CA2702498A1 - Solid catalyst useful for converting an alkylene oxide to an alkylene glycol - Google Patents
Solid catalyst useful for converting an alkylene oxide to an alkylene glycol Download PDFInfo
- Publication number
- CA2702498A1 CA2702498A1 CA2702498A CA2702498A CA2702498A1 CA 2702498 A1 CA2702498 A1 CA 2702498A1 CA 2702498 A CA2702498 A CA 2702498A CA 2702498 A CA2702498 A CA 2702498A CA 2702498 A1 CA2702498 A1 CA 2702498A1
- Authority
- CA
- Canada
- Prior art keywords
- ion exchange
- exchange resin
- quaternary ammonium
- glycol
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title abstract 5
- 125000002947 alkylene group Chemical group 0.000 title abstract 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title abstract 4
- -1 alkylene glycol Chemical compound 0.000 title abstract 3
- 239000011949 solid catalyst Substances 0.000 title 1
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 3
- 239000003456 ion exchange resin Substances 0.000 abstract 3
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 3
- 239000004793 Polystyrene Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229920002223 polystyrene Polymers 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 230000036571 hydration Effects 0.000 abstract 1
- 238000006703 hydration reaction Methods 0.000 abstract 1
- 125000005496 phosphonium group Chemical group 0.000 abstract 1
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
- C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
- C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Polyethers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/872,318 | 2007-10-15 | ||
| US11/872,318 US8053609B2 (en) | 2007-10-15 | 2007-10-15 | Solid catalyst useful for converting an alkylene oxide to an alkylene glycol |
| PCT/US2008/078654 WO2009051972A1 (en) | 2007-10-15 | 2008-10-03 | Solid catalyst useful for converting an alkylene oxide to an alkylene glycol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2702498A1 true CA2702498A1 (en) | 2009-04-23 |
Family
ID=40534877
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2702498A Abandoned CA2702498A1 (en) | 2007-10-15 | 2008-10-03 | Solid catalyst useful for converting an alkylene oxide to an alkylene glycol |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8053609B2 (enExample) |
| EP (1) | EP2212023B1 (enExample) |
| JP (1) | JP2011501692A (enExample) |
| KR (1) | KR101502921B1 (enExample) |
| CN (1) | CN101821002B (enExample) |
| BR (1) | BRPI0818057B1 (enExample) |
| CA (1) | CA2702498A1 (enExample) |
| MX (1) | MX2010004077A (enExample) |
| RU (1) | RU2470706C2 (enExample) |
| TW (1) | TWI527625B (enExample) |
| WO (1) | WO2009051972A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106478375A (zh) * | 2015-08-25 | 2017-03-08 | 中国石油化工股份有限公司 | 一种以阴离子交换树脂为催化剂合成邻二醇类化合物的方法 |
| CN106478374A (zh) * | 2015-08-25 | 2017-03-08 | 中国石油化工股份有限公司 | 一种通过开环反应制备邻二醇类化合物的方法 |
| CN106478365A (zh) * | 2015-08-25 | 2017-03-08 | 中国石油化工股份有限公司 | 一种邻二醇类化合物的合成方法 |
| CN112239393B (zh) * | 2019-07-17 | 2023-06-06 | 中国石油化工股份有限公司 | 纳米复合离子交换树脂催化剂及其应用 |
| CN116020557A (zh) * | 2021-10-25 | 2023-04-28 | 中国石油化工股份有限公司 | 离子交换树脂催化剂及其制备方法和应用 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6056141B2 (ja) | 1981-02-24 | 1985-12-09 | 株式会社日本触媒 | アルキレングリコールの製造方法 |
| US4560813A (en) | 1984-03-28 | 1985-12-24 | Union Carbide Corporation | Processes for the production of alkylene glycol in the presence of organometalate |
| US4701571A (en) * | 1986-06-30 | 1987-10-20 | Union Carbide Corporation | Process for the production of alkylene glycols with metalate-containing solids |
