CA2805769C - Catalyst components for the polymerization of olefins - Google Patents

Catalyst components for the polymerization of olefins Download PDF

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Publication number
CA2805769C
CA2805769C CA2805769A CA2805769A CA2805769C CA 2805769 C CA2805769 C CA 2805769C CA 2805769 A CA2805769 A CA 2805769A CA 2805769 A CA2805769 A CA 2805769A CA 2805769 C CA2805769 C CA 2805769C
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Canada
Prior art keywords
catalyst component
compound
solid catalyst
peak
diffraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2805769A
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English (en)
French (fr)
Other versions
CA2805769A1 (en
Inventor
Jochem T. M. Pater
Dario Liguori
Gianni Vitale
Gianni Collina
Diego Brita
Tiziano Dall'occo
Giampiero Morini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Poliolefine Italia SRL
Original Assignee
Basell Poliolefine Italia SRL
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Publication of CA2805769A1 publication Critical patent/CA2805769A1/en
Application granted granted Critical
Publication of CA2805769C publication Critical patent/CA2805769C/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CA2805769A 2010-08-24 2011-08-10 Catalyst components for the polymerization of olefins Active CA2805769C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US80689210A 2010-08-24 2010-08-24
US12/806,892 2010-08-24
EP10175027 2010-09-02
EP10175027.1 2010-09-02
PCT/EP2011/063730 WO2012025379A1 (en) 2010-08-24 2011-08-10 Catalyst components for the polymerization of olefins

Publications (2)

Publication Number Publication Date
CA2805769A1 CA2805769A1 (en) 2012-03-01
CA2805769C true CA2805769C (en) 2017-11-21

Family

ID=44629937

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2805769A Active CA2805769C (en) 2010-08-24 2011-08-10 Catalyst components for the polymerization of olefins

Country Status (10)

Country Link
US (1) US10155825B2 (enExample)
EP (1) EP2609124B1 (enExample)
JP (1) JP5898200B2 (enExample)
KR (1) KR101835309B1 (enExample)
CN (1) CN103052656B (enExample)
BR (1) BR112013004167B1 (enExample)
CA (1) CA2805769C (enExample)
ES (1) ES2645793T3 (enExample)
RU (1) RU2579371C2 (enExample)
WO (1) WO2012025379A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10138310B2 (en) * 2010-08-24 2018-11-27 Equistar Chemicals, Lp Preparation of LLDPE resins and films having low gels
JP2018505249A (ja) * 2014-12-12 2018-02-22 サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ ポリエチレン組成物およびその組成物を含む管
BR112018070434B1 (pt) * 2016-04-29 2022-10-25 Basell Poliolefine Italia S.R.L Componente catalisador sólido e processo para homopolimerização ou copolimerização de olefinas
EP3458536A1 (en) 2016-05-20 2019-03-27 Equistar Chemicals LP In-line polyolefin based adhesive compositions having graft polyolefin/elastomer copolymers
CA3024106A1 (en) * 2016-05-20 2017-11-23 Equistar Chemicals, Lp Processes for producing in-line polyolefin based adhesive compositions, and adhesive compositions and films thereof
US11021555B2 (en) 2016-07-15 2021-06-01 Basell Poliolefine Italia S.R.L. Catalyst for the polymerization of olefins
EP3519462A1 (en) 2016-09-30 2019-08-07 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
WO2018094085A1 (en) 2016-11-18 2018-05-24 Equistar Chemicals, Lp Polyolefin materials for rotational molding applications having improved impact properties and color stability
CN110072896B (zh) 2016-12-19 2021-10-26 巴塞尔聚烯烃意大利有限公司 用来聚合烯烃的催化剂组分以及由其获得的催化剂
EP3574048B1 (en) 2017-01-27 2023-07-26 Equistar Chemicals LP Peroxide-modified polyethylene, compositions, and applications
US10654956B2 (en) 2017-05-03 2020-05-19 Equistar Chemicals, Lp Ethylene alpha-olefin copolymers and methods
WO2018206321A1 (en) 2017-05-12 2018-11-15 Basell Poliolefine Italia S.R.L. Process for activating a catalyst for the polymerization of ethylene
US20190077129A1 (en) 2017-09-08 2019-03-14 Equistar Chemicals, Lp Polyolefin based adhesive compositions having grafted polyolefin copolymers and methods of formation
EP3974052A1 (en) * 2020-09-23 2022-03-30 Basell Polyolefine GmbH Vessel system
RU2759723C1 (ru) * 2020-12-23 2021-11-17 Публичное Акционерное Общество "Нижнекамскнефтехим" Способ непрерывного промотирования титан-магниевого катализатора Циглера-Натта в процессах (со)полимеризации олефинов

