CA2878261C - Polymerization processes using reactor components suspended in hydrocarbon gels - Google Patents
Polymerization processes using reactor components suspended in hydrocarbon gels Download PDFInfo
- Publication number
- CA2878261C CA2878261C CA2878261A CA2878261A CA2878261C CA 2878261 C CA2878261 C CA 2878261C CA 2878261 A CA2878261 A CA 2878261A CA 2878261 A CA2878261 A CA 2878261A CA 2878261 C CA2878261 C CA 2878261C
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- CA
- Canada
- Prior art keywords
- reactor
- hydrocarbon
- catalyst
- polymerization
- gel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 122
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 119
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 118
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 80
- 239000000499 gel Substances 0.000 title description 81
- 239000000203 mixture Substances 0.000 claims abstract description 53
- 239000007788 liquid Substances 0.000 claims abstract description 49
- 229920000642 polymer Polymers 0.000 claims abstract description 45
- 150000001336 alkenes Chemical class 0.000 claims abstract description 44
- 239000003349 gelling agent Substances 0.000 claims abstract description 41
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 26
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 9
- 239000003054 catalyst Substances 0.000 claims description 149
- -1 polyethylene Polymers 0.000 claims description 101
- 239000000654 additive Substances 0.000 claims description 61
- 230000000996 additive effect Effects 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 46
- 239000012190 activator Substances 0.000 claims description 44
- 239000002480 mineral oil Substances 0.000 claims description 38
- 230000008569 process Effects 0.000 claims description 24
- 239000012968 metallocene catalyst Substances 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 21
- 235000010446 mineral oil Nutrition 0.000 claims description 20
- 238000001816 cooling Methods 0.000 claims description 14
- 239000004698 Polyethylene Substances 0.000 claims description 11
- 229940083916 aluminum distearate Drugs 0.000 claims description 11
- RDIVANOKKPKCTO-UHFFFAOYSA-K aluminum;octadecanoate;hydroxide Chemical compound [OH-].[Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O RDIVANOKKPKCTO-UHFFFAOYSA-K 0.000 claims description 11
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims description 10
- 229940063655 aluminum stearate Drugs 0.000 claims description 10
- 229920000573 polyethylene Polymers 0.000 claims description 10
- 239000000945 filler Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 10
- 239000001257 hydrogen Substances 0.000 abstract description 10
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 10
- 150000001875 compounds Chemical class 0.000 description 50
- 229940042472 mineral oil Drugs 0.000 description 35
- 239000003446 ligand Substances 0.000 description 32
- 125000001183 hydrocarbyl group Chemical group 0.000 description 29
- 229910052751 metal Inorganic materials 0.000 description 29
- 239000002184 metal Substances 0.000 description 29
- 239000002002 slurry Substances 0.000 description 29
- 125000004429 atom Chemical group 0.000 description 26
- 125000000217 alkyl group Chemical group 0.000 description 21
- 239000000243 solution Substances 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 239000000178 monomer Substances 0.000 description 18
- 239000007789 gas Substances 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
- 150000004678 hydrides Chemical class 0.000 description 15
- 239000002245 particle Substances 0.000 description 14
- WTFAGPBUAGFMQX-UHFFFAOYSA-N 1-[2-[2-(2-aminopropoxy)propoxy]propoxy]propan-2-amine Chemical compound CC(N)COCC(C)OCC(C)OCC(C)N WTFAGPBUAGFMQX-UHFFFAOYSA-N 0.000 description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 13
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- 125000001424 substituent group Chemical group 0.000 description 12
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 9
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- 229910052782 aluminium Inorganic materials 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
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- 239000011651 chromium Substances 0.000 description 8
- 230000000737 periodic effect Effects 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 150000003623 transition metal compounds Chemical class 0.000 description 8
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 125000000129 anionic group Chemical group 0.000 description 7
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
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- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 6
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
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- 125000000304 alkynyl group Chemical group 0.000 description 6
- 125000004104 aryloxy group Chemical group 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229910052804 chromium Inorganic materials 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 125000004122 cyclic group Chemical group 0.000 description 6
- 229910001873 dinitrogen Inorganic materials 0.000 description 6
- 229910052732 germanium Inorganic materials 0.000 description 6
- 125000004404 heteroalkyl group Chemical group 0.000 description 6
- 125000001072 heteroaryl group Chemical group 0.000 description 6
- 229920000098 polyolefin Polymers 0.000 description 6
- 238000001694 spray drying Methods 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 125000004414 alkyl thio group Chemical group 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229920001400 block copolymer Polymers 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 150000004820 halides Chemical class 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 125000005842 heteroatom Chemical group 0.000 description 5
- 125000000623 heterocyclic group Chemical group 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
