CN100376292C - Deodorant composition - Google Patents

Abstract

It is intended to provide a novel deodorant composition which is excellent in the deodorizing effect, makes it possible to give a deodorant composition by a convenient method and shows no decrease in the deodorizing performance even after a long time, once the deodorant being prepared. More specifically, a deodorant composition characterized by containing, as the active ingredient, a colored compound which is obtained by reacting polyphenol in an alkaline solvent in the coexistence of oxygen molecule at a reaction pH value of 6.5 or more. As a substitute for polyphenol, use can be made of a plant extract containing polyphenol but being substantially free from amino acids. It is also possible to further employ an amino acid. Moreover, use can be made of a plant extract and/or a plant body containing polyphenol together with an amino acid.

Description

Deodorant compositions

Technical field

The present invention relates to a kind of new deodorant compositions.Be particularly related to the new deodorant compositions that comprises colored compound, above-mentioned colored compound by in pH value in reaction be 6.5 or above condition under, when oxygen molecule coexists, be alkalescence solvent in the reaction polyphenol make.Say that exactly it relates to the new deodorant compositions that comprises colored compound, above-mentioned colored compound by in pH value in reaction be 6.5 or above condition under, when oxygen molecule coexists, be alkalescence solvent in the reaction concrete polyphenol make; And the new deodorant compositions that comprises colored compound, above-mentioned colored compound by in pH value in reaction be 6.5 or above condition under, when oxygen molecule coexists, be alkalescence solvent in the reaction concrete polyphenol and aminoacid make.More precisely, it relate to a kind of be used for eliminating or reduce the daily life stench (as niff (halitosis), body odor, refrigerator stench, rubbish stench, footgear cupboard the stench of fecaluria stench, factory and industrial waste of body odor, humans and animals of stench, humans and animals) deodorant compositions.

Background technology

Recently, along with the change of variation, the growth in the living standard of life, animation and raising etc., the various aspects around people's life have been paid close attention to.One of them is exactly various malodorous existence.Described main malodor components comprises nitrogen-containing compound, as ammonia, urea, indole, methylindole and amine; Sulphur compound is as methyl mercaptan, hydrogen sulfide and dimethyl sulfide; And lower fatty acid such as butanoic acid.Up to now, there are many relevant malodorous deodorizer reports that are used for eliminating or reducing.

For example, JP-A-11-319051 discloses a kind of deodorizer that comprises weight polyphenol fraction (as active component), and described weight polyphenol fraction extracts from Fructus Mali pumilae.But the deodorizing effect of described deodorizer is not enough.And, also known comprise plant extract and oxidation of phenol enzyme as the deodorant compositions of component (referring to, for example JP-A-9-38183, JP-A-10-212221 etc.).Though the deodorizing effect of these deodorizer is fabulous, there is the suitable complicated problems of preparation method in they.

On the other hand, at Food.Sci.Technol.Res., 6 (3), 186-191 has mentioned concrete polyphenol in 2000 and has confirmed at NH ₄OH solution or NaHCO ₃Deodorizing effect in the solution.And, at Biosci.Biotechnol.Biochem., 65 (10), among the 2121-2130, having mentioned colored compound can prepare by reaction caffeic acid ester and aminoacid.

As for deodorant compositions, require deodorant compositions can keep deodorizing capability as far as possible for a long time.And the expection deodorant compositions has fabulous deodorizing effect to various malodor components such as nitrogen-containing compound, sulphur compound and lower fatty acid.

Disclosure of the Invention

The purpose of this invention is to provide a kind of new deodorant compositions, it has fabulous deodorizing effect, and can make by straightforward procedure.And, a kind of new deodorant compositions is provided, in case preparation deodorizer, even through long-time, its deodoriging properties can not reduce yet.And, a kind of deodorant compositions that many malodor components is had fabulous deodorizing effect is provided.

Based on the broad research that addresses the above problem, the present invention have been found that by in pH value in reaction be 6.5 or above condition under, be when oxygen molecule coexists that reaction concrete polyphenol prepared colored compound has fabulous deodorizing effect in the solvent of alkalescence.And, they have been found that pH value in reaction be 6.5 or above condition under, be when oxygen molecule coexists that reaction concrete polyphenol and the prepared colored compound of aminoacid have fabulous deodorizing effect in the solvent of alkalescence.And even when the compositions that comprises the deodorization component stores for a long time, it is long-time that the deodorizing effect of described deodorant compositions keeps.Based on further research, they have finally finished the present invention.

That is, the present invention is as described below:

(1) deodorant compositions, it comprises the colored compound as active component, described colored compound by in pH value in reaction be 6.5 or above condition under, when oxygen molecule coexists, be alkalescence solvent in the reaction polyphenol make;

(2) deodorant compositions described in (1), wherein, the oxygen molecule in the course of reaction be supplied as 1mg/L or more than;

(3) deodorant compositions described in (1) or (2), wherein, described reaction temperature is 0-60 ℃;

(4) each described deodorant compositions in (1) to (3) wherein, also adds metal ion, and reacts in described response system;

(5) each described deodorant compositions in (1) to (4), wherein, described polyphenol is the polyphenol with neighbour-xenol structure;

(6) each described deodorant compositions in (1) to (4), wherein, described polyphenol is a hydroquinone.

(7) deodorant compositions, it comprises the colored compound as active component, described colored compound by in pH value in reaction be 6.5 or above condition under, be when oxygen molecule coexists that reaction comprises polyphenol but is substantially free of amino acid whose plant extract and makes in the solvent of alkalescence;

(8) each described deodorant compositions in (1) to (7) wherein, also adds aminoacid, and reacts in response system;

(9) deodorant compositions described in (8), wherein, described aminoacid is a-amino acid;

(10) deodorant compositions, it comprises the colored compound as active component, described colored compound by in pH value in reaction be 6.5 or above condition under, be when oxygen molecule coexists that reaction comprises polyphenol and amino acid whose plant extract and/or plant and makes in the solvent of alkalescence.

Preferred forms of the present invention

Below describe the present invention in detail.

In the present invention, polyphenol pH value in reaction be 6.5 or above condition under, when oxygen molecule coexists, be alkalescence solvent in react, make deodorant compositions.

At first, a kind of polyphenol has been described below, it is the raw material that is used to prepare deodorant compositions of the present invention.The used polyphenol of the present invention is meant the chemical compound that has two or more phenolic hydroxyls in the molecule, and also comprises its glucosides in the described polyphenol.Be used for polyphenol of the present invention and do not have what feature restriction, so long as can reach the polyphenol of required purpose.

The object lesson of described polyphenol comprises apigenin, the apigenin glucosides, acacetin, isorhamnetin, the isorhamnetin glycosides, isoquercitrin, epicatechin, the epicatechin gallate, table roasting catechin, table roasting Catechin 3-gallate, esculetin, ethyl protocatechuic acid salt, ellagic acid, catechol, γ-acid, catechuic acid, gardenin, boheic acid extremely, caffeic acid, the coffee ester, chlorogenic acid, keampferol, the keampferol glycosides, quercetin, the quercetin glycosides, quercetin, genistin, the genistin glycoside, gossypetin, the gossypetin glycosides, gossypol, the 4-dihydroxyanthraquinone, 1, the 4-dihydroxy naphthlene, anthocyanidin, anthocyanin, sinensetin, diosmetin, the diosmetin glycosides, 3,4 '-diphenyl glycol, sinapic acid, β-(3,5-two-tert-butyl-hydroxy phenyl) propanoic acid stearyl, zamene, tangeritin, taxifolin, tannic acid, daphnetin, tyrosine, delphinidin, the delphinidin glycosides, theaflavin, theaflavin list gallate, theaflavin two gallates, tricetinidin, DOPA, dopamine, naringenin, naringin, nor-dihydroguaiaretic acid, norepinephrine, hydroquinone, vanillin, the Herba Pogostemonis element, herbacetin, cephrol, vanitrope, vanillin propylene glycol acetal, vanillic acid, two (4-hydroxy phenyl) sulfonic acid, bisphenol-A, catechol, vitexin, 4,4 '-diphenyl glycol, the 4-tert-butyl catechol, the 2-tert-butyl hydroquinone, protocatechuic acid, phloroglucinol, phenolic resins, procyanidin, former delphinidin, phloretin, the phloretin glycosides, fisetin, foline, fervasetin, Pi Ting, phlorhizin, peonidin, the peonidin glycosides, pelargonidin, the pelargonidin glucosides, petunidin, the petunidin glycosides, Tangeretin, hesperidin, gallic acid, epicatechol gallate (gallic acid Lauryl Ester, propyl gallate, the gallic acid butyl ester), manjiferin, enidin, malvin, myricetin, the Fructus Myricae rubrae ketoside, 2,2 '-methylene two (4-methyl-6-tert butyl phenol), 2,2 '-methylene two (4-ethyl-6-tert-butyl phenol), 2,2 '-methylene two (4-methyl-6-tert butyl phenol), 2,2 '-methylene two (4-ethyl-6-tert-butyl phenol), methyl Rhizoma Atractylodis hydrochlorate, the 4-methyl catechol, the 5-methyl catechol, 4-methoxyl group catechol, 5-methoxyl group catechol, methyl catechol-4-carboxylic acid, the 2-methylresorcinol, the oreinol diphenol, morin, limocitrin, the limocitrin glucosides, limocitrol, digicitrine, the digicitrine glucosides, sweet-scented osmanthus is yellow fixed, the sweet-scented osmanthus Huang is decided glucosides, rutin, resorcinol, resveratrol, resorcinol, leucocyanidin, colourless delphinidin etc.

In these polyphenol, the preferred class flavone, as quercetin, epicatechin and table roasting catechin and glycosides thereof, polyphenol, as gallic acid, epicatechol gallate, chlorogenic acid, caffeic acid, coffee ester, tannic acid, catechol, nor-dihydroguaiaretic acid, L-DOPA, 4-methyl catechol, 5-methyl catechol, 4-methoxyl group catechol and 5-methoxyl group catechol and hydroquinone with o-phenol structure.Especially preferred is hydroquinone and the polyphenol with o-phenol structure.This-relation in, described o-phenol structure is meant that wherein two hydroxyls are direct substitution on phenyl ring, and the adjacent structure of hydroxyl.

These polyphenol can use separately or two or more mixture use.

Above polyphenol can prepare by known method, but also can be the commercially available prod.And they can prepare by synthesizing.In addition, can use the weight polyphenol fraction of the height concentration that makes from plant.

In the present invention, also can use plant extract to replace above-mentioned polyphenol.In this case, but described plant extract better is to comprise polyphenol be substantially free of amino acid whose plant extract, as for described plant extract, can use the plant extract that makes by known method, also can be commercially available plant extract.

Can mix and use polyphenolic substance and be substantially free of the amino acid whose plant extract that comprises polyphenol.

And, in the present invention, deodorant compositions also can pH value in reaction be 6.5 or above condition under, be when oxygen molecule coexists that reaction polyphenol and aminoacid make in the solvent of alkalescence.

The aminoacid that the present invention can be used for does not have any particular restriction, as long as it is the aminoacid that can obtain required effect, but wherein especially preferred a-amino acid.In this article, described a-amino acid is meant that one of them amino and a carboxyl are connected the aminoacid on the identical carbon atoms.The example of described a-amino acid comprises glycine, alanine, valine, leucine, isoleucine, glutamic acid, aspartic acid, glutamine, agedoite, serine, threonine, lysine, oxylysine, arginine, histidine, cystine, methionine, phenylalanine, tyrosine, tryptophan, proline, 4-hydroxyproline, cysteine, theanine, amino acid salts (sodium glutamate, NaAsp) etc.

Wherein, especially preferred glycine, alanine, glutamic acid, aspartic acid, lysine, arginine, histidine, serine, cystine, methionine, cysteine, sodium glutamate, NaAsp and tyrosine.

These aminoacid obtain by buying the commercially available prod easily.And these aminoacid can use separately or two or more mix use.And, also can use to comprise amino acid whose plant extract.

In addition, deodorant compositions of the present invention can not contain polyphenol but comprising amino acid whose plant extract replaces aminoacid and polyphenol to make up making substantially by using yet.Herein, " do not contain polyphenol substantially but comprise amino acid whose plant extract " can make by known method, also can buy commercially available product.In this relation, also can mix and use aminoacid and comprise amino acid whose plant extract (wherein being substantially free of polyphenol).

When making deodorant compositions of the present invention, mix to use polyphenol and amino acid whose example to comprise to mix to use to comprise aminoacid but do not contain the plant extract of polyphenol substantially and the example of polyphenol, mix to use and comprise polyphenol but do not contain amino acid whose plant extract substantially and amino acid whose example and mixing uses and comprises polyphenol but do not contain amino acid whose plant extract substantially and comprise aminoacid but do not contain the plant extract of polyphenol substantially.

In deodorant compositions, polyphenol and amino acid whose mixed proportion are not unconditionally specified, this is because described ratio changes with used polyphenol and aminoacid, but better mix described polyphenol and aminoacid, better with 3: 1 to 1: 3 mixed with 9: 1 to 1: 9 ratio (mol ratio).In this relation, as under the situation of raw material, determine prescription with effective use polyphenol and amino acid whose purpose at them; And the situation of not getting rid of any excessive existence in two kinds of materials.

Deodorant compositions of the present invention can by pH value in reaction be 6.5 or above condition under, be when oxygen molecule coexists that reaction polyphenol or polyphenol and aminoacid make in the solvent of alkalescence.

The described solvent that is alkalescence is known, and expression comprises the solvent of alkaline matter, and wherein, alkaline matter is dissolved in solvent such as the water.

Described alkaline matter does not have any particular restriction, and concrete example comprises carbonate or bicarbonate, as sodium carbonate, potassium carbonate, sodium bicarbonate, ammonium carbonate and guanidine carbonate; Borate is as potassium borate and sodium borate; Silicate is as potassium silicate, sodium silicate No.1, sodium silicate No.2, sodium silicate No.3, sodium metasilicate and sodium metasilicate; Dibastic sodium phosphate, sodium sulfate, sodium hydroxide, calcium hydroxide, potassium hydroxide, magnesium hydroxide, ammonium hydroxide, tetrasodium pyrophosphate and potassium pyrophosphate etc.

One or more or the multiple solvent that are used to dissolve these alkaline matters comprise water and various aqueous solvent, and this is a solvent preferably.And, also can use so-called alkaline buffer solution, it uses these alkaline matters and acid.

Above solvent is alkalescence usually, and it was alkali before reaction, but according to the material and the addition thereof that add in the solvent, presents faintly acid sometimes.That is, solvent must be alkali time the before reaction, and when making above-mentioned deodorant compositions, the solvent pH after beginning to react in the described response system be 6.5 or more than, obtain effect preferably then.Concrete is that the pH of described response system is preferably 7-13, is more preferably 8-13.When the pH of response system in the course of reaction less than 6.5 the time, can not make deodorant compositions with better deodorizing effect.

In the present invention, must under the condition of oxygen molecule coexistence, react polyphenol.As for the conventional equipment that oxygen molecule is added in the response system, can be to use air pump (bubbling) or stir described system fast oxygen or air are added in the described system.Reaction under oxygen molecule co-exists in is meant a kind of reaction, and its purpose is to react by oxygen molecule fully being added the polyphenol that comes in the reaction liquid in the accelerated reaction system.In this case, described deodorant compositions can by make the oxygen that adds in the reaction liquid be 1mg/L or more than, better be 2mg/L or efficiently make to come up.Described oxygen supply amount can reach by mode as described below: for example, oxygen, air or its combination frequently are blown into (bubbling) in the response system, perhaps also can reach by stirring reaction liquid under the reaction condition that can keep constant contact at oxygen or air.

Temperature during as for reaction, product of the present invention can make under the solvent refluxing temperature at 0 ℃, and prerequisite is to avoid gained deodorant activities component generation thermal decomposition, 0-60 ℃ more fortunately of described reaction, better, be more preferably under 0 ℃-25 ℃ and carry out at 0 ℃ to 40 ℃.

In the present invention, described polyphenol is at short time (but should proceed from the reality) internal reaction, and described reaction was better carried out a few minutes (2 minutes) by 24 hours, better was about 10 minutes to about 9 hours, was more preferably 10 minutes to 7 hours.In the reaction of the above-mentioned deodorant compositions of preparation, be not to need pressurization especially, but can pressurize.

And, when in the presence of metal ion or slaine (metal ion is discharged in the response system), reacting, can make deodorant activities and stability-enhanced more fabulous deodorant compositions.

As for the preferred metal ion, copper ion, zinc ion, calcium ion, magnesium particle, silver ion, tin ion, aluminium ion or manganese ion have been mentioned.

The example of the chemical compound of release metal ions comprises following: copper compound for example, as copper chloride, copper fluoride, copper sulfate, copper nitrate, Copper hydrate, copper citrate, copper gluconate, aspartic acid copper, cupric glutamate, sodium copper chlorophyllin, copper chlorophyll; Zinc compound is as zinc chloride, zinc fluoride, zinc sulfate, zinc nitrate, zinc hydroxide, zinc citrate, zinc gluconate, aspartic acid zinc, zinc glutamate, zinc phosphate and zinc lactate; Calcium compounds is as calcium chloride, calcium hydroxide, calcium citrate, calcium gluconate, L-calcium glutamate, calcium carbonate, calcium lactate, calcium pantothenate, calcium dihydric pyrophosphate, calcium propionate, calcium sulfate, tricalcium phosphate, calcium hydrogen phosphate, dalcium biphosphate and ethanedioic acid tetraacethyl disodium calcium; Magnesium compound is as magnesium chloride, magnesium sulfate, magnesium hydroxide, L-psicosoma, magnesium oxide and magnesium carbonate; Silver compound is as silver oxide; Tin compound is as stannic chloride, tin acetate and stannic fluoride; Aluminium compound is as aluminum chloride, aluminium hydroxide, aluminium acetate, Alborex M 12, aluminum phosphate and aluminum sulfate; Permanganate is as potassium permanganate; Manganese compound is as manganese sulfate etc.In addition, also can use titanium compound, as titanium dioxide.

The addition of metal ion depends on the state of reaction, better adds described ion, makes the concentration of metal ion in reaction liquid become 0.00001mM to 100mM, and concentration is more preferably 0.00005mM to 10mM, is more preferably 0.1mm to 5mM.

And, in the present invention, after reaction polyphenol or polyphenol and aminoacid make deodorant compositions in basic solvent under the oxygen molecule concurrent conditions, can wherein add metal ion in the past, form deodorant compositions.

In the present invention, when reaction polyphenol and aminoacid makes deodorant compositions in basic solvent under the oxygen molecule concurrent conditions, can use to comprise polyphenol and amino acid whose plant extract replaces polyphenol and aminoacid.As for plant extract in this case, improved and comprised high concentration polyphenol and amino acid whose plant extract.As for plant extract, can use those that known method makes, perhaps can use commercially available product.

For example, deodorant compositions of the present invention also can be by comprising polyphenol and amino acid whose plant extract (promptly, extract from least a portion of the leaf of plant, stem, root, fruit etc.) adds in the solvent that is alkalescence, in course of reaction, reaction liquid transferred to pH6.5 or more than, and handle with 1mg/L or above oxygen supply amount under the solvent refluxing temperature at 0 ℃, the response time is a few minutes to 24 hour.In this case, the example of described alkaline matter and solvent comprise above-described those, described compositions can make by carry out described reaction under above-mentioned identical condition.Comprise polyphenol and amino acid whose plant extract in use and replace under polyphenol and the amino acid whose situation, can also mix to use and comprise polyphenol but do not contain amino acid whose plant extract substantially, comprise aminoacid but do not contain in plant extract, polyphenol and the aminoacid of polyphenol at least a substantially.The example of described plant extract is as described below.And, in the present invention, pH value in reaction be 6.5 or above condition under, when oxygen molecule coexists, be when reaction polyphenol and aminoacid make deodorant compositions in the solvent of alkalescence, also can use to comprise polyphenol and amino acid whose plant replaces polyphenol and aminoacid.In this case, described plant better is to comprise high concentration polyphenol and amino acid whose plant.

For example, deodorant compositions of the present invention also can be by comprising polyphenol and amino acid whose plant (promptly, at least a portion from the leaf of plant, stem, root, fruit etc.) adds in the solvent that is alkalescence, in course of reaction, reaction liquid transferred to pH6.5 or more than, and handle with 1mg/L or above oxygen supply amount under the solvent refluxing temperature at 0 ℃, the response time is a few minutes to 24 hour.The example of described alkaline matter and solvent comprise above-described those, described compositions can make by carry out described reaction under above-mentioned identical condition.As for described plant, can use the plant of giving an example in the following plant extract.Comprise polyphenol and amino acid whose plant in use and replace under polyphenol and the amino acid whose situation, can also mix to use and comprise polyphenol but do not contain amino acid whose plant extract substantially, comprise aminoacid but do not contain in plant extract, polyphenol and the aminoacid of polyphenol at least a substantially.In this article, the amount of " not comprising basically " aminoacid or polyphenol is the amount that can not influence described reaction, and amount is less than detectable limit when measuring according to conventional known method.

