CL2008003903A1 - Uso como aditivo bifuncional de lubricidad y de resistencia al frio para compuestos de hidrocarburos liquidos de al menos un copolimero que comprende: a) unidades derivadas de etileno y/o propileno; b) unidades de formula -(ch2-choocr)-; c) unidades de formula -(ch2-choh)- y d) unidades de formula -(ch2-choocr)-. - Google Patents

Uso como aditivo bifuncional de lubricidad y de resistencia al frio para compuestos de hidrocarburos liquidos de al menos un copolimero que comprende: a) unidades derivadas de etileno y/o propileno; b) unidades de formula -(ch2-choocr)-; c) unidades de formula -(ch2-choh)- y d) unidades de formula -(ch2-choocr)-.

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Publication number
CL2008003903A1
CL2008003903A1 CL2008003903A CL2008003903A CL2008003903A1 CL 2008003903 A1 CL2008003903 A1 CL 2008003903A1 CL 2008003903 A CL2008003903 A CL 2008003903A CL 2008003903 A CL2008003903 A CL 2008003903A CL 2008003903 A1 CL2008003903 A1 CL 2008003903A1
Authority
CL
Chile
Prior art keywords
units
formula
preferentially
hecundane
choocr
Prior art date
Application number
CL2008003903A
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English (en)
Inventor
Dolmazon Nelly
Papin Geraldine
Tort Valerie Heroguez Frederic
Original Assignee
Total Raffinage Marketing
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Publication date
Application filed by Total Raffinage Marketing filed Critical Total Raffinage Marketing
Publication of CL2008003903A1 publication Critical patent/CL2008003903A1/es

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/14—Esterification
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1625—Hydrocarbons macromolecular compounds
    • C10L1/1633—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
    • C10L1/1641—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1817—Compounds of uncertain formula; reaction products where mixtures of compounds are obtained
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
    • C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/14—Use of additives to fuels or fires for particular purposes for improving low temperature properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/082—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Combustion & Propulsion (AREA)
  • Emergency Medicine (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

SINTESIS Y USO DE COPOLIMEROS A BASE DE ETILENO Y/O DE PROPILENO Y DE ÉSTERES VINILICOS MODIFICADOS MEDIANTE INJERTO, EFICACES PARA MEJORAR TANTO LA RESISTENCIA AL FRÍO COMO LA LUBRICIDAD DE LOS HIDROCARBUROS LIQUIDOS, EN CONCRETO LOS DESTILADOS INTERMEDIOS RESULTANTES DE LA DESTILACIÓN DEL PETRÓLEO Y LOS PETRÓLEOS CRUDOS, SOBRE TODO LOS QUE TIENEN BAJO CONTENIDO EN AZUFRE, Y HACE REFERENCIA A UN COPOLIMERO QUE CONTIENE: A) UNIDADES DERIVADAS DEL ETILENO DE FÓRMULA A - (CH2-CH2)N1- Y/O DEL PROPILENO DE FÓRMULA A'- ((CH3)CH2-CH2)N2 CON N1+N2=N QUE VAYA DE 98 A 643, PREFERENTEMENTE DE 124 A 515; N1 SERÁ, DE FORMA VENTAJOSA, IGUAL A N; B) UNIDADES DE FÓRMULA B: - (CH2-CHOOCR1)M-X-, DONDE R1 REPRESENTA A UN GRUPO ALQUILO LINEAL O RAMIFICADO EN C1-C15, PREFERENTEMENTE METILO, PROPILO Y/O UN GRUPO ALQUILO RAMIFICADO ENTRE C5 Y C15, EN EL CUAL LA RAMIFICACIÓN ESTÁ SITUADO EN CUALQUIER PUNTO DEL RADICAL ALQUILO, PREFERENTEMENTE EN LA POSICIÓN 2 Ó 3 DE LA CADENA DE ALQUILO; PREFERENTEMENTE SELECCIONADOS ENTRE LOS COMONÓMEROS VINILICOS PREFERENTES EN C5-C15, PREFERENTEMENTE SELECCIONADOS ENTRE PIVALATO, ISOPENTANOATO, ISOHEXANOATO, ISONONANOATO, ISODECANOATO E/O ISOTRIDECANOATO Y, VENTAJOSAMENTE, ETIL-2 HEXANOATO, NEOALCANOATOS, ESPECIALMENTE NEONONANOATO, NEODECANOATO Y/O NEOUNDECANOATO; DE FORMA QUE M VAYA DE 2 A 105, PREFERENTEMENTE DE 16 A 71, Y X VAYA DE 0,2 A 105, PREFERENTEMENTE DE 1,6 A 71; C) UNIDADES DE FÓRMULA C: - (CH2-CHOH)X1-, EN LA QUE X1 VA DE 0 A ,30X, PREFERENTEMENTE X1 =0; D) UNIDADES DE FÓRMULA D: - (CH2-CHOOCR2)X2-, EN LA QUE X2 VA DE 0,70X A X, PREFERENTEMENTE X2=X Y R2 REPRESENTA UN GRUPO ALQUILO LINEAL O RAMIFICADO SATURADO O INSATURADO EN C8-C24, PREFERENTEMENTE DE C14-C20 E INCLUSO DE C14 A C18, CON X=X1 + X2.
CL2008003903A 2007-12-26 2008-12-24 Uso como aditivo bifuncional de lubricidad y de resistencia al frio para compuestos de hidrocarburos liquidos de al menos un copolimero que comprende: a) unidades derivadas de etileno y/o propileno; b) unidades de formula -(ch2-choocr)-; c) unidades de formula -(ch2-choh)- y d) unidades de formula -(ch2-choocr)-. CL2008003903A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0709093A FR2925909B1 (fr) 2007-12-26 2007-12-26 Additifs bifonctionnels pour hydrocarbures liquides obtenus par greffage a partir de copolymeres d'ethylene et/ou de propylene et d'esters vinyliques

