CA2862473A1 - Procede de preparation de silices precipitees - Google Patents
Procede de preparation de silices precipitees Download PDFInfo
- Publication number
- CA2862473A1 CA2862473A1 CA2862473A CA2862473A CA2862473A1 CA 2862473 A1 CA2862473 A1 CA 2862473A1 CA 2862473 A CA2862473 A CA 2862473A CA 2862473 A CA2862473 A CA 2862473A CA 2862473 A1 CA2862473 A1 CA 2862473A1
- Authority
- CA
- Canada
- Prior art keywords
- acid
- concentration
- mass
- silicate
- reaction medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 44
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims description 50
- 239000000377 silicon dioxide Substances 0.000 title claims description 23
- 239000002253 acid Substances 0.000 claims abstract description 151
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 71
- 239000012429 reaction media Substances 0.000 claims abstract description 67
- 230000008569 process Effects 0.000 claims abstract description 26
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 51
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 33
- 238000006243 chemical reaction Methods 0.000 claims description 27
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 22
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 22
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 20
- 239000000725 suspension Substances 0.000 claims description 12
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 11
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- 235000019253 formic acid Nutrition 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 6
- 239000012141 concentrate Substances 0.000 claims description 5
- 238000000889 atomisation Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 2
- 238000002360 preparation method Methods 0.000 abstract description 12
- 229920000642 polymer Polymers 0.000 description 10
- 239000000203 mixture Substances 0.000 description 6
- 230000005070 ripening Effects 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 238000005056 compaction Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 239000001763 2-hydroxyethyl(trimethyl)azanium Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000019743 Choline chloride Nutrition 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229930003427 Vitamin E Natural products 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- SGMZJAMFUVOLNK-UHFFFAOYSA-M choline chloride Chemical compound [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 description 2
- 229960003178 choline chloride Drugs 0.000 description 2
- -1 choline chloride) Chemical compound 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 239000012763 reinforcing filler Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229940034610 toothpaste Drugs 0.000 description 2
- 239000000606 toothpaste Substances 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229940046009 vitamin E Drugs 0.000 description 2
- 235000019165 vitamin E Nutrition 0.000 description 2
- 239000011709 vitamin E Substances 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- ZMZINYUKVRMNTG-UHFFFAOYSA-N acetic acid;formic acid Chemical compound OC=O.CC(O)=O ZMZINYUKVRMNTG-UHFFFAOYSA-N 0.000 description 1
- 239000002535 acidifier Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 238000007907 direct compression Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000021395 porridge Nutrition 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/126—Preparation of silica of undetermined type
- C01B33/128—Preparation of silica of undetermined type by acidic treatment of aqueous silicate solutions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
- C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicon Compounds (AREA)
- Paper (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1200212 | 2012-01-25 | ||
| FR1200212A FR2985991B1 (fr) | 2012-01-25 | 2012-01-25 | Nouveau procede de preparation de silices precipitees |
| PCT/EP2013/051234 WO2013110655A1 (fr) | 2012-01-25 | 2013-01-23 | Procede de preparation de silices precipitees |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2862473A1 true CA2862473A1 (fr) | 2013-08-01 |
Family
ID=48044728
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2862473A Abandoned CA2862473A1 (fr) | 2012-01-25 | 2013-01-23 | Procede de preparation de silices precipitees |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9695054B2 (enExample) |
| EP (1) | EP2807118A1 (enExample) |
| KR (1) | KR20140116524A (enExample) |
| CN (1) | CN104066682A (enExample) |
| AU (1) | AU2013211587A1 (enExample) |
| BR (1) | BR112014018028A8 (enExample) |
| CA (1) | CA2862473A1 (enExample) |
| FR (1) | FR2985991B1 (enExample) |
| MX (1) | MX354838B (enExample) |
| RU (1) | RU2581407C2 (enExample) |
| WO (1) | WO2013110655A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2984870B1 (fr) | 2011-12-23 | 2014-03-21 | Rhodia Operations | Nouveau procede de preparation de silices precipitees. |
| MX356674B (es) | 2011-12-23 | 2018-06-08 | Rhodia Operations | Proceso novedoso para preparar sílices. |
