CA2831273C - Anode for electrowinning and method for electrowinning using same - Google Patents
Anode for electrowinning and method for electrowinning using same Download PDFInfo
- Publication number
- CA2831273C CA2831273C CA2831273A CA2831273A CA2831273C CA 2831273 C CA2831273 C CA 2831273C CA 2831273 A CA2831273 A CA 2831273A CA 2831273 A CA2831273 A CA 2831273A CA 2831273 C CA2831273 C CA 2831273C
- Authority
- CA
- Canada
- Prior art keywords
- electrowinning
- anode
- oxide
- catalytic layer
- amorphous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005363 electrowinning Methods 0.000 title claims abstract description 260
- 238000000034 method Methods 0.000 title claims description 44
- 230000003197 catalytic effect Effects 0.000 claims abstract description 126
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 100
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 99
- 229910052751 metal Inorganic materials 0.000 claims abstract description 77
- 239000002184 metal Substances 0.000 claims abstract description 76
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims abstract description 75
- 229910001936 tantalum oxide Inorganic materials 0.000 claims abstract description 75
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 claims abstract description 62
- 229910001925 ruthenium oxide Inorganic materials 0.000 claims abstract description 59
- 239000000758 substrate Substances 0.000 claims abstract description 39
- 239000010936 titanium Substances 0.000 claims abstract description 37
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 34
- 150000002739 metals Chemical class 0.000 claims abstract description 13
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 claims description 33
- 229910000457 iridium oxide Inorganic materials 0.000 claims description 33
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 24
- 229910052715 tantalum Inorganic materials 0.000 claims description 24
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 24
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 23
- 229910052725 zinc Inorganic materials 0.000 claims description 23
- 239000011701 zinc Substances 0.000 claims description 23
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 21
- 229910052707 ruthenium Inorganic materials 0.000 claims description 21
- 229910017052 cobalt Inorganic materials 0.000 claims description 19
- 239000010941 cobalt Substances 0.000 claims description 19
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 19
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 19
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 15
- 229910052697 platinum Inorganic materials 0.000 claims description 12
- 229910052741 iridium Inorganic materials 0.000 claims description 11
- 229910045601 alloy Inorganic materials 0.000 claims description 10
- 239000000956 alloy Substances 0.000 claims description 10
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 239000010955 niobium Substances 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
- 229910052703 rhodium Inorganic materials 0.000 claims description 3
- 239000010948 rhodium Substances 0.000 claims description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 41
- 229910052760 oxygen Inorganic materials 0.000 abstract description 41
- 239000001301 oxygen Substances 0.000 abstract description 41
- 230000002829 reductive effect Effects 0.000 abstract description 38
- 229910000978 Pb alloy Inorganic materials 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 125
- 230000000052 comparative effect Effects 0.000 description 79
- 238000005979 thermal decomposition reaction Methods 0.000 description 39
- 239000000243 solution Substances 0.000 description 29
- 230000000694 effects Effects 0.000 description 23
- 238000007086 side reaction Methods 0.000 description 22
- 239000002243 precursor Substances 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 13
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 12
- -1 cobalt oxyhydroxide Chemical compound 0.000 description 11
- 238000005868 electrolysis reaction Methods 0.000 description 11
- 229910021645 metal ion Inorganic materials 0.000 description 10
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 9
- 239000011133 lead Substances 0.000 description 9
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 8