The example of plant extract comprises can be from Aloe, the Pimpinella anisum Linn. seed, Ramulus Sambuci Williamsii, Radix Et Caulis Acanthopanacis Senticosi, Caulis et Folium Lini, orange blossom, allspice, Adeps Bovis seu Bubali, Rhizoma et radix valerianae, Flos Chrysanthemi, Fructus Capsici powder, Elettaria cardamomum (L.) Maton, Cortex cinnamomi japonici (Ramulus Cinnamomi), Bulbus Allii, the Fructus cari carvi seed, clove tree, the cumin seed, cola, the Herba Coriandri seed, the Java Toxicodendron verniciflnum (Stokes) F. A. Barkley (Rhus verniciflua Stokes), Stigma Croci, Pericarpium Zanthoxyli, gin, Cortex Cinnamomi, Rhizoma Zingiberis Recens, Fructus Anisi Stellati, the St.Johns wart, the Herba Apii graveolentis seed, savoury, Semen Sesami, wine plant, tarragon, Rhizoma Curcumae Longae, Ji, Fructus anethi (Anethumgraveolens), Semen Myristicae, Herba Urticae Cannabinae, Hibisci Mutabilis, Radix Hamamelidis Mollis, birch, Herba Ocimi (Herba Ocimi Pilosi), bigarabe, Fructus Foeniculi, Flos Primulae Vittatae, Semen Trigonellae, Herba Verbenae, bay tree, hop, boldo, Wasabia japonic (Euterma Wasabi), the Semen Papaveris seed, Galla Turcica (Galla Helepensis), Calendula arvensis L., calabash, Adeps Bovis seu Bubali, Caulis et Folium Brassicae junceae, Chiba over sixty years of age (Millefeuille), mentha leave, Herba melissae axillaris, Semen Myristicae, gamma hch, Gentiana (Gentiana scabra var.buergeri), Fructus Rosae, Herba Rosmarini Officinalis, Rosmarinus (rosmarinusofficinalis), the Helianthi seed, Pericarpium Vitis viniferae, Fructus Mali pumilae, Folium Dauci Sativae, Fructus Musae, Fructus Fragariae Ananssae, Fructus Pruni, Fructus Persicae, Fructus Pruni salicinae, Fructus Ananadis comosi, pears, Fructus Kaki, Fructus Pruni pseudocerasi, Fructus Caricae, Fructus Mangifera Indicae, American Avocado Tree, melon, Folium Eriobotryae, Fructus Fici, Fructus actinidiae chinensis, european plum, blue berry, black berry, Fructus Rubi, mossberry, coffee is given birth to bean, cacao bean, Semen Vitis viniferae, grape fruit, Semen Caryae Cathayensis, Fructus anacardii, Semen Castaneae, Cortex cocois radicis, Semen arachidis hypogaeae, Semen Juglandis, green tea, black tea, oolong, Nicotiana tabacum L., Folium Perillae, the garden Moschus, Salvia japonica Thunb., Garden lavender, Mentha viridis L, Mentha arvensis L. syn.M.haplocalyxBrig, the speckle Ji, hyssop, sweet basil, Calendula arvensis L., Herba Taraxaci, Carlina acaulis, the Anthemis Chamomile, the Japan Radix Agrimoniae, licorice, Pimpinella anisum Linn., yarrow, Eucalyptus, Artemisia absinihium L, Balm, Radix Angelicae Sinensis, Semen Trigonellae, Fructus Capsici (capsicum annuum var.angulosum), Fructus Foeniculi, Fructus Capsici, the Herba Coriandri seed, the Herba Coriandri seed, the Fructus Foeniculi seed, Rhizoma Zingiberis Recens, Wasabia japonic (Euterma Wasabi), Origanum (origanum majorana), Origanum (origanum vulgare), Caulis et Folium Brassicae junceae, parsley, Fructus Piperis powder, savoury, tarragon, Flos Lilii viriduli, scurvy grass, the Fructus anethi seed, citrus fruits etc.Can mix and use in these plant extracts two or more.

In preparation during deodorant compositions of the present invention, additive commonly used can with response system in coexist.

Therefore, make colored compound, it is the active component of deodorant compositions of the present invention.The color of gained reaction liquid changes with polyphenol kind, aminoacid existence, aminoacid kind and their ratio as initial substance.And because the density of described color also changes with response time and pH, described color is not unconditionally specified.

For example, when chlorogenic acid as an example the time, the color of described reaction liquid is flaxen in initial reaction stage, and overstrike becomes crineous at last as time passes.For quercetin, the color of described reaction liquid is pink in initial reaction stage, passes red increasing in time, becomes the burgundy color at last.For gallic acid, the color of described reaction liquid is faint yellow in initial reaction stage, As time goes on becomes light green, becomes bottle green at last.For catechol, the color of described reaction liquid is a pale red in initial reaction stage, passes overstrike in time, becomes crineous at last.

And, under the situation of selecting glycine as aminoacid and reaction, reaction liquid with chlorogenic acid is green, described reaction liquid with (+)-catechin is red, reaction liquid with protocatechuic acid is red, and the reaction liquid with catechol is pink, and the reaction liquid with esculetin is a brown, reaction liquid with hydroquinone is a brown, and the reaction liquid with quercetin is that reaction liquid red and that have gallic acid is a brown.

As for polyphenol or polyphenol and amino acid whose reaction in most cases, described reaction liquid is a light colour in initial reaction stage, but described reactant liquor is known from experience deepening, becomes dead color at last.Kind, polyphenol and amino acid whose combination and the reaction condition of required time of the colour-darkening of described reaction liquid with polyphenol changes, but after the reaction beginning a few minutes, about sometimes 20 or 30 minutes.

As mentioned above, the deodorant compositions that makes of the present invention comprises colored compound.Described colored compound plays the effect of deodorant activities component.Described colored compound has various chemical constitutions, for example, the product of polyphenol (raw material), by polyphenol make polymerizate, polyphenol and amino acid whose product, the oxide of the polymeric reaction product, the oxide of polyphenol, above-mentioned product and the polymerizate that make by polyphenol and aminoacid, and various free radicals also are classified as colored compound one class of the present invention as phenoxy group base (being the oxidation product of polyphenol).

The ratio of contained colored compound is that 10ppm is to 100 weight % in the deodorant compositions of the present invention.

The molecular weight of the colored compound in the preferred gained deodorant compositions greater than reaction before molecular weight or the polyphenol and the amino acid molecular amount sum of polyphenol (raw material), be 10000 or below.

The molecular weight of described colored compound makes by the following method.Promptly, the deodorant compositions that makes by above either party's method concentrates by centrifugal, and determine that described concentrate is to see through the filter membrane with some holes, and still stay on the filter membrane, determine corresponding molecular weight according to the hole size of the filter membrane of residual concentrate on it thus.As for used filter membrane, can use commercially available product.

Deodorizer active component among the present invention can be by reacting the oxide that described raw material and oxygen molecule make, and therefore, the molecular weight ranges of described deodorant activities component as mentioned above.

The reaction liquid that comprises the deodorant activities component that makes thus can be used as deodorant compositions, need not further processing.Perhaps, if need,, make the deodorant compositions that comprises high concentration deodorant activities component by further concentrating method or other method of the reaction liquid that comprises the deodorant activities component.And, remove liquid component in the reaction liquid that comprises the deodorant activities component by known method such as vacuum drying method or lyophilization, can make the solid deodorizer compositions.Perhaps, described liquid can be bearing on arbitrary carrier as liquid, solid or gelatinous mass, forms deodorant compositions.

The preferred embodiment of described liquid comprises water, aqueous alcohol, lower alcohol (methanol, ethanol, butanols, propanol etc.), polynary alcohol radical organic solvent (ethylene glycol, propylene glycol etc.), benzylalcohol, glycerol, monoglyceride, diglyceride, animal and plant oil, quintessence oil etc.

Described solid preferred embodiment comprises porous carrier, and is for example sugared, as dextrin, cyclodextrin, glucose, lactose and starch; Plastic carrier is as plastic grain and foam plastics; Inorganic particle such as silica gel particle, kieselguhr, activated clay, Vermiculitum, aluminium oxide, zeolite, perlite, clay pit, Unglazed ceramic device, pottery, metal, glass and active carbon; The polymer that can absorb water; Natural carrier is as Buckwheat shell, rice husk, sawdust and baked products thereof; Fibrous carrier is as fiber, coma polymers, fibre bundle, non woven fibre, knitted fabric, textile, paper pulp, paper, paper products (cardboard, cellular etc.); Synthetic molecules is as crown ether, cryptand, cyclophane and carixarene etc.In this article, described " porous " comprises porous situation of carrier itself and the situation that has many spaces between carrier.

The example of gelatinous mass comprises aqueous gel, as carrageenin, CVP Carbopol ETD2050, crosslinked polyacrylic acid, hydroxyethyl-cellulose, carboxymethyl cellulose sodium acrylate, agar, gelatin, pectin, pharselan, xanthan gum, locust bean gum, Du Lan (duran) glue and collagen; The oil-base gel agent is as metal fatty acid salt and diphenyl methylene sorbitol.They can use or mix use separately.

For method at carrier upper support deodorant compositions of the present invention, mentioned the deodorant compositions that for example adheres to solution state by methods such as coating, dipping, sprayings, carry out the method for drying (for example, descending air-dry 12 hours) afterwards at 60 ℃.

Deodorant compositions of the present invention can use after use gelatin, arabic gum, Arginine sodium, cellulose derivative such as ethyl cellulose, polyvinyl alcohol, vinyl methyl ether-copolymer-maleic anhydride, styrene-maleic anhydride copolymer, polyethylene, polystyrene, paraffin etc. carry out encapsulation by known method.

And, especially using with solution state under the situation of deodorant compositions of the present invention, reduce the amount of oxygen that is dissolved in the solution as far as possible and can significantly improve the storage stability that the present invention is the compositions of solution form, and convenient the use.The roughly standard of the amount of the dissolved oxygen of being convenient to store for example is 0.0005 weight %, is more preferably 0.00015 weight % or following.

As for the method that reduces the amount of dissolved oxygen in the solution as far as possible, known method be can use, the method for the described solution of storage, the method that described solution is outgased handle specifically are included under the reduced pressure, with the method for nitrogen or argon replaces, the method for in nitrogen or argon gas atmosphere, handling etc.

Using with solid state under the situation of described deodorant compositions, when described deodorant compositions with have hygroscopy or bibulous chemical compound when existing together, described chemical compound absorbs airborne dampness efficiently, therefore, the reacting field that is suitable for deodorant compositions can be provided, this situation is more preferably for described deodorant compositions presents deodorizing effect.

As for example with hygroscopy or bibulous chemical compound, can use air by the dampness deliquescence and in air the salt and the alkali metal of strong absorption dampness, use especially in practice to have hygroscopy or bibulous salt.

Concrete example comprises lithium chloride, sodium chloride, potassium chloride, magnesium chloride, ammonium magnesium chloride, magnesium chloride sodium, magnesium chloride potassium, manganese chloride, manganese chloride potassium, antimony chloride, cobaltous chloride antimony, zinc chloride, iron chloride, bismuth chloride, beryllium chloride, calcium bromide, zinc bromide, copper bromide, ferric bromide, cobaltous bromide, calcium bromide, lithium iodide, sodium iodide, magnesium iodide, calcium iodide, ferric iodide, Nickel diiodide., Chile saltpeter, potassium nitrate, magnesium nitrate, ammonium nitrate, lithium nitrate, Chile saltpeter, lime nitrate, beryllium nitrate, magnesium nitrate, manganese nitrate, cerous nitrate, ammonium ceric nitrate, ferric nitrate, copper nitrate, lithium chlorate, calcium chlorate, magron, zinc chlorate, cadmium chlorate, cobaltous chlorate, copper chlorate, potassium carbonate, lithium sulfate, the zinc sulfate ammonium, Antimonous sulfate, iron sulfate, the cadmium sulfate ammonium, Ammonium hyposulfite., potassium phosphate, ammonium phosphite, potassium phosphite, the phosphorous acid hydrazine, sodium hypophosphite, potassium hypophosphite, sodium permanganate, acerdol, strontium permanganate, magnesium permanganate, zinc permanganate, sodium hydroxide, potassium hydroxide etc.Can use separately or mix and use in these salt two or more.

The only amount of the chemical compound with hygroscopy or high-hygroscopicity of described coexistence becomes with the kind of described chemical compound, the environment and the required purposes of use, therefore described amount is not unconditionally specified, for example, mention 0.1-10 weight equivalent into described deodorant compositions.

In the present invention, add various commercially available additives in the deodorant compositions that can make toward above-mentioned method.The example of described additive comprises extender, antioxidant, dyestuff, known deodorization material, is used to reduce malodorous enzyme, surfactant, spice, aromatic, stabilizing agent, antibacterial, hygroscopic agent (polymer of calcium chloride, high-hydroscopicity etc.), excipient (lactose etc.) etc.

Deodorant compositions of the present invention can be separately and their mix, perhaps with they in two or more mixing, therefore, can make specific deodorant compositions and deodorizer.Especially when antibacterial being sneaked in the described deodorant compositions, described deodorizing effect is collaborative to be improved, and therefore, can prepare more characteristic deodorant compositions and deodorizer, by described reagent and other additive are mixed, shows the performance of described additive.The combined amount of above-mentioned additive does not have special remarkable, as long as described amount can reach required purpose.

Described hygroscopic agent comprises sugar, polysaccharide, finished starch, casein, gelatin, carboxymethyl cellulose (CMC hereinafter referred to as), lecithin etc.

As for antioxidant, known butylated hydroxytoluene, butylated hydroxyanisole (BHA), citric acid, biofavoic acid, glutathion, selenium, licopene, vitamin A, vitamin E and vitamin C, and azole derivatives, free radical scavenger (making by various plant extracts), enzyme with non-oxidizability, as superoxide dismutase and glutathione peroxidase etc.

As for dyestuff, known have dyestuff, color lake, an organic synthetic dye (Colophonium dyestuff), as organic pigment, natural dye, inorganic pigment etc.Concrete is, known Hibisci Mutabilis dyestuff, the Pericarpium Citri tangerinae dyestuff, the feather dyestuff, the Thallus Porphyrae dyestuff, the duberry dyestuff, the Sucus Vitis viniferae dyestuff, the blackberry dyestuff, the blue berry dyestuff, the Fructus Mori dyestuff, the morello cherry dyestuff, the black currant dyestuff, the sweet certain kind of berries dyestuff of sieve, the paplica powder, Fructus Hordei Germinatus extract, rutin, flavonoid, the red cabbage dyestuff, the Radix Dauci Sativae dyestuff, the Semen Phaseoli dyestuff, the Rhizoma Curcumae Longae dyestuff, olive leaf tea, the Pericarpium Citri tangerinae dyestuff, the chlorella dyestuff, the Stigma Croci dyestuff, the Folium Perillae dyestuff, the Fructus Fragariae Ananssae dyestuff, the Herba Cichorii dyestuff, the Semen Caryae Cathayensis dyestuff, fructus zizaniae caduciflorae embryo tooth dyestuff, safflower, the Rhizoma Dioscoreae esculentae dyestuff, lac dye, the Thallus Laminariae (Thallus Eckloniae) dyestuff, the Bulbus Allii Cepae dyestuff, the tamarind dyestuff, the chilli dyestuff, the Fructus Gardeniae dyestuff, Fructus Gardeniae (Gardenia jasminoides) dyestuff, the sikon dyestuff, the redwood dyestuff, the krill dyestuff, the Fructus Citri junoris dyestuff, carotene, Carmel (carmel), sodium iron chlorophyllin, riboflavin, norbixin potassium, norbixin sodium, alamanee, erythromycin, new coccin, phloxin B, rose bengal, Xylene Red, cutoradin, sunset yellow, light green (first green), light blue,, indigo carmine, lake red C, lithol red, rhodamine, phloxin, indigo-blue, cerise, orange I, the Sudan's indigo plant etc.Inorganic pigment comprises Muscovitum, Talcum, calcium carbonate, Kaolin, silicic acid anhydride, aluminium oxide, colcother, ferrum oxide, ultramarine, carbon black, titanium dioxide, zinc oxide, Muscovitum, bismuth oxychloride, boron nitride, photochromic pigment, hybrid fine powder, synthetic mica etc.

Described antibacterial comprises the Semen Coicis extract of benzoic acid, sodium benzoate, p-Hydroxybenzoic acid isopropyl ester, p-Hydroxybenzoic acid isobutyl ester, ethylparaben, methyl parahydroxybenzoate, butyl p-hydroxybenzoate, propyl p-hydroxybenzoate, sodium sulfate, sodium thiosulfate, potassium metabisulfite, sorbic acid, potassium sorbate, dehydro sodium acetate, thujaplicin, Radix Angelicae Sinensis extract, Benzoinum extract, wild-tansy extract, egg protein extract, enzymolysis etc.

The known deodorant example comprises the deodorizer that is formed by the iron sulfate desulfidation, as ferrous sulfate and iron chloride; The deodorizer that works by the chemical reaction of acid reagent, alkaline reagent, oxidant etc.; By the addition of (as addition agents) such as (methyl) esters of acrylic acid, maleic acid esters or Biformyl (as condensing agent) or condensation and the deodorizer that forms; The deodorizer that works by the ion exchange of amphoteric ion-exchange resin, cation exchange resin, anion exchange resin etc.; Adhere to or adsorption and the deodorizer that works by the chemical substance of the alkalescence or the mixture of acid absorption activated carbon, active carbon and chemical reagent etc.; The deodorizer that works by the adsorption of porous adsorbent such as neutral active carbon, fibrous carbon deodorizer, zeolite and activated clay; Form deodorizer by the enzyme catalysis of oral cavity food antibacterial LS-1 lactobacillus, yeast, soil bacteria etc. or its bacteriogenic digestive enzyme; The deodorizer that works by the anticorrosion or bactericidal action of toluene-sodium-sulfonchloramide, parabens, phenol etc.; Deodorizer as Fructus Kaki polyphenol, tea catechin, Herba Rosmarini Officinalis extract, oolong tea extract, tansy extract, white oak leaf extract and Testa oryzae/Semen sojae atricolor roasted extract etc.In addition, also comprise cyclodextrin, champignon extract, Lu Yi Persian Camellia sinensis (rooibos) extract, sodium iron chlorophyllin, active carbon, zeolite etc.

The example that is used to reduce malodorous enzyme comprises carbohydrase, lipase, protease, phytase etc.By in deodorant compositions, sneaking into these enzymes, can improve described deodorizing effect.

Described surfactant comprises nonionic (polyoxyethylene groups Arrcostab, fatty acid alkanol amides etc.), acyl glutamic acid type etc.These surfactants better use separately or two or more mix use.The example of described polyoxyethylene groups Arrcostab comprises polyoxyethylene groups stearate, polyoxyethylene groups hardened castor oil etc.The example of described fatty alkanoic acid alkylolamides comprises cocoanut fatty acid diethanolamide.Described acyl glutamic acid type comprises saturated and unsaturated fatty acid and the coco-nut oil fatty acid with 12-18 carbon atom; the sclerosis coco-nut oil fatty acid; palm oil fatty acid; hardened palm oil fatty acid; tallow acid; the glutamate of hardened tallow fatty acid and their combinations etc.; more particularly, comprise N-coco-nut oil fatty acid acyl group-L-glutamic acid triethanolamine; lauroyl-L-glutamic acid triethanolamine; N-coco-nut oil fatty acid-acyl group-L-sodium glutamate; N-lauroyl-L-sodium glutamate; N-myristoyl-L-sodium glutamate; N-coco-nut oil fatty acid-hardened tallow fatty acid-acyl group-L-sodium glutamate; N-coco-nut oil fatty acid-acyl group-L-Kaglutam etc.

And, spice and/or aromatic can be added in the deodorant compositions.As a result, can cover the strange abnormal smells from the patient of base material, and pleasant fragrance is provided.

The mixed volume of spice and/or aromatic changes with the application purpose of used polyphenol and aminoacid, deodorant compositions, its using method etc., but is about the 0.001-500 equivalent of deodorizer weight usually.

The used spice of the present invention comprises the synthesizing fragrant chemical reagent, as spice of esters, alcohols, aldehydes, ketone, acetal, phenol, ethers, lactone, furans, hydro carbons and acids, natural origin etc.

Example as the esters in the synthesizing fragrant chemical reagent of above-mentioned spice comprises esters of acrylic acid (methyl; ethyl etc.); acetoacetic ester (methyl; ethyl etc.); anisic acid esters (methyl; ethyl etc.); benzoates (pi-allyl; isopentyl; ethyl; geranyl; linalyl; phenylethyl; hexyl; cis-3-hexenyl; benzyl; methyl etc.); o-aminobenzoa class (cinnamyl; cis-3-hexenyl; methyl; ethyl; linalyl; isobutyl group etc.); N-methyl o-aminobenzoa class (methyl; ethyl etc.); isovalerate (amyl group; pi-allyl; isopentyl; isobutyl group; isopropyl; ethyl; octyl group; geranyl; cyclohexyl; citronellyl; terpenyl; linalyl); cinnamyl; phenylethyl; butyl; propyl group; hexyl; benzyl; methyl; rhodinyl etc.); isopropylformic acid. esters (isopentyl; geranyl; citronellyl; terpenyl; cinnamyl; octyl group; neryl; phenylethyl; phenyl propyl; the phenoxy group ethyl; butyl; propyl group; isopropyl; hexyl; benzyl; methyl; ethyl; linalyl; rhodinyl etc.); 9-undecylenic acid esters (pi-allyl; isopentyl; butyl; ethyl; methyl etc.); caprylate esters (pi-allyl; isopentyl; ethyl; octyl group; hexyl; butyl; methyl; linalyl etc.); octenoic acid esters (methyl; ethyl etc.); octyne carboxylic acid esters (methyl; ethyl etc.); caproic acid esters (pi-allyl; amyl group; isopentyl; methyl; ethyl; isobutyl group; propyl group; hexyl; cis-3-hexenyl; trans-the 2-hexenyl; linalyl; geranyl; cyclohexyl etc.); caproic acid esters (methyl; ethyl etc.); valeric acid esters (amyl group; isopropyl; isobutyl group; ethyl; cis-3-hexenyl; trans-the 2-hexenyl; cinnamyl; phenylethyl; methyl etc.); formate ester (anisyl; isopentyl; isopropyl; ethyl; octyl group; geranyl; citronellyl; cinnamyl; cyclohexyl; tyerpinyl; phenylethyl; butyl; propyl group; hexyl; cis-3-hexenyl; benzyl; linalyl; rhodinyl etc.); .beta.-methylacrylic acid esters (isobutyl group; ethyl; cyclohexyl etc.); cinnamate derivative (pi-allyl; ethyl; methyl; isopropyl; propyl group; the 3-phenyl propyl; benzyl; cyclohexyl; methyl etc.); succinic acid esters (single menthyl; diethyl; dimethyl etc.); acetate esters (anisyl; amyl group; α-amyl group cinnamyl; isopentyl; isobutyl group; isopropyl; different pulegium base; isobornyl; the sub-perfume base of isobutyl; eugenyl; the 2-ethyl-butyl; ethyl; the 3-octyl group; carvacryl; the dihydro carvacryl; the p-tolyl; the o-tolyl; geranyl; α or β-santalyl; cyclohexyl; the ring neryl; the dihydro cuminyl; dimethyl benzyl Ka Biji; cinnamyl; the styrene propyl group; decyl; dodecyl; tyerpinyl; amidino groups; neryl; nonyl; phenylethyl; phenyl propyl; butyl; furfuryl group; propyl group; hexyl; cis-3-hexenyl; trans-the 2-hexenyl; cis-3-nonene base; cis-6-nonene base; cis-3; cis-6-nonadiene base; 3-methyl-2-butene base; menthyl; heptyl; benzyl; bornyl; myrcenyl; the dihydromyrcene base; myrtenyl; methyl; the 2-methyl butyl; menthyl; linalyl; rhodinyl etc.); salicylic acid esters (pi-allyl; isopentyl; phenyl; phenylethyl; benzyl; ethyl; methyl etc.), cyclohexyl alkanoic acid esters (cyclohexyl-acetic acid ethyl ester; allyl cyclohexyl propionate; allyl cyclohexane butyrate; allyl cyclohexanehexanoate; cyclohexyl capric acid allyl ester; allyl cyclohexanevalerate etc.); stearic acid esters (ethyl; propyl group; butyl etc.); sebacic acid ester (diethyl; dimethyl etc.); capric acid esters (isopentyl; ethyl; butyl; methyl etc.); dodecylic acid esters (isopentyl; ethyl; butyl etc.); lactic acid ester (isopentyl; ethyl; butyl etc.); n-nonanoic acid esters (ethyl; phenylethyl; methyl etc.); nonenoic acid esters (pi-allyl; ethyl; methyl etc.); hydroxycaproic acid esters (ethyl; methyl etc.); phenylacetic acid esters (isopentyl; isobutyl group; ethyl; geranyl; citronellyl; cis-3-hexenyl; methyl etc.); phenoxyacetic acid esters (pi-allyl; ethyl; methyl etc.); furancarboxylic acid esters (furancarboxylic acid ethyl ester; the furancarboxylic acid methyl ester; the own ester of furancarboxylic acid; furan propanoic acid isobutyl group etc.); propionic acid ester (anisyl; pi-allyl; ethyl; amyl group; isopentyl; propyl group; butyl; isobutyl group; isopropyl; benzyl; geranyl; cyclohexyl; citronellyl; cinnamyl; tetrahydrofurfuryl; tricyclic decenyl; heptyl; bornyl; methyl; menthyl; linalyl; tyerpinyl; the Alpha-Methyl propiono; Beta-methyl propiono etc.); enanthic acid esters (pi-allyl; ethyl; octyl group; propyl group; methyl etc.); heptyne carboxylic acid esters (pi-allyl; ethyl; propyl group; methyl etc.); myristic acid esters (isopropyl; ethyl; methyl etc.); phenyl glycerine esters of gallic acid (phenyl glycerine acetoacetic ester; 3-aminomethyl phenyl ethyl glycerate; p-methyl-beta-phenyl ethyl glycerate etc.); 2-Methyl Butyric Acid esters (methyl; ethyl; octyl group; phenylethyl; butyl; hexyl; benzyl etc.); 3 Methylbutanoic acid esters (methyl; ethyl etc.); butyric acid ester (anisyl; amyl group; pi-allyl; isopentyl; methyl; ethyl; propyl group; octyl group; amidino groups; linalyl; geranyl; cyclohexyl; citronellyl; cinnamyl; neryl; terpenyl; phenyl propyl; the beta-phenyl ethyl; butyl; hexyl; cis-3-hexenyl; trans-the 2-hexenyl; benzyl; rhodinyl etc.); hydroxybutyric acid esters (3-beta-hydroxymethyl butyrate; ethyl ester or menthyl ester etc.) etc.

