CA2814131C - High strength phosphate-based cement having low alkalinity - Google Patents
High strength phosphate-based cement having low alkalinity Download PDFInfo
- Publication number
- CA2814131C CA2814131C CA2814131A CA2814131A CA2814131C CA 2814131 C CA2814131 C CA 2814131C CA 2814131 A CA2814131 A CA 2814131A CA 2814131 A CA2814131 A CA 2814131A CA 2814131 C CA2814131 C CA 2814131C
- Authority
- CA
- Canada
- Prior art keywords
- cement
- dry
- phosphate mixture
- product
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004568 cement Substances 0.000 title claims abstract description 49
- 229910019142 PO4 Inorganic materials 0.000 title claims abstract description 27
- 239000010452 phosphate Substances 0.000 title claims abstract description 27
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 52
- 235000019796 monopotassium phosphate Nutrition 0.000 claims abstract description 42
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 claims abstract description 42
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 15
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 15
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims abstract description 13
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims abstract description 13
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229910000389 calcium phosphate Inorganic materials 0.000 claims abstract description 7
- 235000019691 monocalcium phosphate Nutrition 0.000 claims abstract description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 77
- 239000000395 magnesium oxide Substances 0.000 claims description 41
- 239000002002 slurry Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 238000009408 flooring Methods 0.000 claims description 10
- 239000000919 ceramic Substances 0.000 claims description 9
- 239000012779 reinforcing material Substances 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000011521 glass Substances 0.000 claims description 6
- 239000004005 microsphere Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 5
- 239000011152 fibreglass Substances 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
- 230000009969 flowable effect Effects 0.000 claims description 4
- 239000010451 perlite Substances 0.000 claims description 4
- 235000019362 perlite Nutrition 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 239000005909 Kieselgur Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000008262 pumice Substances 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims 5
- 238000005266 casting Methods 0.000 claims 1
- 239000012783 reinforcing fiber Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 238000003892 spreading Methods 0.000 claims 1
- 239000000835 fiber Substances 0.000 description 23
- 239000000463 material Substances 0.000 description 13
- -1 polypropylene Polymers 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 239000010881 fly ash Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 230000002787 reinforcement Effects 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920000271 Kevlar® Polymers 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 239000004761 kevlar Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229920002748 Basalt fiber Polymers 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000010754 BS 2869 Class F Substances 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012615 aggregate Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002969 artificial stone Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical group [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000011499 joint compound Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910021487 silica fume Inorganic materials 0.000 description 1
- 239000003469 silicate cement Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/60—Flooring materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/60—Flooring materials
- C04B2111/62—Self-levelling compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/909,483 | 2010-10-21 | ||
| US12/909,483 US8663382B2 (en) | 2010-10-21 | 2010-10-21 | High strength phosphate-based cement having low alkalinity |
| PCT/US2011/056638 WO2012054429A1 (en) | 2010-10-21 | 2011-10-18 | High strength phosphate-based cement having low alkalinity |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2814131A1 CA2814131A1 (en) | 2012-04-26 |
| CA2814131C true CA2814131C (en) | 2019-02-19 |
Family
