CH617643A5 - Composition intended for the physicochemical activation of water - Google Patents

Abstract

The composition in the solid, liquid or mixed state contains active substances and excipients making it possible for the active substances to be added steadily and gradually to water under pressure issuing from irrigating apparatuses and their nozzles. The composition may contain a wide range of different active substances which may be distributed in a predetermined concentration in the running water issuing from the nozzles of showers, of bath taps, in water entering flush cisterns of lavatories and in irrigating water issuing from watering nozzles. Depending on the respective choice of the active substance the composition can therefore be employed in the field of hygienic and cosmetological sanitary and agricultural douches or sprays.

Description

The present invention relates to a solid, liquid or mixed composition, intended for the physicochemical activation of running water under pressure, containing active substances, more particularly the physicochemical activation of shower water, flushing water from toilets and agricultural irrigation water.

The present invention finally makes it possible to make the pressurized running water benefit from the showers of various specific properties, in particular therapeutic, cosmetological, aromatic ... in the same way as the bathing water can benefit.

The invention also makes it possible to systematically charge the water retaining the hunts with disinfectant, odoriferous, pickling, descaling, coloring ... substances by the same piping of the hunting tank.

The invention also makes it possible to automatically load agricultural irrigation water with disinfectant, antiparasitic, fertilizing substances, etc. by the same tap for distributing water.

Obtaining these results therefore involves devices to be inserted, inserted or integrated in the piping, in the taps or in the nozzles of the showering devices, the watering devices and the flushing devices.

Such devices therefore relate to sanitary technology. The supply of these devices, as well as that of similar devices, requiring original compositions described in the present invention, relates to the techniques of pharmacy, perfumery, cosmetology, drugstore and agronomy.

There are no known products that can be used to modify the properties of shower water, except products intended exclusively for body washing.

Are particularly well known liquid soaps, emulsifiable by water from showers, during its passage through an appropriate device.

Are also known, for washing the body in the shower, water-soluble foaming tablets, obtained by compression of several hundred bars. These tablets are designed to dissolve pell-mell at the bottom of a perforated bag at its base, hooked by an elastic band to the spray head of a shower.

Finally, well-known formulas of foaming / detergent, foam-breaking, alkalizing, neutralizing compositions intended exclusively for body and hair washing are known. These formulas are prepared in the form of cream or bread, which can be dissolved or mixed with shower water, passing through suitable equipment.

All these washing products do not relate to the present invention which explicitly excludes all body and hair washing in a shower solubilizing or mixing a detergent, a solid soap or a liquid soap in its water, experience proving that such showers lack cleaning efficiency and, in addition, result in a significant waste of special detergent for showers.

To overcome these drawbacks, the present invention has designed a special shower spray for body washing and shampooing. This shower-reservoir supplies, at will, a special detergent for showers which, at no time, is in contact with the water, inside said shower, but which this water heats indirectly.

The object of the invention is not to formulate a new body and hair wash product, which can be dissolved or mixed with shower water, using equipment, but to participate in the development of industrial products. unpublished. This invention recommends the use of excipient and carrier substances, recognized without harmfulness after long use and by experience, to be added to specific active substances, chosen by the skilled person in his corporation. These original industrial products are called compositions during the description of the invention.

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The compositions which are the subject of the invention are intended for the supply of existing devices or which must exist subsequently.

The hot mixing of excipients with active substances constitutes the solidified compositions. These solidified compositions will be used naked or fixed in perforated capsules whose shapes will promote eddies and swirls under the action of the water flow.

The hot or cold mixing of excipients with active substances constitutes the liquefied compositions.

The mixed compositions are in the form of powders, granules, crystals, pastes, gels, etc. These compositions will be used in permeable sachets or in perforated capsules.

The choice of excipients and active substances is determined by the invention, because of their melting, solidification and viscosity zones.

The solid compositions according to the invention are characterized in that they are slowly and gradually hydrofusible, under the dampening effect of an emission of water of predetermined temperature, sprayed on its surface.