The example that is used as the alcohols of spice of the present invention better comprises aliphatic alcohol class (isoamyl alcohol, different pulegol, 2-Ethylhexyl Alcohol, the 1-capryl alcohol, the 3-capryl alcohol, 1-octene-3-alcohol, 1-decanol, the 1-dodecanol, 2,6-nonadienol (nonadienol), nonyl alcohol, the 2-nonyl alcohol, cis-6-nonenol, trans-2, cis-6-nonadienol, cis-3, cis-6-nonadienol, butanols, hexanol, cis-3-hexenol, trans-the 2-hexenol, the 1-undecyl alcohol, enanthol, the 2-enanthol, 3-methyl-1-pentene alcohol etc.), terpene alcohols (carveol, baras camphor, isoborneol, carveol, menthol, geraniol, α-or β-santalol, citronellol, 4-fragrant and mellow (thujanol), terpinol, the 4-terpinol, nerol, myrcenol, myrtenol, menthol, dihydromyrcenol, 2,6-Dimethyl-2-octanol, nerolidol, hydroxyl Fructus Citri Limoniae nerol, farnesol, perilla alcohol, rhodinol, linalool etc.), aromatic alcohol (Pimpinella anisum Linn. alcohol, α-1 amyl group cinnamyl alcohol, isopropyl benzyl methanol, carvacrol, cuminyl alcohol, dimethyl benzyl carbinol, cinnamyl alcohol, the phenyl allyl alcohol, phenylethanol, beta-phenyl ethanol, the 3-phenyl propanol, benzylalcohol etc.) etc.

The example that is used as the aldehydes of spice of the present invention better comprises aldehydes (acetaldehyde, octanal, aldehyde C-9, capraldehyde, the hendecanal, 2,6-dimethyl-5-enanthaldehyde, 3,5,5-trimethyl enanthaldehyde, cis-3, cis-6-azel aldehyde, trans-2, cis-6-azel aldehyde, valeral, propionic aldehyde, different propionic aldehyde, hexanal, trans-the 2-hexanal, cis-3-hexanal, the 2-valeral, lauric aldehyde, Tetradecanal, trans-the 4-capraldehyde, trans-the 2-tridecylic aldehyde, trans-the 2-lauric aldehyde, trans-the 2-hendecanal, 2, the 4-sorbaldehyde, cis-6-aldehyde C-9, trans-the 2-aldehyde C-9,2 methyl butyraldehyde etc.), aromatics aldehydes (anisaldehyde, the a-amyl cinnamic aldehyde), α-Jia Jirouguiquan, cyclamen aldehyde, p-cumene ethylhexanal, ethyl vanillin, cumal, salicylide, cinnamic aldehyde, o-, m-or p-tolyl aldehyde, vanillin, piperonal, phenyl acetaldehyde, piperonal, benzaldehyde, 4-methyl-2-phenyl-2-pentenals, the p-methoxycinnamic aldehyde, p-methoxy methyl benzaldehyde etc.), terpene aldehyde (geranial, citral, citronellal, α-sinensal, β-sinensal, perillaldehyde, hydroxycitronellal, tetrahydrocitral, myrtenol, cyclocitral, isocyclocitral, citronellyl oxygen acetaldehyde, neral, the alpha-methylene citronellal, cumal (myrac aldehyde), neral, safranal etc.) etc.

The preferred example that is used as the ketone of spice of the present invention better comprises cyclic ketones class (menthone; isomenthone; carvone; dihydro carvone; pulegone; menthone; 1-acetyl group-3; 3-dimethyl-1-cyclohexene; cis-jasmone; α-; β-or γ-irone; ethyl maltol; the 3-methyl isophthalic acid; 2-cyclopentanedione (cyclotene); the dihydro nootkatone; 3; 4-dimethyl-1; the 2-Ketocyclopentane; 4; 5-dimethyl-3-hydroxyl-2 (5H)-furanone (sotolone); α-; β-; γ-or δ-damascenone; α-; β-or γ-damascenone; nootkatone; the 2-second month in a season-butyl cyclohexanone; maltol; α-; β-or γ-purple sieve (orchid) ketone; α-; β-or γ-crystal violet sieve (orchid) ketone; α-; β-or γ-different crystal violet sieve (orchid) ketone; furan alcohol (furaneol); Camphora etc.); fragrance ketone (acetonaphthone; 1-Phenylethanone.; anisyl acetone; menthone; the p-methyl acetophenone; anisyl acetone; p-methoxyacetophenone etc.); straight chain ketone (biacetyl; methyl n-heptyl ketone; biacetyl; 2-heptanone; 2; the 3-heptadione; 2 pentanone; methylpentanone; methyl nonyl ketone; 3-methyl naphthalenone; methylheptanone; the 3-heptanone; dipropyl ketone; the 3-octanone; 2, the 3-acetyl butyryl; the 2-undecyl ketone; the dimethyl octanone; 6-methyl-5-heptyne-3-ketone etc.) etc.

The preferred example that is used as the acetal of spice of the present invention comprises the acetaldehyde diethyl acetal, acetaldehyde diamyl acetal, acetaldehyde dihexyl acetal, acetaldehyde propylene glycol acetal, acetaldehyde ethyl cis-3-hexenyl acetal, benzaldehyde glycerol acetal, benzaldehyde propylene glycol acetal, the citral dimethyl-acetal, the citral diethyl acetal, citral propylene glycol acetal, citral ethylene glycol ethyl ethers acetal, Phenylacetaldehyde dimethyl acetal, citronellyl methyl acetal, Acetoaldehydephenylethylpropyl acetal, the hexanal dimethyl-acetal, hexanal dihexyl acetal, hexanal propylene glycol acetal, trans-2-hexenoic aldehyde diethyl acetal, trans-2-hexenoic aldehyde propylene glycol acetal, cis-3-hexenoic aldehyde diethyl acetal, the enanthaldehyde diethyl acetal, enanthaldehyde ethylene glycol ethyl ethers acetal, octanal d methyl acetal, the aldehyde C-9 dimethyl-acetal, the capraldehyde dimethyl-acetal, the capraldehyde diethyl acetal, 2-methyl hendecanal dimethyl-acetal, the citronellal dimethyl-acetal, ambersage (making) by Givaudan, oacetic acid ethylene glycol ethyl ethers acetal, 2-hydrocinnamicaldehyde dimethyl-acetal etc.

The preferred example that is used as the phenol of spice among the present invention comprises acetaminol, isoeugenol, 2-methoxyl group-4-vinylphenol, thymol, carvacrol, guaiacol, chavicol etc.

The preferred example that is used as the ethers of spice of the present invention comprises anethole, 1,4-eucalyptole, 1,8-eucalyptole, dibenzyl ether, Linalool oxide, limonene oxide, nerol oxide, Flos Rosae Rugosae oxide, methyl isoeugenol, estragole, isopentyl phenyl ether, betanaphthyl methyl ether, phenyl propyl ether, p-cresyl methyl ether, vanillyl butyl ether, a-tyerpinyl methyl ether, citronellyl ether, geranyl ether, Flos Rosae Rugosae-furan, tea Neptunea cumingi alkane, decyl methyl ether, aminomethyl phenyl methyl ether etc.

Comprise γ-or δ-Gui Neizhi, γ-Geng Neizhi, nonyl lactone, γ-or δ-caprolactone, γ-or δ-Xin Neizhi, γ-or δ--undecalactone, δ-dodecylic acid lactone, δ-2-dodecylic acid lactone, methyl lactone, 5-hydroxyl-8-9-undecylenic acid delta-lactone, JSM-LAC (Z)-7-Decen-5-olide, menthyl lactone, dihydrocoumarin, octahydrocoumarin, 6-Methylcoumarin etc. as the preferred example of the lactone of spice of the present invention.

The preferred example that is used as the furans of spice of the present invention comprises furan; the 2-methylfuran; the 3-methylfuran; the 2-ethyl furan; 2; 5-diethyl oxolane; 3-hydroxy-2-methyl oxolane; 2-(methoxy) furan; 2; the 3-dihydrofuran; menthofuran; furfural; 5 methyl furfural; 3-(2-furyl)-2-methyl-2-acrylic aldehyde; 5-(hydroxymethyl) furfural; 2; 5-dimethyl-4-hydroxyl-3 (2H)-furanone (furanone) (furaneol); 4; 5-dimethyl-3-hydroxyl-2 (5H) furanone (sotolone); 2-ethyl-4-hydroxy-5-methyl base-3 (2H)-furanone (high furan alcohol); 5-ethyl-3-hydroxy-4-methyl-2 (5H) furanone (homosotolone); the 3-methyl isophthalic acid, 2-cyclopentanedione (cyclotene); 2 (5H)-furanones; 4-methyl-2 (SH)-furanone; 5-methyl-2 (5H)-furanone; 2-methyl-3 (2H)-furanone; 5-methyl-3 (2H)-furanone; 2-acetyl furan ketone; 2-acetyl group-5-methylfuran; furfuryl alcohol; the pyromucic acid methyl ester; the pyromucic acid ethyl ester; furfuryl acetate etc.

Comprise α-bisabolene, β-caryophyllene, p-cymol, terpinene, terpinolene, cadinene, farnesene, limonene, ocimene, myrcene, α-or nopinene, 1 as the preferred example of the hydro carbons of spice of the present invention, 3,5-11 triolefins, valencene etc.

In addition, comprise sad, n-nonanoic acid, capric acid, 2-capric acid, geranic acid, dodecylic acid, lauric acid, stearic acid, lactic acid, phenylacetic acid, acetone acid, trans-2-methyl-2-penetenoic acid, 2-methyl-cis-3-penetenoic acid, 2-methyl-4-penetenoic acid, cyclohexane-carboxylic acid etc. as the preferred example of the acids of spice of the present invention.

And, example as the spice of the natural origin of spice comprises Pimpinella anisum Linn., orange, Fructus Citri Limoniae, Citrus aurantium Linn., Citrus, Semen Tritici aestivi, bergamot, Fructus Citri Limoniae, Balm, Fructus Citri grandis, elemi, Olibanum, Herba Cymbopogonis Citrari, orange blossom oil, Adeps Bovis seu Bubali, Radix Angelicae Pubescentis, anistree, Herba Ocimi (Herba Ocimi Pilosi), Laurel, Rhizoma Acori Graminei, Flos Chrysanthemi, Herba Coriandri, Elettaria cardamomum (L.) Maton, Cortex cinnamomi japonici (Ramulus Cinnamomi), Cortex Cinnamomi, Oleum menthae, Mentha viridis L, Herba Menthae, pennyroyal, Fructus Piperis powder, Folium Perillae, Cupressaceae, Adeps Bovis seu Bubali, cascarilla, Rhizoma Zingiberis Recens, parsley, Folium Pini, Salvia japonica Thunb., hyssop, Camellia sinensis, mustard, Radix Cochleariae officinalis, clarisage, Flos Caryophylli, brandy (cognac), Herba Coriandri, tarragon, Eucalyptus, Fructus Foeniculi, lignum-vitae, Fructus anethi, Cortex Melaleucae leucadendrae, Herba Chenopodii, Gan Jiaoshu, Juniperus oxycedrus, Semen Trigonellae, Bulbus Allii, bay tree, Semen Myristicae, mil, Semen Myristicae, PiceameyeriRehd. Et Wils., Flos Pelargonii, Herba Cymbopogonis Citrari, Lavandula, Lavandula hybrida, Cymbopogon martini, Flos Rosae Rugosae, Herba Rosmarini Officinalis, Lignum Santali Albi, Quercus acutissima Carr., applewood, Vetiveria zizanoides, ligaloes, rosewood, Herba Pogostemonis, frostweed, Cuminum cyminum L, Moschus, the fragrant cananga, Trillium tschonoskii Maxim, Fructus Capsici, Herba Apii graveolentis, Thomas balsam, djenne, inmortel, Benzoinum, jasmine, Cortex cinnamomi japonici (Ramulus Cinnamomi), Polianthes tuberosa L., reseda, Calendula arvensis L., Herba Mimosae Pudicae, opopanax, orris, Rhizoma et radix valerianae, licorices etc. also can be used perfume composition contained in the spice of these natural origins.

Be used for aromatic of the present invention and comprise spice of hydro carbons, alcohols, phenols, aldehydes and/or acetal, ketone and/or ketal class, ethers, musk ambrette, acids, lactone, esters, halogen-containing chemical compound, natural origin etc.Hydro carbons as aromatic of the present invention does not have any particular restriction, as long as they are the VOCs that comprise carbon and hydrogen.Its example comprises aliphatic hydrocarbon, alicyclic hydro carbons, terpene hydrocarbons, aromatic hydrocarbons etc.Preferred example comprises 1,3,5-11 triolefins, the p-cymol, australene, α-phellandrene, β-caryophyllene, nopinene, Δ-carene, different-ocimene, ocimene, dihydromyrcene, cinene, Salvia Sclare L. alkene, cedrene, terpinene, terpinolene, valencene, heerabolene, farnesene, myrcene, limonene, longifolene, diamantane (obsolete), different longifolene, camphene, guaiene, biphenyl, diphenyl methane, biphenyl, 3,7-dimethyl-1,3, the 6-sarohornene, 4-isopropyl-1-methyl-2-propenylbenzene, 7-methyl-3-methylene-1, the 6-octadiene, the p-ethyl styrene, α-p-dimethyl styrene, isoprene, 11 triolefins, hendecane, the octadecane diene, octadecane, octadecylene, octane, octene, cumene, sabinene, cyclohexane extraction, cyclohexene, cyclopentadiene, bicyclopentadiene, styrene, naphthalane, decane, the tetradecane, tetralin, dodecane, tridecane, tridecylene, naphthalene, nonane, nonene, norcamphane, norcamphene, hexadecane, hexane, 17 diene, heptadecane, 17 alkene, heptane and pentadecane.Preferred example comprises 1,3,5-11 triolefins, p-cumene, australene, α-phellandrene, β-caryophyllene, nopinene, Δ-carene, different-ocimene, ocimene, dihydromyrcene, cinene, Salvia Sclare L. alkene, cedrene, terpinene, terpinolene, valencene, heerabolene, farnesene, myrcene, limonene, longifolene, diamantane (obsolete), different longifolene and camphene.

Alcohols as aromatic of the present invention does not have any particular restriction, as long as they are the VOCs with hydroxyl.Its example comprises aliphatic alcohol class, alicyclic alcohols, terpene alcohols, aromatic alcohols etc.Preferred example comprises the 10-undecyl alcohol, 1-octene-3-alcohol, 2,6-nonanediol (nonadienol), 2-tert-butyl group Hexalin, 2-Ethylhexyl Alcohol, the 2-enanthol, 3,5, the 5-trimethyl hexanol, the 3-capryl alcohol, the 3-phenyl propanol, the L-menthol, n-decyl alcohol, alpha-alpha-dimethyl benzylalcohol, p-tert-butyl group Hexalin, p-methyl dimethoxy base benzyl carbinol, α, 3,3-trimethyl-2-norcamphane methanol α-n-amyl group cinnamyl alcohol, α-fenchylalcohol, the beta-phenyl ethyl alcohol, Pimpinella anisum Linn. alcohol, succinum nuclear, ambrein, different nonyl alcohol, isophytol, different pulegol, isoborneol, Ethyl linalool, capryl alcohol, carveol, geraniol, santalol, cis-3-oneself-1-alcohol, cis-6-nonenol, citronellol, dihydro-α-terpinol, dihydro-citronellol, dihydromyrcenol, the dihydro linalool, Phenylethyl dimethyl carbinol, dimethyl benzyl carbinol, cinnamyl alcohol, the secondary ethanol of benzene, cedrol, terpinol, terpinene-4-alcohol, Timberol, tetrahydrogeraniol, 2,6-Dimethyl-2-octanol, the tetrahydrochysene artemisol, tetrahydrolialool, nerol, nerolidol, nonyl alcohol, nonyl alcohol, nopol, hydrogen tropyl alcohol, Bacdanol, patchouli alcohol, farnesol, phytol, phenylethyl Methylethyl methanol, the phenoxy group ethyl alcohol, furfuryl alcohol, vetiverol, perilla alcohol, benzyl alcohol, May bloom alcohol, myrcenol, myrtenol, lavandulol, linalool, 1-(2,2, the 6-trimethylcyclohexyl) own-3-alcohol, 1,1-dimethyl-3-phenyl propanol, the 1-Decanol, the 1-lauryl alcohol, 1-nonene-3-alcohol, the 1-enanthol, 1-amylene-3-alcohol, 2,2-dimethyl-3-phenyl propanol, 2,4-dimethyl-3-cyclohexene-1-methanol, 2, the 4-dimethylbenzyl alcohol, 2, the 4-hexanediol, 2,5,5-trimethyl octahydro-2-naphthalene alcohol, 2,6-dimethyl-g-2-alcohol, 2-isobutyl group-4-hydroxy-4-methyl Pentamethylene oxide., the 2-undecyl alcohol, sec-n-octyl alcohol, the 2-nonyl alcohol, 2-phenyl propyl alcohol, 2-2 methyl-3-butene-2-alcohol, 2-methyl-4-(2,2,3-trimethyl-3-cyclopentenyl)-2-butylene alcohol, 2-methyl-4-(2,2,3-trimethyl-3-cyclopentenyl) butanols, 2-methyl capryl alcohol, 2-methyl decanol, 2-methoxyl group-2-phenylethyl alcohol, 3,3-dimethyl-2-[3-norcamphane-2-ethanol, 3,4,5,6,6-pentamethyl-2-enanthol, 3,6-dimethyl-octa-3-alcohol, 3,7-dimethyl-1-capryl alcohol, 3,7-dimethyl-7-methoxyl group suffering-2-alcohol, the 3-occidentalol, the 3-lauryl alcohol, the 3-enanthol, 3-methyl isophthalic acid-phenyl-3-amylalcohol, 3-methyl-2-butene-1-alcohol, 3-methyl-5-(2,2,3-trimethyl-3-cyclopentenyl) five-2-alcohol, 3-methyl-5-phenyl amylalcohol, the 3-methyl anyl alcohol, the 4-isopropyl cyclohexanol, the 4-occidentalol, 4-methyl-3-decene-5-alcohol, 5-methyl-2-phenyl-2-hexanol, 6,8-dimethyl-2-nonyl alcohol, the 9-decenol, 9-decen-1-ol, E.G. single-butyl ether, the second month in a season-undecyl alcohol, the second month in a season-octyl group alcohol, the second month in a season-nonyl alcohol, α, α, p-trimethylphenyl ethyl alcohol, α, alpha-alpha-dimethyl phenylethyl alcohol, α-isobutyl phenenyl ethyl alcohol, α-bisabolol, a-propyl group phenyl ethyl alcohol, β, γ-hexanol, β-clove tree enol, γ-4-dimethyl-3-5 cyclohexene-1-propanol, different-Herba Ocimi (Herba Ocimi Pilosi) alcohol, Ambestol, Santalex, different cyclogeraniol, different dihydro lavandulol, the isobutyl group benzyl carbinol, undecyl alcohol, ethylene glycol, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, the glycol monomethyl propyl ether, the glycol monomethyl methyl ether, Herba Ocimi (Herba Ocimi Pilosi) alcohol, α-(3,3-dimethyl-2-norborny) ethanol (Camekol DH), Cuminum cyminum L alcohol, the geranyl linalool, the sabinene hydrate, diethylene glycol, diethylene glycol monoethyl ether, the diglycol monotertiary butyl ether, the diglycol monotertiary propyl ether, diethylene glycol monomethyl ether, the cyclohexyl ethyl alcohol, ring methylene citronellol, cis-4-hexen-1-ol, cis-p-isopropylcyclohexyl-methanol, dihydrocarveol, dipropylene glycol, dipropylene glycol list ether, the dipropylene glycol single-butyl ether, dipropylene glycol list propyl ether, DPGME, dimethyl octanol, dimethyl ethenyl carbinol, sclareol, decahydro-β-naphthalene alcohol, tetrahydrochysene is different-Herba Ocimi (Herba Ocimi Pilosi) alcohol, trans-sec-n-octyl alcohol, trans-the 2-hexanol, trans-blatter alcohol, neopentyl alcohol, hydrocinnamyl alcohol, cephrol, 10-Pinen-3-ol, butane-1, the 3-glycol, butane-1, the 3-2-ethoxyethanol, butane-1,3-glycol single-butyl ether, butane-1,3-glycol list propyl ether, butane-1,3-glycol monomethyl ether, butane-2, the 3-glycol, butane-2, the 3-2-ethoxyethanol, butane-2,3-glycol single-butyl ether, butane-2,3-glycol list propyl ether, butane-2,3-glycol monomethyl ether, butanediol, propylene glycol, dihydroxypropane single-ether, the propylene glycol single-butyl ether, propylene glycol list propyl ether, propylene glycol monomethyl ether, hexamethylene glycol, the hexyl glycol, the pentamethylene glycol, convallarol, methyl beta-phenyl ethyl alcohol and methyl sandeflor.Its preferred example comprises the 10-undecyl alcohol, 1-octene-3-alcohol, 2,6-11 dienols, 2-tert-butyl group Hexalin, 2-Ethylhexyl Alcohol, the 2-enanthol, 3,5, the 5-trimethyl hexanol, the 3-capryl alcohol, 3-phenyl propyl alcohol, the L-menthol, n-decyl alcohol, α-Er Jiajibianji alcohol, p-tert-butyl group Hexalin, p-methyl dimethoxy base benzyl carbinol, α, 3,3-trimethyl-2-norcamphane methanol, α-n-amyl group cinnamyl alcohol, the a-fenchylalcohol, (3-phenylethyl alcohol, Pimpinella anisum Linn. alcohol, succinum nuclear, ambrein, different nonyl alcohol, different phytol, different pulegol, isoborneol, Ethyl linalool, capryl alcohol, carveol, geraniol, santalol, cis-3-hexene-1-oI, cis-6-nonyl alcohol, citronellol, dihydro-α-terpinol, dihydro-citronellol, dihydromyrcenol, the dihydro linalool, 3,5-dimethylphenyl ethanol, dimethyl benzyl alcohol, cinnamyl alcohol, the secondary ethanol of benzene, cedrol, terpinol, terpinene-4-alcohol, Timberol, tetrahydrogeraniol, 2,6-Dimethyl-2-octanol, the tetrahydrochysene artemisol, tetrahydrolialool, nerol, nerolidol, nonyl alcohol, nonyl alcohol, nopol, hydrogenation tropyl alcohol, Bacdanol, patchouli alcohol, farnesol, phytol, phenylethyl Methylethyl methanol, the phenoxy group ethyl alcohol, furfuryl alcohol, vetiverol, perilla alcohol, benzyl alcohol, May bloom alcohol, myrcenol, myrtenol, lavandulol and linalool.

