CA2701091A1 - Process for manufacturing a galvannealed steel sheet by dff regulation - Google Patents

Process for manufacturing a galvannealed steel sheet by dff regulation Download PDF

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Publication number
CA2701091A1
CA2701091A1 CA2701091A CA2701091A CA2701091A1 CA 2701091 A1 CA2701091 A1 CA 2701091A1 CA 2701091 A CA2701091 A CA 2701091A CA 2701091 A CA2701091 A CA 2701091A CA 2701091 A1 CA2701091 A1 CA 2701091A1
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CA
Canada
Prior art keywords
steel sheet
oxide
process according
temperature
soaking
Prior art date
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Granted
Application number
CA2701091A
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French (fr)
Other versions
CA2701091C (en
Inventor
Jean-Michel Mataigne
Florence Bertrand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ArcelorMittal France SA
Nippon Steel Corp
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Individual
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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/34Methods of heating
    • C21D1/52Methods of heating with flames
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/54Furnaces for treating strips or wire
    • C21D9/56Continuous furnaces for strip or wire
    • C21D9/561Continuous furnaces for strip or wire with a controlled atmosphere or vacuum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/11Making amorphous alloys
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • C23C2/0222Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating in a reactive atmosphere, e.g. oxidising or reducing atmosphere
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • C23C2/0224Two or more thermal pretreatments
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06Zinc or cadmium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26After-treatment
    • C23C2/261After-treatment in a gas atmosphere, e.g. inert or reducing atmosphere
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26After-treatment
    • C23C2/28Thermal after-treatment, e.g. treatment in oil bath
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/40Plates; Strips

Abstract

The invention deals with a process for manufacturing a hot-dip galvannealed steel sheet having a TRIP microstructure, and comprising, by % by weight, 0.01 <= C <= 0.22%, 0.50 <=
Mn <= 2.0%, 0.5 < Si <= 2.0%, 0.005 <= Al <= 2.0%, Mo < 0.01 %, Cr <=1.0%, P < 0.02%, Ti <= 0.20%, V <= 0.40%, Ni <=
1.0%, Nb <= 0.20%, the balance of the composition being iron and unavoidable impurities resulting from the smelting, said process comprising the steps consisting in: - oxidizing said steel sheet in order to form a layer of iron oxide on the surface of the steel sheet, and to form an.
internal oxide of at least one type of oxide selected from the group consisting of Si oxide, Mn oxide, Al oxide, complex oxide comprising Si and Mn, complex oxide comprising Si and Al complex oxide comprising Al and Mn, and complex comprising Si, Mn and Al, -reducing said oxidized steel sheet in order to reduce the layer of iron oxide, - hot-dip galvanising said reduced steel sheet to form a zinc-based coated steel sheet, and - subjecting said zinc-based coated steel sheet to an alloying treatment to form a galvannealed steel sheet.

Claims (11)

1. Process for manufacturing a hot-dip galvannealed steel sheet having a TRIP microstructure comprising ferrite, residual austenite and optionally martensite and/or bainite, said process comprising the steps consisting in:
- providing a steel sheet whose composition comprises, by weight:
0.01 <= C <= 0.22%
0.50 <= Mn <= 2.0%
0.5 < Si <= 2.0%
0.005 <= Al <= 2.0 Mo < 0.01%
Cr <= 1.0%
P < 0.02%
Ti <= 0.20%
V <= 0.40%
Ni <= 1.0%
Nb <= 0.20%, the balance of the composition being iron and unavoidable impurities resulting from the smelting, - oxidizing said steel sheet by heating it from ambient temperature to a temperature T1 between 680 to 800°C, in a direct flame furnace where the atmosphere comprises air and fuel with an air-to-fuel ratio between 1.0 and 1.2 in order to form a layer of iron oxide on the surface of the steel sheet, and to form an internal oxide of at least one type of oxide selected from the group consisting of Si oxide, Mn oxide, Al ;oxide, complex oxide comprising Si and Mn, complex oxide comprising Si and Al, complex oxide comprising Al and Mn, and complex comprising Si, Mn and Al, - reducing said oxidized steel sheet in order to reduce the layer of iron oxide, - hot-dip galvanising said reduced steel sheet to form a zinc-based coated steel sheet, and - subjecting said zinc-based coated steel sheet to an alloying treatment to form a galvannealed steel sheet.
2. Process according to claim 1, wherein said steel sheet comprises, in %
by weight, P < 0Ø 10%.
3. Process according to claim 1 or 2, wherein said steel sheet comprises, in % by weight, Mo <= 0.006%.
4. Process according to any one of claims 1 to 3, wherein the reduction of.
said oxidized steel sheet consists of a heat treatment performed in an atmosphere comprising more than 15% by volume of hydrogen, the balance being nitrogen and unavoidable impurities, said heat treatment comprising a heating phase from the temperature T1 to a soaking temperature T2, a soaking phase at said soaking temperature T2 for a soaking time t2, and a cooling phase from said soaking temperature T2 to a cooling temperature T3.
5. Process according to claims 4, wherein said soaking temperature T2 is between 770 and 850 °C.
6. Process according to claim 4 or 5, wherein said soaking time t2 is between 20 and 180 s.
7. Process according to any one of claims 4 to 6, wherein said cooling temperature T3 is between 460 to 510°C.
8. Process according to any one of claims 3 to 7, wherein said reduction is performed in a radiant tube furnace or in a resistance furnace.
9. Process according to, any one of claims 1 to 8, wherein the hot-dip galvanizing is performed by hot-dipping said reduced steel sheet in a molten bath comprising 0.08 to 0.135% by weight of aluminium, the balance being zinc and unavoidable impurities.
10. Process according to claim 9, wherein the temperature of said molten bath is between 450 and 500°C.
11. Process according to any one of claims 1 to 10, wherein said alloying treatment is performed by heating said zinc-based coated steel sheet at a temperature T4 between 460 and 510°C for a soaking time t4 between and 30 s.
CA2701091A 2007-06-29 2008-06-06 Process for manufacturing a galvannealed steel sheet by dff regulation Active CA2701091C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07290816A EP2009129A1 (en) 2007-06-29 2007-06-29 Process for manufacturing a galvannealed steel sheet by DFF regulation
EP07290816.3 2007-06-29
PCT/IB2008/001462 WO2009004425A1 (en) 2007-06-29 2008-06-06 Process for manufacturing a galvannealed steel sheet by dff regulation