These solid compositions are heterogeneous aggregates:

- specific active substances, of all origins (solids and / or liquids, hydrophilic and / or hydrophobic) chosen by a person skilled in the art in his corporation, and

- of excipients recommended by the invention.

The excipients have the function, not only of aggregating the active preparation, but also of absorbing the liquid substances thereof, in order to obtain a hard mass at room temperature. This mass will either be shaped by extrusion, or formed in molds, or poured into perforated capsules in the shapes appropriate to the devices.

In addition, these excipients / solidifiers are water-solubilizers and / or water-dispersants and / or hydroemulsifiers of these active substances and their amalgamated solvents.

In other words, these excipient / solidifying substances will make it possible to dissolve, wet, disperse, solvate and emulsify, instantly, in pressurized running water which passes through or emanates from an irrigating device, the active substances sharing the active product.

To formulate and properly weight a mass of composition from which one wishes, for example, to draw by molding cartridges or capsules of solidified perfume, one should not stop at a simple hydrofusion, uncontrolled, of various compositions, obtained by itself flaking of water during its rapid passage, or by impregnation, or by imbibition, or by rustling, but we must consider:

a) the average temperature of the shower water, knowing that the approximate temperature of this water, at the outlet of a nozzle, is from 10 ° to 25 ° for cold showers, from 26 ° to 37 ° for showers lukewarm, from 38 ° to 45 ° for hot showers;

b) the volume of water required for the duration of a shower,

knowing that a high pressure of water proportionally increases its flow and hastens all the more the dissociation of the active cartridge.

For example, a rain shower, of low pressure, requires approximately 10 to 201 of water in 5 minutes, while a rain shower or jet, of high pressure, can imply a water consumption of the order of 30 to 501 in 5 min.

Knowing that any active preparation is unsuitable, as it is, to be introduced into one of the distribution devices, with a view to validly activating the water for showers and the water for flushing; knowing that any active preparation can be the fruit of a very simple or very complex formula, agglomerating the most varied substances and solvents: hydrophilic and hydrophobic, lipophilic and lipophobic; various states: liquid, solid, powdery, gaseous ...; knowing that any active preparation can be a true solution, a sol, a gel, a simple or mixed emulsion, a

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jelly, foam, dissolved or potential gas ...; it is advisable, according to the invention, to solidify the composition, so as to prolong or slow down its duration of thermofusion in a device, and also, to make it capable of dissolving and / or dispersing in the water of the shower or hunting.

The choice of excipient and / or solidifying substances, having to be subordinated to the average temperature of cold, lukewarm or hot showers, it is advisable to choose, wisely, the substances likely to delay and regularize the alluvial dissociation of the product cartridge active in a device. The solidifying and / or excipient substances must, according to the invention, be chosen according to their melting and solidification zone and to their compatibility with the active substance.

Among the solidification factors, those of vegetable, animal or mineral origin are chosen, the melting point (PF) of which allows mixtures and combinations capable of providing the agglomerated mass with a melting zone close to the temperature of cold showers, warm showers and hot showers.

These solidification factors are, for example:

- oils and fats of all origins, totally or partially hydrogenated, such as:

peanut oil (m.p .: 68 ° -69 ° C)

sesame oil (m.p .: 68.5 ° C)

cottonseed oil (m.p .: 62 ° -63 ° C)

soybean oil (m.p .: 69 ° -71 ° C)

coconut oil (m.p .: 43 ° -45 ° C)

palm kernel oil (m.p .: 40 ° C)

palm oil (m.p .: 35 ° -45 ° C)

whale oil (m.p .: varying from 34 ° to 56 ° C, depending on hydrogenation)

turtle oil (m.p .: 24.6 ° -26.6 ° C)

squalene oil castor oil (m.p .: 86 ° -90 ° C)

coconut butter (Cochin copra-neige) (m.p .: 20-28 ° C)

spermaceti (m.p .: 49 ° C)

Axonge grease (m.p .: 36 ° -42 ° C)

mutton tallow (m.p .: 44 ° -45 ° C)

beef tallow (m.p .: 42.5 ° -49 ° C)

beeswax (m.p .: 63 ° -64 ° C)

carnauba wax (m.p .: 83 ° -91 ° C)