Publications (1)

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CL2008003903A1 true CL2008003903A1 (es) 2009-06-05

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CL2008003903A CL2008003903A1 (es) 2007-12-26 2008-12-24 Uso como aditivo bifuncional de lubricidad y de resistencia al frio para compuestos de hidrocarburos liquidos de al menos un copolimero que comprende: a) unidades derivadas de etileno y/o propileno; b) unidades de formula -(ch2-choocr)-; c) unidades de formula -(ch2-choh)- y d) unidades de formula -(ch2-choocr)-.

Country Status (17)

Country Link
US (1) US20100275508A1 (es)
EP (1) EP2231728B1 (es)
JP (1) JP2011508041A (es)
KR (1) KR101605782B1 (es)
CN (1) CN101910218B (es)
AR (1) AR069987A1 (es)
AT (1) ATE537242T1 (es)
BR (1) BRPI0820359A2 (es)
CA (1) CA2709009C (es)
CL (1) CL2008003903A1 (es)
EA (1) EA019963B1 (es)
ES (1) ES2382305T3 (es)
FR (1) FR2925909B1 (es)
PT (1) PT2231728E (es)
TW (1) TWI439541B (es)
UA (1) UA101824C2 (es)
WO (1) WO2009106743A2 (es)

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FR3005061B1 (fr) 2013-04-25 2016-05-06 Total Raffinage Marketing Additif pour ameliorer la stabilite a l'oxydation et/ou au stockage de carburants ou combustibles hydrocarbones liquides
FR3017876B1 (fr) 2014-02-24 2016-03-11 Total Marketing Services Composition d'additifs et carburant de performance comprenant une telle composition
FR3017875B1 (fr) 2014-02-24 2016-03-11 Total Marketing Services Composition d'additifs et carburant de performance comprenant une telle composition
RU2599778C2 (ru) * 2014-12-24 2016-10-20 Акционерное общество "Ангарский завод полимеров" Депрессорная присадка к дизельным топливам на основе сополимеров этилена и дизельное топливо на основе этой присадки
FR3034778B1 (fr) 2015-04-10 2017-04-28 Total Marketing Services Additif dispersant des asphaltenes et ses utilisations
EP3144059A1 (en) 2015-09-16 2017-03-22 Total Marketing Services Method for preparing microcapsules by double emulsion
FR3105251B1 (fr) 2019-12-20 2022-11-04 Total Marketing Services Procédé d’extraction d’une huile brute avec injection de résine
FR3118056B1 (fr) 2020-12-22 2024-01-05 Total Marketing Services Composition d’additifs comprenant un copolymere et une resine
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EP2231728A2 (fr) 2010-09-29
FR2925909A1 (fr) 2009-07-03
TWI439541B (zh) 2014-06-01
CA2709009A1 (en) 2009-09-03
BRPI0820359A2 (pt) 2015-05-12
PT2231728E (pt) 2012-01-16
AR069987A1 (es) 2010-03-03
US20100275508A1 (en) 2010-11-04
EP2231728B1 (fr) 2011-12-14
CA2709009C (en) 2016-05-03
ES2382305T3 (es) 2012-06-07
TW200932890A (en) 2009-08-01
CN101910218B (zh) 2013-02-13
JP2011508041A (ja) 2011-03-10
KR20100117559A (ko) 2010-11-03
ATE537242T1 (de) 2011-12-15
CN101910218A (zh) 2010-12-08
KR101605782B1 (ko) 2016-03-23
WO2009106743A2 (fr) 2009-09-03
UA101824C2 (ru) 2013-05-13
WO2009106743A3 (fr) 2009-11-26
EA019963B1 (ru) 2014-07-30
FR2925909B1 (fr) 2010-09-17

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