CA2628481C

CA2628481C - Cigarette package provided with internal envelopes made from polymer film

Info

Publication number: CA2628481C
Application number: CA 2628481
Authority: CA
Inventors: Detlef Busch; Bjoern Dragun; Bertram Schmitz; Yvonne Duepre
Original assignee: Treofan Germany GmbH and Co KG
Current assignee: Treofan Germany GmbH and Co KG
Priority date: 2005-11-03
Filing date: 2006-10-31
Publication date: 2014-09-16
Anticipated expiration: 2026-10-31
Also published as: CN101300177B; JP5478887B2; WO2007051791A3; PL1951596T3; EP1951596A2; CA2628481A1; PT1951596E; WO2007051791A2; DE102005053343B3; KR20080064123A; RU2426680C2; ES2434033T3; RU2008122044A; SI1951596T1; US20080277297A1; EP1951596B1; JP2009515780A; CN101300177A

Abstract

The invention relates to a single- or multilayer biaxially oriented film, which contains 70-100 % by weight polymer consisting of at least one type of aliphatic hydroxycarboxylic acid, and which is used in the form of an inner liner of a cigarette package.

Description

. .

POLYMER FILM Description [001] Cigarette packaging with inner wrappings made of polymer film [002] The invention concerns a cigarette packaging comprising at least one outer packaging, and an inner wrapping for cigarettes. The invention furthermore concerns an inner liner.

[003] Cigarette packagings are conventionally constructed in such a way that the packaging contents, namely a collection of cigarettes, are surrounded by an inner wrapping. In the prior art, this inner wrapping consists of a cut sheet of aluminium foil. an aluminium-paper lamination or a piece of metallised paper.
This inner wrapping is often imprinted or embossed. Earlier cut sheets are today conventionally replaced by inner wrappings made of paper. The inner wrapping is often imprinted or metallised, if necessary in combination with embossment, on the outside.

[004] When manufacturing the packaging, the cigarettes are wrapped in this inner wrapping, the so-called inner liner, and the wrapped collection of cigarettes are folded by the packaging machine with the outer packaging, for example a flip-top lid packaging or a paper label.

[005] The inner liner can consist of printed paper, metallised paper or other lamellar materials. These materials are pulled onto the packaging machine off a roll and cut to the appropriate length. If necessary, selected perforations are made in order to produce a target cut-off point which makes possible a selected tearing open of the inner liner upon first opening of the packaging.

[006] Paper and metal films are particularly advantageous because of the folding properties and the tearing properties. In this type of use, the strips of material must feature good folding properties (dead-fold) which ensure that the cigarettes being wrapped are wrapped up firm enough to remain as a bundle up until the point at which the outer packaging, is put in place. Furthermore, the tearing behaviour performs an important role, in that a controlled opening of the liner is ensured. Finally, the cuts must feature a good flatness, in order that the handling is not hindered by the strips of material furling up.

[007] This set of properties is well fulfilled by paper and metallised papers.
Film made of thermoplastic polymers have inherently poor folding properties and therefore are generally not suitable material for this usage. Moreover, plastic films in the form of small cuts tend to curl up, i.e. these cuts roll up along or across the length of the film strip all by themselves.

[008] As plastic films nevertheless often have advantages over paper both from the point of view of environmental aspects and in terms of cost, the substitution of paper in various uses is a request constantly put to the film manufacturer.

[009] So underlying the invention was the task of making available a film suitable for use as the inner liner of cigarette packaging, and which met the demands of this usage.

[010] This task is solved by the use of a single-layered or multilayered, biaxially-oriented film as the inner liner of a cigarette packaging, such that the film contains 70 to 100% by weight of a polymer made of at least one aliphatic hydroxyl carboxylic acid.

[011] The invention comes into use particular for flip packs and soft packaging. The inner liner made of polyhydroxycarboxylic acid film, preferably PSA film, is particularly suitable for flip packs. These cartons conventionally consist of thin card. A piece of the carton serves to pick up the contents of the packaging, namely a collection of cigarettes which is surrounded on all sides by the folded inner wrapping made of polyhydroxycarboxylic acid or PSA. There is a lid disposed on a back side of the carton, which is connected to the carton over a fold line. Further details of the embodiment of flip packs are known and described e.g.
in DE 43 33 462, a description to which explicit reference is made here.