| RU2002726C1 (ru) | 1992-05-19 | 1993-11-15 | Государственное научно-производственное предпри тие "Совинтех" | Способ получени алкиленгликолей |
| RU2001901C1 (ru) | 1992-05-19 | 1993-10-30 | Государственное научно-производственное предпри тие "Совинтех" | Способ получени алкиленгликолей |
| JPH07204523A (ja) * | 1994-01-19 | 1995-08-08 | Mitsubishi Chem Corp | 陰イオン交換樹脂およびその製造方法 |
| CZ292902B6 (cs) | 1994-01-31 | 2004-01-14 | Shell Internationale Research Maatschappij B. V. | Způsob přípravy ethylenglykolu |
| JPH07289912A (ja) * | 1994-03-01 | 1995-11-07 | Mitsubishi Chem Corp | 固体塩基性触媒 |
| WO1997033850A1 (fr) | 1996-03-11 | 1997-09-18 | Valery Fedorovich Shvets | Procede de production d'alcyleneglycols |
| CA2268158A1 (en) * | 1996-10-04 | 1998-04-09 | The Dow Chemical Company | A method for producing glycols |
| JP3815045B2 (ja) * | 1997-04-30 | 2006-08-30 | 三菱化学株式会社 | アルキレングリコール類の製造方法 |
| ES2200399T3 (es) * | 1997-12-18 | 2004-03-01 | Dow Global Technologies Inc. | Procedimiento de produccion de etilenglicol. |
| US6156942A (en) * | 1998-12-14 | 2000-12-05 | Shell Oil Company | Catalyst stabilizing additive in the hydrolysis of alkylene oxides |
| MY121124A (en) * | 1998-12-14 | 2005-12-30 | Shell Int Research | Catalyst stabilising additive in the hydrolysis of alkylene oxides |
| US6153801A (en) * | 1998-12-14 | 2000-11-28 | Shell Oil Company | Carboxylates in catalytic hydrolysis of alkylene oxides |
| MY120595A (en) * | 1998-12-14 | 2005-11-30 | Shell Int Research | Quaternary phosphonium salt catalysts in catalytic hydrolysis of alkylene oxides |
| PE20001571A1 (es) * | 1998-12-14 | 2001-01-26 | Shell Int Research | Carboxilatos en la hidrolisis catalitica de oxidos de alquileno |
| US6211419B1 (en) * | 2000-04-24 | 2001-04-03 | The Dow Chemical Company | Process for the preparation of alkylene glycols |
| JP2002030112A (ja) * | 2000-07-18 | 2002-01-31 | Mitsubishi Chemicals Corp | アニオン交換樹脂、その製法及びこれを用いるクランピング防止方法 |
| US6730816B2 (en) * | 2000-12-29 | 2004-05-04 | Rohm And Haas Company | High productivity bisphenol-A catalyst |
| JP2005060289A (ja) * | 2003-08-11 | 2005-03-10 | Mitsui Chemicals Inc | フェノール類の製造方法 |
-
2007
- 2007-10-15 US US11/872,318 patent/US8053609B2/en active Active
-
2008
- 2008-10-03 EP EP08838859.0A patent/EP2212023B1/en active Active
- 2008-10-03 JP JP2010528950A patent/JP2011501692A/ja active Pending
- 2008-10-03 CN CN200880111607.XA patent/CN101821002B/zh active Active
- 2008-10-03 CA CA2702498A patent/CA2702498A1/en not_active Abandoned
- 2008-10-03 RU RU2010119451/04A patent/RU2470706C2/ru active
- 2008-10-03 BR BRPI0818057-1A patent/BRPI0818057B1/pt active IP Right Grant
- 2008-10-03 KR KR1020107010705A patent/KR101502921B1/ko active Active
- 2008-10-03 MX MX2010004077A patent/MX2010004077A/es active IP Right Grant
- 2008-10-03 WO PCT/US2008/078654 patent/WO2009051972A1/en not_active Ceased
- 2008-10-09 TW TW097139098A patent/TWI527625B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0818057B1 (pt) | 2022-05-17 |
| KR20100090260A (ko) | 2010-08-13 |
| BRPI0818057A2 (pt) | 2015-03-31 |
| EP2212023B1 (en) | 2016-05-11 |
| CN101821002B (zh) | 2014-11-05 |
| TWI527625B (zh) | 2016-04-01 |
| US20090099393A1 (en) | 2009-04-16 |
| RU2010119451A (ru) | 2011-11-27 |
| CN101821002A (zh) | 2010-09-01 |
| RU2470706C2 (ru) | 2012-12-27 |
| KR101502921B1 (ko) | 2015-03-16 |
| MX2010004077A (es) | 2010-05-24 |
| US8053609B2 (en) | 2011-11-08 |
| WO2009051972A1 (en) | 2009-04-23 |
| EP2212023A4 (en) | 2010-12-01 |
| TW200934586A (en) | 2009-08-16 |
| EP2212023A1 (en) | 2010-08-04 |
| JP2011501692A (ja) | 2011-01-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20130807 |
|
| FZDE | Discontinued |
Effective date: 20151005 |