CA2877796C - Revetement catalytique et procede de conversion de composes oxygenes en olefines - Google Patents
Revetement catalytique et procede de conversion de composes oxygenes en olefines Download PDFInfo
- Publication number
- CA2877796C CA2877796C CA2877796A CA2877796A CA2877796C CA 2877796 C CA2877796 C CA 2877796C CA 2877796 A CA2877796 A CA 2877796A CA 2877796 A CA2877796 A CA 2877796A CA 2877796 C CA2877796 C CA 2877796C
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- further preferably
- zeolites
- present
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 182
- 238000000034 method Methods 0.000 title claims abstract description 181
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 80
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 74
- 230000008569 process Effects 0.000 title claims description 178
- 239000011248 coating agent Substances 0.000 title claims description 28
- 238000000576 coating method Methods 0.000 title claims description 28
- 239000010457 zeolite Substances 0.000 claims abstract description 121
- 239000000758 substrate Substances 0.000 claims abstract description 106
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 35
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims description 139
- 239000011230 binding agent Substances 0.000 claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- 229910001868 water Inorganic materials 0.000 claims description 34
- 238000001035 drying Methods 0.000 claims description 28
- 238000002360 preparation method Methods 0.000 claims description 28
- 241000264877 Hippospongia communis Species 0.000 claims description 27
- 238000001354 calcination Methods 0.000 claims description 27
- 238000011068 loading method Methods 0.000 claims description 27
- 150000001298 alcohols Chemical class 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 21
- 239000007787 solid Substances 0.000 claims description 21
- 238000005470 impregnation Methods 0.000 claims description 20
- 239000002904 solvent Substances 0.000 claims description 18
- 239000000919 ceramic Substances 0.000 claims description 10
- 239000006260 foam Substances 0.000 claims description 9
- 238000010924 continuous production Methods 0.000 claims description 8
- 239000008188 pellet Substances 0.000 claims description 7
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 6
- 150000002170 ethers Chemical class 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000007769 metal material Substances 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- -1 aliphatic alcohols Chemical class 0.000 claims description 3
- 150000001728 carbonyl compounds Chemical class 0.000 claims description 3
- 238000004898 kneading Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 230000029936 alkylation Effects 0.000 claims description 2
- 238000005804 alkylation reaction Methods 0.000 claims description 2
- 238000004231 fluid catalytic cracking Methods 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 93
- 239000007789 gas Substances 0.000 description 45
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 34
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 30
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 25
- 239000000126 substance Substances 0.000 description 22
- 229910021536 Zeolite Inorganic materials 0.000 description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 15
- 239000000725 suspension Substances 0.000 description 15
- 239000011777 magnesium Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 230000003197 catalytic effect Effects 0.000 description 12
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 12
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 10
- 229910052878 cordierite Inorganic materials 0.000 description 9
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 9
- 229910052749 magnesium Inorganic materials 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 238000006555 catalytic reaction Methods 0.000 description 8
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 8
- 235000012239 silicon dioxide Nutrition 0.000 description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- 229910052681 coesite Inorganic materials 0.000 description 7
- 229910052906 cristobalite Inorganic materials 0.000 description 7
- 230000006872 improvement Effects 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 229910052682 stishovite Inorganic materials 0.000 description 7
- 229910052905 tridymite Inorganic materials 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 238000003618 dip coating Methods 0.000 description 6
- 229910010271 silicon carbide Inorganic materials 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 150000005215 alkyl ethers Chemical class 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- 239000012153 distilled water Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 5
