrophilic chains onto hydrophobic polymers, and articles thereof |
Non-Patent Citations (2)
Title |
---|
氯化聚乙烯接枝水溶性单体. 冯东东等.湖北大学学报(自然科学版),第23卷第1期. 2001 |
氯化聚乙烯接枝水溶性单体. 冯东东等.湖北大学学报(自然科学版),第23卷第1期. 2001 * |
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Publication number | Publication date |
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CN1814642A (en) | 2006-08-09 |
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Owner name: SHANDONG RIKE NEW MATERIALS CO., LTD. Free format text: FORMER OWNER: ZHAO DONGRI Effective date: 20091127 |
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Effective date of registration: 20091127 Address after: Shandong city of Weifang province high tech Zone Weihe Road East of Cherry Street South Patentee after: Shandong Rike New Material Co., Ltd. Address before: Shandong Changle Economic Development Zone Shandong Weifang Daily Chemical Co., Ltd. Patentee before: Zhao Dongri |
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ASS | Succession or assignment of patent right |
Owner name: SHANDONG RIKE RUBBER PLASTIC TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANDONG RIKE NEW MATERIAL CO., LTD. Effective date: 20130412 |
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Effective date of registration: 20130412 Address after: 256800, No. 9, outer ring south, Zhanhua County, Binzhou City, Shandong Province Patentee after: SHANDONG RIKE RUBBER AND PLASTIC TECHNOLOGY CO., LTD. Address before: 261025 Shandong city of Weifang province high tech Zone Weihe Road East of Cherry Street South Patentee before: Shandong Rike New Material Co., Ltd. |