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- 230000003068 static effect Effects 0.000 description 5
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- 125000000547 substituted alkyl group Chemical group 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 4
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 4
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 4
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
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- 238000012685 gas phase polymerization Methods 0.000 description 4
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 238000007689 inspection Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000006384 oligomerization reaction Methods 0.000 description 4
- 239000011236 particulate material Substances 0.000 description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 125000003107 substituted aryl group Chemical group 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
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- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
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- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 229920006300 shrink film Polymers 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- SCABQASLNUQUKD-UHFFFAOYSA-N silylium Chemical class [SiH3+] SCABQASLNUQUKD-UHFFFAOYSA-N 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229920006302 stretch film Polymers 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229940105125 zinc myristate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229940057977 zinc stearate Drugs 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C08F2/005—Scale prevention in a polymerisation reactor or its auxiliary parts by addition of a scale inhibitor to the polymerisation medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261695713P | 2012-08-31 | 2012-08-31 | |
| US61/695,713 | 2012-08-31 | ||
| PCT/US2013/055994 WO2014035763A1 (en) | 2012-08-31 | 2013-08-21 | Polymerization processes using reactor components suspended in hydrocarbon gels |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2878261A1 CA2878261A1 (en) | 2014-03-06 |
| CA2878261C true CA2878261C (en) | 2020-09-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2878261A Active CA2878261C (en) | 2012-08-31 | 2013-08-21 | Polymerization processes using reactor components suspended in hydrocarbon gels |
Country Status (10)
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6739186B2 (ja) * | 2016-02-19 | 2020-08-12 | 三井化学株式会社 | オレフィン重合体の製造方法 |
| KR102546537B1 (ko) * | 2021-05-10 | 2023-06-23 | 지에스칼텍스 주식회사 | 올레핀 중합용 메탈로센 담지 촉매 조성물 및 이의 제조 방법 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3780135A (en) * | 1970-07-21 | 1973-12-18 | Phillips Petroleum Co | Introducing catalyst into a reactor |
| US4351913A (en) * | 1981-02-19 | 1982-09-28 | Siecor Corporation | Filling materials for electrical and light waveguide communications cables |
| US6149693A (en) | 1996-02-06 | 2000-11-21 | Ethox Chemicals, Inc. | Hydrocarbon gels useful in formation fracturing |
| US6433068B1 (en) * | 1997-03-07 | 2002-08-13 | David S. Morrison | Hydrocarbon gels as suspending and dispersing agents and products |
| US6025411A (en) * | 1997-06-23 | 2000-02-15 | Block Drug Company, Inc. | Denture adhesive comprising a polymeric activator and methods of preparing the same |
| US6933258B2 (en) * | 2000-12-19 | 2005-08-23 | Univation Technologies, L.L.C. | Catalyst composition and methods for its preparation and use in a polymerization process |
| EP1489110B1 (en) | 2003-06-20 | 2012-01-18 | Borealis Polymers Oy | Method for preparing an olefin polymerisation catalyst composition |
| DE602004015128D1 (de) * | 2004-12-17 | 2008-08-28 | Borealis Tech Oy | Verfahren zur Polymerisation von Olefinen in Gegenwart eines Olefin Polymerisationskatalysators |
| US8263047B2 (en) | 2005-09-29 | 2012-09-11 | Wickenhauser Alan J | Topical anesthetic for dental procedures |
| CN102066429B (zh) * | 2008-06-13 | 2015-01-28 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂体系 |
| US7947631B2 (en) | 2008-06-24 | 2011-05-24 | Brine-Add Fluids Ltd. | Gelled hydrocarbons for oilfield processes and methods of use |
| CN102471408A (zh) * | 2009-07-28 | 2012-05-23 | 尤尼威蒂恩技术有限责任公司 | 使用负载型受限几何构型催化剂的聚合方法 |
| JP5618289B2 (ja) * | 2010-07-07 | 2014-11-05 | 国立大学法人山口大学 | ゲル化剤及びゲル |
| JP2012082158A (ja) * | 2010-10-12 | 2012-04-26 | Sanwa Chemical Mfg Co Ltd | ゲル化炭化水素の品質保持方法 |
| ES2640318T3 (es) * | 2010-12-22 | 2017-11-02 | Univation Technologies, Llc | Aditivo para procedimientos de polimerización de olefinas |
-
2013
- 2013-08-21 JP JP2015529865A patent/JP2015526583A/ja active Pending
- 2013-08-21 RU RU2015111337A patent/RU2015111337A/ru not_active Application Discontinuation
- 2013-08-21 EP EP13759361.2A patent/EP2890724B1/en active Active
- 2013-08-21 WO PCT/US2013/055994 patent/WO2014035763A1/en active Application Filing
- 2013-08-21 US US14/413,367 patent/US9228033B2/en active Active
- 2013-08-21 CA CA2878261A patent/CA2878261C/en active Active
- 2013-08-21 IN IN11212DEN2014 patent/IN2014DN11212A/en unknown
- 2013-08-21 BR BR112015004279A patent/BR112015004279A2/pt not_active IP Right Cessation
- 2013-08-21 CN CN201380040896.XA patent/CN104520339B/zh active Active
- 2013-08-21 MY MYPI2015700603A patent/MY169984A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US9228033B2 (en) | 2016-01-05 |
| BR112015004279A2 (pt) | 2017-07-04 |
| WO2014035763A1 (en) | 2014-03-06 |
| IN2014DN11212A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2015-10-02 |
| EP2890724A1 (en) | 2015-07-08 |
| CA2878261A1 (en) | 2014-03-06 |
| CN104520339A (zh) | 2015-04-15 |
| EP2890724B1 (en) | 2022-01-12 |
| CN104520339B (zh) | 2017-03-08 |
| US20150166692A1 (en) | 2015-06-18 |
| JP2015526583A (ja) | 2015-09-10 |
| MY169984A (en) | 2019-06-19 |
| RU2015111337A (ru) | 2016-10-20 |
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| EEER | Examination request |
Effective date: 20180821 |