ID=44903402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2814131A Active CA2814131C (en) | 2010-10-21 | 2011-10-18 | High strength phosphate-based cement having low alkalinity |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8663382B2 (enExample) |
| EP (1) | EP2630103B1 (enExample) |
| JP (1) | JP5767714B2 (enExample) |
| CN (1) | CN103140453B (enExample) |
| AR (1) | AR083484A1 (enExample) |
| BR (1) | BR112013008124B1 (enExample) |
| CA (1) | CA2814131C (enExample) |
| MX (1) | MX2013003971A (enExample) |
| PL (1) | PL2630103T3 (enExample) |
| UA (1) | UA111953C2 (enExample) |
| WO (1) | WO2012054429A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9815738B2 (en) | 2012-10-09 | 2017-11-14 | Premier Magnesia, Llc | Magnesium phosphate cement |
| US9809494B2 (en) * | 2012-10-09 | 2017-11-07 | Premier Magnesia, Llc | Magnesium phosphate cement |
| US10336036B2 (en) | 2013-03-15 | 2019-07-02 | United States Gypsum Company | Cementitious article comprising hydrophobic finish |
| US10479728B2 (en) | 2013-08-12 | 2019-11-19 | Certainteed Gypsum, Inc. | Struvite-K and Syngenite composition for use in building materials |
| US9422193B2 (en) | 2013-08-12 | 2016-08-23 | Certainteed Gypsum, Inc. | Struvite-K and syngenite composition for use in building materials |
| KR101692017B1 (ko) * | 2014-03-31 | 2017-01-03 | 강원대학교산학협력단 | 보통콘크리트에 기포 혼입 후 숏팅을 통한 섬유보강콘크리트 제조장치 및 이의 제조방법 |
| US9725369B2 (en) * | 2014-08-13 | 2017-08-08 | Crispycrete, Llc | Method of processing unhardened concrete |
| CN104261795A (zh) * | 2014-09-19 | 2015-01-07 | 深圳大学 | 一种磷酸盐胶凝材料及其制备方法 |
| CN104228184B (zh) * | 2014-09-19 | 2015-12-02 | 深圳大学 | 一种磷酸盐基纤维复合材料及其制备方法 |
| MX2018008581A (es) * | 2016-01-12 | 2019-01-10 | Premier Magnesia Llc | Cemento de fosfato de magnesio. |
| CN107344841B (zh) * | 2017-06-14 | 2019-08-30 | 上海建工集团股份有限公司 | 一种超轻可喷涂泡沫混凝土及其制品的制备方法 |
| US10759697B1 (en) | 2019-06-11 | 2020-09-01 | MSB Global, Inc. | Curable formulations for structural and non-structural applications |
| WO2025096623A1 (en) * | 2023-10-31 | 2025-05-08 | National Technology & Engineering Solutions Of Sandia, Llc | Calcium aluminate phosphate cements |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2455758A (en) | 1941-12-10 | 1948-12-07 | Greger Herbert Hans | Method of preparing a. mineral binder |
| DE1471243A1 (de) | 1964-11-20 | 1969-08-14 | Setsuo Higashi | Verfahren zum Herstellen einer mit Wasser schnell abbindenden Zementmasse,insbesondere fuer die Zahnheilkunde |
| US3879209A (en) | 1971-12-01 | 1975-04-22 | Republic Steel Corp | Process for preparing fast-setting aggregate compositions and products of low porosity produced therewith |
| US3960580A (en) | 1974-11-21 | 1976-06-01 | W. R. Grace & Co. | Magnesium phosphate concrete compositions |
| US4504555A (en) | 1982-09-07 | 1985-03-12 | Masonite Corporation | Composition and process for forming inorganic resins and resulting product |
| US4721659A (en) | 1985-11-12 | 1988-01-26 | Stauffer Chemical Company | Process for applying a cementitious material to a structural base and article produced therefrom |
| US5002610A (en) | 1985-12-12 | 1991-03-26 | Rhone-Poulenc Basic Chemicals Co. | Process for making reinforced magnesium phosphate fast-setting cements |
| US5178845A (en) | 1988-04-20 | 1993-01-12 | Norian Corporation | Intimate mixture of calcium and phosphate sources as precursor to hydroxyapatite |
| US5053212A (en) | 1988-04-20 | 1991-10-01 | Norian Corporation | Intimate mixture of calcium and phosphate sources as precursor to hydroxyapatite |
| WO1992004293A1 (en) | 1990-08-31 | 1992-03-19 | Calvin Shubow | Bonded aggregate compositions and binders for the same |
| US5605713A (en) | 1991-11-22 | 1997-02-25 | Boltong; Maria G. | Process for the preparation of calcium phosphate cements and its application as bio-materials |
| US5382289A (en) | 1993-09-17 | 1995-01-17 | Ashland Oil, Inc. | Inorganic foundry binder systems and their uses |
| US5496399A (en) | 1994-08-23 | 1996-03-05 | Norian Corporation | Storage stable calcium phosphate cements |
| FR2742142B1 (fr) | 1995-12-08 | 1998-01-16 | Rhone Poulenc Chimie | Nouvelle phase liante pour ciments phosphomagnesiens et leur utilisation pour la preparation de mortiers |
| US5830815A (en) | 1996-03-18 | 1998-11-03 | The University Of Chicago | Method of waste stabilization via chemically bonded phosphate ceramics |
| US6204214B1 (en) | 1996-03-18 | 2001-03-20 | University Of Chicago | Pumpable/injectable phosphate-bonded ceramics |