- 238000000151 deposition Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 229910003460 diamond Inorganic materials 0.000 description 5
- 239000010432 diamond Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- RTBHLGSMKCPLCQ-UHFFFAOYSA-N [Mn].OOO Chemical compound [Mn].OOO RTBHLGSMKCPLCQ-UHFFFAOYSA-N 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 238000005240 physical vapour deposition Methods 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 230000000452 restraining effect Effects 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 description 4
- 239000011686 zinc sulphate Substances 0.000 description 4
- 235000009529 zinc sulphate Nutrition 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 229910001429 cobalt ion Inorganic materials 0.000 description 3
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 3
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- 229910001437 manganese ion Inorganic materials 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- OEIMLTQPLAGXMX-UHFFFAOYSA-I tantalum(v) chloride Chemical compound Cl[Ta](Cl)(Cl)(Cl)Cl OEIMLTQPLAGXMX-UHFFFAOYSA-I 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 150000002697 manganese compounds Chemical class 0.000 description 2
- 239000002905 metal composite material Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 229910021518 metal oxyhydroxide Inorganic materials 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- JODOMBGKVAIYRQ-UHFFFAOYSA-N [Nb].[Ta].[Ti] Chemical compound [Nb].[Ta].[Ti] JODOMBGKVAIYRQ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000006263 metalation reaction Methods 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- 229910000484 niobium oxide Inorganic materials 0.000 description 1
- RJSRQTFBFAJJIL-UHFFFAOYSA-N niobium titanium Chemical compound [Ti].[Nb] RJSRQTFBFAJJIL-UHFFFAOYSA-N 0.000 description 1
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- BIXNGBXQRRXPLM-UHFFFAOYSA-K ruthenium(3+);trichloride;hydrate Chemical compound O.Cl[Ru](Cl)Cl BIXNGBXQRRXPLM-UHFFFAOYSA-K 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- VSSLEOGOUUKTNN-UHFFFAOYSA-N tantalum titanium Chemical compound [Ti].[Ta] VSSLEOGOUUKTNN-UHFFFAOYSA-N 0.000 description 1
- PBACCOSPRYQTNC-UHFFFAOYSA-J tetrachloroiridium hexahydrate dihydrochloride Chemical compound O.O.O.O.O.O.Cl.Cl.Cl[Ir](Cl)(Cl)Cl PBACCOSPRYQTNC-UHFFFAOYSA-J 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- ZTWIEIFKPFJRLV-UHFFFAOYSA-K trichlororuthenium;trihydrate Chemical compound O.O.O.Cl[Ru](Cl)Cl ZTWIEIFKPFJRLV-UHFFFAOYSA-K 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/16—Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011067365A JP4916040B1 (ja) | 2011-03-25 | 2011-03-25 | 電解採取用陽極および該陽極を用いた電解採取法 |
| JP2011-067365 | 2011-03-25 | ||
| PCT/JP2012/057426 WO2012133136A1 (ja) | 2011-03-25 | 2012-03-23 | 電解採取用陽極およびそれを用いた電解採取法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2831273A1 CA2831273A1 (en) | 2012-10-04 |
| CA2831273C true CA2831273C (en) | 2016-02-23 |
Family
ID=46171009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2831273A Expired - Fee Related CA2831273C (en) | 2011-03-25 | 2012-03-23 | Anode for electrowinning and method for electrowinning using same |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20140054180A1 (ja) |
| EP (1) | EP2690200B1 (ja) |
| JP (1) | JP4916040B1 (ja) |
| KR (1) | KR101577664B1 (ja) |
| CN (1) | CN103476970B (ja) |
| AU (1) | AU2012234150B2 (ja) |
| CA (1) | CA2831273C (ja) |
| CL (1) | CL2013002745A1 (ja) |
| ES (1) | ES2557194T3 (ja) |
| RU (1) | RU2568546C2 (ja) |
| WO (1) | WO2012133136A1 (ja) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2847210C (en) | 2011-09-01 | 2020-04-14 | Simon TRUDEL | Electrocatalytic materials, and methods for manufacturing same |
| JP5522484B2 (ja) * | 2011-09-13 | 2014-06-18 | 学校法人同志社 | 電解めっき用陽極および該陽極を用いる電解めっき法 |
| JP5008043B1 (ja) * | 2011-09-13 | 2012-08-22 | 学校法人同志社 | 塩素発生用陽極 |
| US9178219B2 (en) * | 2012-12-20 | 2015-11-03 | Ford Global Technologies, Llc | Electrochemical device including amorphous metal oxide |
| US9790605B2 (en) | 2013-06-27 | 2017-10-17 | Yale University | Iridium complexes for electrocatalysis |
| US10081650B2 (en) | 2013-07-03 | 2018-09-25 | Yale University | Metal oxide-organic hybrid materials for heterogeneous catalysis and methods of making and using thereof |
| CN105980845B (zh) * | 2014-02-12 | 2018-11-06 | 学校法人同志社 | 离子传感器以及定量法 |
