CA2670040A1 - Method for treating ligno-cellulosic materials - Google Patents
Method for treating ligno-cellulosic materials Download PDFInfo
- Publication number
- CA2670040A1 CA2670040A1 CA002670040A CA2670040A CA2670040A1 CA 2670040 A1 CA2670040 A1 CA 2670040A1 CA 002670040 A CA002670040 A CA 002670040A CA 2670040 A CA2670040 A CA 2670040A CA 2670040 A1 CA2670040 A1 CA 2670040A1
- Authority
- CA
- Canada
- Prior art keywords
- treatment
- alkaline
- stage
- temperature
- pectin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 54
- 239000012978 lignocellulosic material Substances 0.000 title claims description 8
- 238000011282 treatment Methods 0.000 claims abstract description 56
- 229920001277 pectin Polymers 0.000 claims abstract description 55
- 239000001814 pectin Substances 0.000 claims abstract description 52
- 235000010987 pectin Nutrition 0.000 claims abstract description 52
- 239000003513 alkali Substances 0.000 claims abstract description 24
- 238000004537 pulping Methods 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims description 41
- 238000004061 bleaching Methods 0.000 claims description 25
- 239000002023 wood Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 14
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000007844 bleaching agent Substances 0.000 claims description 7
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
- 239000002738 chelating agent Substances 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 230000000087 stabilizing effect Effects 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 4
- 239000011121 hardwood Substances 0.000 claims description 3
- 239000011122 softwood Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 2
- 238000005886 esterification reaction Methods 0.000 claims description 2
- 150000004679 hydroxides Chemical class 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 235000012254 magnesium hydroxide Nutrition 0.000 claims description 2
- 125000004492 methyl ester group Chemical group 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000010902 straw Substances 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
- 150000002978 peroxides Chemical class 0.000 description 17
- 238000002203 pretreatment Methods 0.000 description 13
- 239000000835 fiber Substances 0.000 description 11
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 10
- 125000000129 anionic group Chemical group 0.000 description 10
- 238000003776 cleavage reaction Methods 0.000 description 10
- 238000010520 demethylation reaction Methods 0.000 description 10
- 230000007017 scission Effects 0.000 description 10
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 9
- 241000218657 Picea Species 0.000 description 9
- 125000002091 cationic group Chemical group 0.000 description 9
- 238000003379 elimination reaction Methods 0.000 description 9
- AEMOLEFTQBMNLQ-YMDCURPLSA-N D-galactopyranuronic acid Chemical compound OC1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-YMDCURPLSA-N 0.000 description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 229920001131 Pulp (paper) Polymers 0.000 description 8
- 230000017858 demethylation Effects 0.000 description 8
- 239000000706 filtrate Substances 0.000 description 8
- 239000003643 water by type Substances 0.000 description 8
- 239000010813 municipal solid waste Substances 0.000 description 7
- 229920002488 Hemicellulose Polymers 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000007670 refining Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 5
- 235000019341 magnesium sulphate Nutrition 0.000 description 5
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical group O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- -1 "anionic trash" Chemical compound 0.000 description 3
- 241000183024 Populus tremula Species 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- 238000006140 methanolysis reaction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- VQUZNVATTCZTQO-UHFFFAOYSA-N D-xyluronic acid Natural products O=CC(O)C(O)C(O)C(O)=O VQUZNVATTCZTQO-UHFFFAOYSA-N 0.000 description 2
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 description 2
- 235000008124 Picea excelsa Nutrition 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 239000013043 chemical agent Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 229940097043 glucuronic acid Drugs 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 230000000930 thermomechanical effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920001221 xylan Polymers 0.000 description 2
- 150000004823 xylans Chemical class 0.000 description 2
- AEMOLEFTQBMNLQ-AQKNRBDQSA-N D-glucopyranuronic acid Chemical compound OC1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-AQKNRBDQSA-N 0.000 description 1
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 1
- 229920000209 Hexadimethrine bromide Polymers 0.000 description 1