| US6136088A (en) | 1997-10-09 | 2000-10-24 | Mbt Holding Ag | Rapid setting, high early strength binders |
| US6561269B1 (en) | 1999-04-30 | 2003-05-13 | The Regents Of The University Of California | Canister, sealing method and composition for sealing a borehole |
| US20020009622A1 (en) | 1999-08-03 | 2002-01-24 | Goodson David M. | Sprayable phosphate cementitious coatings and a method and apparatus for the production thereof |
| US6458423B1 (en) | 1999-08-03 | 2002-10-01 | David M. Goodson | Sprayable phosphate cementitious coatings and a method and apparatus for the production thereof |
| US20040132608A1 (en) | 2000-06-22 | 2004-07-08 | Lally Thomas Joseph | Multi-purpose refractory material |
| US7045476B1 (en) | 2000-06-22 | 2006-05-16 | Thomas Joseph Lally | Aerated refractory, method for producing high-temperature structural members |
| US7429290B2 (en) | 2000-06-22 | 2008-09-30 | Thomas Joseph Lally | Fire-retardant coating, method for producing fire-retardant building materials |
| WO2003031367A2 (en) | 2001-08-10 | 2003-04-17 | Ceratech, Inc. | Composote materials and methods of making and using such composite materials |
| FI115046B (fi) | 2001-11-01 | 2005-02-28 | Kautar Oy | Hydraulisesti kovettuva sideaineseos ja menetelmä sen valmistamiseksi |
| US6776837B2 (en) | 2001-11-30 | 2004-08-17 | The University Of Chicago | Formation of chemically bonded ceramics with magnesium dihydrogen phosphate binder |
| US7062888B2 (en) | 2003-05-27 | 2006-06-20 | Lawrence M. Rich | Vapor and termite barrier and method for concrete slab construction |
| US20050160944A1 (en) | 2004-01-23 | 2005-07-28 | The University Of Chicago | Permafrost ceramicrete |
| US7204880B1 (en) | 2004-05-21 | 2007-04-17 | Turner Terry A | Rapid setting cement |
| US7527098B2 (en) | 2004-05-27 | 2009-05-05 | Halliburton Energy Services, Inc. | Methods of increasing the thickening times of phosphate-based cementitious compositions in high-temperature wellbores |
| US7160383B2 (en) | 2004-06-15 | 2007-01-09 | Uchicago Argonne, Llc | Composition and application of novel sprayable phosphate cement (grancrete) that bonds to styrofoam |
| US7595092B2 (en) | 2006-03-01 | 2009-09-29 | Pyrotite Coating Of Canada, Inc. | System and method for coating a fire-resistant material on a substrate |
| US7699928B2 (en) | 2006-07-14 | 2010-04-20 | Grancrete, Inc. | Sprayable and pumpable phosphate cement |
| US20080171179A1 (en) * | 2007-01-11 | 2008-07-17 | Quiet Solution, Llc | Low embodied energy wallboards and methods of making same |
| US20100101457A1 (en) | 2007-05-25 | 2010-04-29 | Surace Kevin J | Low embodied energy sheathing panels and methods of making same |
| DE102008009390A1 (de) | 2007-08-24 | 2009-02-26 | Bayer Materialscience Ag | Niedrigviskose wässrige Klebstoff-Polymer-Dispersionen |
| CN101381219A (zh) | 2008-10-09 | 2009-03-11 | 上海交通大学 | 磷酸盐快速修补建筑材料 |
-
2010
- 2010-10-21 US US12/909,483 patent/US8663382B2/en active Active
-
2011
- 2011-10-18 PL PL11776982T patent/PL2630103T3/pl unknown
- 2011-10-18 WO PCT/US2011/056638 patent/WO2012054429A1/en not_active Ceased
- 2011-10-18 JP JP2013534990A patent/JP5767714B2/ja not_active Expired - Fee Related
- 2011-10-18 CN CN201180047985.8A patent/CN103140453B/zh not_active Expired - Fee Related
- 2011-10-18 BR BR112013008124-4A patent/BR112013008124B1/pt not_active IP Right Cessation
- 2011-10-18 CA CA2814131A patent/CA2814131C/en active Active
- 2011-10-18 MX MX2013003971A patent/MX2013003971A/es active IP Right Grant
- 2011-10-18 UA UAA201305799A patent/UA111953C2/uk unknown
- 2011-10-18 EP EP11776982.8A patent/EP2630103B1/en not_active Not-in-force
- 2011-10-19 AR ARP110103870 patent/AR083484A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013540098A (ja) | 2013-10-31 |
| AR083484A1 (es) | 2013-02-27 |
| CN103140453A (zh) | 2013-06-05 |
| CA2814131A1 (en) | 2012-04-26 |
| BR112013008124A2 (pt) | 2018-04-24 |
| US8663382B2 (en) | 2014-03-04 |
| JP5767714B2 (ja) | 2015-08-19 |
| EP2630103B1 (en) | 2021-02-24 |
| EP2630103A1 (en) | 2013-08-28 |
| RU2013120408A (ru) | 2014-11-27 |
| UA111953C2 (uk) | 2016-07-11 |
| WO2012054429A1 (en) | 2012-04-26 |
| PL2630103T3 (pl) | 2021-07-26 |
| US20120100295A1 (en) | 2012-04-26 |
| BR112013008124B1 (pt) | 2020-07-14 |
| CN103140453B (zh) | 2016-01-20 |
| MX2013003971A (es) | 2013-06-28 |
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