CA2546898C - Polysilazane thermosetting polymers for use in chromatographic systems and applications - Google Patents

Polysilazane thermosetting polymers for use in chromatographic systems and applications Download PDF

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Publication number
CA2546898C
CA2546898C CA2546898A CA2546898A CA2546898C CA 2546898 C CA2546898 C CA 2546898C CA 2546898 A CA2546898 A CA 2546898A CA 2546898 A CA2546898 A CA 2546898A CA 2546898 C CA2546898 C CA 2546898C
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Canada
Prior art keywords
set forth
fluid
adsorbent material
permeable mass
particulate adsorbent
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Expired - Lifetime
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CA2546898A
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English (en)
French (fr)
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CA2546898A1 (en
Inventor
William R. Betz
Christopher M. Linton
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Sigma Aldrich Co LLC
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Sigma Aldrich Co LLC
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Priority to CA2945455A priority Critical patent/CA2945455C/en
Publication of CA2546898A1 publication Critical patent/CA2546898A1/en
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Publication of CA2546898C publication Critical patent/CA2546898C/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28026—Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
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    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
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    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
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    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
    • B01J20/3223—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating by means of an adhesive agent
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    • C—CHEMISTRY; METALLURGY
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Composite Materials (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Devices For Use In Laboratory Experiments (AREA)
  • Chemically Coating (AREA)
  • Paints Or Removers (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Polymers (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
CA2546898A 2003-11-20 2004-11-19 Polysilazane thermosetting polymers for use in chromatographic systems and applications Expired - Lifetime CA2546898C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2945455A CA2945455C (en) 2003-11-20 2004-11-19 Polysilazane thermosetting polymers for use in chromatographic systems and applications

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US52365403P 2003-11-20 2003-11-20
US60/523,654 2003-11-20
PCT/US2004/038832 WO2005052544A2 (en) 2003-11-20 2004-11-19 Polysilazane thermosetting polymers for use in chromatographic systems and applications

Related Child Applications (1)

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CA2945455A Division CA2945455C (en) 2003-11-20 2004-11-19 Polysilazane thermosetting polymers for use in chromatographic systems and applications

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CA2546898A1 CA2546898A1 (en) 2005-06-09
CA2546898C true CA2546898C (en) 2016-11-22

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CA2546898A Expired - Lifetime CA2546898C (en) 2003-11-20 2004-11-19 Polysilazane thermosetting polymers for use in chromatographic systems and applications
CA2945455A Expired - Lifetime CA2945455C (en) 2003-11-20 2004-11-19 Polysilazane thermosetting polymers for use in chromatographic systems and applications

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US (5) US7815864B2 (enExample)
EP (1) EP1713577B1 (enExample)
JP (3) JP5580507B2 (enExample)
CA (2) CA2546898C (enExample)
WO (1) WO2005052544A2 (enExample)

Families Citing this family (51)