| RU2657747C2 (ru) * | 2016-04-20 | 2018-06-15 | Общество с ограниченной ответственностью "БИНАКОР-ХТ" (ООО "БИНАКОР-ХТ") | Анод электролизера для получения порошков сплавов металлов |
| CN109689937B (zh) * | 2016-09-09 | 2020-03-03 | 迪诺拉永久电极股份有限公司 | 碱性水电解用阳极的制造方法和碱性水电解用阳极 |
| WO2019172160A1 (ja) * | 2018-03-07 | 2019-09-12 | デノラ・ペルメレック株式会社 | 電解用電極及びその製造方法 |
| US11639142B2 (en) | 2019-01-11 | 2023-05-02 | Ford Global Technologies, Llc | Electronic control module wake monitor |
| JP7341395B2 (ja) * | 2019-10-30 | 2023-09-11 | 住友金属鉱山株式会社 | 廃リチウムイオン電池からの銅、ニッケル、コバルトの回収方法 |
| WO2023208026A1 (zh) * | 2022-04-28 | 2023-11-02 | 中国石油化工股份有限公司 | 一种过渡金属掺杂的铱基复合催化剂及其制备和应用 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1151365B (it) * | 1982-03-26 | 1986-12-17 | Oronzio De Nora Impianti | Anodo per procedimenti elettrilitici |
| JPS61281889A (ja) * | 1985-06-06 | 1986-12-12 | Koji Hashimoto | 電解用電極材料 |
| JPS6233790A (ja) * | 1985-08-02 | 1987-02-13 | Koji Hashimoto | 活性化非晶質合金電極 |
| US5314601A (en) | 1989-06-30 | 1994-05-24 | Eltech Systems Corporation | Electrodes of improved service life |
| JP3463966B2 (ja) | 1995-09-25 | 2003-11-05 | 石福金属興業株式会社 | 電解用電極の製造方法 |
| US6139705A (en) * | 1998-05-06 | 2000-10-31 | Eltech Systems Corporation | Lead electrode |
| IT1302581B1 (it) * | 1998-10-01 | 2000-09-29 | Nora De | Anodo con migliorato rivestimento per la reazione di evoluzione diossigeno in elettroliti contenenti manganese. |
| JP3914162B2 (ja) | 2003-02-07 | 2007-05-16 | ダイソー株式会社 | 酸素発生用電極 |
| US7258778B2 (en) | 2003-03-24 | 2007-08-21 | Eltech Systems Corporation | Electrocatalytic coating with lower platinum group metals and electrode made therefrom |
| AU2005250240B2 (en) * | 2004-06-03 | 2011-06-30 | Rio Tinto Alcan International Limited | High stability flow-through non-carbon anodes for aluminium electrowinning |
| JP4771130B2 (ja) * | 2005-11-25 | 2011-09-14 | ダイソー株式会社 | 酸素発生用電極 |
| JP2007246987A (ja) | 2006-03-16 | 2007-09-27 | Japan Carlit Co Ltd:The | 電極製造用塗布液、及び該塗布液を使用して製造された電解用電極 |
| JP2008050675A (ja) | 2006-08-28 | 2008-03-06 | Ishifuku Metal Ind Co Ltd | 電解用電極 |
| ITMI20061974A1 (it) | 2006-10-16 | 2008-04-17 | Industrie De Nora Spa | Anodo per elettrolisi |
| BRPI0818104B1 (pt) | 2007-11-16 | 2018-11-21 | Akzo Nobel Nv | processo de produção de clorato de metal álcali |
| US8022004B2 (en) | 2008-05-24 | 2011-09-20 | Freeport-Mcmoran Corporation | Multi-coated electrode and method of making |
| EP2508651B1 (en) * | 2008-06-09 | 2015-02-25 | The Doshisha | Cobalt electrowinning method |
| JP4516618B2 (ja) * | 2008-06-23 | 2010-08-04 | 学校法人同志社 | コバルトの電解採取用陽極および電解採取法 |
| JP4516617B2 (ja) * | 2008-06-09 | 2010-08-04 | 学校法人同志社 | 亜鉛の電解採取用陽極および電解採取法 |
| JP5013438B2 (ja) * | 2009-12-08 | 2012-08-29 | 学校法人同志社 | 金属の電解採取用陽極および電解採取方法 |
-
2011
- 2011-03-25 JP JP2011067365A patent/JP4916040B1/ja active Active
-
2012
- 2012-03-23 US US14/007,488 patent/US20140054180A1/en not_active Abandoned
- 2012-03-23 KR KR1020137024065A patent/KR101577664B1/ko active IP Right Grant
- 2012-03-23 AU AU2012234150A patent/AU2012234150B2/en not_active Ceased
- 2012-03-23 ES ES12763572.0T patent/ES2557194T3/es active Active
- 2012-03-23 CA CA2831273A patent/CA2831273C/en not_active Expired - Fee Related
- 2012-03-23 EP EP12763572.0A patent/EP2690200B1/en active Active
- 2012-03-23 CN CN201280016122.9A patent/CN103476970B/zh not_active Expired - Fee Related
- 2012-03-23 RU RU2013147642/02A patent/RU2568546C2/ru active
- 2012-03-23 WO PCT/JP2012/057426 patent/WO2012133136A1/ja active Application Filing
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2013
- 2013-09-25 CL CL2013002745A patent/CL2013002745A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP4916040B1 (ja) | 2012-04-11 |
| CL2013002745A1 (es) | 2014-04-25 |
| CA2831273A1 (en) | 2012-10-04 |
| CN103476970B (zh) | 2016-07-06 |
| KR20140002749A (ko) | 2014-01-08 |
| AU2012234150B2 (en) | 2015-07-02 |
| ES2557194T3 (es) | 2016-01-22 |
| AU2012234150A1 (en) | 2013-11-14 |
| RU2013147642A (ru) | 2015-04-27 |
| KR101577664B1 (ko) | 2015-12-15 |
| RU2568546C2 (ru) | 2015-11-20 |
| US20140054180A1 (en) | 2014-02-27 |
| EP2690200A4 (en) | 2014-03-19 |
| EP2690200B1 (en) | 2015-10-07 |
| WO2012133136A1 (ja) | 2012-10-04 |
| JP2012201925A (ja) | 2012-10-22 |
| EP2690200A1 (en) | 2014-01-29 |
| CN103476970A (zh) | 2013-12-25 |
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