- fatty acids of solid consistency, such as:

stearic acid (m.p .: 69.6 ° C)

palmitic acid (m.p .: 61 ° C)

myristic acid (m.p .: 54 ° C)

Iauric acid (m.p .: 44 ° C)

ricinoleic acid (m.p .: 17 ° C)

- solid fatty acid alkylolamides, such as:

monoethanolamide of stearic acid (mp: 67 ° C) monoethanolamide of myristic acid (mp: 53 ° C) mono- and diethanolamide of iauric acid (mp: 46 ° C) mono- and diethanolamide d 'lauric / myristic acids (mp: 47 ° C)

stearic acid triethanolamide (m.p .: 44 ° -46 ° C) isauranolamide of iauric acid (m.p .: 43 ° C)

and all possible mixtures of fatty acids: Iauric, myristic, palmitic, stearic, ricinoleic, tending to obtain the desired melting zone for the solid active product

- technical fatty alcohols of solid consistency, such as: stearyl alcohol (m.p .: 55 ° -57 ° C)

cetyl alcohol (m.p .: 46 ° -49 ° C)

myristylic alcohol (m.p .: 37.2 ° -37.5 °)

- solid, chemically pure fatty alcohols, such as:

stearyl alcohol C 18 (m.p .: 57.3 ° -57.8 ° C)

cetyl alcohol C 16 (m.p .: 48 ° -49 ° C)

myristyl alcohol C 14 (m.p .: 37.2 ° -37.5 ° C)

Iauric alcohol C 12 (m.p .: 23.5 ° -24 ° C)

decyl alcohol C 10 (m.p .: 6.5-7 ° C)

The fatty alcohols, of solid consistency, are chosen because they do not become rancid, emulsify immediately, and above all can absorb several times their weight of liquid active substances; moreover, their pH is neutral.

Fatty alcohols C 10, C12, C14; C16, C 18 and their mixtures, as well as C 20 if the finished product requires a higher hydrofusion point, make it possible to obtain finished compositions of solid consistency, although possibly comprising from 1 to 50% of their total weight. liquid, hydrophilic and / or hydrophobic active substances.

The compositions thus obtained, also comprising solidifiers such as alkanolamides of fatty acids and suitable surfactants, are of solid consistency in ambient air, but hydrofusible under the scouring or touching effect of cold, lukewarm water. or hot under pressure, in temperature zones that can vary between 1 and 65 ° C.

Such compositions can also comprise other absorbent substances of liquids, such as lanolin and cholesterol, and support loads of absorbent and hardening powders, of all origins, such as talc, starch, carbonate of magnesia, zinc stearate, titanium white, zinc oxide, alumina oxide, titanium oxide, colloidal kaolin, silica gel, kaolin gel ...

The first anionic surfactant which may be suitable is diu- soap, such as coconut, coconut, palm kernel, tallow, castor / glycerin soaps.

Hard soaps are good excipients for solidifying and delaying the dissociation, dissolution and dispersion of the active preparations incorporated therein, by the fact that they are emulsifiers of fatty substances. Indeed, the soap git by the process known as of solvation, which makes adhere the dirty fats of the washing to its lipophilic group, so that the fats contaminated by the washing are entrained with it in water.

In the shower or in hunting, the soap loaded with the specific active preparation will make the fatty substances active adhere, by solvation, to its lipophilic group. The shower or flush water will disperse the dissociated particles as the soap disintegrates.

Preferably, pure white soap powder, of very good quality, neutral and uncharged, will be used, except for the specific active complex which will be added to it by kneading; then we will pass this extruder to the extruder, from which we will draw bungs of adequate profile and length, to be used as is or to strike in various forms in suitable molds.

However, in order to obtain results clearly superior to those obtained by the use of ordinary soaps, which do not adapt well to hard water and which hydrolyze shower water, it is recommended to use other Surfactants at choose from the range of anionic, nonionic and / or cationic tensides for oil-in-water emulsions, such as sulphates of anionic fatty alcohols and polyglycolic ethers of nonionic fatty alcohols.