| FR2985990B1 (fr) | 2012-01-25 | 2014-11-28 | Rhodia Operations | Nouveau procede de preparation de silices precipitees a morphologie, granulometrie et porosite particulieres |
| FR2985992B1 (fr) | 2012-01-25 | 2015-03-06 | Rhodia Operations | Nouveau procede de preparation de silices precitees |
| FR2985993B1 (fr) | 2012-01-25 | 2014-11-28 | Rhodia Operations | Nouveau procede de preparation de silices precipitees |
| MY192838A (en) * | 2016-12-19 | 2022-09-12 | Evonik Operations Gmbh | Stannous compatible silica |
| ES3067672T3 (en) * | 2017-12-27 | 2026-05-25 | Rhodia Operations | Precipitated silica and process for its manufacture |
| US12291459B2 (en) * | 2019-06-27 | 2025-05-06 | Rhodia Operations | Precipitated silica and process for its manufacture |
| MX2024007946A (es) * | 2021-12-23 | 2024-09-02 | Rhodia Operations | Silice precipitada y proceso para su fabricacion. |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3639845A1 (de) | 1986-11-21 | 1988-06-01 | Degussa | Faellungskieselsaeuren, verfahren zu ihrer herstellung und verwendung |
| FR2646673B1 (fr) * | 1989-05-02 | 1991-09-06 | Rhone Poulenc Chimie | Silice sous forme de bille, procede de preparation et son utilisation au renforcement des elastomeres |
| FR2678259B1 (fr) | 1991-06-26 | 1993-11-05 | Rhone Poulenc Chimie | Nouvelles silices precipitees sous forme de granules ou de poudres, procedes de synthese et utilisation au renforcement des elastomeres. |
| KR0158071B1 (ko) * | 1993-09-29 | 1998-11-16 | 마르끄 델렌느 | 침강 실리카 |
| DE19526476A1 (de) * | 1995-07-20 | 1997-01-23 | Degussa | Fällungskieselsäure |
| FR2763581B1 (fr) * | 1997-05-26 | 1999-07-23 | Rhodia Chimie Sa | Silice precipitee utilisable comme charge renforcante pour elastomeres |
| WO2002030818A2 (en) | 2000-10-13 | 2002-04-18 | University Of Cincinnati | Methods for synthesizing precipitated silica and use thereof |
| FR2818966B1 (fr) * | 2000-12-28 | 2003-03-07 | Rhodia Chimie Sa | Procede de preparation de silice precipitee contenant de l'aluminium |
| JP4515761B2 (ja) * | 2001-08-13 | 2010-08-04 | ロディア・シミ | シリカの製造方法、特定の細孔寸法及び／又は粒度分布を有するシリカ並びにそれらの特に重合体強化のための使用 |
| US6869595B2 (en) * | 2001-12-21 | 2005-03-22 | J.M. Huber Corporation | Abrasive compositions for clear toothpaste |
| FR2902781B1 (fr) * | 2006-06-27 | 2008-09-05 | Rhodia Recherches Et Technologies Sas | Silice precipitee pour application papier |
| CN102137813A (zh) | 2008-09-01 | 2011-07-27 | 赢创德固赛有限责任公司 | 制备沉淀二氧化硅的方法、沉淀二氧化硅及其用途 |
| FR2949455B1 (fr) * | 2009-09-03 | 2011-09-16 | Rhodia Operations | Nouveau procede de preparation de silices precipitees |
| FR2949454B1 (fr) * | 2009-09-03 | 2011-09-16 | Rhodia Operations | Nouveau procede de preparation de silices precipitees |
| FR2962996B1 (fr) | 2010-07-23 | 2012-07-27 | Rhodia Operations | Nouveau procede de preparation de silices precipitees |
| FR2984870B1 (fr) | 2011-12-23 | 2014-03-21 | Rhodia Operations | Nouveau procede de preparation de silices precipitees. |
| MX356674B (es) | 2011-12-23 | 2018-06-08 | Rhodia Operations | Proceso novedoso para preparar sílices. |
| FR2985992B1 (fr) | 2012-01-25 | 2015-03-06 | Rhodia Operations | Nouveau procede de preparation de silices precitees |
| FR2985990B1 (fr) | 2012-01-25 | 2014-11-28 | Rhodia Operations | Nouveau procede de preparation de silices precipitees a morphologie, granulometrie et porosite particulieres |
| FR2985993B1 (fr) | 2012-01-25 | 2014-11-28 | Rhodia Operations | Nouveau procede de preparation de silices precipitees |
-
2012
- 2012-01-25 FR FR1200212A patent/FR2985991B1/fr not_active Expired - Fee Related
-
2013
- 2013-01-23 CA CA2862473A patent/CA2862473A1/fr not_active Abandoned
- 2013-01-23 US US14/373,797 patent/US9695054B2/en not_active Expired - Fee Related
- 2013-01-23 BR BR112014018028A patent/BR112014018028A8/pt not_active Application Discontinuation
- 2013-01-23 WO PCT/EP2013/051234 patent/WO2013110655A1/fr not_active Ceased
- 2013-01-23 CN CN201380006528.3A patent/CN104066682A/zh active Pending
- 2013-01-23 EP EP13713364.1A patent/EP2807118A1/fr not_active Withdrawn
- 2013-01-23 KR KR1020147023224A patent/KR20140116524A/ko not_active Abandoned
- 2013-01-23 RU RU2014134531/05A patent/RU2581407C2/ru not_active IP Right Cessation
- 2013-01-23 MX MX2014009000A patent/MX354838B/es active IP Right Grant
- 2013-01-23 AU AU2013211587A patent/AU2013211587A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| RU2581407C2 (ru) | 2016-04-20 |
| AU2013211587A1 (en) | 2014-08-07 |
| RU2014134531A (ru) | 2016-03-20 |
| FR2985991A1 (fr) | 2013-07-26 |
| WO2013110655A1 (fr) | 2013-08-01 |
| CN104066682A (zh) | 2014-09-24 |
| US20150037235A1 (en) | 2015-02-05 |
| BR112014018028A2 (enExample) | 2017-06-20 |
| EP2807118A1 (fr) | 2014-12-03 |
| FR2985991B1 (fr) | 2014-11-28 |
| MX354838B (es) | 2018-03-21 |
| US9695054B2 (en) | 2017-07-04 |
| BR112014018028A8 (pt) | 2017-07-11 |
| KR20140116524A (ko) | 2014-10-02 |
| MX2014009000A (es) | 2015-03-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20140722 |
|
| FZDE | Discontinued |
Effective date: 20181102 |