CA2938060A1 - Method for producing polyurethane rigid foams and polyisocyanurate rigid foams - Google Patents

Method for producing polyurethane rigid foams and polyisocyanurate rigid foams Download PDF

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Publication number
CA2938060A1
CA2938060A1 CA2938060A CA2938060A CA2938060A1 CA 2938060 A1 CA2938060 A1 CA 2938060A1 CA 2938060 A CA2938060 A CA 2938060A CA 2938060 A CA2938060 A CA 2938060A CA 2938060 A1 CA2938060 A1 CA 2938060A1
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CA
Canada
Prior art keywords
component
mol
polyol
polyester polyol
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2938060A
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English (en)
French (fr)
Inventor
Tobias KALUSCHKE
Gunnar Kampf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CA2938060A1 publication Critical patent/CA2938060A1/en
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/14—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4288—Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/487—Polyethers containing cyclic groups
    • C08G18/4879—Polyethers containing cyclic groups containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0038—Use of organic additives containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/66—Substances characterised by their function in the composition
    • C08L2666/84—Flame-proofing or flame-retarding additives

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
CA2938060A 2014-02-11 2015-01-27 Method for producing polyurethane rigid foams and polyisocyanurate rigid foams Abandoned CA2938060A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14154645 2014-02-11
EP14154645.7 2014-02-11
PCT/EP2015/051569 WO2015121057A1 (de) 2014-02-11 2015-01-27 Verfahren zur herstellung von polyurethan-hartschäumen und polyisocyanurat-hartschäumen

Publications (1)

Publication Number Publication Date
CA2938060A1 true CA2938060A1 (en) 2015-08-20

Family

ID=50071499

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2938060A Abandoned CA2938060A1 (en) 2014-02-11 2015-01-27 Method for producing polyurethane rigid foams and polyisocyanurate rigid foams

Country Status (12)

Country Link
US (1) US10259906B2 (enExample)
EP (1) EP3105274B1 (enExample)
JP (1) JP2017509738A (enExample)
KR (1) KR102338624B1 (enExample)
CN (1) CN105980438A (enExample)
BR (1) BR112016017431A8 (enExample)
CA (1) CA2938060A1 (enExample)
ES (1) ES2673860T3 (enExample)
MX (1) MX367477B (enExample)
PL (1) PL3105274T3 (enExample)
RU (1) RU2016136382A (enExample)
WO (1) WO2015121057A1 (enExample)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3091147C (en) 2018-02-16 2022-03-08 H.B. Fuller Company Electric cell potting compound and method of making
JP7323106B2 (ja) * 2018-04-10 2023-08-08 ステパン カンパニー 改善された低温ｒ値を有するポリオールブレンド及び硬質フォーム
CA3109540A1 (en) * 2018-08-16 2020-02-20 Basf Se Environmentally friendly driven polyurethane spray foam systems
WO2020089439A1 (en) * 2018-11-02 2020-05-07 Covestro Deutschland Ag A rigid polyurethane precast panel
CN111138618A (zh) * 2018-11-02 2020-05-12 科思创德国股份有限公司 聚氨酯硬质预制板
CN114213797A (zh) * 2022-01-11 2022-03-22 陈小云 一种耐磨防刮smc模塑料及其制备方法
CN119013337A (zh) 2022-04-04 2024-11-22 巴斯夫欧洲公司 用于从聚氨酯硬质泡沫回收基于亚磷酸酯的阻燃剂的价值链返回方法
EP4612224A1 (en) 2022-11-03 2025-09-10 Basf Se Value chain return process for the recovery of not bonded additives by extraction from polyurethane or polyisocyanurate rigid foams and depolymerization of the polyurethane rigid foams
CN120153019A (zh) 2022-11-03 2025-06-13 巴斯夫欧洲公司 用于从废聚氨酯和聚异氰脲酸酯硬质泡沫的解聚中回收聚合亚甲基亚苯基胺（pMDA）作为其HCl盐的价值链返回方法
WO2025016860A1 (en) 2023-07-14 2025-01-23 Basf Se Process for recycling polyurethane foams
WO2025016927A1 (en) 2023-07-14 2025-01-23 Basf Se Method for selecting, from a foam mix comprising one or more foam pieces, target foam pieces, method and pre-processing arrangement for pre-processing a foam mix for feeding a reactor of a recycling process and respective computer program
WO2025016900A1 (en) 2023-07-14 2025-01-23 Basf Se Process for recycling polyurethane waste through remonomerization by hydro ammonolysis
WO2025016952A1 (en) 2023-07-14 2025-01-23 Basf Se Method and system for classifying polyurethane objects from a waste stream
EP4491364A1 (en) 2023-07-14 2025-01-15 Basf Se Method and pre-processing arrangement for pre-processing a foam mix for feeding a reactor
WO2025016903A1 (en) 2023-07-14 2025-01-23 Basf Se Recovery of polyesterols from polyesterol-based polyurethanes via hydrolysis and re-condensation
WO2025016861A1 (en) 2023-07-14 2025-01-23 Basf Se Method and pre-processing arrangement for pre-processing a foam mix for feeding a reactor of a recycling process for recovering raw materials and respective computer program
WO2025016920A1 (en) 2023-07-14 2025-01-23 Basf Se Process for autocatalytic hydroglycolytic or hydrolytic cleavage of waste streams containing polyurethane
WO2025016934A1 (en) 2023-07-14 2025-01-23 Basf Se Recycling of pu-softfoams with graft polyol content
WO2025190718A1 (en) 2024-03-13 2025-09-18 Basf Se Method for selecting target foam pieces from a vehicle scrap material
WO2025190719A1 (en) 2024-03-13 2025-09-18 Basf Se Method for selecting and pre-processing target foam elements from a vehicle scrap material
WO2025190721A1 (en) 2024-03-13 2025-09-18 Basf Se Method for recycling a polymer material from a vehicle scrap material