- 229910052712 strontium Inorganic materials 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 238000004939 coking Methods 0.000 description 4
- 230000009849 deactivation Effects 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 238000000265 homogenisation Methods 0.000 description 4
- 239000000395 magnesium oxide Substances 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 238000002604 ultrasonography Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000002734 clay mineral Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 3
- NJXPYZHXZZCTNI-UHFFFAOYSA-N 3-aminobenzonitrile Chemical compound NC1=CC=CC(C#N)=C1 NJXPYZHXZZCTNI-UHFFFAOYSA-N 0.000 description 2
- 241000269350 Anura Species 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 238000005815 base catalysis Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001983 dialkylethers Chemical class 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 229910052566 spinel group Inorganic materials 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 125000006526 (C1-C2) alkyl group Chemical group 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- ZZBAGJPKGRJIJH-UHFFFAOYSA-N 7h-purine-2-carbaldehyde Chemical compound O=CC1=NC=C2NC=NC2=N1 ZZBAGJPKGRJIJH-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 229910001680 bayerite Inorganic materials 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 229910001649 dickite Inorganic materials 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229910001679 gibbsite Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B01J35/45—Nanoparticles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0248—Coatings comprising impregnated particles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
La présente invention concerne un catalyseur pour convertir des composés oxygénés en oléfines, comprenant un substrat de support et une couche appliquée sur le substrat, la couche contenant une ou plusieurs zéolites de structure MFI, MEL et/ou MWW, la ou les zéolithes contenant un ou plusieurs métaux alcalino-terreux. L'invention concerne aussi la préparation et l'utilisation de ce catalyseur, ainsi qu'un procédé pour convertir des composés oxygénés en oléfines au moyen du catalyseur.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12174293.6 | 2012-06-29 | ||
EP12174293 | 2012-06-29 | ||
PCT/EP2013/063436 WO2014001412A2 (fr) | 2012-06-29 | 2013-06-26 | Revêtement catalytique et procédé de conversion de composés oxygénés en oléfines |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2877796A1 CA2877796A1 (fr) | 2014-01-03 |
CA2877796C true CA2877796C (fr) | 2020-06-30 |
Family
ID=48703493
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2877796A Expired - Fee Related CA2877796C (fr) | 2012-06-29 | 2013-06-26 | Revetement catalytique et procede de conversion de composes oxygenes en olefines |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2866934A2 (fr) |
JP (1) | JP6466325B2 (fr) |
CN (2) | CN109453804A (fr) |
AU (1) | AU2013283349B2 (fr) |
BR (1) | BR112014031094A8 (fr) |
CA (1) | CA2877796C (fr) |
MX (1) | MX2014015736A (fr) |
RU (1) | RU2015102718A (fr) |
WO (1) | WO2014001412A2 (fr) |
ZA (1) | ZA201500361B (fr) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9597669B2 (en) | 2012-06-29 | 2017-03-21 | Basf Se | Catalyst and process for the conversion of oxygenates to olefins |
US20140005455A1 (en) | 2012-06-29 | 2014-01-02 | Basf Se | Process for the conversion of oxygenates to olefins |
US10005702B2 (en) | 2012-06-29 | 2018-06-26 | Basf Se | Catalyst coating and process for the conversion of oxygenates to olefins |
US9682367B2 (en) | 2014-10-22 | 2017-06-20 | King Fahd University Of Petroleum And Minerals | Monolith structure loaded with metal promoted nanozeolites for enhanced propylene selectivity in methanol conversion |
US9675971B2 (en) | 2014-10-22 | 2017-06-13 | King Fahd University Of Petroleum And Minerals | Honeycomb monolith structure loaded with nanozeolites for enhanced propylene selectivity in methanol conversion |
CN111760589A (zh) * | 2020-07-10 | 2020-10-13 | 大唐国际化工技术研究院有限公司 | 分子筛催化剂及其制备方法和应用 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4049573A (en) | 1976-02-05 | 1977-09-20 | Mobil Oil Corporation | Zeolite catalyst containing oxide of boron or magnesium |
DE2830787B2 (de) | 1978-07-13 | 1981-02-19 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von stickstoffhaltigen kirstallinen Metallsilikaten mit Zeolithstniktur |
DE3006471A1 (de) | 1980-02-21 | 1981-08-27 | Basf Ag, 6700 Ludwigshafen | Kristalline isotaktische zeolithe, verfahren zur herstellung derselben sowie deren verwendung als katalysatoren |