Phenols as aromatic of the present invention does not have any particular restriction, as long as they are the organic compound with fragrance or pleasant abnormal smells from the patient, they are phenolic compound and derivant thereof, and its example comprises unit price, bivalence or tervalent phenolic compound, polyphenol or its ether derivant.Its preferred example comprises p-cresol, isoeugenol, chavicol methyl ether, acetaminol, hinokitol, benzylisoeugenol, the benzyl acetaminol, the methyl isoeugenol, methyleugenol, the 2-methoxynaphthalene, 2, the 6-syringol, the 4-ethyl guaiacol, 4-methyl guaiacol, 5-acrylic 3,8-dimethyl-5-(.alpha.-hydroxyisopropyl)-.DELTA.9-octahydroazulene, β-naphthalene alcohol isobutyl ether, the p-chavicol, the p-ethyl-phenol, isosafrole, the ethyl isoeugenol, the catechol dimethyl ether, carvacrol, guaiacol, creosol, safrole, dihydroeugenol, thymol, the anol, the hydroquinone dimethyl ether, vanitrope, the ethoxy naphthalene, methoxybenzene, resorcinol dimethyl ether and shogaol.

Aldehydes or acetal as aromatic of the present invention do not have any particular restriction, as long as they are the VOCs that have aldehyde radical or acetal group in the molecule.Its example comprises aliphatic aldehydes or acetal, terpene aldehyde or acetal, aromatic aldehyde or acetal etc.Preferred example comprises the 10-undecylene aldehyde, 2,4-dimethyl-4,4a, 5,9b-tetrahydro indole [1,2d]-1,3-two oxines, 2, the 4-decanedial, 2, the 6-azel aldehyde, 2-butyl-4,4,6-trimethyl-1, the 3-diox, 2-hexyl-5-methyl isophthalic acid, the 3-dioxolanes, the 2-methyl hendecanal, the 2-methyl hendecanal, 2-methyl hendecanal dimethyl-acetal, 3-ethyl-2,4-dioxy spiral shell [5.5] 10 one-8-alkene, 3-ethyl-8 (9), 11-dimethyl-2,4-dioxy spiral shell [5.5] 10 one-8-alkene, 3-propyl group bicyclo-[2.2.1]-heptan-5-alkene-2-carboxyl aldehyde, 4-isopropyl-5,5-dimethyl-1, the 3-diox, the 4-enanthaldehyde, 5-methyl-5-propyl group-2-(1-methyl butyl)-1, the 3-diox, the o-methoxycinnamic aldehyde, the o-methoxybenzaldehyde, p-tolyl aldehyde, the a-n-jasminolene, the a-amyl cinnamic aldehyde, acetaldehyde, acetaldehyde ethyl linalyl acetal, the acetaldehyde diethyl acetal, anisaldehyde, aldehyde C-10, aldehyde C-11, aldehyde C-12, aldehyde C-6, aldehyde C-6 DEA, aldehyde C-6 DMA, aldehyde C-6 PG acetal, aldehyde C-8, aldehyde C-8 DEA, aldehyde C-8DMA, aldehyde C-9, aldehyde C-9 DEA, aldehyde C-9 DMA, isocyclocitral, ethyl vanillin, canthoxal, Fructus Cucumidis sativi aldehyde, Cuminum cyminum L aldehyde, geranial, cyclamen aldehyde, cis-6-aldehyde C-9, citral, citronellal, the citronellyl oxy-aldehyde, Folium eucalypti globueli (Eucalyptus globulus Labill.) aldehyde, Dupical, trans-the 2-hexanal, trans-the 2-hexenoic aldehyde, diethyl acetal, 2,4-dimethyl cyclohexene-3-base formaldehyde (Triplal), neral, hydrogenation tropine aldehyde, vanillin, the 5-hydroxycitronellal, phenyl acetaldehyde, phenyl acetaldehyde P.G. acetal, Phenylacetaldehyde dimethyl acetal, furfural, 2,2-dimethyl (3-3-is to phenethyl) propionic aldehyde (Floralozone), piperonal, helional, perillaldehyde, bergamot aldehyde, beltaldehyde, bernaldehyde, benzaldehyde, equal lauryl aldehyde, lauryl aldehyde, melonal, syringic aldehyde, lilestralis, 2,4,6-triisopropyl-1,3, the 5-trioxane, 2,4-11 carbon dialdehyde, 2, the 4-suberic aldehyde, 2,4-dioxy-3-methyl-7,10-methylene spiral shell [5.5]-hendecane, 2,4-12 carbon dialdehyde, 2, the 4-azel aldehyde, 2, the 4-sorbaldehyde, 2, the 4-heptadienal, 2,5,6-trimethyl-4-enanthaldehyde, 2,6,10-trimethyl-5,9-11 carbon dialdehyde, 2-methyl-3-(4-aminomethyl phenyl)-propionic aldehyde 2-methyl-4-(2,6,6-trimethyl-2-cyclohexenyl group) 3-crotonaldehyde, 2 methyl butyraldehyde, the 3-hydrocinnamicaldehyde, 3-hydrocinnamicaldehyde dimethyl-acetal, 3-methyl-5-phenyl pentenals, 4-(2,2,6-trimethyl-2 (1)-cyclohexene)-2 methyl butyraldehyde, 4-(4-methyl)-3-hexamethylene-1-diene)-pentenals, 4-methyl-2-phenyl-2-pentenals, 5-(hydroxymethyl)-2-furfural, 5,9-dimethyl-4, the 9-decanedial, 5 methyl furfural), the n-valeral, p-tert-butyl group hydrocinnamaldehyde, p-isobutyl group-Alpha-Methyl hydrocinnamaldehyde, p-isopropyl hydrogenation tropyl aldehyde, p-hydrogenated methyl tropyl aldehyde, p-aminomethyl phenyl acetaldehyde, p-methylenedioxy phenoxy ethylhexanal, the p-methoxybenzaldehyde, a-n-amyl cinnamic aldehyde diethyl acetal, the jasminal dimethyl-acetal, α-Camphora olefine aldehydr, α-Jia Jirouguiquan, (3-hydrogenated methyl cinnamic aldehyde, γ-n-jasminolene, the sub-perfume base acetal of acetaldehyde ethyl isobutyl, the acetaldehyde ethyl is trans-3-hexenyl acetal, acetaldehyde ethylphenyl ethyl acetal, acetaldehyde ethylhexyl acetal, acetaldehyde citronellyl ethyl acetal, acetaldehyde citronellyl methyl acetal, 2-acetaldehyde phenylethyl n-propyl group acetal, aldehyde C-13, aldehyde C-14, aldehyde C-5, aldehyde C-7, aldehyde C-7 DEA, aldehyde C-7 DMA, isovaleral, octahydro-4,7-methylene-1H-indenes carboxyl aldehyde, caryophyllin aldehyde, geranyl oxygen acetaldehyde, safranal, salicyl aldehyde, cyclocitral, cis-3-hexenoic aldehyde, cis-3-hexenoic aldehyde diethyl acetal, cis-4-decenal, citral PG acetal, the citral diethyl acetal, the citral dimethyl-acetal, citronellal EQ acetal, dihydro indenyl-2, the 4-diox, the dimethyl octanal, cinnamic aldehyde, the capraldehyde diethyl acetal, the capraldehyde dimethyl-acetal, tetrahydrocitral, the lauric aldehyde dimethyl-acetal, trans-the 2-undecylene aldehyde, trans-2-decylene-1-aldehyde, trans-2-laurylene aldehyde, trans-2-three decenals, trans-the 2-nonenyl aldehyde, trans-2-heptenic aldehyde, trans-the 2-pentenals, trans-the 4-decenal, trimethyl laurylene aldehyde, the trimethyl decanedial, hydrogenation tropyl aldehyde E.G. acetal, hydrogenation tropyl aldehyde dimethyl-acetal, vanillin P.G. acetal, paraldehydum, hydroxycitronellal, diethyl acetal, phenyl acetaldehyde, 2,3-butanediol acetal, phenyl acetaldehyde, 2,4-dihydroxy-4-methylpentane acetal, phenyl acetaldehyde, the diisobutyl acetal, phenoxy acetaldehyde, the furfuryl group acrylic aldehyde, enanthaldehyde E.G. acetal, the piperonal diethyl acetal, the piperonal dimethyl-acetal, benzaldehyde PG acetal, benzaldehyde glyceryl acetal, the benzaldehyde diethyl acetal, the benzaldehyde dimethyl-acetal, formaldehyde cyclo-dodecyl ethyl acetal, the methyl capraldehyde, the methyl nonyl acetaldehyde dimethyl-acetal, methylvanillin, amyl group methoxyl group two cyclopentenes carboxyl aldehyde and methoxy citronellal.Preferred example comprises the 10-undecylene aldehyde, 2,4-dimethyl-4,4a, 5,9b-tetrahydroindene [1,2d]-1,3-two oxines, 2, the 4-decanedial, 2, the 6-azel aldehyde, 2-butyl-4,4,6-trimethyl-1, the 3-diox, 2-hexyl-5-methyl isophthalic acid, the 3-dioxolanes, the 2-methyl hendecanal, 2-methyl hendecanal dimethyl-acetal, 3-ethyl-2,4-dioxy spiral shell [5.5] 10 one-8-alkene, 3-ethyl-8 (9), 11-dimethyl-2,4-dioxy spiral shell [5.5] 10 one-8-alkene, 3-propyl group bicyclo-[2.2.1]-heptan-5-alkene-2-carboxyl aldehyde, 4-isopropyl-5,5-dimethyl-1, the 3-diox, the 4-enanthaldehyde, 5-methyl-5-propyl group-2-(I-methyl butyl)-1, the 3-diox, the o-methoxycinnamic aldehyde, the o-methoxybenzaldehyde, the p-tolyl aldehyde, α-n-jasminolene, jasminal, acetaldehyde, acetaldehyde ethyl linalyl acetal, the acetaldehyde diethyl acetal, anisaldehyde, aldehyde C-10, aldehyde C-11, aldehyde C-12, aldehyde C-6, aldehyde C-6DEA, aldehyde C-6 DMA, aldehyde C-6 PG acetal, aldehyde C-8, aldehyde C-8 DEA, aldehyde C-S DMA, aldehyde C-9, aldehyde C-9 DEA, aldehyde C-9 DMA, isocyclocitral, ethyl vanillin, kantokisal, Fructus Cucumidis sativi aldehyde, Cuminum cyminum L aldehyde, geranial, cyclamen aldehyde, cis-6-nonenyl aldehyde, citral, Herba Cymbopogonis Citrari, the citronellyl oxy-aldehyde, the Folium eucalypti globueli (Eucalyptus globulus Labill.) orange, DupicaL, trans-the 2-hexenoic aldehyde, trans-2-hexenoic aldehyde diethyl acetal, Triplal, neral, hydrogenation tropyl aldehyde, vanillin, hydroxycitronellal, phenyl acetaldehyde, phenyl acetaldehyde P.G. acetal, Phenylacetaldehyde dimethyl acetal, furfural, Floralozone, piperonal, helional, perillaldehyde, bergamot aldehyde, beltaldehyde, bernaldehyde, benzaldehyde, equal cinnamic aldehyde, cinnamic aldehyde, melonal, syringic aldehyde and lilestralis.

Ketone or ketal as aromatic of the present invention do not have any restriction, as long as they are the volatile compounds that have ketone group or ketal group in the molecule, comprise aliphatic ketone or ketal, terpenes ketone or ketal, aromatics ketone or ketal etc.Preferred example comprises the 2-second month in a season-butyl cyclohexanone; 2-acetyl group-3; 3-dimethyl norcamphane; 2-acetyl group-5-methylfuran; the 2-acetyl furan; 2-butyl-1; 4-dioxy spiral shell [4; 4] nonane; 2-hexyl Pentamethylene.; 3-hydroxyl-4; 5-dimethyl-2-(5H)-furanone; 5-ethyl-3-hydroxy-4-methyl-2[5H]-furanone; 6-methyl-3; 5-heptadiene-2-ketone; the d-pulegone; the L-carvone; o-tert-butyl group Ketohexamethylene p-tert-butyl Ketohexamethylene; the p-methyl acetophenone; the p-methoxyacetophenone; α-dinascone; the a-fenchone; Beta-methyl naphthyl ketone; acetyl cedrene; 1-Phenylethanone.; anisyl acetone; pi-allyl α-purple sieve (orchid) ketone; purple sieve (orchid) ketone; different-E-super; isojasmone; different damascenone; isolonglifolene ketone; irone; the ethyl isoamyl ketone; ethyl maltol; cashmeran (Cashmeran); carone; Camphora; Koavone; cyclotene; anti-form-1 0 jasmone; dihydro carvone; dihydro jasmone; dibenzyl ketone; cedralone; sotolone; damascenone; Damascus ketone; trimofix (trimofix0); nootkatone; furan alcohol; canoe cedar ketone; florex; vertfix; verbenone; benzophenone; maltol; crystal violet sieve (orchid) ketone; methyl cyclopentene ketone; methyl heptenone; menthone; frambinone; 1-(4-methoxyphenyl)-1-penten-3-one; I-(p-Herba Menthae-6-yl)-1-acetone; 1-acetyl group-3; 3-dimethyl-1-cyclohexene; 2-(1-cyclohexene-1-yl) encircles Ketohexamethylene; 2; 2; 5; 5-tetramethyl-4-isopropyl-1; the 3-diox; 2; 2; 5-trimethyl-5-amyl group Ketocyclopentane; 2; 3; S-trimethyl cyclohexene-4-base 1-ketone; 2; the 3-acetyl butyryl; 2; 3-heptane diketone; 2; the 3-pentanedione; 2; 4-two tert-butyl Ketohexamethylene; 2; 5; 5-trimethyl-2-phenyl-1; the 3-diox; 2; 6; 10-trimethyl-1-acetyl group-2; 5; 9-cyclododecane triolefin; 2; 6; 6-trimethyl-2-cyclohexene-1; the 4-diketone; 2-n-butadiene-3; 5; 5 (3; 3; S)-trimethylcyclohexanone 2-n-heptyl cycloheptanone; 2 '-acetonaphthone; the 2-undecyl ketone; methyln-hexyl ketone; 2-cyclopenta Ketocyclopentane; methyl n-undecyl ketone; methyl n-heptyl ketone; 2-hydroxyl-6-isopropyl-3-methyl-2-Ketohexamethylene; 2-butanone; 2-heptanone; alismone; 2 pentanone; 2-amyl group-2-Ketocyclopentane; 2-amyl group Ketocyclopentane; 3; 3-Dimethylcyclohexyl ketone; 3; 4-dimethyl-1; the 2-Ketocyclopentane; 3; the 4-hexanone; 3; 5-dimethyl-1; the 2-Ketocyclopentane; 3-acetyl group-2; the 5-dimethyl furan; the 3-octanone; the 3-nonanone; 3-hydroxymethyl-methyl n-heptyl ketone; the 3-hexanone; the 3-heptanone; the 3-hepten-2-one; 3-methyl-4-phenyl-3-butene-2-ketone; 3-methyl-5-(2; 2; 3-trimethyl-3-cyclopentenyl)-3-amylene-2-ketone; 3-methyl-5-propyl group-2-Ketohexamethylene; 4-(4-hydroxy 3-methoxybenzene base)-2-butanone; 4-(4-methoxyphenyl)-3-butene-2-ketone; 4 (5)-acetyl group-7; 7; 9-(7; 9; 9)-trimethyl bicyclo-[4.3.0] ninth of the ten Heavenly Stems-1-alkene; 4; 7-dihydro-2-(3-pentynyl)-1; 3-two Austria put down former times; 4; 7-dihydro-2-isopentyl-2-methyl isophthalic acid; 3-two Austria put down former times; uncle 4--amyl group Ketohexamethylene; 4-oxygen isophorone; 4-cyclohexenyl group-4-methyl base-2 pentanone; dipropyl ketone; 4-methyl-3-amylene-2-ketone; 4-methyl-4-phenyl-2 pentanone; 4-methylene-3; 5; 6; 6-tetramethyl-2-heptanone; 5-encircles hexadecylene-1-ketone; 5-hydroxyl-4-octanone; 5-phenyl-5-methyl-3-hexanone; 5-methyl-2; the 3-acetyl butyryl; 7-methyl-3,5-dihydro-2H-benzo two Austria put down-3-ketone former times; p-hydroxy phenyl butanone; p-methoxybenzene benzylacetone; Alpha-Methyl anisylacetone acetyl group isovaleryl; the acetyl group caryophyllene; 5-acetyl group dimethyl tetrahydro benzindane acetoin; Acetolon; 1-Phenylethanone. neopentyl glycol acetal; acetone; atrinone; inferior anisylacetone; the amyl group Ketocyclopentane; oacetic acid E.G. ketal; oacetic acid propylene glycol acetal; the oxidation cedrene; isopropyl is ketene not; geranyl acetone; diacetyl; DAA; barosma camphor; Ketohexamethylene; cyclonene; Ketocyclopentane; cis-2-acetonyl-4-methyl Pentamethylene oxide.; the dimethyl octanone; (4-hydroxy-3-methoxyphenyl)ethyl methyl ketone; cedrone; auraptene; piperitenone; menthone; piperonylacetone; farnesyl acetone; pseudoionone; butylideneacetone; furfuryl acetone; propiophenone; garden heliotrope tropyl acetone Dan Lv oxane (verdoxane); BENZYLIDENE ACETONE; equal furanone; Mesityl oxide; methyl α-Fu Nan base ketal; methyl isopropyl Ketone; methyl ionone (methyliritone); methyl cedorilone and methyltetrahydrofuran ketone.Other preferred embodiment comprises 2-second month in a season-butyl cyclohexanone 2-acetyl group-3; 3-dimethyl norcamphane; 2-acetyl group-5-methylfuran; the 2-acetyl furan; 2-butyl-1; 4-dioxy spiral shell [4; 4] nonane; 2-hexyl Ketocyclopentane; 3-hydroxyl-4; 5-dimethyl-2-(5H)-furanone; 6-methyl-3,5-heptadiene-2-ketone; the d-pulegone; the L-carvone; o-tert-butyl group Ketohexamethylene; p-tert-butyl Ketohexamethylene; the p-methyl acetophenone; the p-methoxyacetophenone; α-dinascone; α-fenchone; Beta-methyl naphthyl ketone; acetyl cedrene; 1-Phenylethanone.; anisyl acetone; pi-allyl α-purple sieve (orchid) ketone; purple sieve (orchid) ketone; different-E-super; isojasmone; different damascenone; isolonglifolene ketone; irone; the ethyl isoamyl ketone; ethyl maltol; cashmeran; carone; Camphora; Koavone; cyclotene; cis-jasmone; dihydro carvone; dihydro jasmone; dibenzyl ketone; cedralone; sotolone; damascenone; Damascus ketone; trimofix 0; nootkatone; furan alcohol; canoe cedar ketone; florex; vertfix; verbenone; benzophenone; maltol; crystal violet sieve (orchid) ketone; methyl cyclopentene ketone; methyl heptenone; menthone; Fructus Rubi corchorifolii Immaturus ketone.

