CA2895232C - Small crystal zsm-5, its synthesis and use - Google Patents

Small crystal zsm-5, its synthesis and use Download PDF

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Publication number
CA2895232C
CA2895232C CA2895232A CA2895232A CA2895232C CA 2895232 C CA2895232 C CA 2895232C CA 2895232 A CA2895232 A CA 2895232A CA 2895232 A CA2895232 A CA 2895232A CA 2895232 C CA2895232 C CA 2895232C
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molecular sieve
zsm
theta
peak
product
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French (fr)
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CA2895232A1 (en
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Allen W. Burton
Christine E. Kliewer
Mobae Afeworki
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ExxonMobil Chemical Patents Inc
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ExxonMobil Chemical Patents Inc
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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    • B01J35/617—500-1000 m2/g
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    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/007—Borosilicates
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    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
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    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • C—CHEMISTRY; METALLURGY
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    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
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    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
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    • C07C5/52—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor with a hydrocarbon as an acceptor, e.g. hydrocarbon disproportionation, i.e. 2CnHp -> CnHp+q + CnHp-q
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
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    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
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    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/86—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by NMR- or ESR-data
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    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
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    • C07—ORGANIC CHEMISTRY
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    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/46—Iron group metals or copper
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
CA2895232A 2012-12-21 2013-11-22 Small crystal zsm-5, its synthesis and use Active CA2895232C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261740908P 2012-12-21 2012-12-21
US61/740,908 2012-12-21
EP13155722.5 2013-02-19
EP13155722 2013-02-19
PCT/US2013/071456 WO2014099262A1 (en) 2012-12-21 2013-11-22 Small crystal zsm-5, its synthesis and use

Publications (2)

Publication Number Publication Date
CA2895232A1 CA2895232A1 (en) 2014-06-26
CA2895232C true CA2895232C (en) 2020-07-28

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CA2895232A Active CA2895232C (en) 2012-12-21 2013-11-22 Small crystal zsm-5, its synthesis and use

Country Status (10)

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US (2) US10081552B2 (OSRAM)
EP (3) EP3056470B1 (OSRAM)
JP (1) JP6238377B2 (OSRAM)
KR (1) KR102166191B1 (OSRAM)
CN (2) CN104870367B (OSRAM)
CA (1) CA2895232C (OSRAM)
RU (1) RU2640759C2 (OSRAM)
SG (2) SG11201503973UA (OSRAM)
WO (1) WO2014099262A1 (OSRAM)
ZA (1) ZA201503617B (OSRAM)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11201503973UA (en) * 2012-12-21 2015-06-29 Exxonmobil Chem Patents Inc Small crystal zsm-5, its synthesis and use
US10053403B2 (en) 2015-02-04 2018-08-21 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes
US10118165B2 (en) 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes
WO2016129659A1 (ja) * 2015-02-13 2016-08-18 東ソー株式会社 ペンタシル型ゼオライト及びその製造方法
US9851313B2 (en) * 2015-03-03 2017-12-26 Panalytical B.V. Quantitative X-ray analysis—ratio correction
CA3015142C (en) 2016-02-19 2022-02-15 Exxonmobil Research And Engineering Company Small crystal, high surface area emm-30 zeolites, their synthesis and use
US10273161B2 (en) 2017-01-11 2019-04-30 Chevron U.S.A. Inc. Synthesis of MFI framework type molecular sieves
CN113454027B (zh) * 2019-02-27 2023-06-27 雪佛龙美国公司 分子筛ssz-115、其合成和用途
EP4017940A1 (en) 2019-08-20 2022-06-29 ExxonMobil Research and Engineering Company Metal-organic framework catalysts and their use in catalytic cracking
US10737946B1 (en) * 2019-08-29 2020-08-11 Chevron U.S.A. Inc. Synthesis of aluminum-containing molecular sieves of SEW framework type
JP2022163831A (ja) * 2021-04-15 2022-10-27 東ソー株式会社 Ｍｆｉ型ゼオライト
EP4406646B1 (en) 2023-01-27 2025-10-01 Hindustan Petroleum Corporation Limited Nano size crystal zsm-5 and its preparation and applications thereof
WO2025058925A1 (en) 2023-09-12 2025-03-20 ExxonMobil Technology and Engineering Company Zeolitic materials in polyolefin decomposition via pyrolysis