[012] The collection of cigarettes, the contents of the packaging, is surrounded on all sides by the inner wrapping according to the invention. The unit so arising as the packaging contents is a block of cigarettes. According to the invention, a film made of polyhydroxycarboxylic acid, preferably a PLA film, is introduced to the cigarette wrapping in order to manufacture such a block of cigarettes.

[013] The film is cut to the suitable width for this purpose and pulled onto the packaging machine off a roll as a ream and cut to the appropriate length. The shape of the cut depends on the type of folding coming into use. For example, the tailored film cut is laid around the collection of cigarettes according to the principle of side folding. Connected to a continuous, closed bottom side are a front side and a back side. An upper end wall is likewise formed by folding, such that interior pointed corners and trapezoid pointed edges are formed.

= CA 02628481 2008-05-02 [014] In a further embodiment, the inner wrapping of the upper area can be provided with a draw-off strap, a so-called flap. For this purpose a perforated line or some other kind of weakening line is made over the full width of the cut. Upon first opening of the package, the draw-off strap is detached by catching the outer pointed edge.

[015] The cut is generally separated from the strips of material in such a way that the cut lies in the longitudinal direction. The strips of material can be provided with printing surfaces if necessary, which advantageously are arranged with a gap between them in the direction running along the length of material. The cross cuts for dividing the cuts are carried across the film lengthwise. The exact positioning of the dividing line can be carried out with a print mark control because of the printer's imprints.

[016] Alternatively, the cut can be constructed in such a way that the width of the strip of film corresponds to the length of the cut. With this arrangement, the cuts are aligned normal to the length of the strip of material. In these cases, the strip of material is provided with continuing strips of print on both sides, in particular of varying widths.

[017] Cuts and techniques for folding the inner liner, units for imprinting cuts and further details and known in the prior art and described e.g. in DE 201 20 977 or DE 43 33 462 or DE 25 11 241, to which explicit reference is made here.

[018] The packaging with inner liner constructed in the way described are generally additionally provided with an outer wrapping made of film, in particular polypropylene film or cellophane.

[019] According to the invention, the inner liner is made of a biaxially-oriented film, which can feature one or several layers. The main constituent of the film is a polymer made of at least one aliphatic hydroxyl carboxylic acid. In general, the film contains at least 70-100% polymers made of aliphatic polyhydroxycarboxylic acid, preferably PSA. Embodiments made of 80-99% by weight, preferably 85-95% by weight of the named polymers, in each case relative to the weight of the film, are preferred.

[020] Surprisingly, a film made of polyhydroxycarboxylic acid, preferably PLA
is excellent for use as inner liner. It was found that the film fixes in place the cigarette bundle sufficiently after the impaction. The film shows now disruptions during handling on the packaging machine. I turned out that the cuts have = CA 02628481 2008-05-02 surprisingly little furling, sometimes none at all, and so avoid the problems of other thermoplastic films. Moreover, films are particularly advantageous, because with them a good stable workability is given even in fluctuating climatic conditions. It was shown, the in comparison the paper, fluctuating temperatures or a fluctuating humidity hardly affects the film and its properties and has no effects on its use as inner liner and can always be handled equally well.

[021]

[022] Both single-layered and multilayered films made of aliphatic polyhydroxycarboxylic acid are suitable for use according to the invention.
Multilayered films are generally constructed out of a thick base layer which features the largest layer thickness and makes up 60 to <100% of the total thickness of the film. This base layer is provided with (a) top layer(s), preferably on both sides but only on one side if necessary. In further embodiments, additional intermediate layers or coatings of the outer surface of the multilayered film are possible, through which four or five-layered, coated or uncoated, films are obtained. The thickness of the top layer generally lies in a range from 0.5 to pm, preferably 0.5 - 6 m, in particular 1 to 3 . The total thickness of the film according to the invention lies in range from 20 to 100 m, preferably 25 to 80 m, in particular 30 to 60 m. The top layers are the layers with form the outer layers of the film. Intermediate layers are by naturally attached between the base layer and the top layers. Following embodiments to the layers of the film count analogously in the same way for single-layered embodiments of the film.