Among the anionic surfactants of solid consistency in the temperature zones of interest, it is possible, in addition to the soap, to mention, without limitation:

- primary and secondary alkyl sulphates, such as sodium lauryl sulphates (C 12, C 14, C 16, C 18) in powders, in flakes, in needles, which are practically odorless

- alkylarylsulfonates, such as sodium dodecylbenzenesulfonate, powder

- alkylethanolamidesulfonates, such as sodium laurylethanolami-desulfate, powder

- alkylbenzylidazolsulfonate, powder

- mono-, di- and triglyceridesulfates, such as sodium monolaurylgly-cerylsulfate, powder

- alkylsulfoacetates, such as sodium laurylsulfoacetate, powder

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- mono- and diglyceridesulfoacetates

- alkylsulfosuccinates, such as sodium mono- and dioctylsulfosuc-cinate and their diamylic, dihexylic, dibutyl and dioxyl derivatives: granules and powders

- alkylsulfopropionates, such as sodium alkylpropionylsulfonate, in powder.

Among the nonionic tensides of solid consistency, there may be mentioned without limitation:

- saponin, powder

- fatty esters of di- and tri-alcohol, such as:

glyceryl monostearate (m.p .: 54C-58 ° C)

ethylene glycol monostearate (m.p .: 55 ° C)

diethylene glycol monostearate (m.p .: 43 ° -49 ° C)

double glycol / glyceryl stearate (m.p .: 50 ° -57 ° C) glyceryl monolaurate (m.p .: 20 ° -25 ° C)

ethylene glycol monolaurate (m.p .: 45 ° C)

double glycol / glycerin laurate (m.p .: 38 ° C)

glyceryl myristate diethylene glycol myristate propylene glycol / glyceryl monopalmipate (m.p .: 30 ° C) to be emulsified by adding a sodium hydroxide soap or triethanolamine or an anionic alkyl sulfate

- fatty esters of sorbitol, such as:

sorbitan monostearate (m.p .: 51 ° C)

sorbitan tristearate (m.p .: 48.5 ° C)

sorbitan tetrastearate (m.p .: 54 ° C)

sorbitan monopalmipate (m.p .: 45 ° C)

- fatty esters of polyoxyethylene, such as:

the polyoxyethylenated ester of stearic acid (mp: 34 ° -49 ° C) the polyoxyethylenated ester of cetyl acid (mp: 36 ° -44 ° C) the polyoxyethylenated sorbitan monostearate (mp: 36 ° -40 ° C )

polyoxyethylenated sorbitan tristearate (m.p .: 30 ° -35 ° C)

polyoxyethylene stearate polyoxyethylene derivatives of lanolin

- fatty alcohols polyoxyethylenated with 15 to 30 moles of ethylene oxide, such as:

polyoxyethylene ether of cetyl alcohol (mp: 25 ° -38 ° C) polyoxyethylene ether of lauryl alcohol (mp: 36 ° -42 ° C) polyoxyethylene ether of oleic alcohol (mp: 34 ° - 49 ° C) polyoxyethylenated ether of stearyl alcohol (mp: 42 ° -49 ° C) with 1 to 30 moles of ethylene oxide.

■ A solid composition is for example obtained at a minimum melting temperature, by kneading and homogenization, of the excipients / solidifiers, and of the specific active substances, chosen according to the particular formula of the preparer.

The liquefied mass at a temperature little higher than the desired solidification temperature is molded in molds, with imprints suitable for the stores of the devices.

These molds may include cavities arranged to receive turbulence capsules, of a shape suitable for the supports which will support them in the stores of the devices. The composition can thus be poured directly into the capsules.

As for the gadget devices designed to be impregnated, filled or coated with solidified active product, they are obtained by soaking in a bath of active product whose temperature is slightly higher than the freezing temperature.

The excipient / carrier surfaces, which can be incorporated into the active substances to constitute liquid compositions, are characterized by the fact that they must be water-soluble and / or hydroemulsive at predetermined temperatures; and also that they must be capable of hydrosolubilizing and / or hydroemulsifying and / or hydrodispersing the active principles and their possible agglomerated solvents.