DD238733A1 (de) * | 1984-12-29 | 1986-09-03 | Leuna Werke Veb | Herstellung selektiver olefinkatalysatoren |
JPS6251630A (ja) * | 1985-08-29 | 1987-03-06 | Agency Of Ind Science & Technol | 低級オレフインの製造方法 |
US4692423A (en) | 1985-12-04 | 1987-09-08 | Mobil Oil Corporation | Method for preparing structured catalytic solids |
DE4009459A1 (de) * | 1990-03-23 | 1991-09-26 | Metallgesellschaft Ag | Verfahren zur erzeugung von niederen olefinen |
ATE339249T1 (de) | 1993-04-23 | 2006-10-15 | Exxonmobil Res & Eng Co | Molekularsiebschichten und verfahren zu ihrer herstellung |
JPH07241471A (ja) * | 1994-03-04 | 1995-09-19 | Nissan Motor Co Ltd | 排ガス浄化用吸着触媒の製造方法 |
JP3498410B2 (ja) * | 1995-03-07 | 2004-02-16 | 日産自動車株式会社 | 排気ガス浄化用触媒 |
US5925800A (en) | 1996-12-31 | 1999-07-20 | Exxon Chemical Patents Inc. | Conversion of oxygenates to hydrocarbons with monolith supported non-zeolitic molecular sieve catalysts |
JP2005514319A (ja) * | 2002-10-24 | 2005-05-19 | エクソンモービル・ケミカル・パテンツ・インク | 酸触媒の安定化 |
NZ550026A (en) * | 2004-03-22 | 2009-10-30 | Celgene Corp | Methods of using and compositions comprising immunomodulatory compounds for the treatment and management of skin diseases or disorders |
JP2008080301A (ja) * | 2006-08-30 | 2008-04-10 | Jgc Corp | アルカリ土類金属化合物含有ゼオライト触媒およびその調製方法、並びに、低級炭化水素の製造方法 |
JP5303131B2 (ja) * | 2006-09-19 | 2013-10-02 | 株式会社日本自動車部品総合研究所 | 炭素系物質燃焼触媒及びその製造方法、触媒担持体及びその製造方法 |
CN101239875B (zh) * | 2007-02-07 | 2010-11-10 | 中国石油化工股份有限公司 | 由甲醇制取丙烯的方法 |
CN102802792A (zh) * | 2009-06-22 | 2012-11-28 | 日挥株式会社 | 低级烯烃制造用催化剂及使用其制造低级烯烃的方法 |
EP2335810B1 (fr) * | 2009-12-11 | 2012-08-01 | Umicore AG & Co. KG | Réduction catalytique sélective d'oxydes d'azote dans du gaz d'échappement de moteurs diesel |
BR112014031391B1 (pt) * | 2012-06-29 | 2020-12-08 | Basf Se | processos para a preparação de um catalisador para a conversão de oxigenados em olefinas |
-
2013
- 2013-06-26 MX MX2014015736A patent/MX2014015736A/es unknown
- 2013-06-26 WO PCT/EP2013/063436 patent/WO2014001412A2/fr active Application Filing
- 2013-06-26 EP EP13732467.9A patent/EP2866934A2/fr not_active Withdrawn
- 2013-06-26 CN CN201811397259.9A patent/CN109453804A/zh active Pending
- 2013-06-26 CA CA2877796A patent/CA2877796C/fr not_active Expired - Fee Related
- 2013-06-26 JP JP2015519079A patent/JP6466325B2/ja not_active Expired - Fee Related
- 2013-06-26 AU AU2013283349A patent/AU2013283349B2/en not_active Ceased
- 2013-06-26 BR BR112014031094A patent/BR112014031094A8/pt not_active IP Right Cessation
- 2013-06-26 CN CN201380042077.9A patent/CN104582841A/zh active Pending
- 2013-06-26 RU RU2015102718A patent/RU2015102718A/ru not_active Application Discontinuation
-
2015
- 2015-01-19 ZA ZA2015/00361A patent/ZA201500361B/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2014001412A3 (fr) | 2014-02-27 |
CN109453804A (zh) | 2019-03-12 |
WO2014001412A2 (fr) | 2014-01-03 |
MX2014015736A (es) | 2015-09-04 |
CA2877796A1 (fr) | 2014-01-03 |
BR112014031094A2 (pt) | 2017-06-27 |
AU2013283349A1 (en) | 2015-01-22 |
JP2015522408A (ja) | 2015-08-06 |
ZA201500361B (en) | 2016-03-30 |
CN104582841A (zh) | 2015-04-29 |
EP2866934A2 (fr) | 2015-05-06 |
AU2013283349B2 (en) | 2017-05-04 |
RU2015102718A (ru) | 2016-08-20 |
JP6466325B2 (ja) | 2019-02-06 |
BR112014031094A8 (pt) | 2021-01-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2877796C (fr) | Revetement catalytique et procede de conversion de composes oxygenes en olefines | |
CA2959196C (fr) | Appareil et procede de production d'essence, d'olefines et de composes aromatiques a partir de composes oxygenes | |
US10213773B2 (en) | Process for the conversion of oxygenates to olefins | |
CA2842388C (fr) | Procede de fabrication d'un catalyseur comprenant une zeolithe modifiee par du phosphore et utilisation de ladite zeolithe | |
CA2844363C (fr) | Catalyseur comprenant une zeolithe modifiee par du phosphore et ayant partiellement une structure alpo | |
AU2014368547B2 (en) | Catalyst and process for the conversion of oxygenates to olefins | |
WO2015094681A1 (fr) | Catalyseur de conversion d'oxygénats en aromatiques | |
RU2563648C2 (ru) | Улучшенный способ получения катализатора на основе цеолита для превращения метанола в олефины | |
TW200306890A (en) | Molecular sieve compositions, catalyst thereof, their making and use in conversion processes | |
US10005702B2 (en) | Catalyst coating and process for the conversion of oxygenates to olefins | |
AU2013283347A1 (en) | Catalyst and method for the conversion of oxygenates to olefins | |
JP2019069967A (ja) | 酸素含有物質からオレフィンへの転化のための方法 | |
US20150057481A1 (en) | Method for dehydrating and isomerising alcohols using a non-zeolite aluminosilicate solid |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request |
Effective date: 20180626 |
|
MKLA | Lapsed |
Effective date: 20210628 |