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Publication number Priority date Publication date Assignee Title
CA2546898C (en) * 2003-11-20 2016-11-22 Sigma-Aldrich Co. Polysilazane thermosetting polymers for use in chromatographic systems and applications
US20080023630A1 (en) * 2005-11-22 2008-01-31 Ciphergen Biosystems Inc. Polymer probe doped with conductive material for mass spectrometry
US7892596B2 (en) * 2005-12-19 2011-02-22 GM Global Technology Operations LLC Nanoparticle coating process for fuel cell components
US7485225B2 (en) * 2006-03-31 2009-02-03 Perry Equipment Corporation Composite adsorbent block for the treatment of contaminated fluids
JP5011026B2 (ja) * 2007-08-21 2012-08-29 シャープ株式会社 多孔質構造体を用いた特定ガス成分濃縮装置、及び特定ガス成分検出装置
EP2304423B1 (en) 2008-07-18 2019-02-20 Waters Technologies Corporation Devices having an inert surface and methods of making same
EP2251452B1 (en) 2009-05-13 2018-07-18 SiO2 Medical Products, Inc. Pecvd apparatus for vessel coating
US7985188B2 (en) 2009-05-13 2011-07-26 Cv Holdings Llc Vessel, coating, inspection and processing apparatus
US9458536B2 (en) 2009-07-02 2016-10-04 Sio2 Medical Products, Inc. PECVD coating methods for capped syringes, cartridges and other articles
US11624115B2 (en) 2010-05-12 2023-04-11 Sio2 Medical Products, Inc. Syringe with PECVD lubrication
EP2572369A1 (en) 2010-05-21 2013-03-27 Eidgenössische Technische Hochschule Zürich High-density sample support plate for automated sample aliquoting
EP2627724A4 (en) * 2010-08-17 2014-04-09 Texas State University San Marcos A Component Of The Texas State University System PERMANENT CERAMIC NANOCOMPOSITE HEAT INSULATION LAYERS FOR METALS AND FIRE-RESISTANT MATERIALS
US8657483B2 (en) 2010-09-03 2014-02-25 Cabot Norit Americas, Inc. Apparatuses for dilute phase impregnation of a milled sorbent with a chemical compound in an aqueous solution
US9878101B2 (en) 2010-11-12 2018-01-30 Sio2 Medical Products, Inc. Cyclic olefin polymer vessels and vessel coating methods
US9272095B2 (en) 2011-04-01 2016-03-01 Sio2 Medical Products, Inc. Vessels, contact surfaces, and coating and inspection apparatus and methods
US9821418B2 (en) 2011-06-30 2017-11-21 International Business Machines Corporation Adsorption heat exchanger devices
US11116695B2 (en) 2011-11-11 2021-09-14 Sio2 Medical Products, Inc. Blood sample collection tube
CN103930595A (zh) 2011-11-11 2014-07-16 Sio2医药产品公司 用于药物包装的钝化、pH保护性或润滑性涂层、涂布方法以及设备
US9856400B2 (en) 2012-04-27 2018-01-02 Burning Bush Group, Llc High performance silicon based coating compositions
EP2846755A1 (en) 2012-05-09 2015-03-18 SiO2 Medical Products, Inc. Saccharide protective coating for pharmaceutical package
US10138381B2 (en) 2012-05-10 2018-11-27 Burning Bush Group, Llc High performance silicon based thermal coating compositions
US8809445B2 (en) * 2012-06-22 2014-08-19 Texas Research International, Inc. Room temperature cured vinyl silazane compositions
CN107236453B (zh) 2012-07-03 2019-06-11 伯宁布什集团有限公司 硅基高性能涂料组合物
US20150297800A1 (en) 2012-07-03 2015-10-22 Sio2 Medical Products, Inc. SiOx BARRIER FOR PHARMACEUTICAL PACKAGE AND COATING PROCESS