In other words, the carrier substances contained in the composition have the task, according to the invention, of intervening to dissolve, solvate, emulsify, instantly disperse,

directly or indirectly in pipes, taps or nozzles, active substances in running water under pressure from showers, flushes and sprinklers.

, A liquefied composition is further characterized by its viscosity coefficient which must be appropriate for the type of device which it supplies. The choice of viscosity coefficients, to be respected, is subject to the size of the capillary tubes and / or to that of the nozzles providing liquefied composition, as well as to the capillary channels, or not, of the keys of taps or of push buttons.

The viscosity coefficient of a liquid composition can be measured at a constant temperature of 20 ° C, according to the Afnor T standard. 30-014 (Afnor cuts of 2.5-4 and 6), between 0.2 and 50 St CGS.

In order to formulate and properly weigh a liquefied composition designed to be poured into the tank of a dispensing device, one must not only take into account the chemical compatibility of the vehicles to be used, in mixture or in combination, with the specific active substances, but also choose substances whose solidification zone does not risk, with cold water, altering the preset viscosity of the final product.

Among the excipients and vehicles of liquid consistency, there may be mentioned:

- liquid fatty alcohols, such as:

hexyl alcohol C 6

octyl alcohol C 8. decyl alcohol C 10 dodecyl alcohol C 12

- mineral oils

- vegetable and animal oils and liquid gylcerides derived from fatty acids, such as:

castor oil tall oil oleic acid octyl ester oleic acid decyl ester 2 octyldodecanol (Eutanol-Dehydag)

myristic acid isopropyl ester palmitic acid isopropyl ester

“Anionic” tensides of liquid consistency at 20 ° C

- Potash soaps and amino soaps of liquid fatty acids.

- Primary and secondary alkyl sulphates, such as: ammonium lauryl sulphate monoethanolamine lauryl sulphate diethanolamine lauryl sulphate triethanolamine lauryl monoethanolamine lauryl ether sulphate triethanolamine lauryl ethersulethurium lauryl methersulphurium methane sulphureturate ethyl methane sulphureturethyethyl methane

- Secondary alkyl sulfates of the Teepol and Tergitol type.

- Alkylarylsulfonates, such as dodecylbenzene- (or toluene) -sulfonate of triethanolamine.

- Alkylethanolamides sulfonates and alkylamidosulfosuccinates, such as mono- and dioctylsulfosuccinates and their dihexylic, dioctyl, diamylic and dibutyl derivatives.

- The sulfated glycerides of animal and vegetable oils, such as:

sodium sulforicinate, ammonium, triethanolamine mono- and sodium glyceryl sulphate diricinoleate sodium monolaurylglyceryl sulphate.

- The alkylpolypeptides.

- Alkylsulfosuccinates, such as sodium dioctylsulfosuccinate.

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Liquid nonionic tensides

- Fatty esters of di- and tri-alcohol, such as pantaerythritis tetraalcohol.

- Esters of sorbitan and polyoxyethylenated fatty acids, such as polyoxyethylenated sorbitan monolaurate (viscosity: 250/400 cPo)

sorbitan monopalmipate p.o.é. (V: 400/600) sorbitan monoleate p.o.é. (V: 375/480)

sorbitan trioleate p.o.é. (V: 250/450).

- Polyoxyethylenated fatty alcohols, such as: polyoxyethylenated laurylether (V: 25/100 cPo).

- Polyoxyethylenated fatty acids and glycerides, such as: oleic acid p.o.é.

castor oil p.o.é.

tallöl p.o.é.

turtle oil p.o.é.

avocado oil p.o.é.

mink oil p.o.é.

Cationic tensides of solid and liquid consistency

- Fatty alkylamines salts, such as hexadecylamine hydrochloride.

- Quaternary ammonium salts, such as:

laurylbenzyltrimethylammonium bromide or chloride bromide or cetyltrimethylammonium chloride octylphenoxymethyldimethylbenzylammonium bromide didecyldimethylammonium bromide.

- Alkylpyridinium salts, such as:

cetylpyridinium chloride laurylpyridinium chloride laurylpyridinium sulfate.

