CH659326A5 - Procede et dispositif de surveillance de l'etat redox d'elements dans le verre. - Google Patents
Procede et dispositif de surveillance de l'etat redox d'elements dans le verre. Download PDFInfo
- Publication number
- CH659326A5 CH659326A5 CH4159/84A CH415984A CH659326A5 CH 659326 A5 CH659326 A5 CH 659326A5 CH 4159/84 A CH4159/84 A CH 4159/84A CH 415984 A CH415984 A CH 415984A CH 659326 A5 CH659326 A5 CH 659326A5
- Authority
- CH
- Switzerland
- Prior art keywords
- glass
- potential
- working electrode
- electrodes
- redox state
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 22
- 238000012544 monitoring process Methods 0.000 title claims description 11
- 239000011521 glass Substances 0.000 claims description 81
- 239000006060 molten glass Substances 0.000 claims description 23
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 14
- 238000005259 measurement Methods 0.000 claims description 12
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 229910052697 platinum Inorganic materials 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 5
- 239000000446 fuel Substances 0.000 claims description 4
- 239000005361 soda-lime glass Substances 0.000 claims description 4
- 229910001260 Pt alloy Inorganic materials 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 46
- 229910052742 iron Inorganic materials 0.000 description 25
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 24
- 239000011593 sulfur Substances 0.000 description 24
- 229910052717 sulfur Inorganic materials 0.000 description 24
- 230000000694 effects Effects 0.000 description 13
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 5
- 241000894007 species Species 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000003487 electrochemical reaction Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- -1 iron ions Chemical class 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000011669 selenium Substances 0.000 description 4
- 238000010408 sweeping Methods 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 229910001447 ferric ion Inorganic materials 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 230000002441 reversible effect Effects 0.000 description 3
- 229910052711 selenium Inorganic materials 0.000 description 3
- 238000004876 x-ray fluorescence Methods 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 229910000629 Rh alloy Inorganic materials 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910001448 ferrous ion Inorganic materials 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 2
- 235000003197 Byrsonima crassifolia Nutrition 0.000 description 1
- 240000001546 Byrsonima crassifolia Species 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 101000582992 Homo sapiens Phospholipid phosphatase-related protein type 5 Proteins 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 102100020725 WAP four-disulfide core domain protein 5 Human genes 0.000 description 1
- 230000032900 absorption of visible light Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 230000005298 paramagnetic effect Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/38—Concrete; Lime; Mortar; Gypsum; Bricks; Ceramics; Glass
- G01N33/386—Glass
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/416—Systems
- G01N27/48—Systems using polarography, i.e. measuring changes in current under a slowly-varying voltage
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Immunology (AREA)
- Engineering & Computer Science (AREA)
- Pathology (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Molecular Biology (AREA)
- Ceramic Engineering (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Glass Compositions (AREA)
- Glass Melting And Manufacturing (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB838323519A GB8323519D0 (en) | 1983-09-01 | 1983-09-01 | Monitoring redox state of elements in glass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH659326A5 true CH659326A5 (fr) | 1987-01-15 |
Family
ID=10548211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH4159/84A CH659326A5 (fr) | 1983-09-01 | 1984-08-30 | Procede et dispositif de surveillance de l'etat redox d'elements dans le verre. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4557743A (https=) |
| JP (1) | JPS60155966A (https=) |
| AU (1) | AU566848B2 (https=) |
| BE (1) | BE900397A (https=) |
| BR (1) | BR8404417A (https=) |
| CA (1) | CA1216893A (https=) |
| CH (1) | CH659326A5 (https=) |
| DE (1) | DE3431987A1 (https=) |
| ES (2) | ES535778A0 (https=) |
| FR (1) | FR2555753B1 (https=) |
| GB (2) | GB8323519D0 (https=) |
| IN (1) | IN161617B (https=) |
| IT (1) | IT1179080B (https=) |
| NL (1) | NL8402633A (https=) |
| SE (1) | SE457667B (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2700393B1 (fr) * | 1993-01-14 | 1995-03-31 | Souchon Neuvesel Verreries | Procédé et dispositif de détermination de l'état d'oxydation d'un matériau ionique en fusion. |