Ether as spice of the present invention does not have any particular restriction, as long as they are the VOCs that have ether in the molecule.Its example comprises aliphatic ether, terpenes ether, aromatic oxide etc.Preferred example comprises 1, the 4-eucalyptole, 1, the 8-eucalyptole, p-tolyl methyl ether, β-caryophyllene oxide, the betanaphthyl isobutyl ether, the betanaphthyl ether, β--naphthyl methyl ether, anethole, Tu Jing Jie oxane, isopentyl phenyl ether, the isobornyl methyl ether, grisalva, the Radix Pecteilis susannae methyl ether, diphenyl oxidation thing, cedramber, Cupressus funebris Endl. METH ether, teas pyrans (teaspyran), nerol oxide, the phenylethyl methyl ether, 1-methyl isophthalic acid methoxyl group cyclododecane (madrox), Linalool oxide, limette alcohol, Rhubofix, rhouboflor, rose oxide, the Flos Rosae Rugosae furan, 13-oxygen bicyclo-[10.3.0] pentadecane, 1-methyl ring dodecyl methyl ether, 2,2,6-trimethyl-6-vinyl oxolane, 2,2-dimethyl-5-(1-methyl isophthalic acid-acrylic)-Pentamethylene oxide., 2-ethylidene-6-isopropoxy bicyclo-[2.2.1] heptane, 2-oxygen spiral shell [4.7] dodecane, 2-butyl-4,6-dimethyl dihydropyran, 2-methyl-2-butene base phenyl ether, 3,3, S-trimethylcyclohexyl ether, 3-oxygen bicyclo-[10.3.0]-5 penta-6-alkene, 4-pi-allyl methoxybenzene, 5-isopropenyl-2-methyl-2-vinyl decahydro furan, 8,9-epoxy cedrene, the n-decave, the tert-butyl hydroquinone dimethyl ether, the ene epoxide, α-tyerpinyl methyl ether, the allyl phenyl ether, the isopentyl benzyl oxide, different longifolene epoxide, ethyl o-methoxy-benzyl ether, the ocimene epoxide, the geranyl ether, cyclodecene ylmethyl ether, the cyclohexyl ether, the cyclohexyl phenyl ether, citric acid oxide (citroxide), citric acid neryl ether, dibenzyl ether, juniparome, the cedrol methyl ether, decyl methyl ether, the tricyclic decenyl methyl ether, the trimethylcyclododecatriene epoxide, the aminomethyl phenyl ether, the methyl hexyl ether, methylbenzyl ether, the limonene oxide, 1, the 2-dimethoxy benzene, the 3-dimethoxy benzene, 1,4-dimethoxy-2-tert-butyl benzene, ethylene glycol diethyl ether, the ethylene glycol bisthioglycolate butyl ether, the ethylene glycol bisthioglycolate propyl ether, ethylene glycol dimethyl ether, diethyl ether, diethyl carbitol, the diethylene glycol dibutyl ethers, the diethylene glycol dipropyl ether, diethylene glycol dimethyl ether, dimethyl ether, oxolane, propylene glycol diethyl ether and propylene glycol dimethyl ether.Preferred its example comprises 1,4-eucalyptole, 1,8-eucalyptole, p-tolyl methyl ether, β-caryophyllene oxide, betanaphthyl isobutyl ether, β--neonerolin, β--naphthyl methyl ether, anethole, native chaste tree mustard oxane, isopentyl phenyl ether, isobornyl methyl ether, grisalva, Radix Pecteilis susannae methyl ether, diphenyl oxidation thing, cedramber, cedar wood alcohol methyl ether, teas pyrans, nerol oxide, phenylethyl methyl ether, madrox, Linalool oxide, limette alcohol, Rhubofix, rhouboflor, rose oxide and Flos Rosae Rugosae furan.

Synthetic elk perfume (or spice) as aromatic of the present invention does not have any particular restriction, as long as they are the organic compound that have muskiness or be similar to muskiness, its example comprises 10-oxygen hexadecane lactide, 11-oxygen hexadecane lactide, 12-oxygen hexadecane lactide, the Moschus lactone, Ambreton, exaltolide, cyclopentadecanone, galaxolide, ring hexadecane lactide, the cyclopentadecane lactide, cyclopentadecanone, civetone, husky Valley Moschus, celestolide, tonalid, fantolide, valerolactone, formyl ethyl tetramethyl tetralin, muscone, versalide etc.

Acid as aromatic of the present invention does not have any restriction; as long as they are the organic compound that have carboxyl in the molecule, its example comprises phenylacetic acid; 2 Ethylbutanoic acid; 2 ethyl hexanoic acid; the 2-capric acid; the 2-caproic acid; 2-methyl-2-valeric acid; 2-Methyl Butyric Acid; the 2-methyl enanthic acid; the 4-valeric acid; the 4-methylvaleric acid; hendecanoic acid; dodecylic acid; sad; oleic acid; the ridge gemic acid; cinnamic acid; stearic acid; .beta.-methylacrylic acid; capric acid; dodecylic acid; tridecanoic acid; n-nonanoic acid; hydrocinnamic acid; acetone acid acid; propanoic acid; caproic acid acid; enanthic acid; myristic acid; lactic acid; linoleic acid; linoleic acid; levulinie acid; oxalic acid; glutamic acid; citric acid; succinic acid; tartaric acid; p-phthalic acid; vanillic acid; valine; phytic acid; Fumaric acid; benzoic acid; malic acid; maleic acid; malonic acid etc.

Lactone as aromatic of the present invention does not have any particular restriction, as long as they are the organic compound that have lactone group in the molecule, its example comprises aliphatic lactone, terpenes lactone, aromatics lactone etc.Preferred its example comprises 6-Methylcoumarin, alpha-angelica lactone, γ-n-butyrolactone, γ-undecyl lactone, γ-Xin Neizhi, γ-decalactone, nonyl lactone, gamma-valerolactone, γ-Ji Neizhi, γ-Geng Neizhi, δ-2-decenol lactone, δ-undecyl lactone, δ-Xin Neizhi, δ-Gui Neizhi, δ-myristyl lactone, δ-dodecyl lactone, δ-tridecyl lactone, δ-nonalactone, δ-caprolactone, ε-decalactone, ε-dodecyl lactone, aldehyde C-14 (Fructus Persicae), aldehyde C-18 (Cortex cocois radicis), Whiskey lactone, dihydrojasmone lactone, JSM-LAC (Z)-7-Decen-5-olide, JSM-LAC (Z)-7-Decen-5-olide, methyl γ-decalactone, the menthyl lactone, 4,6,6 (4,4,6)-trimethyl Pentamethylene oxide .-2-ketone, the 7-decylene-1, the 4-lactone, octahydrocoumarin, dihydrocoumarin, the dodecyl lactone, 3-n-butylidene naphthalene, the 3-n-butyl phthalate, 3-propylidene naphthalene and 3-propyl group phthalic acid ester.

Esters as aromatic of the present invention does not have any restriction, as long as they are the VOCs that have ester group in the molecule, its example comprises aliphatic esters, terpenes esters and aromatics esters etc.

Halide-containing as aromatic of the present invention does not have any particular restriction, as long as they are the harogenide with fragrance or pleasant abnormal smells from the patient, its example comprises p-dichloro-benzenes and bromostyrene.

The aromatic material that is used as the natural origin of aromatic of the present invention does not have any particular restriction, and its example comprises almond oil, Oleum Anisi Stellati, Oleum Terebinthinae, spice wood oil, Radix Angelicae Sinensis oil, Ambra Grisea, ambre, Radix seu folium abelmoschi moschati oil, ylang-ylang oil, Oleum sesami, wintergreen oil, elemi oil, the pure oil of Quercus acutissima Carr., the Quercus acutissima Carr. quintessence oil, Quercus acutissima Carr. oil, red do not have oil, the pure oil of orris, orange oil, the pure oil of orange blossom, cascarrilla oil, castoreum, Oleum Cinnamomi, the pure oil of Cortex Cinnamomi, Oleum Cinnamomi, cananga oil, the Chamomile oil blue, chamomile oil, oil of Rhizoma Acori Graminei, cardamom oil, kahikatea Oleum sesami, caraway oil, guaiac wood oil, the lignum-vitae fatty oil, cymin oil, clove tree boulbon oil, cloves oil, Radix Aucklandiae oil, copaiba balsam, Balsam copaiba, Fructus Coriandri oil, Resina Cupressi, Oleum Santali albi, cystlabdanum oil, cedarwood oil, citronella oil, civet, the pure oil of jasmine, juniper berry oil, Oleum Camphora, jonquil absolute, oil of ginger, the Rhizoma Zingiberis Recens Rhizoma et radix valerianae oil, Ceylon cinnamon oil, Oleum Anisi Stellati, Benzoinum, oil of spike, Oleum Menthae Rotundifoliae, sage oil, Salvia Sclare L.oil, Herba Erodii oil, Flos Pelargonii oil, bourbon's Flos Pelargonii oil, Celery oil, thyme oil, estragon oil, tangerine oil, tuberose absolute, tolu balsam, Diptheryx odorata oil, Semen Myristicae oil, narcissus absolute, bitter orange oil, Herba Verbenae oil, violet leaf absolute oil, Oleum Pini, basil oil, parsley-seed oil, patchouli oil, Rhizoma et radix valerianae oil, Rhizoma et radix valerianae fat, Hyssop oil., Semen Armeniacae Amarum oil, Herba vallisneriae Spiralis oil, Japanese cypress oil, the arhat fruit oil, pimento oil, the hyacinth absolute oil, petitgrain oil, Buchu oil, laurel fat, the Folium citri sinensis Rhizoma et radix valerianae oil, Folium citri sinensis Paraguay oil, the Folium citri sinensis bergamot oil, the Folium citri sinensis mandarin orange, the Folium citri sinensis Fructus Citri Limoniae oil, vertivazulene (grass) oil, bourbon's Caulis Miscanthis floriduli, pennyroyal oil, oil of pepper, Oleum menthae, Peruvian balsam, Peru balsam oil, bergamot oil, Benzoinum oil, benzoin, Oleum Rosae Rugosae, hooil, horwood oil, Majorana hortensis oil, mandarin oil, the Herba Mimosae Pudicae absolute oil, mil oil, Moschus Vietnam tincture, Semen Myristicae oil, merrissa oil, Oleum Eucalypti, white lemon oil, Essential lavender oil, labdanum oil, Essential lavender oil, roux oil, Fructus Citri Limoniae oil, Indian oil of verbena, Oleum Rosae Rugosae, Bulgarian Rose oil, oil of rosemary, Roman chamomille oil, laurel fat and lovage oil.These natural materials can various forms, as quintessence oil, fat, balsam, face cream, absolute oil, concretion and tincture.

The chemical name that has below shown trade name and popular name in the above-mentioned material:

Dupical (Quest): 4-(three ring [5.2.1.02.6] inferior decyls-8) butyraldehyde.

Jasmal: acetic acid 3-amyl group tetrahydropyran-4-base ester.

Aphermate (IFF): formic acid α, 3,3 ³-trimethyl-cyclohexane methyl ester.

Floralozon (IFF): p-ethyl-α, alpha-alpha-dimethyl hydrocinnamaldehyde.

Cyclogalbanate (Dragoco): cyclohexyl fluoroacetic acid pi-allyl fat

Estragole: methyl chavicol.

Rhubofix (Firmenich): spiral shell [1,4-menthyl naphthalene-2 (1H), 2 '-oxirane, 3,4,4a, 5,8,8a-six hydrogen-3 ', 7-dimethyl (1) and spiral shell [1,4-menthyl naphthalene-(2H), and 2 '-oxirane] 3,4,4a, 5,8,8a-six hydrogen-3 ', the heterogeneous mixture of 6-dimethyl (2).

Triplal (IFF): dimethyl tetrahydro benzaldehyde

Koavone (IFF): 4-methylene-3,5,5,6-tetramethyl-2-heptanone

Limetol:2,2,6-trimethyl-6-vinyl Pentamethylene oxide.

Ambroxan (Henkel): decahydro-3a, 6,6,9a-tetramethyl-naphthalene [2.1-b] furan

Damascenone: α-damascone, β-damascone, γ-damascone, δ-damascone.

Damascus ketone: α-damascenone, β-damascenone, γ-darnascenone

Purple sieve (orchid) ketone: α-purple sieve (orchid) ketone, β-purple sieve (orchid) ketone, γ-purple sieve (orchid) ketone.

Crystal violet sieve (orchid) ketone: α-n-crystal violet sieve (orchid) ketone, β-n-crystal violet sieve (orchid) ketone, γ-n-crystal violet sieve (orchid) ketone, α-different-crystal violet sieve (orchid) ketone, β-different-crystal violet sieve (orchid) ketone, γ-different-crystal violet sieve (orchid) ketone.

Sandal:bacdanol (IFF): 2-ethyl-4-(2,2,3-trimethyl-3-ring heptan-1-yl)-2-butylene-1-alcohol,

Brahaimanol (Dragoco): 2-methyl-4-(2,2,3-trimethyl-3-ring heptan-1-yl) butanols,

Madranol (Dragoco): β-2,2,3-tetramethyl-3-cycloheptenyl-2-butanols

Sandalore (Givaudan): 3-methyl-5-(2,2,3-front three basic ring-3-amylene-1-yl)-pentane-2-alcohol

3,3-dimethyl-5-(2,2,3-trimethyl-cyclopentene-1-yl)-penta-4-alkene-2-alcohol

Methyl sandeflor (TPC): 2-methyl isophthalic acid-(methyl bicyclic [2.2.1]-heptan-5-alkene-2-yl)-amylene-3-alcohol, Sandeol (MS) etc.

Moschus: Cashmeran (IFF): 1,2,3,5,6,7-six hydrogen-1,1,2,3,3-pentamethyl-4H-indenes-4-ketone

Galaxolide (IFF): 1,3,4,6,7,8-six hydrogen-4,6,6,7,8,8-pregnancy basic ring penta-γ-2-.alpha.-5:6-benzopyran

Tonalid (PFW): 6-acetyl group-1,1,2,4,4,7-hexamethyl naphthane

Phantolid:5-acetyl group-1,1,2,3,3,6-hexamethyl indane

Versalide:7-acetyl group-1,1,4,4-tetramethyl-6-ethyl-1,2,3,4-naphthane

Exaltolide: oxa-ring hexadecane-2-ketone

Exaltone: cyclopentadecanone

Oxalide:10-oxa-hexadecane lactide

12-oxygen hexadecane lactide, brazilic acid ethylidene ester,

Celestol ide (IFF): the 4-acetyl group-6-tert-butyl group-1,1-dimethyl indane

Traseolide (Quest): 5-acetyl group-3-isopropyl-1,1,2,6-tetramethyl indane

Traseolide (Quest), ethylidene dodecanedioic acid ester, 5-ring hexadecane alkene-1-ketone etc.

Iso-E-Super (IFF): 7-acetyl group-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl-naphthalene

Timberol (Dragoco): 1-(2,2,6-trimethyl-cyclohexane-1-yl)-oneself-3-alcohol.

Irone: α-irone, β-Yuan Weitong, γ-irone.

α-Dynascone (Firmenich): 1-(5,5-dimethyl cyclohexene-1-yl)-4-amylene-1-ketone.

And, except above-mentioned spice and aromatic, can use at " Nippon niokeru Shokuhin KoryoKagoubutsu no Siyou Jittai Chosa " (2000 ^ThKosei Kagaku Kenkyu Hokokusho; (on March 6th, 1996 published for NihonKoryo Kogyokai (publication in March calendar year 2001), " Gosei koryo-Kgaku to Shohin Chisiki ", by Motoichi Indoh work, The Chemical Daily Co., Ltd.), " Perfume andFlavor Chemicals (Aroma Chemicals) 1,2 " (Steffen Arctender (1969)) described spice and aromatic.

Can use these spice and aromatic separately or mix both or the many persons who uses in them.

As for these base materials, also can use commercially available base material.And, as for simple material, can use synthetic or by the material of natural material such as plant purification.Also can be by the described quintessence oil of known anticorrosion preparation, balsam, face cream, absolute oil, concretion, tincture etc.

Many kinds of stenches can be eliminated or alleviate to deodorant compositions of the present invention effectively.

Specifically, it can eliminate or reduce the various stenches (comprising the stink sensation) in the daily life effectively, as the excrement of bad abnormal smells from the patient (halitosis), body odor, refrigerator stench, people, animal and birds and stench, body odor and the rubbish stench of urine, the stench of factory and trade waste.

And deodorant compositions of the present invention is to sulphur compound such as methyl mercaptan, hydrogen sulfide and dimethyl sulfide, nitrogen-containing compound such as ammonia, urea, indole, the smelly class of excrement and amine, and lower fatty acid such as butyro-deodorizing effect are fabulous.Wherein, the compositions of deodorizer of the present invention is especially good to the deodorizing effect of sulphur compound such as methyl mercaptan, hydrogen sulfide and dimethyl sulfide.

And deodorizer of the present invention can add in following product or the article, shows deodorizing effect.Concrete is that described product or article comprise oral care product, as collutory, toothpaste, chewing gum, tablet, hard sugar, soft sweet, capsule and mouthspray; Be used for the article that house pet and animal comprise Canis familiaris L., cat, rabbit, hamster and parakeet, as cat sand, cat sleep cane and cover; Cleaning agent such as laundry detergents, kitchen cleaning agent, bathroom detergent, carpet cleaner and toilet cleaner; Cosmetics such as soap, bath gel, the soap of washing one's hands, lotion, skin cleaner, Antiperspirant, foot cleaning spraying and foot-powder, hair care product such as shampoo, hair conditioner, hair abluent, hair dye, agent for permanent hair waving, wax, hair jelly and mousse; Health product is as diaper, mat, sanitary towel, coverlet, towel and moisture paper tissue papers; Household cleaning product, the filter of the spraying of footwear cupboard, shoe pad, rubbish spraying, air freshener and air conditioning agent, deodorizer, hair-dryer and exhauster, refrigerator with deodorizer, clothes with deodorizer, the deodorization fiber of the deodorizer of deodorizer, drawer, closet and cabinet, indoor or automobile-used deodorizer, toilet deodorant, textile, clothes (underwear and socks), vehicle heelpiece, the deodorizer that is used for factory and trade waste and other various deodorizer.

Under situation about deodorant compositions of the present invention being added in above product or the article, described amount is not unconditionally specified, he depends on the using method of kind, environment for use, application and described product or article, but usually adds with the amount of the 0.001-100 weight % of described product or article.

When using deodorizer combination of the present invention to remove stench, can use known method.For example, when by described compositions is directly sprayed, sprinkling, wiping, submergence or be placed into the place that there is malodor components or position or estimate may produce on the place or position of malodor components, use solid matter, gelatinous mass or the liquid substance of deodorant compositions of the present invention thus, it can be eliminated stench or prevent its generation.And deodorant compositions of the present invention can use by spraying method.

The invention provides deodorant compositions, it shows that various malodor components are had fabulous deodorizing effect.Deodorant compositions of the present invention has fabulous deodorizing effect to malodor components such as sulphur compound such as methyl mercaptan, hydrogen sulfide and dimethyl sulfide and lower fatty acid such as butanoic acid and isovaleric acid, also amine malodor components such as ammonia (alkalescence) is had fabulous deodorizing effect.And the method that is used to prepare described deodorant compositions is simple relatively.And, in case make described deodorant compositions, even described deodorant compositions also can keep its deodoriging properties after storing for a long time.Therefore, described compositions is exactly so-called significantly fabulous deodorant compositions.

Embodiment

Below with reference to embodiment the present invention has been described in further detail, but the present invention never is limited to this.

Embodiment 1, the preparation deodorant compositions

By being added, the described various polyphenol of 1mmol table 1 comprise 50mL 0.05M Na ₂CO ₃The agitator inside of solution (pH 11.2), and air can free-flow and the reaction liquid surface fully and under the condition that air contact 25 ℃ of whole down stirrings or leave standstill after the stirring under the same conditions, make deodorant compositions thus.Described mixing time and time of repose are as shown in table 1.

Embodiment 2, to the deodorizing effect of methyl mercaptan

(Tokyo KaseiKogyo Co. Ltd.) adds in the bottle of 20mL, and covers described bottle with Parafilm, stirs down at 25 ℃ afterwards with 15% methyl mercaptan aqueous solution of embodiment 1 described 2mL deodorant compositions and 4 microlitres.After 10 minutes, the upper gas that makes 50mL in the bottle is measured the concentration of sulphur compound (being retained in the gas, is malodor components) by gas detecting tube (being made by GastechCorporation), calculates the deodorization rate according to following formula.Described result is presented in the table 1.

Deodorization rate (%)=100 * { 1-(A/B) }

In above formula, A is meant the concentration of the malodor components of surveying, and B is meant the concentration to the malodor components of surveying in the same old way.

Described to pass through to add 0.05M Na in the same old way ₂CO ₃Solution (pH 11.2), rather than adding 2mL embodiment 1 described deodorant compositions prepares.

Time showing shown in the table from beginning to stir the time finishing to the preparation deodorant compositions with the preparation deodorant compositions.Be meant the mixing time when the preparation deodorant compositions in 1 hour, 2 hours and 3 hours.Described deodorant compositions after 4 hours is to stir the compositions that left standstill afterwards in 3 hours.This is equally applicable to following table, except the table 18.

Table 1

Polyphenol	1 hour	2 hours	3 hours	4 hours	1 day	5 days	8 days
								Catechol	78.3	100.0	100.0	100.0	100.0	100.0	100.0
Chlorogenic acid	100.0	100.0	100.0	100.0	100.0	100.0	86.7
								(+)-catechin	25.0	66.7	83.3	91.7	100.0	100.0	63.3
Quercetin	100.0	100.0	100.0	100.0	100.0	85.0	-
								Gallic acid	100.0	100.0	100.0	100.0	100.0	100.0	100.0

In table, numeral deodorization rate (%), "-" expression does not have the situation (this is equally applicable to hereinafter) of measurement.

Comparative Examples 1 uses single phenol to prepare deodorant compositions

Except the described various single phenol of use table 2 come the substitution list 1 described polyphenol, make deodorant compositions as identical mode as described in the embodiment 1.

Comparative Examples 2 is used the deodorizing effect of the deodorant compositions of single phenol to methyl mercaptan

Except using Comparative Examples 1 described various deodorant compositions to replace the deodorant compositions of embodiment 1 described 2mL, measure the deodorizing effect of deodorant compositions as described in the Comparative Examples 1 as identical mode as described in the embodiment 2, and calculate described deodorization rate.The results are shown in Table 2.