- Sapamines (Ciba), such as citrate, acetate, lactate, sapamine hydrochloride.

In order to cause a stable and immediate emulsion in running water of hydrophobic particles dissociated from the solidified compositions, or released from the solidified compositions, or released from the liquefied compositions, it is advisable to add to certain compositions which are devoid thereof, and to d 'others that contain insufficiently, an absorption wheel of lipophilic particles released by dilution.

The di-, tri- and polyols which are excellent stabilizers for these ultra-fast emulsions are chosen.

These are, in particular, both for liquefied compositions and for solidified compositions, glycerol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols 200, 300, 400, 500 , 600, or the hexitols: sorbitol, mannitol. And, for solidified active products: Carbowax polyethylene glycols of molecular weight from 1000 to 4000 whose melting point varies from 35 to 55 ° C.

In addition, the solidified and liquefied compositions may also contain, in their composition, other excipients / carriers capable of improving their structure. These excipients / carriers will be chosen stabilizers, thickeners, swellers and viscosity correctors according to the invention.

These are, for example:

- non-volatile jellies of gelatin, pectin, agar, starch, colloidal silica, colloidal kaolin, bento-nites, alginates,

- cellulose esters, such as ethylcellulose, methylcelululose, benzylcellulose, carboxymethylcellulose; or polyvinyl alcohols, polyacrylates ...

- mucilages and various gums of carob, carragheen, arabic, tragacanth ...

- various water-soluble resins, such as glycol abietate.

The solidified and liquefied compositions according to the invention allow in particular a very large number of applications, which can be carried out by showers like activated baths.

We can, for example, get

- showers activated by synthetic salts from certain spas, and usually intended for the activation of home baths, with a view to preparing and / or prolonging crenotherapeutic cures,

- stimulating, calming, eupneic, convalescent showers and affusions ...

- insecticide showers, insect repellant showers and more specifically anti-mosquito showers,

- chlorobromo-iodine showers of sea salt, algae showers, sulfur showers, alkaline showers ...

(Perfumery and cosmetology can prepare, at their discretion, specific active compositions, aromatic or aesthetic, with a view to obtaining a new category of products, shower activators.)

- showers of starch, bran, casein, cosmetic milks, sea salt, various alkalizing or acidifying salts, algae, alginates ...

- nascent carbon dioxide showers,

- aromatic foam showers, various specific foams,

- antiperspirant and deodorant showers ...

- finally, scented and scented showers and showers, emanating from subtle olfactory compositions, incorporated into the excipients / carriers described.

Perfumery is thus discovering a new category of products to add to its range of perfumes, perfumes, toilet waters and even colognes.

Each perfumer can thus create, in his personal olfactory notes, water scents for showers, composed with the same perfume concentrates and / or toilet concentrates that he usually uses, by infusing them in alcohol, to obtain his toilet waters and its prestigious perfumes.

In addition, perfume and / or massage showers can be several times daily, without risking contraindications, as is sometimes done by aromatic body rubs with colognes, which use ethyl alcohol as a vehicle.

On the other hand, the sanitary, uniting with perfumery, would find it advantageous to have products activating the water from the hunts. These active products are said to supply dispensing devices, producing deodorizing, covering, odoriferous olfactory notes more subtle than those usually known in this field.

Some examples of solidified compositions

To get a perfumed and flavoring shower:

% weight

Cetyl alcohol C 16 15

Iauric acid monoethanolamide

(Comperlan LM-Dehydag) 28

Iauric acid mono-isopropanolamide

(Comperlan LP-Dehydag) 11

Myristic acid monoethanolamide

(Comperlan MM-Dehydag) 4

Cetostearyl alcohol approx. 30 moles of ethylene oxide

(Emulgin B 3-Dehydag) 10

Concentrated fragrance chosen compound + possible coloring 32

100

A molded cartridge of 3 g of this composition allows, for example, at a temperature of 37-40 ° C, either a continuous scented shower for 20 minutes, or a very large number of scented rinses after body treatments.

