CA2579579C - Methode de raffinage de cuivre a feu continu - Google Patents
Methode de raffinage de cuivre a feu continu Download PDFInfo
- Publication number
- CA2579579C CA2579579C CA2579579A CA2579579A CA2579579C CA 2579579 C CA2579579 C CA 2579579C CA 2579579 A CA2579579 A CA 2579579A CA 2579579 A CA2579579 A CA 2579579A CA 2579579 C CA2579579 C CA 2579579C
- Authority
- CA
- Canada
- Prior art keywords
- copper
- liquid
- oxidized
- oxidation reactor
- slag
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 141
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 129
- 239000010949 copper Substances 0.000 title claims abstract description 129
- 238000000034 method Methods 0.000 title claims abstract description 41
- 238000007670 refining Methods 0.000 title claims abstract description 21
- 239000007788 liquid Substances 0.000 claims abstract description 65
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 47
- 230000003647 oxidation Effects 0.000 claims abstract description 43
- 239000007789 gas Substances 0.000 claims abstract description 32
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000001301 oxygen Substances 0.000 claims abstract description 27
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 27
- 239000002893 slag Substances 0.000 claims abstract description 25
- 239000012535 impurity Substances 0.000 claims abstract description 21
- 238000010079 rubber tapping Methods 0.000 claims abstract description 16
- 239000000567 combustion gas Substances 0.000 claims abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 13
- 230000001590 oxidative effect Effects 0.000 claims abstract description 11
- 238000002485 combustion reaction Methods 0.000 claims abstract description 9
- 239000000446 fuel Substances 0.000 claims abstract description 7
- 230000007935 neutral effect Effects 0.000 claims abstract description 6
- 239000000919 ceramic Substances 0.000 claims abstract description 5
- 230000005484 gravity Effects 0.000 claims abstract description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 38
- 239000003638 chemical reducing agent Substances 0.000 claims description 30
- 239000003345 natural gas Substances 0.000 claims description 18
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 11
- 239000007924 injection Substances 0.000 claims description 11
- 239000003575 carbonaceous material Substances 0.000 claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 239000005864 Sulphur Substances 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 239000003610 charcoal Substances 0.000 claims description 6
- 235000010269 sulphur dioxide Nutrition 0.000 claims description 6
- 239000004291 sulphur dioxide Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000003245 coal Substances 0.000 claims description 3
- 239000000571 coke Substances 0.000 claims description 3
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 3
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 3
- 229940112669 cuprous oxide Drugs 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000011133 lead Substances 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 239000003921 oil Substances 0.000 description 7
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 238000009434 installation Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000002792 vascular Effects 0.000 description 5
- 239000003517 fume Substances 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 241000512668 Eunectes Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000735215 Lepidocybium flavobrunneum Species 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000010747 number 6 fuel oil Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000006057 reforming reaction Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0028—Smelting or converting
- C22B15/005—Smelting or converting in a succession of furnaces
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0028—Smelting or converting
- C22B15/0052—Reduction smelting or converting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/006—Pyrometallurgy working up of molten copper, e.g. refining
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
L'invention concerne un raffinage au feu intensif en continu du cuivre comprenant les étapes consistant: à tarauder en continu un cuivre liquide (4) dans un premier réacteur d'oxydation; l'oxydation de cuivre liquide avec des gaz de combustion renfermant de l'oxygène ou avec de l'air; à former simultanément des impuretés de recueil de crasses; à tarauder en continu le cuivre oxydé et à raffiner les crasses provenant du premier réacteur (8); à tarauder en continu le cuivre oxydé dans un second réacteur de réduction; à réduire le cuivre au moyen de carbone et à réduire des gaz formés par la combustion partielle de combustible et du carbone et à tarauder en continu le cuivre réduit (14).