Table 2

Single phenol	1 hour	2 hours	3 hours	4 hours	1 day	5 days
							The p-coumaric acid	-8.3	-8.3	-8.3	-8.3	0.0	0.0
Ferulic acid	-8.3	-8.3	0.0	0.0	13.3	20.0

In p-coumaric acid and ferulic acid arbitrarily, show that described deodorization rate is low, extremely low to the production efficiency of the effective component of deodorization.

Embodiment 3, the preparation deodorant compositions

By being added, the 1mmol chlorogenic acid comprises 50mL 0.05MNa ₂CO ₃The agitator inside of solution (pH 11.2), and air can free-flow and the reaction liquid surface fully and under the condition that air contact 25 ℃ of integral body stirrings 3 hours down.Then, described reaction liquid lyophilizing, and make the Powdered deodorant compositions of the reddish brown Huang of 460mg.

Embodiment 4, to the deodorizing effect of methyl mercaptan

Replace the 2mL embodiment 1 described deodorant compositions except using, measure the deodorizing effect of deodorant compositions as described in the embodiment 3 as embodiment 2 identical modes by 20mg embodiment 3 described deodorant compositions being dissolved in the solution that makes in the 2mL water.As a result, described deodorization rate is 100%.

Comparative Examples 3, the preparation deodorant compositions

By being added, the 1mmol chlorogenic acid comprises 50mL 0.05M Na ₂CO ₃The agitator inside of solution (pH 11.2), wherein, dissolved oxygen is removed by ultrasonic Treatment under vacuum (vacuum pump) condition, and whole stirring under 25 ℃ in nitrogen atmosphere, leaves standstill after perhaps stirring under the same conditions.Described mixing time and time of repose are as shown in table 3.Described deodorant compositions is xanchromatic.

Comparative Examples 4 is to the deodorizing effect of methanol mercaptan

Except using the 2mL deodorant compositions described in the Comparative Examples 3 to replace the deodorant compositions of embodiment 1 described 2mL, measure the deodorizing effect of the deodorant compositions of Comparative Examples 3 as identical mode as described in the embodiment 2, and calculate described deodorization rate.It is described that the results are shown in Table 3.

Table 3

	1 hour	2 hours	3 hours	7 hours	24 hours
						The deodorant compositions of Comparative Examples 3	16.7	8.3	8.3	8.3	8.3

Under the condition that oxygen molecule is not provided, in the preparation deodorant compositions, show that the deodorization rate in any response time is extremely low, extremely low to the production efficiency of the effective component of deodorization.

Embodiment 5, the preparation deodorant compositions

By described various polyphenol of 1mmol table 4 and the adding of 1mmol glycine are comprised 50mL 0.05M Na ₂CO ₃The reactor inside of solution (pH11.2), and fully and under the condition that air contact 25 ℃ of stirrings or leave standstill after the stirring under the same conditions down, make deodorant compositions thus.Described mixing time and time of repose are as shown in table 5.

(the 3rd day result) is as shown in table 4 for the tone of gained deodorant compositions.

Table 4

Polyphenol	The tone of deodorizer (reaction liquid)
		Chlorogenic acid	Green
(+)-catechin	Red
		Protocatechuic acid	Red
Catechol	Rose pink
		Esculetin	Brown
Hydroquinone	Brown
		Quercetin	Red
Gallic acid	Bottle green
		Tannic acid	Reddish brown Huang

Embodiment 6, to the deodorizing effect of methyl mercaptan

Except using 2mL embodiment 5 described deodorant compositions to replace the 2mL embodiment 1 described deodorant compositions, measure the deodorizing effect of deodorant compositions as described in the embodiment 5 as embodiment 2 identical modes, and calculate described deodorization rate.The results are shown in Table 5.

Table 5

	1 hour	2 hours	3 hours	4 hours	1 day	3 days	7 days	15 days	19 days	27 days
											A	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0
B	66.7	100.0	100.0	100.0	100.0	100.0	100.0	73.3	66.7	53.3
											C	50.0	-	53.3	68.3	-	81.7	85.0	-	50.0	50.0
D	66.7	53.3	71.7	86.7	-	100.0	50.0	-	8.3	8.3
											E	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0
F	83.3	76.7	76.7	-	81.7	-	-	-	-	40.0
											G	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0
H	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0
											I	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0	100.0

In table, A represents catechol; B represents chlorogenic acid; C represents protocatechuic acid; D represents (+) catechin; E represents quercetin; F represents esculetin; G represents gallic acid; H represents that hydroquinone and I represent tannic acid.

Comparative Examples 5 uses single phenol to prepare deodorant compositions

Except using the described various single phenol of 1mmol table 6 to replace the described polyphenol of 1mmol tables 4, make deodorant compositions as identical mode as described in the embodiment 5.

(the 3rd day result) is as shown in table 6 for the tone of gained deodorant compositions.

Table 6

Single phenol	The tone of deodorant compositions (reaction liquid)
		The p-coumaric acid	Do not have
Ferulic acid	Faint yellow

Comparative Examples 6 is used the deodorizing effect of the deodorant compositions of single phenol to methyl mercaptan

Except using 2mL Comparative Examples 5 described various deodorant compositions to replace the 2mL embodiment 1 described deodorant compositions, measure the deodorizing effect of deodorant compositions as described in the Comparative Examples 5 as identical mode as described in the embodiment 2, and calculate the deodorization rate.The results are shown in Table 7.

Table 7

	1 hour	2 hours	3 hours	4 hours	1 day	3 days	7 days	15 days	19 days	27 days
											The p-coumaric acid	33.3	33.3	0.0	0.0	0.0	0.0	0.0	0.0	0.0	0.0
Ferulic acid	0.0	8.3	8.3	8.3	0.0	0.0	0.0	0.0	0.0	0.0

Embodiment 7, the preparation deodorant compositions

Except each seed amino acid of the chlorogenic acid that uses the described lmmol of table 8 and 1mmol, make deodorant compositions as identical mode as described in the embodiment 5.

The tone of gained deodorant compositions is as shown in table 8.And the pH of various reaction liquids has been described and to evaluation from the abnormal smells from the patient of various deodoring materials.

Table 8

Aminoacid	Tone	pH	The material stench
				Gly	Bottle green	9.3	Little smelly
Ala	Bottle green	9.4	Little smelly
				Val	Bottle green	9.6	Little smelly
Leu	The band blackish green	9.4	Little smelly
				Ile	Bottle green	9.4	Little smelly
Glu	Bottle green	9.0	Little smelly
				Gln	Bottle green	9.2	Little smelly
Asn	Bottle green	9.1	Little smelly
				Asp	Bottle green	8.7	Little smelly
Lys	Bottle green	9.7	The bean flavor
				Arg	Bottle green	9.8	Little smelly
His	Bottle green	9.3	No stink
				Ser	Blush	9.2	Almost there is not stink
Thr	Blush	9.2	Little smelly
				Met	Bottle green	9.2	Smelly
Cys-Cys	Bottle green	9.1	Little smelly
				Phe	Bottle green	9.3	Smelly
Tyr	Bottle green	-	Almost there is not stink
				Trp	Bottle green	-	Smelly
Pro	Bottle green	-	Smelly
				Glu-Na	Bottle green	-	Almost there is not stink
Asp-Na	Bottle green	-	Almost there is not stink

In table, described color, pH and abnormal smells from the patient have shown color, pH and the abnormal smells from the patient of reaction liquid after the reaction of each deodorant compositions of preparation begins 3 days.

Embodiment 8, to the deodorizing effect of methyl mercaptan

Except the various deodorant compositions that use embodiment 7 described 2mL, measure the deodorization rate of each deodorant compositions as described in the embodiment 7 as identical mode as described in the embodiment 2.The results are shown in Table 9.

Table 9

Aminoacid	10 minutes	30 minutes	1 hour	2 hours	3 hours	24 hours	7 days	132 days
									Gly	56.7	56.7	100.0	100.0	100.0	100.0	100.0	33.3
Ala	98.3	100.0	100.0	100.0	100.0	100.0	100.0	25.0
									Val	100.0	100.0	100.0	100.0	100.0	100.0	100.0	0
Leu	100.0	100.0	100.0	100.0	100.0	100.0	100.0	0
									Ile	98.3	100.0	100.0	100.0	100.0	100.0	100.0	0
Glu	97.5	98.3	100.0	100.0	100.0	100.0	100.0	50.0
									Gln	46.7	50.0	66.7	83.3	91.7	100.0	100.0	0
Asn	41.7	66.7	73.3	90.0	100.0	100.0	100.0	8.3
									Asp	16.7	16.7	36.7	65.0	68.3	68.3	75.0	25.0
Lys	100.0	100.0	100.0	100.0	100.0	100.0	100.0	50.0
									Arg	100.0	100.0	100.0	100.0	100.0	100.0	100.0	33.3
His	68.3	85.0	91.7	100.0	100.0	100.0	100.0	33.3
									Ser	65.7	81.7	91.7	100.0	100.0	100.0	100.0	8.3
Thr	65.0	81.7	91.7	100.0	100.0	100.0	100.0	0
									Met	45.0	78.3	91.7	91.7	100.0	100.0	100.0	28.3
Cys-Cys	95.0	98.3	100.0	100.0	100.0	100.0	100.0	91.7
									Phe	75.0	85.0	100.0	100.0	100.0	100.0	100.0	36.7
Tyr	65.0	56.7	78.3	86.7	96.7	100.0	100.0	53.3
									Trp	53.3	36.7	75.0	91.7	100.0	100.0	100.0	33.3
Pro	100.0	100.0	100.0	100.0	100.0	100.0	100.0	0
									Glu-Na	-	-	83.3	83.3	90.0	91.7	66.7	0
Asp-Na	-	-	98.3	98.3	100.0	100.0	66.7	0

Embodiment 9, the preparation deodorant compositions

The glycine of 1mmol chlorogenic acid and 1mmol is added in the reactor, and toward wherein adding 50mL 0.05M Na ₂CO ₃Solution (pH 11.2).Stirred 3 hours down at 25 ℃ under the condition that described whole material is abundant at energy with air contacts.Then, described product lyophilizing makes the blackish green Powdered deodorant compositions of 535mg.

Embodiment 10, to the deodorizing effect of methanol mercaptan

, and add beyond the 2mL distilled water deodorization rate as described in measuring as identical mode as described in the embodiment 2 except the Powdered deodorant compositions that uses embodiment 9 described 28mg replaces embodiment 1 described deodorant compositions.

As a result, described deodorization rate is 100%.

Embodiment 11, the preparation deodorant compositions

With 50mL 0.05M Na ₂CO ₃Solution (pH 11.2) adds in the reactor, and toward wherein adding the described various plant extracts of table 10 (comprising polyphenol and amino acid whose extract), making described polyphenol content is 1mmol then.Stir down at 25 ℃ under the condition that described whole material is abundant at energy with air contacts, perhaps under identical condition, stir, leave standstill then, make deodorant compositions thus.Described mixing time and time of repose are as described in Table 10.

Embodiment 12, to the deodorizing effect of methyl mercaptan

Use embodiment 11 described various deodorant compositions, deodorization rate as described in measuring as identical mode as described in the embodiment 2.The results are shown in Table 10.

Table 10

	1 hour	3 hours	24 hours	4 days	36 days
						Coffee is given birth to the bean extract	100.0	100.0	100.0	100.0	100.0
Green tea extract	100.0	100.0	100.0	100.0	100.0
						Fructus Mali pumilae extract	100.0	100.0	100.0	100.0	100.0
Herba Rosmarini Officinalis extract	100.0	100.0	100.0	100.0	100.0
						The Mentha arvensis L. syn.M.haplocalyxBrig extract	100.0	100.0	100.0	100.0	100.0
The Mentha viridis L extract	100.0	100.0	100.0	100.0	100.0
						Pericarpium Vitis viniferae extract	100.0	100.0	100.0	100.0	100.0
Semen Vitis viniferae extract	100.0	100.0	100.0	100.0	100.0

Coffee is given birth to the bean extract: polyphenol content 45 weight %

Green tea extract: polyphenol content 30 weight %

Fructus Mali pumilae extract: polyphenol content 60 weight %

Herba Rosmarini Officinalis extract: polyphenol content 50 weight %

Mentha arvensis L. syn.M.haplocalyxBrig extract: polyphenol content 32 weight %

Mentha viridis L extract: polyphenol content 33 weight %

Pericarpium Vitis viniferae extract: polyphenol content 90 weight %

Semen Vitis viniferae extract: polyphenol content 40 weight %

Give birth in the situation of bean extract, Fructus Mali pumilae extract, Herba Rosmarini Officinalis extract, Mentha arvensis L. syn.M.haplocalyxBrig extract and Mentha viridis L extract at coffee, calculate polyphenol content with chlorogenic acid.Under the situation of green tea extract, calculate described content with catechol.In the situation of Pericarpium Vitis viniferae extract and Semen Vitis viniferae extract, described content is as described in the identification of the manufacturer.

Preparation coffee is given birth to the bean extract

Under the condition that adds 10 weight equivalent water, under 90-95 ℃, stir and extracted the living bean of coffee in 2 hours.After filtering, described filtrate is desolvated to concentrate by removing under reduced pressure, makes coffee and gives birth to bean extract (productive rate of giving birth to bean in coffee is about 16.8%).

The preparation green tea extract

Under the condition that adds 20 weight equivalent water, under 90-95 ℃, stir and extracted green tea in 2 hours.After filtering, described filtrate is desolvated to concentrate by removing under reduced pressure, makes green tea extract (productive rate in green tea is about 25.7%).

Fructus Mali pumilae extract: make as Nikka Whisky K.K.

The preparation Herba Rosmarini Officinalis extract

Under the 30% aquiferous ethanol condition that adds 20 weight equivalents, under 45-50 ℃, stir and extracted dried Herba Rosmarini Officinalis in 2 hours.After filtering, described filtrate is desolvated to concentrate by removing under reduced pressure, makes Herba Rosmarini Officinalis extract (productive rate of counting with the Herba Rosmarini Officinalis of doing is about 15.4%).

Preparation Mentha arvensis L. syn.M.haplocalyxBrig extract

Under the condition that adds 10 weight equivalent water, under 90-95 ℃, stir to extract in 2 hours and handle the peppercorn Herba Menthae of having removed oil ingredient by distillation.After filtering, described filtrate is desolvated to concentrate by removing under reduced pressure, makes Mentha arvensis L. syn.M.haplocalyxBrig extract (productive rate in dried Mentha arvensis L. syn.M.haplocalyxBrig is about 17.8%).

Preparation Mentha viridis L extract

Under the condition that adds 10 weight equivalent water, under 90-95 ℃, stir to extract in 2 hours and handle the dried Mentha viridis L of having removed oil ingredient by distillation.After filtering, described filtrate is desolvated to concentrate by removing under reduced pressure, makes Mentha viridis L extract (productive rate in dried Mentha viridis L is about 15.8%).

Pericarpium Vitis viniferae extract: make by Polyphenolics

Semen Vitis viniferae extract: make by Polyphenolics

Embodiment 13

By grinder the Fructus Mali pumilae peel of doing (Fuji's kind) is pulverized, make apple powder.The sodium carbonate liquor that adds 800mL 50mM in the 80g powder, whole material fully with condition that air contacts under in 40 ℃ of following vigorous stirring 3 hours (reaction solution pH is 7.6).After filtering described reaction liquid, described filtrate is dry under reduced pressure, makes 81.6g deodorant compositions powder (counting 102% with the peel of doing).

Embodiment 14

The sodium carbonate liquor that adds 1600mL 50mM in the green tea of doing toward 80g, whole material fully with condition that air contacts under in 30 ℃ of following vigorous stirring 1 hour (reaction solution pH is 8.7).After filtering described reaction liquid, described filtrate lyophilising under reduced pressure makes 51.8g deodorant compositions powder (counting 64% with the peel of doing).

Embodiment 15

By grinder 100g being handled the dry Folium Perillae leaf and the stem that remove the part of deoiling by distillation pulverizes.Toward the sodium carbonate liquor (pH 11.2) that wherein adds the 50mM of 20 weight equivalents, whole material fully with condition that air contacts under in 25 ℃ of following vigorous stirring 3 hours (reaction solution pH is 8.5).After filtering described reaction liquid, described filtrate lyophilizing makes 25.8g deodorant compositions powder (counting 25.8% with the Folium Perillae of doing).

Embodiment 16

Give birth to the sodium carbonate liquor (pH 11.2) that adds the 50mM of 10 weight equivalents in the bean toward 100g coffee, whole material fully with condition that air contacts under in 15 ℃ of following vigorous stirring 3 hours (reaction solution pH is 7.8).After filtering described reaction liquid, described filtrate lyophilizing makes 17.3g deodorant compositions powder (give birth to bean with coffee and count 17.3%).

Embodiment 17

The sodium carbonate liquor (pH 11.2) that adds the 50mM of 10 weight equivalents in the Pericarpium Vitis viniferae of doing toward 100g, whole material fully with condition that air contacts under in 15 ℃ of following vigorous stirring 3 hours (reaction solution pH is 7.3).After filtering described reaction liquid, described filtrate lyophilizing makes 15.4g deodorant compositions powder (counting 15.4% with the Pericarpium Vitis viniferae of doing).

Embodiment 18

Except using the solution that the various deodorant compositions powder dissolutions of gained among the 40mg embodiment 13-17 are obtained in 2mL water to replace the embodiment 1 described deodorant compositions, deodorization rate as described in measuring as identical mode as described in the embodiment 2.It is described that the results are shown in Table 11.

Table 11

Deodorant compositions	The solution tone	The deodorization rate
			Embodiment 13 (from Pericarpium Mali pumilae)	Red	100％
Embodiment 14 (from green tea)	Red	100％
			Embodiment 15 (from Folium Perillae)	Red	100％
Embodiment 16 (giving birth to bean) from coffee	Green	100％
			Embodiment 17 (from Pericarpium Vitis viniferae)	Red	100％

Embodiment 19 and Comparative Examples 7

In reactor, mix the gallic acid of 1mmol, sodium glutamate and the concentration Na as described in Table 12 of 1mmol ₂CO ₃The NaOH aqueous solution that aqueous solution or concentration are as described in Table 13.Whole material can and condition that air fully contacts under at room temperature stir, perhaps stirring is under the same conditions left standstill then, makes deodorant compositions thus.Described mixing time and time of repose are shown in table 12 and 13.

Use above each deodorant compositions, measure the deodorization rate as identical mode as described in the embodiment 2.In formula shown in the corresponding embodiment 2 B in the same old way, add the alkaline solution of concentration shown in table 12 and 13, replace described deodorant compositions.

The result is shown in table 12 and 13.

Table 12

Na 2CO 3Aqueous solution	3 hours	1 day	3 days	5 days	20 days	28 days	The pH of reaction liquid in the course of reaction	The pH of alkaline solution before the reaction
									1M	100.0	100.0	100.0	100.0	100.0	100.0	10.7	11.6
500mM	100.0	100.0	100.0	100.0	100.0	100.0	10.6	11.5
									100mM	100.0	100.0	100.0	100.0	100.0	100.0	9.9	11.4
50mM	100.0	100.0	100.0	100.0	100.0	100.0	9.0	11.4
									25mM	100.0	100.0	100.0	100.0	85.0	56.7	8.0	11.4
10mM	0	0	25.0	25.0	36.7	16.7	6.0	11.1
									1mM	0	0	0	0	0	0	4-5	10.9

Table 13

The NaOH aqueous solution	3 hours	1 day	3 days	5 days	14 days	21 days	The pH of reaction liquid in the course of reaction	The pH of alkaline solution before the reaction
									1M	100.0	100.0	100.0	100.0	100.0	100.0	12.9	13.5
500mM	100.0	100.0	100.0	100.0	100.0	100.0	12.8	13.4
									100mM	100.0	100.0	100.0	100.0	100.0	100.0	10.1	12.8
50mM	100.0	100.0	100.0	100.0	100.0	100.0	8.0	12.5
									25mM	100.0	100.0	100.0	100.0	50.0	50.0	7.0	12.2
10mM	0	0	0	0	0	0	4.6	11.8
									1mM	0	0	0	0	0	0	4.6	10.7

After beginning 3 days, described reaction (stirring) measures the pH of described reaction liquid.

In any alkaline solution, the deodorant compositions that makes under reaction liquid pH6.5 or the above condition in course of reaction presents fabulous deodorizing effect, but, in course of reaction reaction liquid pH be 6.0 or below the deodorization rate of the deodorant compositions that makes low.

Embodiment 20 and Comparative Examples 8, the preparation deodorant compositions

In the reactor that wherein has the following basic solvent of 50mL, alkaline buffer solvent or neutral buffered solvent, add 1mmol chlorogenic acid and 1mmol glycine, whole material stirs down at 25 ℃, perhaps after 25 ℃ are stirred down, leave standstill, make deodorant compositions thus.Described mixing time and time of repose are as shown in table 14.

(A) 0.05M NaHCO ₃Solution (pH8.3)

(B) 0.05M NaHCO ₃/ Na ₂CO ₃Solution (pH9.1)

(C) 0.05M NaHCO ₃/ Na ₂CO ₃Solution (pH10.0)

(D) 0.05M Na ₂CO ₃Solution (pH11.2)

(E) 0.05M Na ₂HPO ₄/ Na ₂H ₂PO ₄Solution (pH6.5)

Embodiment 21, to the deodorizing effect of methyl mercaptan

Use embodiment 20 described various deodorant compositions, measure the deodorizing effect of embodiment 20 as identical mode as described in the embodiment 2.In for embodiment 2 described formula B in the same old way, add the solvent of (A)-(E), rather than deodorant compositions.

The result is as shown in table 14.

Table 14

	3 hours	4 hours	6 hours	8 hours	24 hours	The pH of reaction liquid in the course of reaction	The pH of alkaline solution before the reaction
								(A)	16.7	25.0	75.0	83.3	83.3	6.5	8.3
(B)	33.3	71.7	100.0	100.0	100.0	9.0	9.1
								(C)	50.0	81.7	100.0	100.0	100.0	10.0	10.0
(D)	91.4	100.0	100.0	100.0	100.0	9.3	11.2
								(E)	0.0	0.0	0.0	0.0	0.0	6.5	6.5

In table, (A), (B), (C), (D) and (E) expression use 0.05M NaHCO respectively ₃Solution (pH8.3), 0.05MNaHCO ₃/ Na ₂CO ₃Solution (pH9.1), 0.05M NaHCO ₃/ Na ₂CO ₃Solution (pH10.0), 0.05M Na ₂CO ₃The deodorant compositions that solution (pH11.2) and 0.05M Na2HPO4/Na2H2PO4 solution (pH6.5) make.