[023] Surprisingly, films with a minimum thickness of 20 m are particularly advantageous for use as inner liner according to the invention. If the thickness of the film lies under 20 m, then congestions occur on the machine. It was found that surprisingly thin films function even better in the use according to the invention. When the film thickness is too large, the film shows too large reset forces, so that the wrapped cigarettes slip out of the bundle before the outer flip pack can be applied. Therefore a maximum thickness of 100 m should not be exceeded.

[024] The film, as well as the individual layers of the film if necessary, contain(s) 70 to around 100% by weight, preferably 80 to 98% by weight of a polymer made of at least one of the aliphatic hydroxycarboxylic acids, hereinafter also called PHC
or polyhydroxy carboxulic acids. This means homopolymers or mix polymerisates, which are made up of polymeristae units of aliphatic hydroxyl carboxylic acids. Among the PHC suitable for the present invention, poly lactic acids are particularly suitable. These are hereinafter called PLA (poly lactic acid).
Here too, both homopolymers which are made up only of lactic acid units, and also mix polymerisates which predominantly contain lactic acid units (>50%) bonded with other aliphatic hydroxyl lactic acid units, are meant by the term PSA.

[025] As monomers of the aliphatic polyhydroxycarboxylic acids (PHC), aliphatic mono-, di- or trihydroxycarboxylic acids, or their dimer cyclic esters, are suitable, among which lactic acid in its D- or L- form is preferred. These kinds of polymers are known in the prior art and are commercially available. The manufacture of poly lactic acids is likewise described in the prior art and takes place over catalytic ring-opening polymerisation of lactide (1,4-dioxane-3,6-dimethyl 2,5-dione), the dimerised cyclic ester of the lactic acid, hence PSA
is often also called polylactide. The manufacture of PSA is described in the following publications: US 5,208,297, US 5,247,058 or US 5,357,035.

[026] Polylactic acids made up exclusively of lactic acid units are preferred.
In this connexion PSA homopolymers containing 80-100% by weight L-lactic acid units, corresponding to 0 to 20% by weight D-lactic acid units, are particularly preferred. Even higher concentrations of D-lactic acid units can be contained as comonomers in order to decrease the crystallinity. If necessary, the polylactic acid can additionally feature various aliphatic polyhydroxycarboxylic acid units as comonomers from the lactic acid, for example glycolic acid units, 3-hydroxy propanoic acid units, 2,2-dimethy1-3-hydroxypropanoic acid units or higher homologues of the hydroxycarboxylic acids with up to 5 carbon atoms.

[027] Preferred are lactic acid polymers (PLA) with a melting point of 110 to 170 C, preferably from 125 to 165 C, and a melt flow index (DIN measurement 53 735 at 2.16 N load and 190 C) of 1 to 50g/10 min, preferably from I to 30 g/10 min.
The molecular weight of the PLA lies in a range of at least 10 000 to 500 000 (counting mean), preferably 50 000 to 300 000 (counting mean). The glass transition temperature lies in the Tg lies in a range from 40 to 100 C, preferably 40 to 80 C.

[028] The individual layers of the film each contain 70 to around 100% by weight of the previously described polymers, preferably 80 to 98% by weight, as well as additional additives if necessary, like neutralising agents, stabilisers, lubricants, static inhibitors and fillers. They are advantageously added to the polymer or the polymer mixture before melting on. Phosphorous bonds, like phosphoric acids or phosphoric acid esters, for example, are introduced as stabilisers. The individual layers can basically feature the same composition as regards polymers and additives. In general, the composition of the base layer is different from the composition of the remaining layers. In particular, additives like anti-blocking agents or lubricants are added to the top layers, whereas fillers or pigments are preferably introduced into the base layer. Construction and composition of the individual layers of the film can nevertheless vary within wide boundaries.

[029] It was found that transparent and white embodiments without vacuoles are especially well suited for this use. It is known about polypropylene films that opaque PP films with vacuoles in the base layer feature better folding properties than transparent PP films. The vacuole-free PLA films surprisingly also show very good folding properties in this use in comparison to vacuolated embodiments. In the sense of the present invention, transparent films are to be understood as those with a light permeability according to ASTM-D 1003-77 lies over 75%, preferably over 95%. White PLA films are coloured white by the addition of white pigment, but have no vacuoles either. These embodiments generally contain TiO2 in a quantity of 1 ¨ 12% by weight in at least one layer, if necessary several. Basically, TiO2 can be added in these quantities to one or both top layers or also to one or both intermediate layers.