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920002230 Pectic acid Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- KDCIHNCMPUBDKT-UHFFFAOYSA-N hexane;propan-2-one Chemical compound CC(C)=O.CCCCCC KDCIHNCMPUBDKT-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000008206 lipophilic material Substances 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- LCLHHZYHLXDRQG-ZNKJPWOQSA-N pectic acid Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)O[C@H](C(O)=O)[C@@H]1OC1[C@H](O)[C@@H](O)[C@@H](OC2[C@@H]([C@@H](O)[C@@H](O)[C@H](O2)C(O)=O)O)[C@@H](C(O)=O)O1 LCLHHZYHLXDRQG-ZNKJPWOQSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 239000010318 polygalacturonic acid Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004076 pulp bleaching Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C1/00—Pretreatment of the finely-divided materials before digesting
- D21C1/06—Pretreatment of the finely-divided materials before digesting with alkaline reacting compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/02—Pretreatment of the raw materials by chemical or physical means
- D21B1/021—Pretreatment of the raw materials by chemical or physical means by chemical means
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/08—Removal of fats, resins, pitch or waxes; Chemical or physical purification, i.e. refining, of crude cellulose by removing non-cellulosic contaminants, optionally combined with bleaching
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20075729A FI121310B (fi) | 2007-10-17 | 2007-10-17 | Menetelmä pektiiniä sisältävien lignoselluloosapitoisten materiaalien käsittelemiseksi |
FI20075729 | 2007-10-17 | ||
PCT/FI2008/050574 WO2009050336A1 (en) | 2007-10-17 | 2008-10-15 | Method for treating ligno-cellulosic materials |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2670040A1 true CA2670040A1 (en) | 2009-04-23 |
Family
ID=38656876
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002670040A Abandoned CA2670040A1 (en) | 2007-10-17 | 2008-10-15 | Method for treating ligno-cellulosic materials |
Country Status (13)
Country | Link |
---|---|
US (1) | US20100269994A1 (xx) |
EP (1) | EP2201170A1 (xx) |
CN (1) | CN101568685A (xx) |
AR (1) | AR068684A1 (xx) |
AU (1) | AU2008313591A1 (xx) |
BR (1) | BRPI0806106A2 (xx) |
CA (1) | CA2670040A1 (xx) |
CL (1) | CL2008003043A1 (xx) |
FI (1) | FI121310B (xx) |
MX (1) | MX2009005832A (xx) |
RU (1) | RU2009117645A (xx) |
WO (1) | WO2009050336A1 (xx) |
ZA (1) | ZA200903900B (xx) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003008703A1 (en) * | 2001-07-19 | 2003-01-30 | Andritz Inc. | Four stage alkaline peroxide mechanical pulping |
US20040200586A1 (en) * | 2002-07-19 | 2004-10-14 | Martin Herkel | Four stage alkaline peroxide mechanical pulping |
US8845860B2 (en) | 2010-09-16 | 2014-09-30 | Georgia-Pacific Consumer Products Lp | High brightness pulps from lignin rich waste papers |
CN105735022B (zh) * | 2016-02-24 | 2018-04-13 | 孔凡宾 | 一种造纸制浆药液及使用该药液的制浆工艺 |
CN108071041A (zh) * | 2017-12-21 | 2018-05-25 | 岳阳林纸股份有限公司 | 一种混合材漂白化机浆的制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5433825A (en) * | 1992-02-06 | 1995-07-18 | The United States Of America As Represented By The Secretary Of Agriculture | Method for pulping wood chips separate alkali and peroxymonosulfate treatments |
US20040200586A1 (en) * | 2002-07-19 | 2004-10-14 | Martin Herkel | Four stage alkaline peroxide mechanical pulping |
US7384502B2 (en) * | 2002-12-24 | 2008-06-10 | Nippon Paper Industries Co., Ltd. | Process for impregnating, refining, and bleaching wood chips having low bleachability to prepare mechanical pulps having high brightness |
US20050003516A1 (en) * | 2003-04-16 | 2005-01-06 | Novozymes A/S | Enzymatic treatment of paper making |
US8262851B2 (en) * | 2006-08-10 | 2012-09-11 | Andritz Inc. | Processes and systems for the pulping of lignocellulosic materials |
-
2007
- 2007-10-17 FI FI20075729A patent/FI121310B/fi not_active IP Right Cessation
-
2008
- 2008-10-06 AR ARP080104362A patent/AR068684A1/es not_active Application Discontinuation
- 2008-10-15 MX MX2009005832A patent/MX2009005832A/es unknown
- 2008-10-15 CA CA002670040A patent/CA2670040A1/en not_active Abandoned
- 2008-10-15 AU AU2008313591A patent/AU2008313591A1/en not_active Abandoned
- 2008-10-15 ZA ZA200903900A patent/ZA200903900B/xx unknown
- 2008-10-15 CL CL2008003043A patent/CL2008003043A1/es unknown
- 2008-10-15 WO PCT/FI2008/050574 patent/WO2009050336A1/en active Application Filing
- 2008-10-15 CN CNA2008800012938A patent/CN101568685A/zh active Pending
- 2008-10-15 BR BRPI0806106-8A patent/BRPI0806106A2/pt not_active IP Right Cessation
- 2008-10-15 US US12/516,638 patent/US20100269994A1/en not_active Abandoned
- 2008-10-15 EP EP08839424A patent/EP2201170A1/en not_active Withdrawn
- 2008-10-15 RU RU2009117645/12A patent/RU2009117645A/ru not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
RU2009117645A (ru) | 2011-02-10 |
EP2201170A1 (en) | 2010-06-30 |
MX2009005832A (es) | 2009-06-16 |
CL2008003043A1 (es) | 2009-04-24 |
ZA200903900B (en) | 2010-08-25 |
AR068684A1 (es) | 2009-11-25 |
WO2009050336A1 (en) | 2009-04-23 |
FI20075729A (fi) | 2009-04-18 |
BRPI0806106A2 (pt) | 2011-08-30 |
AU2008313591A1 (en) | 2009-04-23 |
FI20075729A0 (fi) | 2007-10-17 |
CN101568685A (zh) | 2009-10-28 |
US20100269994A1 (en) | 2010-10-28 |
FI121310B (fi) | 2010-09-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FZDE | Discontinued |
Effective date: 20131015 |