Under the situation that adds chlorogenic acid and glycine and reaction in the buffer solution of described pH6.5, the pH of reaction liquid remains on 6.5 in the course of reaction, and does not observe deodorizing effect in any response time.

On the other hand, when the pH of reaction liquid in the course of reaction is 6.5, observe deodorizing effect, before reaction solvent be alkalescence and pH because and chlorogenic acid and glycine reactant become under 6.5 the situation and form deodorant compositions.

From embodiment 19,20 and 21, the pH of basic solvent before the kind of basic solvent and concentration and the reaction is not depended in the formation that shows deodorant compositions, but by use pH7.0 or above basic solvent make the pH of reaction liquid in the course of reaction be 6.5 or more than be important factor.

Embodiment 22, the influence of oxygen supply amount

The gallic acid of 1mmol and the sodium glutamate adding of 1mmol are comprised 100mL 0.05M sodium carbonate liquor (pH11.2) reactor inside, then, stir whole material at each temperature providing continuously under the conditions of air in that table 15 is described, and measure dissolved oxygen concentration in time in the reaction liquid.And, under the situation of the 100mL 0.05M sodium carbonate liquor (pH11.2) that does not add gallic acid and sodium glutamate, measure dissolved oxygen concentration in time in the reaction liquid in the same manner.The result is as shown in Table 15.

(TOA Electric K.K. makes to use dissolved oxygen measuring device, oxygen electrode: OE-2102) under 23.4 ℃ and 42.4 ℃, and the Ponal Kit (being made by Dojindo laboraries) that is used for measuring dissolved oxygen measures the concentration of dissolved oxygen in the reaction liquid at 60 ℃ and 80 ℃ and boiling water.

As for the situation after stirring 3 hours at each temperature, shown in embodiment 2, carry out the deodorant activities test.The result is shown in table 16.

Table 15

Reaction temperature	Independent solvent			(+) gallic acid+Glu-Na
							(mixing time)			(mixing time)
	0 minute	10 minutes	3 hours	0 minute	10 minutes	3 hours
							23.4℃	3.7	7.8	7.8	0	0	0
42.2℃	3.2	5.2	5.2	0	0	0
							60.0℃	2.5	2.0	2.0	0	0	0
80.0℃	0.5	1.5	1.5	0	0	0
							Boiling temperature	0.5	0.5	0.5	0	0	0

The amount of dissolved oxygen (Mg/L) in the reaction liquid

Under the situation of independent solvent, under the measurement temperature except boiling temperature, the amount of dissolved oxygen reaches balance stirring in 10 minutes, but along with the temperature described amount reduction that raises.Under the situation that adds gallic acid and sodium glutamate and reaction, the amount of gallic acid at any time is 0 in the reaction liquid.From these results, show when gallic acid and sodium glutamate are dissolved in the basic solvent to have consumed dissolved oxygen rapidly, and afterwards continuous consumption it.

Table 16

Reaction temperature	Stir 3 hours deodorization rate (%)
		23.4℃	100
42.4℃	100
		60.0℃	100
80.0℃	100
		Boiling temperature	25

As for the deodorant activities test of stirring 3 hours under the condition that adds gallic acid and sodium glutamate, the deodorization rate under other reaction temperature except that boiling temperature is 100%, but in the reaction of carrying out under boiling temperature, described deodorization rate is 25%.

From above result as seen, show that the production efficiency of deodorization active component obviously reduces when being reflected under the amount of the dissolved oxygen in the situation of carrying out under the boiling temperature (0.5mg/L).

Embodiment 23, measure molecular weight

The tannic acid of 1mmol and the sodium glutamate adding of 1mmo are comprised in the agitator of 50mL 0.05M sodium carbonate liquor (PH11.2).Stirred 3 hours down at 25 ℃ under the condition that whole material is abundant at energy with air contacts, make deodorant compositions.

1mmol gallic acid and the adding of 1mmol glycine are comprised in the agitator of 50mL 0.05M sodium carbonate liquor (PH11.2).Stirred 3 hours down at 25 ℃ under the condition that whole material is abundant at energy with air contacts, make deodorant compositions.

Make each deodorant compositions of 2g gained carry out centrifugal membrane filtration (3000rpm) 1 hour.In centrifugal membrane filtration, use two types filter membrane, described filter membrane is that its isolated molecule amount is that 3000 filter membrane and isolated molecule amount are 10000 filter membrane.In the isolated molecule amount is 3000 filtration, molecular weight be 3000 or following material separate as filter liquor, and molecular weight separates as filtered residue greater than 3000 material.In the isolated molecule amount is 10000 filtration, molecular weight be 10000 or following material separate as filter liquor, molecular weight separates as filtered residue greater than 10000 material.

After centrifugal membrane filtration, as described in embodiment 2, filter liquor and filtered residue are carried out the deodorant activities test, measure described deodorization rate.In this relation, the liquid that filtered residue is dissolved in gained in the 2g water is called filtered residue liquid.

The result is shown in table 17.

The filter membrane that is used for isolated molecule amount 3000:

Centricon (registered trade mark) YM-3 (making isolated molecule amount 3000 by Millipore)

The filter membrane that is used for isolated molecule amount 10000:

Centricon (registered trade mark) YM-10 (making isolated molecule amount 10000 by Millipore)

Table 17

	The filtration of isolated molecule amount 3000	The filtration of isolated molecule amount 10000
			Tannic acid * Glu-Na filtered residue liquid filter liquor	100100	0 100
Gallic acid * Gly filtered residue liquid filter liquor	100100	0 100

Numeral in the table is meant deodorization rate (%).

In deodorant compositions and deodorant compositions, obtain identical result from gallic acid and glycine from tannic acid and sodium glutamate.That is, in the spin-on filter device of isolated molecule amount 3000, observe powerful deodorant activities in filter liquor and filtered residue liquid.But, in the spin-on filter device of isolated molecule amount 10000, in filter liquor, observe powerful deodorant activities, but in filtered residue liquid, do not observe deodorizing effect.Based on this result, the molecular weight that shows the active component in the deodorant compositions should be 10000 or below.

Embodiment 14, the reaction temperature and the response time of preparation deodorant compositions

1mmol gallic acid and the adding of 1mmol sodium glutamate are comprised in the agitator of 50mL 0.05M sodium carbonate liquor (PH11.2).Whole material can be fully and under the condition that air contact in the described at each temperature time described in stirring is shown of table 18.Take out 2 milliliters reaction liquid in time, according to the described deodorant activities of embodiment 2 described measurements.

The result is shown in table 18.

Mixing time hour	Reaction temperature
								5℃	25℃	40℃	50℃	60℃	70℃	80℃
	0	100	100	100	100	100	100								100
1								100	100	100	100	100	100	100
	2	100	100	100	100	100	100								100
3								100	100	100	100	100	100	100
	4	100	100	100	100	100	100								55
5								100	100	100	100	100	100	0
	6	100	100	100	100	100	100								0
7								100	100	100	100	100	55	0
	8	100	80	75	75	25	0								0
9								100	70	63	63	0＜	-	-
	24	70	＜10	＜0	＜0	＜0	-								-

Numeral in the table is meant the deodorization rate.And "-" is not meant and measures.

As for the relation between reaction (stirring) temperature and the deodorant activities, show that described deodorant activities reduces with the reaction temperature rising.Especially under 70 ℃ or above high temperature, when mixing time long time deodorant activities reduces.Therefore, the reaction temperature that the production efficiency of described deodorization active component is high is 60 ℃ at the most.Described reaction (stirring) time better is about 7 hours.And under 80 ℃ reaction temperature, the time was suitable for forming the deodorization active component at the most in 3 hours, and wherein, the deodorization rate remains on 100%.

Embodiment 25, the influence of metal ion

In reactor, mix 1mmol chlorogenic acid, the sodium glutamate of 1mmol, the Na of 50mL ₂CO ₃Various slaines shown in the table 19 of aqueous solution and 0.25mmol.At room temperature stir under the condition that described whole material is abundant at energy with air contacts, leave standstill after perhaps stirring under the same conditions, make deodorant compositions thus.Described mixing time and time of repose are shown in table 19.And " not adding " in the table is meant under the condition that does not add any slaine and prepares deodorant compositions.

Use above-mentioned deodorant compositions, measure the deodorization rate as same way as described in the embodiment 2.The result is shown in table 19.

Table 19

Each metal ion species	Deodorization rate (%) after 3 hours	Deodorization rate (%) after 48 days	pH	Tone
					Do not add	100.0	45.0	7.8	Blackish green → blackish green
CaCl 2	96.7	83.3	8.0	Green → blackish green
					MgCl 2	100.0	100.0	8.1	Blackish green → blackish green
CuCl 2	100.0	100.0	8.5	Blackish green → blackish green
					MnSO 4	100.0	100.0	8.7	Dark blue-green → dark blue-green
ZnCl 2	100.0	100.0	8.5	Blackish green → blackish green

PH shown in the table is 3 days observed results after reaction (stirring) beginning.

Described tone has shown 3 days and 48 days observed results after reaction (stirring) beginning.

Adding under the situation of metal ion, observing and the persistency of the deodorant activities that (do not add slaine) in the same old way.And, wherein add MgCl ₂, ZnCl ₂Or MnSO ₄Deodorant compositions also shown excellent effect to tone stability.

Embodiment 26, the influence of concentration of metal ions

In reactor, mix 1mmol chlorogenic acid, 1mmol sodium glutamate, 45mL Na ₂CO ₃The MgCl of various concentration shown in the table 20 of aqueous solution and 5mL ₂Aqueous solution.At room temperature stir under the condition that described whole material is abundant at energy with air contacts, leave standstill after perhaps stirring under the same conditions, make deodorant compositions thus.Described mixing time and time of repose are shown in table 20.And " not adding " in the table is meant and do not adding MgCl ₂Prepare deodorant compositions under the condition of aqueous solution.

Use above-mentioned deodorant compositions, measure the deodorization rate as same way as described in the embodiment 2.The result is shown in table 20

Table 20

MgCl 2The concentration of aqueous solution	3 hours	13 days	47 days	pH
					Do not add	100.0	83.3	46.7	7.9
50mM	80.0	100.0	100.0	7.4
					5mM	100.0	100.0	100.0	8.9
0.5mM	100.0	100.0	66.7	9.0
					0.05mM	100.0	100.0	55.0	9.0
0.005mM	100.0	100.0	63.0	9.1
					0.0005mM	100.0	100.0	63.0	9.1

Described pH measures after 3 days in reaction (stirring) beginning.

Even at the MgCl that adds 0.0005mM ₂Under the situation of aqueous solution, the deodorization rate after described 13 days and 47 days is higher than situation about not adding, and therefore, adds MgCL ₂Can improve the active persistent period.

Embodiment 27, to the concentration of various malodorous deodorizing effects and deodorant compositions

1mmol gallic acid and the adding of 1mmol sodium glutamate are comprised in the agitator of 50mL 0.05M sodium carbonate liquor (PH11.2).Stirred 3 hours down at 25 ℃ under the condition that whole material is abundant at energy with air contacts.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.Described powder dissolution makes deodorant compositions solution in water.

Preparation deodorant compositions concentration is the deodorant compositions solution of 10.00mg/mL, and the test deodorant compositions is to the deodorizing effect of methyl mercaptan, ammonia and isovaleric acid.

[to the deodorizing test of methyl mercaptan]

The identical as described in example 2 above mode of described test is carried out.

[to the deodorizing test of ammonia]

The 2mL deodorant compositions is added in the bottle of 50mL, and toward 2.8% the ammonia that wherein adds 5 microlitres.Cover described bottle with Parafilm then, stirred 10 minutes down at 25 ℃ afterwards.Afterwards, the upper gas of 50mL is measured the concentration that is retained in the malodor components in the gas by gas detecting tube (being made by Gastech Corporation) in the bottle, calculates the deodorization rate according to embodiment 2 described formula.

[to the deodorizing test of isovaleric acid]

The 2mL deodorant compositions is added in the bottle of 50mL, and toward the isovaleric acid that wherein adds 40 microlitres.Cover described bottle with Parafilm then, stirred 10 minutes down at 25 ℃ afterwards.Afterwards, the upper gas of 50mL is measured the concentration that is retained in the malodor components in the gas by gas detecting tube (being made by Gastech Corporation) in the bottle, calculates the deodorization rate according to embodiment 2 described formula.

The deodorization rate to methyl mercaptan, ammonia and isovaleric acid that found that is respectively 100%, 80% and 100%.

From this fact as seen, deodorant compositions of the present invention has fabulous deodorizing effect to methyl mercaptan, ammonia and isovaleric acid, and is the multi-purpose deodorant compositions that fabulous deodorizing effect can be provided the malodor components that is alkalescence.

Embodiment 28, to the concentration of the deodorizing effect and the deodorant compositions of methyl mercaptan

1mmol gallic acid and the adding of 1mmol sodium glutamate are comprised in the agitator of 50mL 0.05M sodium carbonate liquor (PH11.2).Stirred 3 hours down at 25 ℃ under the condition that whole material is abundant at energy with air contacts.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.Described powder dissolution makes concentration deodorant compositions solution shown in table 21 in water.

Carry out of the deodorizing effect test of the deodorant compositions solution of various concentration to methyl mercaptan.

[to the deodorizing test of methyl mercaptan]

Test same way as shown in embodiment 2 is carried out.

The result is shown in table 21.

Table 21 deodorization rate %

The concentration of deodorant compositions (mg/ml)	Malodor components
		Methyl mercaptan
	10.00		100
5.00		100
	2.50		100
1.25		100
	0.63		100
0.31		100
	0.15		63

As for deodorizing effect,, therefore, present fabulous deodorizing effect even its deodorization rate also is 100% when the deodorant compositions low concentration is 0.31mg/ml to methyl mercaptan.And, even when concentration is 0.15mg/ml, also can observe deodorizing effect.

Embodiment 29

Concentration to the deodorizing effect and the deodorant compositions of isovaleric acid

1mmol gallic acid and the adding of 1mmol sodium glutamate are comprised in the agitator of 50mL 0.05M sodium carbonate liquor (PH11.2).Stirred 3 hours down at 25 ℃ under the condition that whole material is abundant at energy with air contacts.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.Described powder dissolution makes concentration deodorant compositions solution shown in table 22 in water.

Carry out of the deodorizing effect test of the deodorant compositions solution of various concentration to methyl mercaptan.

[to the deodorizing test of isovaleric acid]

The 2mL deodorant compositions is added in the bottle of 50mL, and toward the isovaleric acid that wherein adds 40 microlitres.Cover described bottle with Parafilm then, stirred 10 minutes down at 25 ℃ afterwards.Afterwards, the upper gas of 50mL is measured the concentration that is retained in the malodor components in the gas by gas detecting tube (being made by Dastech Corporation) in the bottle, calculates the deodorization rate according to embodiment 2 described formula.

The result is shown in table 22.

Table 22 deodorization rate %

The concentration of deodorant compositions (mg/ml)	Malodor components
		Isovaleric acid
	10.00		100
5.00		100
	2.50		100
1.25		90

Embodiment 30, urinate smelly inhibition effect

The sodium carbonate liquor that mixes 20mmol gallic acid, 20mmol sodium glutamate and 1000mL 50M, whole material can at room temperature stir 3 hours under the condition of abundant ingress of air.Afterwards, described reaction liquid drying, and lyophilizing concentrates.Described dried product grinds, and makes 9.6g deodorant compositions powder.

In the dixie cup of diaper (Lifely Urine Pad Sipper: make) with about 1/2 (10g), and add the above-mentioned deodorant compositions of 0.5g thereon as for 500mL by Unicharm Corporation.Then, add the 100ml Urina Hominis, cover described cup with the double-decker of Saran-Wrap (trade name) and aluminium foil.Leaving standstill under 35 ℃ has after 3 hours, 6 hours or 24 hours four members to estimate malodorous sensation.Carry out the evaluation of following project by scoring, evaluation result is represented with the meansigma methods of four member's scorings.

The situation that does not add the deodorant compositions powder is as blank sample.The result as illustrated in fig. 1 and 2.

[assessment item and evaluation score]

Urinate smelly deodorizing effect

1: do not feel that almost urine is smelly

2: feel that some urine are smelly a little

3: feel little by little urinate smelly

4: feel that a little urine is smelly

5: feel that a large amount of urine is smelly

6: feel that intensive urine is smelly

Comprehensive stench intensity (to wholely comprise that urine is smelly, the stench intensity of the system of the abnormal smells from the patient of diaper etc. itself)

0: do not have the stench sensation

1: feel stink as possible a little

2: leicht fallen D/A just can be felt stink

3: obviously feel stink

4: feel stink strongly

5: feel stink insufferably strongly.

The smelly inhibition effect of embodiment 31 urine

The sodium carbonate liquor that mixes 20mmol gallic acid and 1000mL 50M, whole material can at room temperature stir 3 hours under the condition of abundant ingress of air.Afterwards, described reaction liquid drying, and lyophilizing concentrates.Described dried product grinds, and makes 5.8g deodorant compositions powder.

Be applied to method and feeling evaluation on the diaper as identical mode as described in the embodiment 30.Described result as illustrated in fig. 1 and 2.

From Fig. 1 and Fig. 2 as seen, the diaper that has added deodorant compositions of the present invention shows, leave standstill the mark after 24 hours and leave standstill 3 hours marks afterwards identical, therefore, urinate smelly generation and be subjected to obvious suppression, and the weak strength of stink in the whole system makes to have reached intensive deodorizing effect.

Embodiment 32 collutorys

The reactor inside that 1mmol gallic acid and 1mmol sodium glutamate is added the sodium carbonate liquor (pH11.2) of 50mL 0.05M.Whole material can and condition that air contact under 25 ℃ times stirrings 3 hours.Then, described reaction liquid lyophilizing, and leave standstill acquisition deodorant compositions powder.Mix the component of following prescription, make collutory in normal way.

The composition of table 23. collutory

Form	Weight %
		Ethanol	10.00
Polyoxyethylene hydrogenated Oleum Ricini	2.00
		Saccharin sodium	0.02
Glycerol	10.00
		Sodium benzoate	0.05
Deodorant compositions of the present invention	2.00
		The water of purification	Surplus
Amount to	100.0

[deodorizing test]

Water by 4g Bulbus Allii and 1L prepares Bulbus Allii extract.10 milliliters of gained Bulbus Allii extract solution are injected the bottle of 50mL, and further add the above-mentioned collutory of 1mL, mix then.Then, described whole material vibrated 3 minutes down at 34 ℃.According to following evaluation criterion the gained mixture is carried out feeling evaluation by 5 members.Described result is shown as five given fractional meansigma methodss of member.The result is shown in table 24.

[standard score of evaluation]

1 point) do not feel garlic smell

2 points) feel garlic smell a little

3 points) feel some garlic smells

4 points) obviously feel garlic smell a little

5 points) feel garlic smell strongly

6 points) feel garlic smell very consumingly

Table 24

	The average mark of estimating
		The collutory that comprises product of the present invention	1.0
To in the same old way	6.0

In table, described to shown the result who does not add the prepared collutory of product of the present invention in the same old way.

Embodiment 33 toothpaste

The reactor inside that 1mmol tannic acid and 1mmol glycine is added the sodium carbonate liquor (pH11.2) of 50mL 0.05M.Whole material can and condition that air contact under 25 ℃ times stirrings 3 hours.Then, described reaction liquid is concentrated into drying under reduced pressure, makes the deodorant compositions powder.Mix the component of following prescription, and make toothpaste in normal way.

The composition of table 25 toothpaste

Component	Weight %
		Dicalcium phosphate	10.00
Sodium lauryl sulfate	2.00
		Sodium carboxymethyl cellulose	0.50
Saccharin sodium	0.02
		Sodium benzoate	10.00
Deodorant compositions of the present invention	0.10
		Glycerol	Surplus
Amount to	100.00

[deodorizing test]

In toothpaste, to use the effect of eliminating bad implication under the described deodorant compositions situation in order estimating, to adopt following method.

Water is fine rinse the mouth after, the test experimenter remained on the methyl mercaptan sodium solution of 10mL 50ppm in the mouth 1 minute, described solution then spues.Collect implication with the plastic bag of 5L immediately.Afterwards, the toothpaste cleaning teeth that makes more than the usefulness is 2 minutes.Collect implication with the plastic bag of 5L immediately.

Carry out feeling evaluation by four members according to the implication of following evaluation criterion after to cleaning of teeth in the plastic bag, the implication in this and the plastic bag before the cleaning of teeth relatively.The result is presented in the table 26, is four members' average mark.

[evaluation criterion mark]

1 point) do not feel methyl mercaptan

2 points) feel methyl mercaptan a little

3 points) feel some methyl mercaptans

4 points) obviously feel methyl mercaptan a little

5 points) feel methyl mercaptan strongly

6 points) feel methyl mercaptan very consumingly

Table 26

	The meansigma methods of evaluation score
		The toothpaste that comprises product of the present invention	1.0
To (1) in the same old way	6.0
		To (2) in the same old way	4.5

In table, the situation of implication when (1) has shown that the experimenter does not have cleaning teeth has in the same old way shown the situation of using the toothpaste that does not add product of the present invention to (2) in the same old way.

Embodiment 34 tablets

The sodium carbonate liquor (pH11.2) of 50mL 0.05M is added in the reactor, and, make the polyphenol content with regard to chlorogenic acid become 1mmol toward wherein adding the Mentha arvensis L. syn.M.haplocalyxBrig extract.Whole material fully and under the condition that air contact 25 ℃ times stirrings 3 hours.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.Mix the component of following prescription, make tablet in normal way.

The composition of table 27 tablet

Component	Weight %
		Starch	97.5
Sucrose fatty acid ester	0.5
		Deodorant compositions of the present invention	2.0
Amount to	100.00

[deodorizing test]

In tablet, to use the effect of eliminating bad implication under the described deodorant compositions situation in order estimating, to adopt following method.

Water is fine rinse the mouth after, the test experimenter remained on the methyl mercaptan sodium solution of 10mL 50ppm in the mouth 1 minute, described solution then spues.Collect implication with the plastic bag of 5L immediately.Afterwards, they chewed the above tablet that makes 10 minutes.Collect implication with the plastic bag of 5L immediately.