Family Cites Families (22)

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Publication number Priority date Publication date Assignee Title
SU14982A1 (ru) * 1928-02-20 1930-04-30 Б.Г. Соколов Державка дл пластинчатых резцов
NL162661B (nl) 1968-11-21 1980-01-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1.
YU35844B (en) * 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
JPS5373279A (en) * 1976-12-13 1978-06-29 Mitsubishi Chem Ind Ltd Preparation of olefin polymer
US4302565A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
IT1096661B (it) 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
FI80055C (fi) 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
CN1036852C (zh) 1988-03-03 1997-12-31 Bp化学有限公司 烯烃聚合催化剂的预活化载体及其制备方法
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
JP2879347B2 (ja) 1989-10-02 1999-04-05 チッソ株式会社 オレフィン重合用触媒の製法
IT1246614B (it) 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
IT1250731B (it) 1991-07-31 1995-04-21 Himont Inc Procedimento per la preparazione di polietilene lineare a bassa densita'
IT1254279B (it) 1992-03-13 1995-09-14 Montecatini Tecnologie Srl Procedimento per la polimerizzazione in fase gas delle olefine
US5990251A (en) * 1993-07-13 1999-11-23 Bp Chemicals Limited Process for polymerising olefin with a Ziegler-Natta catalyst
IL127230A (en) 1997-03-29 2004-07-25 Montell Technology Company Bv Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom
CA2510679C (en) * 2002-12-18 2013-04-23 Basell Poliolefine Italia S.P.A. Polymerization catalysts comprising titanium and magnesium
EP1572355B1 (en) 2002-12-18 2011-06-29 Basell Poliolefine Italia S.r.l. Magnesium dichloride-based adducts and catalyst components obtained therefrom
KR101167538B1 (ko) * 2003-05-29 2012-07-20 바셀 폴리올레핀 이탈리아 에스.알.엘 촉매 성분의 제조 방법 및 그로부터 수득된 성분들
WO2005058982A1 (en) 2003-12-19 2005-06-30 Basell Polyolefine Gmbh Process for the (co)polymerization of ethylene
US20080051535A1 (en) * 2006-08-23 2008-02-28 Fina Technology, Inc. Promoter system for polymerization processes and polymers formed therefrom
KR20090102802A (ko) 2006-12-20 2009-09-30 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀의 중합을 위한 촉매 성분 및 이로부터 수득된 촉매

Also Published As

Publication number Publication date
BR112013004167A2 (pt) 2016-05-10
BR112013004167B1 (pt) 2020-02-04
JP5898200B2 (ja) 2016-04-06
JP2013536290A (ja) 2013-09-19
KR20130100106A (ko) 2013-09-09
ES2645793T3 (es) 2017-12-07
EP2609124B1 (en) 2017-09-20
US20130158214A1 (en) 2013-06-20
KR101835309B1 (ko) 2018-03-08
CN103052656B (zh) 2016-06-01
WO2012025379A1 (en) 2012-03-01
CN103052656A (zh) 2013-04-17
RU2013112943A (ru) 2014-09-27
US10155825B2 (en) 2018-12-18
RU2579371C2 (ru) 2016-04-10
CA2805769A1 (en) 2012-03-01
EP2609124A1 (en) 2013-07-03

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