[030] The addition of opaque or white-opaque embodiments of the film is basically also possible. These films contain vacuole-initiating fillers in the base layer, for example cycloolefin copolymer (opaque films) and, if necessary, additional pigments (white-opaque films). In this case, too, TiO2 is also preferred as pigment and is introduced in a quantity of up to 10% by weight, preferably 1 to 8% by weight, in each case relative to the base layer.

[031] If necessary, the film can be coated in order to optimise further properties of the film. Typical coatings are adhesion-enhancing, slip-improving or dehesive-operating coatings. If necessary, these additional coatings can be applied over in-line coating by means of aqueous or non-aqueous dispersions before lateral stretching or off-line.

[032] In a further embodiment, the films are metallised as inner liner before use.
Upon use as inner-liner, the metallised side fauns the visible side. In a further embodiment, the film can be metallised on both sides. This embodiment has the additional advantage that direct contact between the cigarettes and the film is avoided, so that no detriments to the taste of the cigarettes because of the film are possible, or rather they are extensively prevented.

[033] In a further embodiment, the metallised or non-metallised film can be additionally provided with an embossment which on the one hand has a decorative character, and which contributes towards a further improved flatness.
Surprisingly, after metallisation and imprinting the films can be handled just as well as the paper inner-liner used until now. What is more, the embossed metallised films come very close to the topical appearance of metallised papers.

[034] The PHC film is manufactured according to the coextrusion procedure known in itself. Within the scope of this procedure, the melt(s) corresponding to the layers of the film are coextruded through a flat die, the multilayered film so obtained is pulled off for hardening on one or several roller(s), the film is subsequently biaxially stretched (oriented), the biaxially-stretched film is heat set and, if necessary, corona- or flame-treated on the surface layer intended for treatment.

[035] The biaxial stretching is generally carried out sequentially. In so doing, stretching preferably happens first in the longitudinal direction (i.e. in the machine direction, = MD direction) and subsequently in the lateral direction (i.e. at a right angle to the machine direction, = TD direction). This leads to an orientation of the molecular chains. The stretching in the longitudinal direction preferably takes place with the help of two rollers running at different speeds, corresponding to the desired stretch ratio. For the lateral stretching, a corresponding clip frame is commonly used. Further description of the film manufacture is carried out according to the example of a flat film extrusion with subsequent sequential stretching.

[036] The melt(s) are pressed through a flat die (sheet die), and the film pressed out is pulled off on one or several outfeed rollers at a temperature of 10 to 100 C, preferably 20 to 80 C, such that it cools off and hardens.

[037] The film so obtained is then stretched along and across the direction of extrusion. The longitudinal stretching will preferably be carried out at a roller temperature of the stretch roller of 40 to 130 C, preferably 50 to 100 C, advantageously with the help of two rollers running at different speeds, corresponding to the desired stretch ratio; the lateral stretching preferably at a temperature of 50 to 130 C, preferably 60 to 120 C with the help of a corresponding clip frame. The longitudinal stretch ratios can vary within a range of 1.5 to 8. In the manufacture of films with a base layer containing vacuole-initiating fillers a high longitudinal stretch ratio of 3 to 6 is preferred, whereas films with a transparent base layer are preferably stretched within a range of 1.5 to 3.5. The lateral stretch ratios lay in the range from 3 to 10, preferably 4 to 7.

[038] Attached to the stretching of the film is its heat setting (heat treatment), where the film is held converging around 0.1 to 10 s long at a temperature of 60 to 150 C
(convergence up to 25%). Subsequently the film is wound up in the conventional manner with a batcher.
[038a] A further embodiment of the invention may relate to use of a single-layered or multilayered, biaxially-oriented film as inner liner of cigarette packaging, wherein the film contains 70 to 100% by weight of polymer of at least one aliphatic polyhydroxycarboxylic acid and the film has a total thickness of at least 20 to 100 i_tm.