Carry out feeling evaluation by four members according to the implication of following evaluation criterion after to chewable tablet in the plastic bag, the implication in this and the plastic bag before the chewable tablet relatively.The result is presented in the table 28, is four members' average mark.

The composition of table 28 tablet

	The meansigma methods of evaluation score
		The tablet that comprises product of the present invention	1.3
To (1) in the same old way	6.0
		To (2) in the same old way	4.8

In table, the situation of implication when (1) has shown that the experimenter does not have chewable tablet has in the same old way shown the situation of using the tablet that does not add product of the present invention to (2) in the same old way.

Embodiment 35 chewing gum

The sodium carbonate liquor (pH11.2) of 50mL 0.05M is added in the reactor, and, make the polyphenol content with regard to catechin become 1mmol toward wherein adding Pericarpium Vitis viniferae extract.Whole material fully and under the condition that air contact 25 ℃ times stirrings 3 hours.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.Mix the component of following prescription, make tablet in normal way.

The composition of table 27 chewing gum

Component	Weight %
		Gel matrix	21.0
Icing Sugar	63.9
		Corn starch	12.5
Acidulant	0.6
		Deodorant compositions of the present invention	2.0
Amount to	100.00

[deodorizing test]

In chewing gum, to use the effect of eliminating implication under the described deodorant compositions situation in order estimating, to adopt following method.

Water is fine rinse the mouth after, the test experimenter remained on the methyl mercaptan sodium solution of 10mL 50ppm in the mouth 1 minute, described solution then spues.Collect implication with the plastic bag of 5L immediately.

Afterwards, their chewing gum of making more than the machonnement is 10 minutes.Collect implication with the plastic bag of 5L immediately.

By four members according to the toothpaste situation in the identical evaluation criterion implication after to machonnement chewing gum in the plastic bag carry out feeling evaluation, chew in this and the plastic bag before the chewing gum implication relatively.The result is presented in the table 30, is four members' average mark.

Table 30

	The meansigma methods of evaluation score
		Product of the present invention	1.3
To (1) in the same old way	6.0
		To (2) in the same old way	4.3

In table, the situation of implication when (1) has shown that the experimenter does not chew chewing gum has in the same old way shown the situation of using the chewing gum that does not add product of the present invention to (2) in the same old way.

Embodiment 36 Antiperspirant

The reactor inside that 1mmol chlorogenic acid and 1mmol sodium glutamate is added the sodium carbonate liquor (pH11.2) of 50mL 0.05M.Whole material can and condition that air contact under 25 ℃ times stirrings 3 hours.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.The component of the following prescription of heating specified amount makes the homogenizing high viscosity solution.Then, in mould, cooling makes the Antiperspirant rod that comprises described deodorant compositions with described solution casting.

The composition of table 31 Antiperspirant rod

Form	Weight %
		The PEG-7 coconut triglyceride	2.0
Hydrogenated oil and fat	5.0
		Myristyl myristate	15.0
The ring-type methylsiloxane	33.0
		Stearyl alcohol	20.0
Different n-nonanoic acid stearyl	3.0

Aluminium chlorohydrate	20.0
		Deodorant compositions of the present invention	2.0
Amount to	100.0

[deodorizing test]

Add the section of the above-mentioned Antiperspirant rod of 2g in the 0.25% butanoic acid aqueous solution of 5mL, whole material at room temperature mixes.After 10 minutes, described mixture carries out feeling evaluation according to following evaluation criterion to described mixture by five specialist crews.The result is shown as the mark meansigma methods of five members in the table 32.

For relatively, use the Antiperspirant rod that does not contain deodorant compositions, identical as mentioned above mode is carried out feeling evaluation.

[evaluation criterion mark]

1 point) do not feel the butanoic acid abnormal smells from the patient

2 points) feel the butanoic acid abnormal smells from the patient a little

3 points) feel some butanoic acid abnormal smells from the patients

4 points) obviously feel some butanoic acid abnormal smells from the patients a little

5 points) feel the butanoic acid abnormal smells from the patient strongly

6 points) feel the butanoic acid abnormal smells from the patient very consumingly

Table 32

	Grading mark meansigma methods
		The Antiperspirant that comprises product of the present invention	1.6
To in the same old way	6.0

In table, described to shown the situation that does not contain the Antiperspirant of product of the present invention in the same old way.

Embodiment 37 Powdered cleaning agent

The reactor inside that the 1mmol gallic acid is added the sodium carbonate liquor (pH11.2) that comprises 50mL 0.05M.Whole material can and condition that air contact under 25 ℃ times stirrings 3 hours.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.Mix the composition of following prescription, make Powdered cleaning agent in normal way.

The composition of the Powdered cleaning agent of table 33

Form	Weight %
		Sodium lauryl sulfate, stearyl sodium sulfate	15.0
Sodium carbonate	15.0
		Sodium metasilicate	13.0
Sodium citrate	15.0
		Carboxymethyl cellulose	2.0
Sodium sulfate	38.0
		Deodorant compositions of the present invention	2.0
Amount to	100.0

[deodorizing test]

Be immersed in the water that comprises Powdered cleaning agent (0.5 weight %) with socks of wearing a day, described cleaning agent comprises the above deodorant compositions that makes, and it at room temperature washed 5 minutes, and cleans.Remaining socks are immersed in the water that comprises Powdered cleaning agent (0.5 weight %), do not add deodorant compositions of the present invention in the described cleaning agent, it at room temperature washs the identical time (5 minutes), and cleans (in the same old way).According to following evaluation criterion described socks are carried out feeling evaluation by five members.The result is shown as the mark meansigma methods of five members in the table 34.

[evaluation criterion mark]

1 point) do not feel the stink that typically suffocates

2 points) feel the stink that typically suffocates a little

3 points) feel some stinks that typically suffocate

4 points) obviously feel some stinks that typically suffocate a little

5 points) feel the stink that typically suffocates strongly

6 points) feel the stink that typically suffocates very consumingly

Table 34

	The evaluation score meansigma methods
		Comprise the Powdered cleaning agent of product of the present invention	1.2
To in the same old way	4.2

Embodiment 38 shampoos

The reactor inside that 1mmol gallic acid and 1mmol sodium glutamate is added the sodium carbonate liquor (pH11.2) that comprises 50mL 0.05M.Whole material can and condition that air contact under 25 ℃ times stirrings 3 hours.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.Mix the composition of following prescription, make shampoo in normal way.

The composition of table 35 shampoo

Component	Weight %
		Sodium lauryl sulfate	40.00
Coco group imidazolinium betaine sodium (cocoamphoacetate)	10.00
		The coconut monoethanolamide diethanolamine	2.00
Butanediol	2.00
		Citric acid	0.35
Sodium chloride	0.10
		Methyl parahydroxybenzoate	0.20
Propyl p-hydroxybenzoate	0.10
		EDTA four sodium	0.10
Green fragrance of a flower material	0.50
		Deodorant compositions of the present invention	2.00
Pure water	Surplus
		Amount to	100.00

[deodorizer test]

In order to estimate the effect of using the shampoo that comprises deodorant compositions to eliminate the abnormal smells from the patient of agent for permanent hair waving, adopt following method.

One thread test is immersed in 50mL agent for permanent hair waving first solution (pH of 6% thioglycolic acid aqueous solution being transferred to 9.3 with ammonia) 30 minutes with wig (1.8g).Wipe first solution that adheres to paper after,, be immersed in agent for permanent hair waving second solution (5% Potassium bromate. aqueous solution) of 50mL 20 minutes then with 100mL water washing wig.Wipe second solution that adheres to paper after, wig is immersed in the water (1 weight %) that 1000mL comprises the above shampoo that makes 5 minutes.After wiping the attached water that comprises shampoo with paper, described wig is with the water washing of 100mL, and wipes attached photo tint with paper.Described wig carries out feeling evaluation by four experts according to following evaluation criterion.The result is shown as the mark meansigma methods of four members in the table 36.

[evaluation criterion]

1 point) do not feel the abnormal smells from the patient of agent for permanent hair waving

2 points) feel the abnormal smells from the patient of agent for permanent hair waving a little

3 points) feel the abnormal smells from the patient of some agent for permanent hair waving

4 points) obviously feel the abnormal smells from the patient of some agent for permanent hair waving a little

5 points) feel the abnormal smells from the patient of agent for permanent hair waving strongly

6 points) feel the abnormal smells from the patient of agent for permanent hair waving very consumingly

Table 36

	The evaluation score meansigma methods
		Comprise the shampoo of product of the present invention	1.5
To in the same old way	5.3

In table, described to shown the situation that does not add the shampoo of product of the present invention in the same old way.

The deodorizing effect of 39 pairs of human excrements of embodiment and urine

The reactor inside that the 1mmol chlorogenic acid is added the sodium carbonate liquor (pH11.2) that comprises 50mL 0.05M.Whole material can and condition that air contact under 25 ℃ times stirrings 3 hours.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.

[deodorizing effect]

The urine and the above-mentioned deodorant compositions of 20mg of 10mL adult male are added in the 100mL bottle, use Parafilm (making) to cover described bottle then, vibrated 10 minutes down at 25 ℃ afterwards by American National Can.And, in the urine and above-mentioned deodorant compositions of 20mg and 10 microlitre Garden lavender spice (making) adding 100mL bottle with the 10mL adult male by TakasagoInternational Corporation, cover described bottle with Parafilm then, vibrated 10 minutes down at 25 ℃ afterwards.

According to following evaluation criterion feeling evaluation is carried out in the inside of bottle by 7 members.Described result is shown as the fractional meansigma methods of 7 members in the table 37.

Compare the analyte of wherein also testing the urinalysis thing and adding the Garden lavender spice (making) of 10 microlitres in the urine by TakasagoInternational Corporation.

[feeling evaluation standard]

1 point) do not feel stench

2 points) feel stench a little

3 points) feel some stenches

4 points) obviously feel some stenches a little

5 points) feel stench strongly

6 points) feel stench very consumingly

Table 37

	The evaluation score meansigma methods
		Urine+product of the present invention	1.3
Urine+product of the present invention+Garden lavender spice	1.0
		Urine	6.0
Urine+Garden lavender spice	4.7

The deodorizing effect of 40 pairs of physiology abnormal smells from the patients of embodiment

The reactor inside that 1mmol tannic acid and 1mmol sodium glutamate is added the sodium carbonate liquor (pH11.2) that comprises 50mL 0.05M.Whole material can and condition that air contact under 25 ℃ times stirrings 3 hours.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.

[deodorizing effect]

10mL physiology malodorant and the above-mentioned deodorant compositions of 50mg are added in the 100mL bottle, cover described bottle with Parafilm then, vibrated 10 minutes down at 25 ℃ afterwards.Then, carry out feeling evaluation by 7 members according to following evaluation criterion.Described result is shown as the fractional meansigma methods of 7 members in the table 38.

Compare, the independent stench analyte that vibrates, and carry out feeling evaluation.

[feeling evaluation standard]

1 point) do not feel stench

2 points) feel stench a little

3 points) feel some stenches

4 points) obviously feel some stenches a little

5 points) feel stench strongly

6 points) feel stench very consumingly

Table 38

	The evaluation score meansigma methods
		The situation that adds product of the present invention	1.4
Malodorant only	6.0

The excrement of embodiment 41 domestic animals and the deodorizing effect of urine

The reactor inside that 1mmol chlorogenic acid and 1mmol sodium glutamate is added the sodium carbonate liquor (pH11.2) that comprises 50mL 0.05M.Whole material can and condition that air contact under 25 ℃ times stirrings 3 hours, leave standstill then and make deodorant compositions.

[deodorizing effect]

10mL above-mentioned deodorant compositions of isolating liquid and 1mL from tame animal manure and urine is added in the 100mL bottle, cover described bottle with Parafilm then, afterwards 25 ℃ of vibrations 10 minutes down.Then, carry out feeling evaluation by 7 members according to following evaluation criterion.Described result is shown as the fractional meansigma methods of 7 members in the table 39.

Compare, only use by culturist's animal manure and the prepared analyte of urine.

[feeling evaluation standard]

1 point) do not feel the stink of excrement and urine

2 points) feel the stink of excrement and urine a little

3 points) feel the stink of some excrement and urine

4 points) obviously feel the stink of some excrement and urine a little

5 points) feel the stink of excrement and urine strongly

6 points) feel the stink of excrement and urine very consumingly

Table 39

	The evaluation score meansigma methods
		The situation that adds product of the present invention	1.3
Only from tame animal manure and urine isolating liquid	6.0

The deodorizing effect of 42 pairs of fishlike smell of embodiment

The sodium carbonate liquor (pH11.2) of 50mL 0.05M is added in the reactor,, make that the polyphenol content with regard to catechol is 1mmol toward wherein adding green tea extract.Under 25 ℃ with condition that air contacts under stirred 3 hours, leave standstill then and make deodorant compositions.

[deodorizing test]

In 5L water, add the deodorant compositions that makes more than the 5mL, thoroughly mix described whole material.The pan that boiled sardine is immersed in the described mixture.At room temperature, after through 10 minutes, take out described pan, the water flush away comprises the solution of deodorant compositions.Then, estimate pan according to following evaluation criterion in the mode of sensation by 5 specialist crews and show abnormal smells from the patient and the degree thereof that exists.Described result is shown as the fractional meansigma methods of 5 members in the table 40.

[evaluation criterion mark]

1 point) do not feel fishlike smell

2 points) feel fishlike smell a little

3 points) feel some fishlike smell

4 points) obviously feel fishlike smell a little

5 points) feel fishlike smell strongly

6 points) feel fishlike smell very consumingly

Table 40

	The evaluation score meansigma methods
		The situation that adds product of the present invention	1.4
To in the same old way	6.0

In table, described to shown in the same old way in situation about not adding under the deodorant compositions condition of the present invention.

The deodorizing effect of 43 pairs of rubbish of embodiment

The reactor inside that the 1mmol tannic acid is added the sodium carbonate liquor (pH11.2) that comprises 50mL 0.05M.Whole material can and condition that air contact under 25 ℃ times stirrings 3 hours, leave standstill then and make deodorant compositions.

[deodorizing effect]

The so-called rubbish that 1kg is comprised vegetable waste, fish rubbish, meat rubbish etc. is as in the Plastic Drum that has lid, water will more than 10 times of the deodorant compositions dilutions that make to make the aqueous solution of 50mL, above described aqueous solution is sprayed onto, cover bucket afterwards.Compare, the water of 50mL is sprayed onto in the identical rubbish of 1kg.After at room temperature keeping 3 days, carry out feeling evaluation according to specified evaluation criterion by 5 members.Described result is shown as the mark meansigma methods of 5 members in the table 41.

[feeling evaluation standard]

1 point) do not feel the stench of rubbish

2 points) feel the stench of rubbish a little

3 points) feel the stench of some rubbish

4 points) obviously feel the stench of some rubbish a little

5 points) feel the stench of rubbish strongly

6 points) feel the stench of rubbish very consumingly

Table 41

	The evaluation score meansigma methods	Estimate
			Product of the present invention	2.4	Observe abnormal smells from the patients such as vegetable own, but almost discover less than the septic abnormal smells from the patient of rubbish
To in the same old way	5.8	Observe the septic abnormal smells from the patient of intensive rubbish

Deodorizing effect in embodiment 44 toilets

The sodium carbonate liquor (pH11.2) of 50mL 0.05M is added in the reactor,, make that the polyphenol content with regard to chlorogenic acid is 1mmol toward wherein adding the Pericarpium Mali pumilae extract.Under 25 ℃ with condition that air contacts under stirred 3 hours.Then, described reaction liquid lyophilizing makes the deodorant compositions powder.

[deodorizing effect]

2g product of the present invention is sprayed onto in the cesspool of toilet, removes excrement by 5 members then.After removing excrement, estimate stink in the toilet in the mode of sensation according to the feeling evaluation standard.The result is presented in the table 42.

[feeling evaluation standard]

1 point) do not feel the excretal odor

2 points) feel the excretal odor a little

3 points) feel some the excretal odors

4 points) obviously feel some the excretal odors

5 points) feel the excretal odor strongly, just as the same degree in the general case.

Table 42

	The evaluation score meansigma methods	Estimate
			Product of the present invention	1.4	Do not use the general case of product of the present invention to compare, almost imperceptible the excretal odor has significantly suppressed the excretal odor.

Embodiment 45, to the deodorizing effect of foul odour

The reactor inside that 1mmol gallic acid and 1mmol glycine is added the sodium carbonate liquor (pH11.2) that comprises 50mL 0.05M.Whole material fully and under the condition that air contact 25 ℃ times stirrings 3 hours, leave standstill then and make deodorant compositions.

[deodorizing effect]

The 4L air is added in the odorless bag of 4L by air pump.Various foul odours (ammonia, Trimethylamine, hydrogen sulfide or methyl mercaptan) are injected wherein adjustments of gas concentration by syringe.Described bag is placed on the assay device of the closed cycle system that air pump is housed, and described air pump is worked under about 1000mL/ minute air capacity.1 milliliter of above-mentioned deodorant compositions is bearing in the absorption cotton (0.2g), described face is placed aerofluxus one side of air benzene.After work 2 hours, use malodorous surplus in described pneumatic cell (Gastech Corporation) the mensuration system, calculate the deodorization rate according to following formula.

Shown in Comparative Examples, the absorption cotton that is soaked with the Galla Turcica (Galla Helepensis) aqueous acid of 1mL 20mM is placed aerofluxus one side of air pump, replace having on it on absorption cotton of above-mentioned deodorant compositions.Then, test similarly, calculate described deodorization rate.The result is illustrated in the table 43.

Deodorization rate (%)=100 * (1-{A/B})

In above formula, A represents the measurement concentration of malodor components, and B is illustrated in the concentration to the malodor components of being surveyed in the same old way.Described to being the absorption cotton that is soaked with 1mL water in the same old way, rather than be soaked with the absorption cotton of the above-mentioned adsorbent composition of 1mL.

Table 43

Foul gas	Initial concentration (ppm)	Deodorization rate (%)
				Deodorant compositions of the present invention	The gallic acid aqueous solution
		Ammonia	60			100.0	85.0
Trimethylamine	130			90.0	70.0
		Methyl mercaptan	100			95.0	0
Hydrogen sulfide	120			100.0	5.0

Deodorant compositions of the present invention has deodorizing effect to various malodor components (comprising amine malodor components such as ammonia and Trimethylamine, sulphur compound such as methyl mercaptan and hydrogen sulfide etc.).

Industrial applicability

Various stenches can be eliminated or reduce to deodorant compositions of the present invention effectively. Concrete is, it is effectively eliminated or reduces various stenches, comprise the stink in the daily life, such as the stink of stink, body odor and the rubbish of the excrement of bad implication (halitosis), body odor, refrigerator stench, people, animal and birds and urine, and the stench of factory and trade waste.

And deodorant compositions of the present invention is to removing sulphur compound such as methyl mercaptan, hydrogen sulfide and dimethyl sulfide; Nitrogen compound such as ammonia, urea, indoles, the smelly class of excrement and amine; And lower fatty acid such as butyric acid have fabulous deodorizing effect. Wherein, deodorant compositions of the present invention has deodorizing effect to sulphur compound such as methyl mercaptan, hydrogen sulfide and dimethyl sulfide.

And deodorant compositions of the present invention can add in following product or the article, shows deodoriging properties. Concrete is that described product or article comprise oral care product, such as mouthwash, toothpaste, gum, tablet, hard candy, soft sweets, capsule and mouthspray; Be used for the article that pet and animal comprise dog, cat, rabbit, hamster and parakeet,, cat sleep cane and sheet husky such as cat; Cleaning agent such as laundry detergents, kitchen cleaning agent, bathroom detergent, home cleaning agent, carpet cleaner and toilet cleaner; Cosmetics such as soap, shower cream, hand-washing soap, lotion, skin cleaner, anhidrotic, foot cleaning spraying and foot-powder, hair care product such as shampoo, hair conditioner, hair cleaning agent, hair dye, agent for permanent hair waving, wax, hair jelly and mousse; Health product is such as diaper, mat, sanitary napkin, coverlet, towel and wet yarn fabric; The household cleaning product, the filter of shoe chest spraying, shoe-pad, rubbish spraying, air freshener and air adjustment humectant, deodorant, hair-dryer and air exhauster, refrigerator with deodorant, clothes with deodorant, the deodorization fiber of the deodorant of deodorant, drawer, closet and cabinet, indoor or vehicle deodorization agent, toilet deodorant, textile, clothes (underpants and socks), vehicle heelpiece, be used for deodorant and other various deodorant of factory and trade waste.

The accompanying drawing summary

Fig. 1 is the figure of the deodorizing effect of deodorant compositions of the present invention on diaper.

Fig. 2 is the figure of the deodorizing effect of deodorant compositions of the present invention on diaper, and its effect is different with the above.

Claims (11)

1. deodorant compositions, it comprises the colored compound as active component, described colored compound is by under the condition of oxygen molecule coexistence, pH value be 6.5 or the above solvent that is being alkalescence in the reaction polyphenol make.

2. deodorant compositions as claimed in claim 1 is characterized in that, in course of reaction the supply of oxygen molecule be 1mg/L or more than.

3. deodorant compositions as claimed in claim 1 or 2 is characterized in that, described reaction temperature is 0-60 ℃.

4. deodorant compositions as claimed in claim 1 is characterized in that, also adds metal ion in described response system, and reacts.

5. deodorant compositions as claimed in claim 1 is characterized in that, described polyphenol is the polyphenol with o-bis-phenol structure.

6. deodorant compositions as claimed in claim 1 is characterized in that described polyphenol is a hydroquinone.

7. deodorant compositions as claimed in claim 1 is characterized in that, also adds aminoacid in described response system, and reacts.

8. deodorant compositions, it comprises the colored compound as active component, described colored compound is by under the condition of oxygen molecule coexistence, pH value be 6.5 or the above solvent that is being alkalescence in reaction comprise polyphenol but do not contain amino acid whose plant extract substantially and make.

9. deodorant compositions as claimed in claim 8 is characterized in that, also adds aminoacid in described response system, and reacts.

10. deodorant compositions as claimed in claim 9 is characterized in that described aminoacid is a-amino acid.

11. deodorant compositions, it comprises the colored compound as active component, described colored compound is by under the condition of oxygen molecule coexistence, pH value be 6.5 or the above solvent that is being alkalescence in reaction comprise polyphenol and amino acid whose plant extract and/or plant and make.