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To obtain a mosquito repellent shower:

% weight

Polyoxyethylenated cetylstearyl alcohol

(Mergital CS 33 A-Atlas) 20

Concentrated insect repellant scent (e.g. lemongrass / 5

lavender) 40

Alkylolamides of fatty acids

(mixing to obtain the desired melting zone,

for a cold, lukewarm or hot shower) _40

100 10

A cartridge of 3 g of this composition allows a shower of 15 minutes. Such a shower impregnates the skin with insect repellant principles for a dozen hours.

To get a hot thalassotherapy shower at home between 37 "and 40" C:

% weight

Powdered, unrefined sea salt 80

Cetylstearyl alcohol with 30 moles of ethylene oxide 20

(Eumulgin B 3-Dehydag) D20

100

(Cold or lukewarm showers of sea water can be obtained, reconstituted by the choice of polyoxyethylenated fatty alcohols.)

A cartridge of petrified sea salt is obtained by mixing in a water bath, at approximately 75 ° C, powdered sea salt and selected excipients.

The choice of excipients determines for the product its hydrofusion zone and its disintegration time, under the flush and / or scouring effect of the shower water flow.

As with sea salt, any substance in the form of crystals, granules and powder can be petrified. One can in particular, with this process, obtain showers of sheep's or cow's milk with dry milk powder, skimmed or not.

Here is an example of a liquefied composition.

To activate cold water from flush tanks:

% weight

Concentrated perfume compound 30

Stripping, descaling, coloring substances (for example) 20

Polyoxyethylenated ester of sorbitan and liquid fatty acids 50

Possible addition of viscosity correctors q.s.

100

By a judicious choice of vehicles, necessarily liquefied at a temperature above 0 ° C., we will obtain, with possible viscosity correctors, the predetermined viscosity allowing the liquefied composition soluble and / or emulsifiable in cold water, to extend along the capillary passages and / or cross the sprinklers of the devices.

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Claims (21)