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1003714B (de) 1956-01-25 1957-03-07 Glanzstoff Ag Verfahren zum Abbau von Polyaethylenterephthalat zu Terephthalsaeuredimethylester
US4529744A (en) * 1982-10-25 1985-07-16 Stepan Company Compatibilized aromatic polyester polyols
US5051528A (en) 1990-04-24 1991-09-24 Eastman Kodak Company Recovery process for ethylene glycol and dimethylterephthalate
US6461536B2 (en) * 1998-02-09 2002-10-08 Basf Corporation Stable polyester polyol composition
WO2006100756A1 (ja) * 2005-03-22 2006-09-28 Kawasaki Kasei Chemicals Ltd. ポリエステルポリオールの製造方法
CA2629090C (en) * 2005-11-14 2014-05-27 Dow Global Technologies Inc. Method of molding rigid polyurethane foams with enhanced thermal conductivity
SI2340269T1 (sl) 2008-10-15 2013-01-31 Basf Se Poliesterski polioli na bazi terefthalične kisline
CA2819569C (en) * 2010-12-02 2020-01-14 Basf Se Polyester polyols based on aromatic dicarboxylic acids
US20120214891A1 (en) * 2011-02-23 2012-08-23 Basf Se Polyester polyols based on aromatic dicarboxylic acids
HUE025196T2 (en) * 2011-03-22 2016-02-29 Basf Se PU rigid foam with low heat and good thermal stability
CA2862774C (en) * 2012-01-02 2020-08-18 Basf Se Producing rigid polyurethane foams and rigid polyisocyanurate foams
US20130251975A1 (en) * 2012-03-23 2013-09-26 Basf Se Producing rigid polyurethane foams and rigid polyisocyanurate foams

Also Published As

Publication number Publication date
KR20160119838A (ko) 2016-10-14
MX367477B (es) 2019-08-23
EP3105274A1 (de) 2016-12-21
US10259906B2 (en) 2019-04-16
PL3105274T3 (pl) 2018-08-31
RU2016136382A3 (enExample) 2018-07-25
WO2015121057A1 (de) 2015-08-20
ES2673860T3 (es) 2018-06-26
JP2017509738A (ja) 2017-04-06
US20160347904A1 (en) 2016-12-01
MX2016009946A (es) 2016-11-11
BR112016017431A8 (pt) 2020-06-16
RU2016136382A (ru) 2018-03-15
KR102338624B1 (ko) 2021-12-14
CN105980438A (zh) 2016-09-28
EP3105274B1 (de) 2018-03-14

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Effective date: 20200124

FZDE Discontinued

Effective date: 20220727

FZDE Discontinued

Effective date: 20220727