CA2880075C - High efficiency processes for olefins, alkynes, and hydrogen co-production from light hydrocarbons such as methane - Google Patents

High efficiency processes for olefins, alkynes, and hydrogen co-production from light hydrocarbons such as methane Download PDF

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Publication number
CA2880075C
CA2880075C CA2880075A CA2880075A CA2880075C CA 2880075 C CA2880075 C CA 2880075C CA 2880075 A CA2880075 A CA 2880075A CA 2880075 A CA2880075 A CA 2880075A CA 2880075 C CA2880075 C CA 2880075C
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Canada
Prior art keywords
stream
hydrogen
methane
carbon dioxide
zone
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CA2880075A
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English (en)
French (fr)
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CA2880075A1 (en
Inventor
Antoine Negiz
Robert B. James
Carl J. Stevens
Paul T. Barger
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Honeywell UOP LLC
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UOP LLC
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/78—Processes with partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/005—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor carried out at high temperatures, e.g. by pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/10—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002—Nozzle-type elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
    • C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
    • C10G9/38—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours produced by partial combustion of the material to be cracked or by combustion of another hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C3/00—Combustion apparatus characterised by the shape of the combustion chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C6/00—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
    • F23C6/04—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
    • F23C6/042—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with fuel supply in stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2201/00—Staged combustion
    • F23C2201/10—Furnace staging
    • F23C2201/102—Furnace staging in horizontal direction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA2880075A 2012-08-21 2013-08-12 High efficiency processes for olefins, alkynes, and hydrogen co-production from light hydrocarbons such as methane Active CA2880075C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261691369P 2012-08-21 2012-08-21
US61/691,369 2012-08-21
PCT/US2013/054469 WO2014031371A1 (en) 2012-08-21 2013-08-12 High efficiency processes for olefins, alkynes, and hydrogen co-production from light hydrocarbons such as methane

Publications (2)

Publication Number Publication Date
CA2880075A1 CA2880075A1 (en) 2014-02-27
CA2880075C true CA2880075C (en) 2018-01-16

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2880075A Active CA2880075C (en) 2012-08-21 2013-08-12 High efficiency processes for olefins, alkynes, and hydrogen co-production from light hydrocarbons such as methane

Country Status (13)

Country Link
US (1) US20140058149A1 (cg-RX-API-DMAC7.html)
EP (1) EP2888036B1 (cg-RX-API-DMAC7.html)
CN (1) CN104540583A (cg-RX-API-DMAC7.html)
AU (2) AU2013306230A1 (cg-RX-API-DMAC7.html)
BR (1) BR112015003265A2 (cg-RX-API-DMAC7.html)
CA (1) CA2880075C (cg-RX-API-DMAC7.html)
EA (1) EA033837B1 (cg-RX-API-DMAC7.html)
IN (1) IN2015DN00628A (cg-RX-API-DMAC7.html)
MX (1) MX2015001602A (cg-RX-API-DMAC7.html)
MY (1) MY177598A (cg-RX-API-DMAC7.html)
SG (1) SG11201500565YA (cg-RX-API-DMAC7.html)
WO (1) WO2014031371A1 (cg-RX-API-DMAC7.html)
ZA (1) ZA201501240B (cg-RX-API-DMAC7.html)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
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US10029957B2 (en) 2012-08-21 2018-07-24 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
US10160697B2 (en) 2012-08-21 2018-12-25 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
EA031840B1 (ru) 2013-11-19 2019-02-28 Юниверсити Оф Вашингтон Тру Итс Сентер Фор Коммершлайзейшн Системы реакторов на основе сверхзвуковой ударной волны и способы синтезирования олефин-углеводородных газов
US9732015B2 (en) 2015-05-29 2017-08-15 Uop Llc Process for the selective hydrogenation of acetylene to ethylene
CA2981187C (en) * 2015-06-23 2019-08-27 Uop Llc Pyrolytic reactor and method of using
PL3313806T3 (pl) * 2015-06-23 2021-07-26 Uop Llc Zintegrowany sposób pirolizy i przekształcania oksygenatu w olefinę
GB2551314B (en) * 2016-06-06 2021-03-17 Kew Tech Limited Equilibium approach reactor
MA45401A (fr) * 2016-06-18 2019-04-24 Think Tank 42 Pty Ltd Procédé et système de capture et de recyclage du carbone
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US10550731B2 (en) * 2017-01-13 2020-02-04 LLT International (Ireland) Ltd. Systems and methods for generating steam by creating shockwaves in a supersonic gaseous vortex
RU2767113C2 (ru) * 2017-06-21 2022-03-16 Юоп Ллк Устройство и способ конверсии метана с использованием сверхзвукового проточного реактора
CN119215805A (zh) 2018-12-10 2024-12-31 埃科纳能源公司 用于产生一种或多种产物的方法和反应器
EP3715320A1 (en) 2019-03-27 2020-09-30 Siemens Aktiengesellschaft Method for generating a gas-product
US11299442B2 (en) * 2020-03-31 2022-04-12 Uop Llc Process for producing acetylene and ethylene
US20220064083A1 (en) * 2020-05-26 2022-03-03 Uop Llc Integrated process for producing acetylene
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Also Published As

Publication number Publication date
EA201500262A1 (ru) 2015-07-30
US20140058149A1 (en) 2014-02-27
CA2880075A1 (en) 2014-02-27
WO2014031371A1 (en) 2014-02-27
EA033837B1 (ru) 2019-12-02
CN104540583A (zh) 2015-04-22
IN2015DN00628A (cg-RX-API-DMAC7.html) 2015-06-26
SG11201500565YA (en) 2015-02-27
EP2888036A1 (en) 2015-07-01
AU2016250335A1 (en) 2016-11-10
BR112015003265A2 (pt) 2017-08-08
ZA201501240B (en) 2016-10-26
MY177598A (en) 2020-09-22
AU2013306230A1 (en) 2015-02-19
MX2015001602A (es) 2015-05-07
EP2888036A4 (en) 2016-05-11
EP2888036B1 (en) 2020-05-13

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