CH430014A - Additive for industrial heating oil - Google Patents

Additive for industrial heating oil

Info

Publication number
CH430014A
CH430014A CH449264A CH449264A CH430014A CH 430014 A CH430014 A CH 430014A CH 449264 A CH449264 A CH 449264A CH 449264 A CH449264 A CH 449264A CH 430014 A CH430014 A CH 430014A
Authority
CH
Switzerland
Prior art keywords
additive
heating oil
industrial heating
oil
solvent
Prior art date
Application number
CH449264A
Other languages
German (de)
Inventor
Fritz Dipl Chem Ochsner
Original Assignee
Autol Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Autol Ag filed Critical Autol Ag
Priority to CH449264A priority Critical patent/CH430014A/en
Publication of CH430014A publication Critical patent/CH430014A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Catalysts (AREA)

Description

  

  Zusatzmittel für     Industrieheizöl       Die vorliegende     Erfindung    betrifft ein Zusatzmittel  für Industrieheizöl.  



  Bei der Verbrennung von Industrieheizöl bilden sich  bekanntlich Schwefeloxyde. Diese können durch Ein  blasen von     Magnesiumoxyd    oder     Dolomit    in die     ölbe-          feuerten    Heizanlagen gebunden werden. Der Grad dieser  Bindung hängt von dem Grad der Oxydation von S02  zu     S03    ab, die entweder in der Gasphase oder an einem  Absorptionsmedium vor sich gehen kann.  



  Es wurde nun gefunden, dass man den Absorptions  wirkungsgrad erhöhen kann, indem man dem Heizöl  Oxydationskatalysatoren zusetzt, die entweder in gelö  ster oder in     disperser    Form die     Überführung    des     S02    in       S03    beim Verbrennungsvorgang im     Rauchgasstrom     oder am Absorptionsmittel     begünstigen.     



  Das     erfindungsgemässe    Zusatzmittel für Industrie  heizöl ist daher dadurch gekennzeichnet, dass es einen  Oxydationskatalysator, z. B. in einem     Lösungs-    oder       Dispersionsmittel        Solventnaphtha,    enthält.  



  Als Oxydationskatalysatoren kommen die Metalle  und Metallverbindungen der 2., 5., 6., 7. und B.     Gruppe     des periodischen Systems, entweder für sich allein oder  in Mischung, in Frage. Bevorzugt sind metallorganische  Verbindungen dieser Elemente.  



  Um den     Zerstäubungseffekt    des Heizöles an der       Brennerdüse    zu verbessern, kann man noch ein     Disper-          giermittel    in Form von öllöslichen     Erdalkaliverbindun-          gen,    z. B. ein Magnesium-,     Calcium-    oder     Bariumsulfon-          at,    zusetzen.

      2  <I>Beispiel 1</I>       Einem        Industrieheizöl        werden        0,01        bis    5     %        Cal-          ciumsulfonat        und        0,001        bis    3     %        Ferrocen        (in        Solvent-          naphtha)    zugesetzt.  



  <I>Beispiel 2</I>       Einem        Industrieheizöl        werden        0,01        bis    5     %        Magne-          siumnaphthenat        und        0,001        bis    3     %        Ferrocen        (in        Sol-          VeritnaDhtha)    zugesetzt.



  Additive for Industrial Fuel Oil The present invention relates to an additive for industrial fuel oil.



  It is well known that sulfur oxides are formed when industrial heating oil is burned. These can be bound by blowing magnesium oxide or dolomite into the oil-fired heating systems. The degree of this binding depends on the degree of oxidation from SO2 to SO3, which can take place either in the gas phase or on an absorption medium.



  It has now been found that the absorption efficiency can be increased by adding oxidation catalysts to the heating oil, which either in dissolved or dispersed form favor the conversion of S02 into S03 during the combustion process in the flue gas stream or on the absorbent.



  The additive according to the invention for industrial heating oil is therefore characterized in that it contains an oxidation catalyst, e.g. B. in a solvent or dispersant solvent naphtha contains.



  The metals and metal compounds of groups 2, 5, 6, 7 and B of the periodic table, either alone or as a mixture, are suitable as oxidation catalysts. Organometallic compounds of these elements are preferred.



  In order to improve the atomization effect of the fuel oil at the burner nozzle, a dispersant in the form of oil-soluble alkaline earth compounds, e.g. B. a magnesium, calcium or barium sulfonate add.

      2 <I> Example 1 </I> 0.01 to 5% calcium sulfonate and 0.001 to 3% ferrocene (in solvent naphtha) are added to an industrial heating oil.



  <I> Example 2 </I> 0.01 to 5% magnesium naphthenate and 0.001 to 3% ferrocene (in Sol-VeritnaDhtha) are added to an industrial heating oil.

Claims (1)

PATENTANSPRUCH Zusatzmittel für Industrieheizöl, dadurch gekenn zeichnet, dass es einen Oxydationskatalysator in einem Lösungs- oder Dispersionsmittel enthält. UNTERANSPRÜCHE 1. Zusatzmittel nach Patentanspruch, dadurch ge kennzeichnet, dass der Oxydationskatalysator ein Metall oder eine Metallverbindung der 2., 5., 6., 7. oder B. Gruppe des periodischen Systems oder eine Mischung derselben ist. 2. Zusatzmittel nach Patentanspruch, dadurch ge kennzeichnet, dass das Lösungsmittel Solventnaphtha ist. 3. PATENT CLAIM Additive for industrial heating oil, characterized in that it contains an oxidation catalyst in a solvent or dispersion medium. SUBClaims 1. Additive according to claim, characterized in that the oxidation catalyst is a metal or a metal compound of the 2nd, 5th, 6th, 7th or B group of the periodic table or a mixture thereof. 2. Additive according to claim, characterized in that the solvent is solvent naphtha. 3. Zusatzmittel nach Patentanspruch, dadurch ge kennzeichnet, -dass es ein Dispergiermittel, z. B. ein Magnesium, Calcium- oder Bariumsulfonat, enthält. Additive according to claim, characterized in that it is a dispersant, e.g. B. a magnesium, calcium or barium sulfonate contains.
CH449264A 1964-04-09 1964-04-09 Additive for industrial heating oil CH430014A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CH449264A CH430014A (en) 1964-04-09 1964-04-09 Additive for industrial heating oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH449264A CH430014A (en) 1964-04-09 1964-04-09 Additive for industrial heating oil

Publications (1)

Publication Number Publication Date
CH430014A true CH430014A (en) 1967-02-15

Family

ID=4277109

Family Applications (1)

Application Number Title Priority Date Filing Date
CH449264A CH430014A (en) 1964-04-09 1964-04-09 Additive for industrial heating oil

Country Status (1)

Country Link
CH (1) CH430014A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2497820A1 (en) * 1981-01-15 1982-07-16 Drew Chem Corp ADDITIVE AND METHOD FOR IMPROVING THE COMBUSTION OF A FUEL FOR A DIESEL ENGINE

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2497820A1 (en) * 1981-01-15 1982-07-16 Drew Chem Corp ADDITIVE AND METHOD FOR IMPROVING THE COMBUSTION OF A FUEL FOR A DIESEL ENGINE

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