617,643 2 1. Composition of solid, liquid or mixed consistency, containing active substances, intended for the physicochemical activation of running water under pressure, characterized in that it comprises excipients allowing the active substances to be added regularly and gradually pressurized water from irrigators and their nozzles. 2. Solid composition according to claim 1, characterized in that it comprises a mixture of excipients of solid consistency capable of supporting specific active substances solid and / or liquids, the solid excipients being chosen, according to their melting points, in the group of water-soluble, water-soluble, water-dispersing and hydroemulsifying excipients, the combination of the excipient with the active substances being capable of dissociating regularly and gradually, without impregnating with water, under the effleurant and / or scouring effect running water whose temperature can vary between 1 and 65 ° C. 3. Solid composition according to claim 2, characterized in that the excipients are absorbents for liquid active substances, for example wetting, hardening, dispersing, solvating, emulsifying, instantaneous in water, hydrophilic and / or hydrophobic molecules , lipophilic and / or lipophobic of all origins, forming the active part of the composition. 4. Solid composition according to claim 3, characterized in that the absorbent excipients are technical or chemically pure fatty alcohols and which are capable of absorbing several times their weight of liquid active substances, these fatty alcohols being chosen from the group of alcohols fat of solid consistency at room temperature in C 10, C 12, C 14, C 16, C 18 and, in addition, cholesterol and lanolin. 5. Composition according to claim 3, characterized in that the excipients are hardeners, capable of contributing to the solidification of the composition, these excipients being for example oils and fats, totally or partially hydrogenated, fatty acids of solid consistency , fatty acid alkylolamides, as well as pulverulent absorbent fillers and pulverulent hardening fillers chosen from talc, starch, magnesia carbonate, magnesia stearate, zinc stearate, titanium oxide, zinc oxide, alumina oxide, kaolin gel, silica gel. 6. Composition according to claim 3, characterized in that the excipients are anionic surfactant compounds of solid consistency, such as sodium soaps, primary and secondary alkyl sulfates, alkylarylsulfonates, alkylethanola midesulfonates, alkylbenzimidazolsulfonates, mono -, di- and triglyceridesulfates, alkylsulfoacetates, mono-, di- and trigly-ceridesulfoacetates, alkylsulfosuccinates, alkylsulfopropionates. 7. Composition according to claim 3, characterized in that the excipients are nonionic surfactant compounds of solid consistency, such as saponin, fatty esters of di- and tri-alcohol, fatty esters of sorbitol and mannitol, polyoxyethylene fatty esters, polyoxyethylene solid fatty alcohols. 8. Composition according to claim 2, characterized in that it contains up to 50% of its weight of liquid active substances, in particular odoriferous and scenting compositions, insect repellent compositions against mosquito bites, cosmetic compositions, compositions aesthetics, body hygiene compositions. 9. Solid composition according to claim 2, characterized in that it comprises, in addition to excipients of solid consistency, dry and pulverulent active substances, of mineral, vegetable and / or animal origin, such as sea salt, algae , natural milk. 10. Composition according to claim 2, characterized in that it is in a usable naked form or in a perforated capsule fixing the solidified composition, or also of any "gadget object, suspensive to the nozzle of an irrigating device. , which is filled, impregnated or coated with the solidified composition. 11. Liquid or mixed composition, according to claim 1, characterized in that it comprises a mixture of liquid excipients, capable of supporting the specific active substances, these liquid excipients being water-soluble, water-soluble, water-dispersible, water-emulsifiable, cold or hot, the liquid composition having a viscosity which allows them, in an appropriate irrigating device, to follow capillary pathways and / or to cross jets, by suction, propulsion or gravity, the viscosity coefficient being between 0.2 and 50 St CGS. 12. Composition according to claim 11, characterized in that the excipients are wetting agents, dispersants, solvating agents, emulsifiers, instantaneous in water, hydrophilic and / or hydrophobic, lipophilic and / or lipophobic molecules of the substances which form the composition. 13. Composition according to claim 11, characterized in that the excipients are mineral oils, vegetable or animal oils, glycerides, liquid fatty alcohols C 6, C 8, C 10, C 12 technical or chemically pure. 14. Composition according to claim 11, characterized in that the excipients are from liquid anionic surfactant compounds, such as potassium soaps and amino liquid liquid soap soaps, primary and secondary liquid alkyl sulfates, alkylarylsulfonates, alkylethanolamidesulfonates, alkylamidosulfosuccinates, glycerides sulfated from animal and vegetable oils, alkylpolypeptides, alkylsulfopropionates, alkylsulfosuccinates. 15. Composition according to claim 11, characterized in that the excipients are nonionic surfactant compounds of liquid consistency, such as fatty esters of di- and tri-alcohol, esters of sorbitan and polyoxyethylenated fatty acids, polyoxyethylenated liquid fatty alcohols, liquid fatty acids and polyoxyethylenated glycerides. 16. Composition according to claim 1, characterized in that it comprises cationic surfactant compounds such as the alkylamines salts of fatty substances, the quaternary ammonium salts, the alkylpyridinium salts. 17. Composition according to claim 11, characterized in that it additionally comprises thickeners, bulking agents, and viscosity correctors, such as gelatin jellies, pectin, agar, alginates, polyvinyl alcohols, cellulose esters, gums, mucilages, natural or synthetic resins. 18. Composition according to Claim 1, characterized in that it additionally comprises stabilizers of emulsions such as dialcohols, tri-alcohols, polyalcohols, liquids or solids. 19. Composition according to claim 1, characterized in that it comprises as active substances deter-sive, descaling, antiseptic substances and additionally water-soluble dyes, perfumes and deodorants, as well as excipients capable of support. 20. Composition according to claim 1, characterized in that it comprises active fertilizing substances, insecticides, fungicides, parasiticides, weed killers, as well as excipients capable of supporting them. 21. Composition according to claim 11, characterized in that it comprises fertilizing active substances, insecticides, fungicides, parasiticides, weed killers and excipients necessarily liquid at a temperature above 0 ° C in order to obtain, with possible correctors viscosity, a predetermined viscosity, allowing the composition to follow the capillary paths and / or pass through the nozzles of an irrigating device. 5 10 15 20 25 30 35 40 45 50 55 60 65