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
JPS59184723A (ja) 1983-04-06 1984-10-20 Res Assoc Petroleum Alternat Dev<Rapad> 結晶性メタロシリケ−トの製造法
US5240892A (en) 1987-09-02 1993-08-31 Mobil Oil Corporation Small crystal ZSM-5, as a catalyst
EP0514715B1 (en) * 1991-05-17 1997-12-29 Asahi Kasei Kogyo Kabushiki Kaisha Method for producing a particulate zeolite
GB9122498D0 (en) * 1991-10-23 1991-12-04 Exxon Chemical Patents Inc Process for preparing uniform mfitype zeolite crystals
ZA933879B (en) * 1992-06-05 1993-12-27 Exxon Chemical Patents Inc ZSM-5-zeolite
ES2172667T3 (es) * 1995-06-06 2002-10-01 Exxonmobil Oil Corp Cristal de grandes dimensiones zsm-5, sintesis y utilizacion del mismo.
DE19951781A1 (de) 1999-10-27 2001-05-03 Sued Chemie Ag Verfahren zur Herstellung von synthetischen Zeolithen mit MFI-Struktur
WO2001049607A1 (en) 2000-01-05 2001-07-12 Exxon Chemical Patents Inc. Porous inorganic macrostructure materials and process for their preparation
CN1100005C (zh) * 2000-06-28 2003-01-29 中国科学院山西煤炭化学研究所 导向剂法快速合成zsm－5分子筛的方法
EP1587756A4 (en) 2002-12-30 2011-07-06 Sk Energy Co Ltd PROCESS FOR THE PREPARATION OF ZSM-5 BY VARIABLE TEMPERATURE WITHOUT ORGANIC STENCIL MATERIAL
CN1281494C (zh) * 2004-06-29 2006-10-25 中国石油化工股份有限公司 一种小晶粒zsm－5沸石的制备方法
ITMI20042136A1 (it) * 2004-11-08 2005-02-08 Sasol Italy S P A Procedimento perfezionato per la preparazione di zeoliti zsm-5
RU2313486C1 (ru) 2006-04-12 2007-12-27 Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") Синтетический цеолит и способ его получения
RU2312063C1 (ru) 2006-04-12 2007-12-10 Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") Синтетический пористый кристаллический материал и способ его получения
RU2313488C1 (ru) 2006-04-24 2007-12-27 Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") Синтетический цеолит и способ его получения
CN100455511C (zh) * 2006-11-10 2009-01-28 南京工业大学 一种合成小晶粒zsm-5沸石分子筛的方法
CN101733143B (zh) * 2008-11-21 2012-08-01 中国石油化工股份有限公司 小晶粒zsm-5分子筛及其用途
KR101147007B1 (ko) * 2009-02-02 2012-05-22 한국과학기술원 싸이클릭다이암모늄을 이용한 메조기공 및 마크로기공을 추가적으로 포함하는 ｂｅａ, ｍｔｗ, ｍｆｉ 구조의 제올라이트의 제조과정
US8951498B2 (en) * 2010-07-30 2015-02-10 University Of Iowa Research Foundation Synthesis of hierarchical nanocrystalline zeolites with controlled particle size and mesoporosity
CN102372284B (zh) * 2010-08-23 2013-01-09 中国石油化工股份有限公司 小晶粒zsm-5沸石的制备方法
KR101923248B1 (ko) 2011-08-04 2018-11-28 엑손모빌 케미칼 패턴츠 인코포레이티드 Emm-23 분자체 물질, 그의 합성 및 용도
CN102502696B (zh) 2011-11-16 2014-04-23 大连理工大学 一种zsm-5沸石的合成方法
SG11201503973UA (en) * 2012-12-21 2015-06-29 Exxonmobil Chem Patents Inc Small crystal zsm-5, its synthesis and use
WO2014099261A1 (en) * 2012-12-21 2014-06-26 Exxonbobil Chemical Patents Inc. Synthesis of zsm-5

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