[039] The following measured values were used to characterise the raw materials and the films:

[040] The invention will hereinafter be explained on the basis of the following execution examples:

8a [041] Example 1:

[042] A transparent, three-layered PLA film with a thickness of around 30!_tm was manufactured by extrusion and subsequent incremental orientation in the longitudinal and lateral directions. The base layer consisted of almost 100%
by weight polylactic acid with a melting point of around 160 C. The layer additionally contained stabilisers and neutralising agents in conventional quantities. Both sealable top layers were fundamentally made up of an amorphous polylactic acid, such that this polylactic acid features an L/D ratio of around 40/60. In addition, the top layers each contained 0.1% y weight Si02-based particles as anti-blocking agents. The thickness of the top layers each came to 2.5pn.

[043] The manufacturing conditions in the individual procedural steps were:

[044] Extrusion: temperatures 170 ¨ 200 C

[045] Temperature of the outfeed roller: 60 C

[046] Longitudinal stretching: temperature: 68 C

[047] Longitudinal stretch ratio: 2.0 [048] Lateral stretching: temperature 88 C

[049] Lateral stretch ratio (effective): 5.5 [050] Fixation: temperature 75 C

[051] Convergence: 5%

[052] Example 2:

[053] A film was manufactured as is described in example 1. In contrast to example 1, no top layer was attached. For the rest, the composition and the manufacturing conditions were unchanged. A transparent film, but a single-layered film with a thickness of 251.1m, was again manufactured.

[054] Example 3:

[055] By extrusion and subsequent incremental orientation in the longitudinal and lateral directions, an opaque, single-layered PLA film with a thickness of 30pm was manufactured. This layer was around 95% by weight made up of a polylactic acid with a melting point of 135 C and a melt flow index of around 3 g/10min and a glass transition temperature of 60 C and around 5% by weight COC (Ticona Topas 6013) with a Tg of 140 C. The layer additionally contains stabilisers and neutralising agent in conventional quantities. The manufacturing conditions in the individual procedural steps were:

[056] Extrusion: temperature 170 ¨ 200 C

[057] Temperature of the outfeed roller: 60 C

[058] Longitudinal stretching: temperature: 68 C

[059] Longitudinal stretch ratio: 4.0 [060] Lateral stretching: temperature: 88 C

[061] Lateral stretch ratio (effective): 5.5 [062] Setting: temperature: 75 C

[063] Convergence: 5%

[064] In this way, an opaque film with characteristic pearlescent shine and a reduced density of around 0.75 g/cm3 is obtained.

[065] The films were introduced on a commercial cigarette packaging machine as inner liner and could be used without huge problems. The non-vacuolated films according to example 1 and 2 showed themselves to be especially advantageous.

[066] In contrast, biaxially oriented polypropylene films could not be adopted in this usage. Because of strong reset forces of the material, the individual cigarettes could not be packaged.

Claims

1. Use of a single-layered or multilayered, biaxially-oriented film as inner liner of cigarette packaging, wherein the film contains 70 to 100% by weight of polymer of at least one aliphatic polyhydroxycarboxylic acid and the film has a total thickness of at least 20 to 100 µm.

2. Use of a film according to claim 1, wherein the film is transparent.

3. Use of a film according to claim 1, wherein the film is white.

4. Use of a film according to claim 1, wherein the film has an opaque, vacuolated base layer.

5. Use of a film according to any one of claims 1 to 4, wherein the film is metallised on one surface.

6. Use of a film according to any one of claims 1 to 4, wherein the film is metallised on both sides.

7. Use of a film according to any one of claims 1 to 6, wherein the film is embossed.

8. Use of a film according to claim 5, wherein the metallised surface of the film is embossed.

9. Use of a film according to any one of claims 1 to 8, wherein the film contains 80 to <98% by weight of a polymer of aliphatic polyhydroxycarboxylic acid in the base layer.

10. Use of a film according to any one of claims 1 to 9, wherein the film features top layers on both sides, and the top layers contain 70 to <100% by weight of a polymer of aliphatic polycarboxylic acid.

11. Use of a film according to any one of claims 1 to 10, wherein the aliphatic polyhydroxycarboxylic acid is a polylactic acid.

12. Use of a film according to any one of claims 1 to 11, wherein the top layer has thickness of 0.5 to 6 µm.

13. Use of a film according to any one of claims 1 to 12, wherein the top layer is sealable.

14. Use of a film according to any one of claims 1 to 13, wherein the cigarette packaging is a flip pack.

15. Use of a film according to any one of claims 1 to 13, wherein the cigarette packaging is a soft packaging.