DE102012014335A1 (de) * 2012-07-19 2014-01-23 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Dispersion, Verfahren zur Beschichtung von Gegenstädenmit dieser Dispersion und Verwendung der Dispersion
WO2014055638A1 (en) * 2012-10-03 2014-04-10 Waters Technologies Corporation Rapid analysis of steroids and steroid derivatives
US9664626B2 (en) 2012-11-01 2017-05-30 Sio2 Medical Products, Inc. Coating inspection method
WO2014078666A1 (en) 2012-11-16 2014-05-22 Sio2 Medical Products, Inc. Method and apparatus for detecting rapid barrier coating integrity characteristics
US9764093B2 (en) 2012-11-30 2017-09-19 Sio2 Medical Products, Inc. Controlling the uniformity of PECVD deposition
EP2925903B1 (en) 2012-11-30 2022-04-13 Si02 Medical Products, Inc. Controlling the uniformity of pecvd deposition on medical syringes, cartridges, and the like
US9662450B2 (en) 2013-03-01 2017-05-30 Sio2 Medical Products, Inc. Plasma or CVD pre-treatment for lubricated pharmaceutical package, coating process and apparatus
US9937099B2 (en) 2013-03-11 2018-04-10 Sio2 Medical Products, Inc. Trilayer coated pharmaceutical packaging with low oxygen transmission rate
WO2014164928A1 (en) 2013-03-11 2014-10-09 Sio2 Medical Products, Inc. Coated packaging
WO2014144926A1 (en) 2013-03-15 2014-09-18 Sio2 Medical Products, Inc. Coating method
US10767259B2 (en) 2013-07-19 2020-09-08 Agilent Technologies, Inc. Components with an atomic layer deposition coating and methods of producing the same
US20150024152A1 (en) * 2013-07-19 2015-01-22 Agilent Technologies, Inc. Metal components with inert vapor phase coating on internal surfaces
US9006355B1 (en) * 2013-10-04 2015-04-14 Burning Bush Group, Llc High performance silicon-based compositions
EP3122917B1 (en) 2014-03-28 2020-05-06 SiO2 Medical Products, Inc. Antistatic coatings for plastic vessels
JP6486161B2 (ja) * 2015-03-24 2019-03-20 東京応化工業株式会社 シリル化剤薬液の調製方法及び表面処理方法
EP4001456A1 (en) 2015-08-18 2022-05-25 SiO2 Medical Products, Inc. Pharmaceutical and other packaging with low oxygen transmission rate
US10876206B2 (en) 2015-09-01 2020-12-29 Silcotek Corp. Thermal chemical vapor deposition coating
EP3672723B1 (en) 2017-08-24 2023-10-18 Sigma-Aldrich Co. LLC Method for making improved hlb copolymers
US11161324B2 (en) 2017-09-13 2021-11-02 Silcotek Corp. Corrosion-resistant coated article and thermal chemical vapor deposition coating process
JP7359774B2 (ja) * 2018-02-23 2023-10-11 シルコテック コーポレーション 液体クロマトグラフィー技術
CN113507972B (zh) * 2019-02-27 2023-10-20 沃特世科技公司 用于色谱效应的经涂覆的流动路径部件
US11747341B2 (en) 2019-03-04 2023-09-05 Waters Technologies Corporation Methods of use for low-bind polypropylene plates and vials
US11666885B2 (en) 2019-04-25 2023-06-06 Saint-Gobain Ceramics & Plastics, Inc. Adsorbent particles and methods of forming thereof
US11724963B2 (en) 2019-05-01 2023-08-15 Corning Incorporated Pharmaceutical packages with coatings comprising polysilazane
WO2020252306A1 (en) 2019-06-14 2020-12-17 Silcotek Corp. Nano-wire growth
KR102317614B1 (ko) 2020-05-29 2021-10-27 한국과학기술연구원 금속 컬럼을 제조하는 방법
US12473635B2 (en) 2020-06-03 2025-11-18 Silcotek Corp. Dielectric article