Publications (2)

Publication Number Publication Date
CA2701091A1 true CA2701091A1 (en) 2009-01-08
CA2701091C CA2701091C (en) 2012-04-17

Family

ID=38608886

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2701091A Active CA2701091C (en) 2007-06-29 2008-06-06 Process for manufacturing a galvannealed steel sheet by dff regulation

Country Status (13)

Country Link
US (1) US20100193081A1 (en)
EP (2) EP2009129A1 (en)
JP (2) JP5713673B2 (en)
KR (1) KR101273308B1 (en)
CN (1) CN101809182B (en)
AR (1) AR067339A1 (en)
AT (1) ATE521726T1 (en)
BR (1) BRPI0813687B1 (en)
CA (1) CA2701091C (en)
ES (1) ES2371985T3 (en)
PL (1) PL2171116T3 (en)
RU (1) RU2451107C2 (en)
WO (1) WO2009004425A1 (en)

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KR20120075260A (en) 2010-12-28 2012-07-06 주식회사 포스코 Hot dip plated steel sheet excellent in plating adhesiveness and method for manufacturing the hot dip plated steel sheet
BR112014007530B1 (en) * 2011-09-30 2018-12-11 Nippon Steel & Sumitomo Metal Corporation high strength hot dip galvanized steel sheet and process for producing it
KR20130076589A (en) * 2011-12-28 2013-07-08 주식회사 포스코 High strength galvanized steel sheet having excellent surface property and coating adhesion method for manufacturing the same
KR101657862B1 (en) * 2012-04-17 2016-09-19 제이에프이 스틸 가부시키가이샤 Method for producing alloyed hot-dip galvanized steel sheet having excellent adhesion to plating and excellent sliding properties
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JP5920249B2 (en) * 2013-03-05 2016-05-18 Jfeスチール株式会社 High strength hot-dip galvanized steel sheet with excellent plating adhesion and method for producing the same
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Also Published As

Publication number Publication date
AR067339A1 (en) 2009-10-07
EP2171116B1 (en) 2011-08-24
BRPI0813687A8 (en) 2015-12-15
ATE521726T1 (en) 2011-09-15
KR20100055389A (en) 2010-05-26
JP2015078438A (en) 2015-04-23
RU2010102924A (en) 2011-08-10
BRPI0813687A2 (en) 2014-12-30
EP2009129A1 (en) 2008-12-31
CN101809182A (en) 2010-08-18
CA2701091C (en) 2012-04-17
WO2009004425A1 (en) 2009-01-08
JP5713673B2 (en) 2015-05-07
BRPI0813687B1 (en) 2018-10-30
CN101809182B (en) 2015-08-05
KR101273308B1 (en) 2013-06-11
RU2451107C2 (en) 2012-05-20
EP2171116A1 (en) 2010-04-07
ES2371985T3 (en) 2012-01-12
PL2171116T3 (en) 2012-01-31
US20100193081A1 (en) 2010-08-05
JP2010532820A (en) 2010-10-14

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