| DE19955827B4 (de) * | 1999-11-20 | 2005-03-31 | Schott Ag | Verfahren zur Unterdrückung der Bildung von O2-Gasblasen an der Kontaktfläche zwischen einer Glasschmelze und Edelmetall |
| US7006228B2 (en) * | 2003-06-24 | 2006-02-28 | Corning Incorporated | Methods for quantifying the oxidation state of glass |
| US20060070405A1 (en) * | 2004-10-06 | 2006-04-06 | Anheuser-Busch, Inc. | Method for the production of amber glass with reduced sulfur-containing emissions |
| US8042362B2 (en) * | 2006-10-30 | 2011-10-25 | Kibol Viktor F | “Kibol's module” plant for producing inorganic fibers of rocks |
| JP5981398B2 (ja) * | 2013-07-12 | 2016-08-31 | 株式会社日本自動車部品総合研究所 | 内燃機関のＳＯｘ濃度検出装置 |
| US11912608B2 (en) | 2019-10-01 | 2024-02-27 | Owens-Brockway Glass Container Inc. | Glass manufacturing |
| US11667555B2 (en) | 2020-02-12 | 2023-06-06 | Owens-Brockway Glass Container Inc. | Glass redox control in submerged combustion melting |
| EP4091998B1 (en) * | 2021-05-21 | 2026-02-18 | Schott Ag | Glass having high uv transmittance and high solarization resistance |
| EP4091999B1 (en) * | 2021-05-21 | 2026-04-08 | Schott Ag | Glass having high uv transmittance and high solarization resistance |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2766423A (en) * | 1951-09-08 | 1956-10-09 | Nat Res Dev | Polarographs |
| GB709826A (en) * | 1951-09-08 | 1954-06-02 | Nat Res Dev | Improvements in or relating to polarographs |
| GB820244A (en) * | 1958-03-18 | 1959-09-16 | Atomic Energy Authority Uk | Improvements in or relating to pulse filter circuits |
| US3295944A (en) * | 1963-01-02 | 1967-01-03 | Owens Illinois Inc | Method for controlling the rate of devitrification |
| US3298872A (en) * | 1963-01-02 | 1967-01-17 | Owens Illinois Inc | Means for generating an electromotive force |
| GB1401761A (en) * | 1971-04-01 | 1975-07-30 | Cambridge Scientific Instr Ltd | Polarographic apparatus |
| US3854919A (en) * | 1971-07-23 | 1974-12-17 | Owens Illinois Inc | Method of forming transparent glass ceramic with compression layer |
| GB1412545A (en) * | 1973-08-07 | 1975-11-05 | A C I Operations | Glass colour changes |
| DE2618392A1 (de) * | 1975-04-28 | 1976-11-11 | Mitsubishi Chem Ind | Voltammetrieanordnung |
| US4358305A (en) * | 1981-09-23 | 1982-11-09 | Ppg Industries, Inc. | Method of and apparatus for analyzing atmosphere of a combustion chamber |
| DD203397A1 (de) * | 1981-12-03 | 1983-10-19 | Volker Herrmann | Verfahren und pruefanordnung zur bestimmung des schmelzverhaltens von glas |
-
1983
- 1983-09-01 GB GB838323519A patent/GB8323519D0/en active Pending
-
1984
- 1984-08-10 AU AU31781/84A patent/AU566848B2/en not_active Ceased
- 1984-08-14 IN IN655/DEL/84A patent/IN161617B/en unknown
- 1984-08-21 BE BE1/11072A patent/BE900397A/fr not_active IP Right Cessation
- 1984-08-22 FR FR8413159A patent/FR2555753B1/fr not_active Expired
- 1984-08-28 IT IT67855/84A patent/IT1179080B/it active
- 1984-08-28 GB GB08421750A patent/GB2145829B/en not_active Expired
- 1984-08-29 ES ES535778A patent/ES535778A0/es active Granted
- 1984-08-29 NL NL8402633A patent/NL8402633A/nl not_active Application Discontinuation
- 1984-08-29 ES ES535777A patent/ES8600820A1/es not_active Expired
- 1984-08-30 DE DE19843431987 patent/DE3431987A1/de not_active Withdrawn
- 1984-08-30 CH CH4159/84A patent/CH659326A5/fr not_active IP Right Cessation
- 1984-08-31 SE SE8404366A patent/SE457667B/sv not_active IP Right Cessation
- 1984-08-31 CA CA000462284A patent/CA1216893A/en not_active Expired
- 1984-08-31 BR BR8404417A patent/BR8404417A/pt not_active IP Right Cessation
- 1984-08-31 JP JP59183621A patent/JPS60155966A/ja active Granted
- 1984-08-31 US US06/646,443 patent/US4557743A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| IT8467855A0 (it) | 1984-08-28 |
| FR2555753B1 (fr) | 1989-01-13 |
| SE8404366D0 (sv) | 1984-08-31 |
| ES535777A0 (es) | 1985-10-16 |
| AU566848B2 (en) | 1987-10-29 |
| US4557743A (en) | 1985-12-10 |
| SE8404366L (sv) | 1985-03-02 |
| DE3431987A1 (de) | 1985-03-21 |
| AU3178184A (en) | 1985-03-07 |
| ES8600820A1 (es) | 1985-10-16 |
| GB8323519D0 (en) | 1983-10-05 |
| FR2555753A1 (fr) | 1985-05-31 |
| CA1216893A (en) | 1987-01-20 |
| NL8402633A (nl) | 1985-04-01 |
| SE457667B (sv) | 1989-01-16 |
| ES8600821A1 (es) | 1985-10-16 |
| GB8421750D0 (en) | 1984-10-03 |
| ES535778A0 (es) | 1985-10-16 |
| IT1179080B (it) | 1987-09-16 |
| IT8467855A1 (it) | 1986-02-28 |
| JPH056661B2 (https=) | 1993-01-27 |
| GB2145829A (en) | 1985-04-03 |
| JPS60155966A (ja) | 1985-08-16 |
| BE900397A (fr) | 1985-02-21 |
| GB2145829B (en) | 1986-09-24 |
| IN161617B (https=) | 1988-01-02 |
| BR8404417A (pt) | 1985-07-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased | ||
| PL | Patent ceased |