CA2848981A1 - Catalyst composition for steam reforming of methane in fuel cells - Google Patents

Catalyst composition for steam reforming of methane in fuel cells Download PDF

Info

Publication number
CA2848981A1
CA2848981A1 CA2848981A CA2848981A CA2848981A1 CA 2848981 A1 CA2848981 A1 CA 2848981A1 CA 2848981 A CA2848981 A CA 2848981A CA 2848981 A CA2848981 A CA 2848981A CA 2848981 A1 CA2848981 A1 CA 2848981A1
Authority
CA
Canada
Prior art keywords
catalyst composition
component
catalyst
aluminum oxide
aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2848981A
Other languages
English (en)
French (fr)
Inventor
Andrian Milanov
Ekkehard Schwab
Alexander Schafer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CA2848981A1 publication Critical patent/CA2848981A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)
CA2848981A 2011-11-09 2012-11-05 Catalyst composition for steam reforming of methane in fuel cells Abandoned CA2848981A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11188453.2 2011-11-09
EP11188453 2011-11-09
PCT/IB2012/056155 WO2013068904A1 (de) 2011-11-09 2012-11-05 Katalysatorzusammensetzung für die methandampfreformierung in brennstoffzellen

Publications (1)

Publication Number Publication Date
CA2848981A1 true CA2848981A1 (en) 2013-05-16

Family

ID=48288608

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2848981A Abandoned CA2848981A1 (en) 2011-11-09 2012-11-05 Catalyst composition for steam reforming of methane in fuel cells

Country Status (7)

Country Link
EP (1) EP2776158B1 (https=)
JP (1) JP6305341B2 (https=)
KR (1) KR102068732B1 (https=)
CN (1) CN103917291A (https=)
CA (1) CA2848981A1 (https=)
DK (1) DK2776158T3 (https=)
WO (1) WO2013068904A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11005115B2 (en) 2016-04-11 2021-05-11 Fuelcell Energy, Inc. Supported nickel catalysts used as direct internal reforming catalyst in molten carbonate fuel cells

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6422981B2 (ja) * 2013-09-12 2018-11-14 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ナトリウム化合物を含有する混合物の押出しによるβ−酸化アルミニウムセラミック
JP6701778B2 (ja) * 2015-02-13 2020-05-27 日本製鉄株式会社 炭化水素の改質による水素の製造方法、水素の製造装置、燃料電池の運転方法、及び燃料電池の運転装置
KR101794316B1 (ko) * 2016-09-09 2017-11-07 주식회사 에코프로 수증기 메탄 개질용 니켈계 촉매 성형체 및 이의 이용
WO2020014060A1 (en) 2018-07-12 2020-01-16 Exxonmobil Research And Engineering Company Vehicle powertrain with on-board catalytic reformer

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4222827B2 (ja) * 2002-03-25 2009-02-12 新日本製鐵株式会社 炭化水素の改質方法
US7771702B2 (en) * 2003-02-20 2010-08-10 University Of Iowa Research Foundation Sulfur-tolerant catalysts and related precursors and processes
JP5354142B2 (ja) * 2006-01-16 2013-11-27 戸田工業株式会社 水蒸気改質用触媒及び反応混合ガスの製造方法
DE102007009556A1 (de) 2007-02-27 2008-10-23 Mtu Cfc Solutions Gmbh Reformierungskatalysator für Schmelzcarbonatbrennstoffzellen
KR100891903B1 (ko) * 2007-10-12 2009-04-03 고려대학교 산학협력단 알루미나-지르코니아 복합산화물 담체에 담지된액화천연가스의 수증기 개질반응용 니켈 촉매 및 그제조방법
JP4436424B2 (ja) 2007-12-27 2010-03-24 新日本製鐵株式会社 タール含有ガスの改質方法
CN101402041B (zh) * 2008-11-12 2010-10-06 西南化工研究设计院 一种富甲烷气自热转化催化剂及其制备方法
EP2467454A4 (en) 2009-08-21 2014-01-22 Univ Sherbrooke STEAM REFORMING OF HYDROCARBON FUELS VIA AN NI-AL SPINELL CATALYST
CN101829577A (zh) * 2010-04-23 2010-09-15 浙江大学 一种复合催化剂及其制备和应用
WO2013068905A1 (en) * 2011-11-08 2013-05-16 Basf Se Process for producing reforming catalyst and reforming of methane

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11005115B2 (en) 2016-04-11 2021-05-11 Fuelcell Energy, Inc. Supported nickel catalysts used as direct internal reforming catalyst in molten carbonate fuel cells
US11600836B2 (en) 2016-04-11 2023-03-07 Fuelcell Energy, Inc. Supported nickel catalysts used as direct internal reforming catalyst in molten carbonate fuel cells
US12255367B2 (en) 2016-04-11 2025-03-18 Fuelcell Energy, Inc. Supported nickel catalysts used as direct internal reforming catalyst in molten carbonate fuel cells

Also Published As

Publication number Publication date
JP2015504356A (ja) 2015-02-12
WO2013068904A1 (de) 2013-05-16
CN103917291A (zh) 2014-07-09
EP2776158B1 (de) 2017-04-26
JP6305341B2 (ja) 2018-04-04
DK2776158T3 (en) 2017-08-28
KR102068732B1 (ko) 2020-01-21
EP2776158A1 (de) 2014-09-17
KR20140099472A (ko) 2014-08-12
EP2776158A4 (de) 2015-12-09

Similar Documents

Publication Publication Date Title
US8993477B2 (en) Catalyst composition for the steam reforming of methane in fuel cells
EP2251080B1 (en) A porous catalytic body that decomposes hydrocarbons and a manufacturing method thereof, a method for manufacturing mixed reformed gas that comprises hydrogen from hydrocarbon, and a fuel cell system
EP2776157B1 (en) Process for producing reforming catalyst and reforming of methane
US20130116116A1 (en) Process for producing a reforming catalyst and the reforming of methane
US6051163A (en) Catalyst for steam-reforming methanol
EP2476484B1 (en) Porous catalytic object for decomposing hydrocarbon and process for producing same, process for producing hydrogen-containing mixed reformed gas from hydrocarbon, and fuel cell system
DK2776158T3 (en) CATALYST COMPOSITION FOR METHANDAM REFORM IN FUEL CELLS
Ni et al. Effect of rare earth on the performance of Ru/MgAl-LDO catalysts for ammonia synthesis
Zhang et al. Thermal decomposition behavior of nickel-iron hydrotalcite and its electrocatalytic properties of oxygen reduction and oxygen evolution reactions
JP2020163334A (ja) ニッケル触媒及びその製造方法
WO2014021224A1 (ja) 炭化水素分解用触媒体、該触媒体を用いた水素含有混合改質ガスを製造する方法、並びに燃料電池システム
US10532343B2 (en) Reforming catalyst material and processes for making and using same
JPH05161848A (ja) 高活性高強度ニッケル／マグネシア系触媒の調製方法
CN105854893B (zh) 一种重整催化剂氧化物活性组分Ni‑Mn‑Mg‑O的制备方法
Su et al. Boosting ammonia decomposition for hydrogen production over Co/CeO 2 catalysts via Sr doping
Orozco et al. Unveiling the temperature-dependent reaction dynamics of Li3BO3: Formation and carbonation mechanisms via in situ synchrotron XRD
JP2006116370A (ja) 一酸化炭素シフト反応触媒

Legal Events

Date Code Title Description
FZDE Discontinued

Effective date: 20181106