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CL2269 | 2004-09-07 | ||
CL2004002269 | 2004-09-07 | ||
PCT/US2005/031731 WO2006029162A1 (fr) | 2004-09-07 | 2005-09-06 | Procede de raffinage au feu en continu du cuivre |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2579579A1 CA2579579A1 (fr) | 2006-03-16 |
CA2579579C true CA2579579C (fr) | 2017-06-13 |
Family
ID=40935504
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2579579A Expired - Fee Related CA2579579C (fr) | 2004-09-07 | 2005-09-06 | Methode de raffinage de cuivre a feu continu |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP2111472A4 (fr) |
KR (1) | KR20080100402A (fr) |
AU (1) | AU2005282475B2 (fr) |
CA (1) | CA2579579C (fr) |
MX (1) | MX2007002764A (fr) |
WO (1) | WO2006029162A1 (fr) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CL2007003701A1 (es) | 2007-12-19 | 2008-08-22 | Univ Chile | Metodo pirometalurgico para reduccion continua de oxigeno desde cobre oxidado que comprende un carguio de cobre liquido, inyeccion del reductor en el lecho empacado, reduccion del oxigeno desde el cobre con gases calientes, evacuacion del cobre reduc |
CL2008000116A1 (es) * | 2008-01-15 | 2008-03-14 | Univ De Chile 51 Empresa Nac D | Metodo pirometalurgico intensivo continuo de conversion de mata de cobre liquida que comprende alimentar dicha mata dentro del primer reactor de oxidacion, suministrar gases al lecho empacado y fundentes silicios, sangrar la escoria, alimentar metal |
CN102146521A (zh) * | 2010-02-08 | 2011-08-10 | 江西稀有金属钨业控股集团有限公司 | 降低紫杂铜再生精炼竖炉铜液含锡量的方法 |
CN102586620B (zh) * | 2012-03-09 | 2014-05-14 | 广西有色再生金属有限公司 | 一种冶炼杂铜的精炼摇炉及其冶炼方法 |
CN102676841A (zh) * | 2012-05-29 | 2012-09-19 | 江苏句容联合铜材有限公司 | 一种铜杆熔炼防氧化工艺 |
CN103436713A (zh) * | 2013-08-23 | 2013-12-11 | 江苏句容联合铜材有限公司 | 一种铜板熔炼装置 |
FI127195B (en) | 2015-05-06 | 2018-01-31 | Outotec Finland Oy | Hot refining of crude copper |
CA3059649C (fr) | 2017-05-10 | 2024-01-02 | Haldor Topsoe A/S | Procede de reduction de la teneur en oxygene dans du cuivre metallique |
WO2021175406A1 (fr) * | 2020-03-02 | 2021-09-10 | Montanuniversität Leoben | Appareil et processus de traitement thermique de matière première contenant des composés du lithium et des composés du phosphore, procédé de récupération du lithium et/ou du phosphore contenus dans le matériau résiduaire de batteries au lithium-ion |
CN111363938B (zh) * | 2020-03-25 | 2021-06-25 | 宁波金田铜业(集团)股份有限公司 | 一种废杂黄铜的改性剂及使用其生产黄铜合金的方法 |
CN113481381A (zh) * | 2021-06-17 | 2021-10-08 | 张家港联合铜业有限公司 | 一种基于二氧化碳的铜火法精炼工艺 |
CN115747508A (zh) * | 2022-11-21 | 2023-03-07 | 中国恩菲工程技术有限公司 | 一种阳极炉精炼阳极铜的方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE622116A (fr) * | 1961-09-27 | |||
GB1146082A (en) * | 1965-03-24 | 1969-03-19 | Sumitomo Metal Mining Co | Method of fire refining copper |
GB1369494A (en) * | 1971-10-06 | 1974-10-09 | Foseco Int | Deoxidisation and desulphurisation of non-ferrous metals |
US4315775A (en) * | 1979-11-28 | 1982-02-16 | Southwire Company | Continuous melting and refining of secondary and/or blister copper |
JP2689540B2 (ja) * | 1988-11-21 | 1997-12-10 | 三菱マテリアル株式会社 | 低酸素含有銅の製造方法及び製造装置 |
GB9211053D0 (en) * | 1992-05-23 | 1992-07-08 | Univ Birmingham | Oxygen smelting |
US5449395A (en) * | 1994-07-18 | 1995-09-12 | Kennecott Corporation | Apparatus and process for the production of fire-refined blister copper |
US5849061A (en) * | 1996-09-20 | 1998-12-15 | The Trustees Of Columbia University In The City Of New York | Process for refining high-impurity copper to anode copper |
US6395059B1 (en) * | 2001-03-19 | 2002-05-28 | Noranda Inc. | Situ desulfurization scrubbing process for refining blister copper |
-
2005
- 2005-09-06 AU AU2005282475A patent/AU2005282475B2/en not_active Ceased
- 2005-09-06 KR KR1020077007827A patent/KR20080100402A/ko not_active Application Discontinuation
- 2005-09-06 CA CA2579579A patent/CA2579579C/fr not_active Expired - Fee Related
- 2005-09-06 MX MX2007002764A patent/MX2007002764A/es unknown
- 2005-09-06 WO PCT/US2005/031731 patent/WO2006029162A1/fr active Application Filing
- 2005-09-06 EP EP05796063A patent/EP2111472A4/fr not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
EP2111472A1 (fr) | 2009-10-28 |
CA2579579A1 (fr) | 2006-03-16 |
KR20080100402A (ko) | 2008-11-18 |
AU2005282475A1 (en) | 2006-03-16 |
WO2006029162A1 (fr) | 2006-03-16 |
EP2111472A4 (fr) | 2009-10-28 |
MX2007002764A (es) | 2008-12-18 |
AU2005282475B2 (en) | 2011-03-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20220906 |