The radiator that contains diamond powder
Technical field
A kind of radiator that contains diamond powder is to be used for coating or filling up packaged chip, is the splendid composite that contains the diamond micro mist of a heat-sinking capability.
Background technology
Because in the past over 30 years, the function of photoelectric subassembly and speed are being with Moore's Law (Moore ' s Low), then promoted nearly one times in per 18 months, and in than progress, the profile of product also develops towards compact direction, function and profile all can improve the power and the frequency of chip, therefore, temperature when causing the operation of chip greatly increases, the high energy chip power has reached a hectowatt (watts) at present, if there is not better cooling mechanism, the temperature of these chips may surpass 100 ℃, make the forfeiture chip functions.
It is made that current chip mostly is semiconductor (as silicon, GaAs), it contains the plain conductor and the insulation film of volume, thermal coefficient of expansion between the two differs several times, its physicochemical characteristic is referring to shown in Figure 1, therefore more than 65 ℃ the time, chip is many can to crack so that it can't bear to use, even operation reluctantly, when temperature during near 100 ℃ semi-conductive electric conductivity can increase, thereby the function of chip is completely lost.
For chip can not burnt out because of overheated, therefore need the used heat that electric current produced is got rid of as early as possible, in addition, the conductor width of chip is narrow more, the speed of its heat extraction is then faster, present chip live width is 0.13 micron, and this moment, chip still can be imbedded in the fastest ceramic on metal sintered body of present heat radiation (as aluminium base carborundum), outside this encapsulating material, dispel the heat with copper sheet again, at last with metal (as copper or aluminium) blade with the fan blast-cold, can meet its heat radiation requirement reluctantly, but effect is not good.
And when below the metal wire reductions to 0.1 micron, the ceramic on metal sintered body has had little time heat radiation, this moment, chip then had the worry of burning, therefore, must be with more effective encapsulating material with hot sucking-off, with diamond film or other method heat is cooled off with every square centimeter of speed more than 30 watts again, can be but suffer from not having suitable material at present with being the encapsulating material that dispels the heat.
In addition, packaging body and the necessary intimate engagement of the fin (as diamond, vacuum gasifying condensate pans, pottery or metal heat sink etc.) that adds, because chip can not bear high temperature, so joint can not weld with motlten metal, therefore be to cohere usually with thermal paste, above-mentioned this thermal paste contains the metal (as silver) or the pottery (as aluminium oxide) of suspension, but the coefficient of heat conduction of these materials is all on the low side, so the seam crossing that coheres of thermal paste also often becomes the bottleneck of heat radiation.
Summary of the invention
The present inventor is because the aforementioned radiator of commonly using that contains diamond powder, in practical application, truly have the not good shortcoming of its heat-sinking capability to exist, and invent again, be about to artificial or natural cheap diamond waste material will pulverize and sieve, its granularity is fit to and the metal dust mixing, this composite is coated or fills up packaged chip, also can sneak into viscose or other organic matter therein, as thermal paste or heat radiation filler, so that this radiator that contains diamond powder can reach best radiating effect, and significantly improve the coefficient of heat conduction of packaging sintering body.
In order to reach aforesaid goal of the invention, the technological means that the present invention used is to be to provide a kind of radiator that contains diamond powder, and its diamond powder and non-diamond partly ratio are 1: 3~3: 1.
The described radiator that contains diamond powder, the particle diameter of its diamond powder is less than 150 microns.
The described radiator that contains diamond powder, the part of its non-diamond contains metal material.
The described radiator that contains diamond powder, its metal contains copper product or aluminum.
The described radiator that contains diamond powder, the part of its non-diamond contains organic matter.
The described radiator that contains diamond powder, its organic matter are epoxy resin, resin or acryl glue.
The described radiator that contains diamond powder, the granularity of its diamond powder has two peak values, and peak-peak is minimum peak 5-9 times.
The described radiator that contains diamond powder, it is used for the encapsulation of chip.
The described radiator that contains diamond powder, it is used for the encapsulation of heat conduction.
The described radiator that contains diamond powder, it is to make with sintering process.
The described radiator that contains diamond powder, it is to form with the organic matter gluing.
For making your auditor can understand the invention structure of this case really, and goal of the invention and effect, below enumerate a specific embodiment now, and cooperate graphic being described in detail as follows:
Description of drawings
Fig. 1 is the pyroconductivity of each material.
Fig. 2 is a profile of the present invention.
In the accompanying drawing:
10--chip cooling material
The 20--chip
The 30--thermal paste
The 40--fin
The specific embodiment
Press, referring to shown in Figure 1, the coefficient of heat conduction of diamond is soprano in all material, and therefore, the rate of heat transfer of diamond when normal temperature is silver of rate of heat transfer the best in the metal or five times of copper.
Because carbonado powder in the past is quite expensive, almost with the gold equivalence, therefore do not meet cost in the use, but, with the carbonado of high-pressure process manufacturing, cost of manufacture is low in recent ten years, therefore its price is go from bad to worse, the waste material of manufacture diamond can pulverize becomes micro mist, and its unit price is lower.In addition, rough diamond all be the carbonado that can not ponder into jewel more than 80%, and these carbonado overproductions are hoarded many decades and also be can not find suitable industrial use.
The present invention pulverizes artificial or natural cheap diamond waste material and sieves with it, its granularity (as 50 microns) is fit to and metal dust (as copper or aluminium) mixing, when mixing, to improve the ratio of diamond volume as far as possible, if the granularity of diamond and metal is suitable, this ratio can be near 1/2, if diamond is than metal dust big (as seven times), then this ratio can be increased to 2/3, cooperates the size particles of diamond, metal powder then can be thinner, the volume ratio that makes diamond is up to 3/4, and the volume ratio of diamond is high more, and the contact area of particle can be big more, the effect of heat radiation will be better, in addition, its diamond powder granularity of selecting for use has two peak values, and peak-peak is 5-9 a times of minimum peak.
When implementing, referring to shown in Figure 2, this chip cooling material 10 can be coated on outside the chip 20, heat-agglomerating makes it become piece, will become the fastest package implementation of heat radiation like this, in addition, the far low metal material of the thermal coefficient of expansion of diamond, therefore, its thermal coefficient of expansion of metal-base composites that contains the volume diamond is then relatively very low, so can mate (thermal coefficient of expansion of silicon wafer is slightly higher than diamond) with the silicon wafer of its encapsulation, so, thermal stress between encapsulation and the silicon wafer produces minimum, and this interface can not divided.
In addition, the radiator that contains diamond powder of the present invention, also can sneak into viscose or other organic matter (as epoxy resin, resin etc.) as thermal paste 30 or the heat radiation filler, this class liquid thermal paste 30 can in order to cohere heat sink material or fill up the encapsulation so that chip in hole.
In sum, the radiator that contains diamond powder of the present invention, the composite of sneaking into diamond can reach best radiating effect, with the radiator encapsulation silicon wafer that contains diamond powder of the present invention, can solve the heat radiation bottleneck that present high power IC (as CPU) is run into, significantly improve its radiating efficiency.