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5534258A (en) * 1978-09-01 1980-03-10 Tokyo Denshi Kagaku Kabushiki Coating solution for forming silica film
GB2077710B (en) 1980-06-11 1983-10-12 Nat Res Dev Synthesising a polysilane
US5008422A (en) * 1985-04-26 1991-04-16 Sri International Polysilazanes and related compositions, processes and uses
US5055431A (en) * 1985-04-26 1991-10-08 Sri International Polysilazanes and related compositions, processes and uses
US4680201A (en) * 1985-10-30 1987-07-14 Stellan Hjerten Coating for electrophoresis tube
DE3717209A1 (de) * 1987-05-22 1988-12-01 Diagen Inst Molekularbio Mittel zur selektiven adsorption von biopolymeren
US5080844A (en) * 1987-08-31 1992-01-14 Gte Laboratories Incorporated SI3N4 process using polysilane or polysilazane as a binder
GB8805992D0 (en) * 1988-03-14 1988-04-13 Shell Int Research Process for preparing non-porous membrane layers
US5325916A (en) * 1989-07-28 1994-07-05 Uop Method of coating aluminum substrates with solid adsorbent
US4941893B1 (en) * 1989-09-19 1996-07-30 Advanced Silicon Materials Inc Gas separation by semi-permeable membranes
US5171736A (en) * 1989-10-16 1992-12-15 Massachusetts Institute Of Technology Preceramic organosilicon-boron polymers
US5208192A (en) * 1990-01-12 1993-05-04 Ethyl Corporation Preceramic polysilazane compositions
JP2844896B2 (ja) * 1990-10-17 1999-01-13 信越化学工業株式会社 耐熱性絶縁塗料
JP2501040B2 (ja) * 1990-12-17 1996-05-29 信越化学工業株式会社 離型性オルガノポリシロキサン組成物およびその硬化物
US5192406A (en) * 1991-01-09 1993-03-09 Supelco Deactivated capillary columns for use in capillary electrophoresis
JPH0517108A (ja) * 1991-07-05 1993-01-26 Kansai Shin Gijutsu Kenkyusho:Kk 改質粉体及び改質粉体の製造方法
US5457151A (en) * 1991-09-24 1995-10-10 Southwest Research Institute Polysilazane adhesive composition
US5349117A (en) * 1992-07-08 1994-09-20 Mobil Oil Corp. Process for sorption separation
US5405655A (en) * 1992-11-19 1995-04-11 Sri International Temperature-resistant and/or nonwetting coatings of cured, silicon-containing polymers
US5447617A (en) * 1994-01-25 1995-09-05 Beckman Instruments, Inc. Coated capillary columns and electrophoretic separation methods for their use
US5653875A (en) * 1994-02-04 1997-08-05 Supelco, Inc. Nucleophilic bodies bonded to siloxane and use thereof for separations from sample matrices
JP3517934B2 (ja) 1994-03-24 2004-04-12 昭和電工株式会社 シリコン膜の形成方法
US5558908A (en) * 1994-11-07 1996-09-24 Lanxide Technology Company, Lp Protective compositions and methods of making same
JP4026724B2 (ja) * 1995-01-27 2007-12-26 ノースイースタン ユニバーシティー 毛管電気泳動のためのポリビニルアルコール（ｐｖａ）をベースとする共有結合の安定した親水性コーティング
AU6973296A (en) * 1995-09-12 1997-04-01 Gelest, Inc. Beta-substituted organosilsesquioxanes and use thereof
JPH0980038A (ja) * 1995-09-14 1997-03-28 Yuji Takayama ガスクロマトグラフ用の金属キャピラリ−カラム及びその製造方法
JPH09157593A (ja) * 1995-12-13 1997-06-17 Showa Electric Wire & Cable Co Ltd 耐熱性塗料
JPH10183369A (ja) * 1996-12-20 1998-07-14 Suzuki Motor Corp アルミニウム材の表面処理方法
EP0988418A1 (de) * 1996-12-23 2000-03-29 Voith Sulzer Papiertechnik Patent GmbH Nasspartie, verfahren zur herstellung einer faserstoffbahn und verwendung der nasspartie
JP3691619B2 (ja) * 1997-01-20 2005-09-07 ジーエルサイエンス株式会社 液体クロマトグラフィー用充填剤及びその処理方法
US6048457A (en) 1997-02-26 2000-04-11 Millipore Corporation Cast membrane structures for sample preparation
JPH10288571A (ja) * 1997-04-14 1998-10-27 Unie Flex:Kk ピペットチップ及びそれを用いた物質抽出方法
DE19732865A1 (de) 1997-07-30 1999-02-04 Basf Ag Siliciumdioxid enthaltender Feststoff mit großer Oberfläche
EP1032546A4 (en) * 1997-09-04 2002-03-20 Pall Corp POROUS CERAMIC STRUCTURES AND MANUFACTURING METHODS THEREOF
US5928515A (en) * 1997-12-12 1999-07-27 Uop Llc Adsorptive separation of 3-hydroxytetrahydrofuran enantiomers
JPH11170428A (ja) * 1997-12-12 1999-06-29 Benkan Corp ガス吸着抑制化基材
DE19800022A1 (de) * 1998-01-02 1999-07-08 Huels Silicone Gmbh Verfahren zur Herstellung von Siliconpolymer-Feststoff-Mischungen für fließfähige RTV2-Silicon-Massen mit niedriger Fließgrenze
US6511760B1 (en) * 1998-02-27 2003-01-28 Restek Corporation Method of passivating a gas vessel or component of a gas transfer system using a silicon overlay coating
JP2000026727A (ja) * 1998-07-06 2000-01-25 Dow Corning Toray Silicone Co Ltd 硬化性シリコーンレジン組成物
US6329488B1 (en) * 1998-11-10 2001-12-11 C. R. Bard, Inc. Silane copolymer coatings
US6444326B1 (en) * 1999-03-05 2002-09-03 Restek Corporation Surface modification of solid supports through the thermal decomposition and functionalization of silanes
US6143057A (en) * 1999-04-23 2000-11-07 The Boc Group, Inc. Adsorbents and adsorptive separation process
US20020096431A1 (en) * 1999-09-01 2002-07-25 Pierre Sevigny Apparatus for the manufacture of a disposable electrophoresis cassette and method thereof
JP2001098220A (ja) * 1999-09-28 2001-04-10 Kankyo Device Kenkyusho:Kk 防藻用光触媒コーティング及びこのコーティングを有する物品
US6329487B1 (en) * 1999-11-12 2001-12-11 Kion Corporation Silazane and/or polysilazane compounds and methods of making
EP1134224B1 (en) * 2000-03-13 2007-05-30 JSR Corporation Cyclosilane compound, and solution composition and process for forming a silicon film
US6416716B1 (en) * 2001-04-20 2002-07-09 Ashok Kumar Shukla Sample preparation device with embedded separation media
US6534184B2 (en) * 2001-02-26 2003-03-18 Kion Corporation Polysilazane/polysiloxane block copolymers
JP2003075421A (ja) * 2001-08-31 2003-03-12 Shiseido Co Ltd カラム充填剤及びその製造方法
WO2004071619A1 (en) * 2003-02-10 2004-08-26 Waters Investments Limited Siloxane-immobilized particulate stationary phases for chromatographic separations and extractions
CA2546898C (en) * 2003-11-20 2016-11-22 Sigma-Aldrich Co. Polysilazane thermosetting polymers for use in chromatographic systems and applications

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