CA2521694C - Materiau d'alliage destine au stockage d'hydrogene et son procede de production - Google Patents

Materiau d'alliage destine au stockage d'hydrogene et son procede de production Download PDF

Info

Publication number
CA2521694C
CA2521694C CA002521694A CA2521694A CA2521694C CA 2521694 C CA2521694 C CA 2521694C CA 002521694 A CA002521694 A CA 002521694A CA 2521694 A CA2521694 A CA 2521694A CA 2521694 C CA2521694 C CA 2521694C
Authority
CA
Canada
Prior art keywords
hydrogen storage
alloy
metal
alloy material
amorphous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002521694A
Other languages
English (en)
Other versions
CA2521694A1 (fr
Inventor
Yoshiaki Arata
Akihisa Inoue
Hisamichi Kimura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Science and Technology Agency
Original Assignee
Japan Science and Technology Agency
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Science and Technology Agency filed Critical Japan Science and Technology Agency
Publication of CA2521694A1 publication Critical patent/CA2521694A1/fr
Application granted granted Critical
Publication of CA2521694C publication Critical patent/CA2521694C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0078—Composite solid storage mediums, i.e. coherent or loose mixtures of different solid constituents, chemically or structurally heterogeneous solid masses, coated solids or solids having a chemically modified surface region
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
    • C04B35/486—Fine ceramics
    • C04B35/488—Composites
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
    • C04B35/6265—Thermal treatment of powders or mixtures thereof other than sintering involving reduction or oxidation
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/10—Alloys containing non-metals
    • C22C1/1078—Alloys containing non-metals by internal oxidation of material in solid state
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/12—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on oxides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C45/00—Amorphous alloys
    • C22C45/10—Amorphous alloys with molybdenum, tungsten, niobium, tantalum, titanium, or zirconium or Hf as the major constituent
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3279—Nickel oxides, nickalates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C04B2235/404—Refractory metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C04B2235/405—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C04B2235/408—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/80—Phases present in the sintered or melt-cast ceramic products other than the main phase
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Powder Metallurgy (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

L'invention concerne un matériau d'alliage destiné au stockage d'hydrogène, obtenu par traitement thermique d'un alliage amorphe dont la composition, en termes de % atomique, est représentée par la formule: Zr100-a-bPdaMb (dans laquelle 15</=a</=40, 0<b</=10, et M représente au moins un métal sélectionné parmi Pt, Au, Fe, Co et Ni) dans une atmosphère d'air ou d'oxygène. Ce matériau d'alliage est caractérisé en ce que Pd, M et un composé de ces derniers sont dispersés sous la forme de particules superfines dans une phase de base de ZrO2. Ce matériau d'alliage présente une proportion de stockage d'hydrogène d'au moins 2,5 % en poids, par rapport au poids de Pd. Il est approprié pour être utilisé en tant que moyen de stockage/transport d'hydrogène. L'invention concerne également un procédé de production dudit matériau d'alliage, consistant à mettre à disposition un bain de fusion d'alliage mère préparé à partir d'un lingot, effectuer une solidification rapide dudit bain à une vitesse de refroidissement d'au moins 10<4> K/s, pour obtenir ainsi un alliage amorphe, et effectuer un traitement thermique oxydant de l'alliage amorphe dans une atmosphère d'air ou d'oxygène à une température comprise entre 250 et 350 DEG C, de façon à réaliser une oxydation sélective de l'élément d'alliage Zr, le métal Pd ou le composé de Pd de stockage d'hydrogène étant ainsi dispersé sous la forme de nanoparticules superfines dans la phase de base de ZrO2.
CA002521694A 2003-04-07 2003-04-07 Materiau d'alliage destine au stockage d'hydrogene et son procede de production Expired - Fee Related CA2521694C (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2003/004416 WO2004090182A1 (fr) 2003-04-07 2003-04-07 Materiau d'alliage destine au stockage d'hydrogene et son procede de production

Publications (2)

Publication Number Publication Date
CA2521694A1 CA2521694A1 (fr) 2004-10-21
CA2521694C true CA2521694C (fr) 2009-07-21

Family

ID=33156440

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002521694A Expired - Fee Related CA2521694C (fr) 2003-04-07 2003-04-07 Materiau d'alliage destine au stockage d'hydrogene et son procede de production

Country Status (3)

Country Link
US (1) US20070169852A1 (fr)
CA (1) CA2521694C (fr)
WO (1) WO2004090182A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2004034406A1 (ja) * 2002-10-11 2006-03-02 プラズマ技研工業株式会社 水素凝結体およびそれを用いた発熱方法
GB0317894D0 (en) * 2003-07-31 2003-09-03 Johnson Matthey Plc Hydrogen supply system
US11430512B2 (en) * 2020-06-29 2022-08-30 Taiwan Semiconductor Manufacturing Company Limited Semiconducting metal oxide memory device using hydrogen-mediated threshold voltage modulation and methods for forming the same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4728580A (en) * 1985-03-29 1988-03-01 The Standard Oil Company Amorphous metal alloy compositions for reversible hydrogen storage
JPS6434443A (en) * 1987-07-14 1989-02-03 Lonza Ag Catalyst for oxidizing carbon compound
US5490970A (en) * 1988-06-28 1996-02-13 Matsushita Electric Industrial Co., Ltd. Method of producing hydrogen-storing alloy and electrode making use of the alloy
JP3720250B2 (ja) * 2000-09-26 2005-11-24 独立行政法人科学技術振興機構 高水素吸蔵合金とその製造方法

Also Published As

Publication number Publication date
US20070169852A1 (en) 2007-07-26
WO2004090182A1 (fr) 2004-10-21
CA2521694A1 (fr) 2004-10-21

Similar Documents

Publication Publication Date Title
JP4989636B2 (ja) 高強度極微細ナノ構造のアルミニウム及び窒化アルミニウム又はアルミニウム合金及び窒化アルミニウム複合材料の製造方法
US20230321720A1 (en) Method of preparing nano-porous powder material
JP5409348B2 (ja) 水素の貯蔵のためのナノ結晶化合物
JP2007522917A (ja) Ｍｇベースの水素吸蔵材料における触媒水素脱着およびその材料の製造方法
KR102539775B1 (ko) 알루미늄 합금 함유 분말체의 제조 방법 및 이의 응용과 합금 스트립
TWI281506B (en) Pre-alloyed bond powders
JP4240380B2 (ja) 磁性材料の製造方法
JP2007520629A (ja) 高い貯蔵容量および優れた室温反応速度を有するＭｇ−Ｎｉ水素吸蔵複合体
JPH07145442A (ja) 軟磁性合金圧密体およびその製造方法
US20090298683A1 (en) Production of a material comprising a mixture of noble metal nanoparticles and rare-earth oxide nanoparticles
JPS6289803A (ja) 硬質合金物品製造用チタン基硬質合金粒子の調製方法
WO1996022401A1 (fr) Alliages de cuivre-tungstene et leur procede de production
CA2521694C (fr) Materiau d&#39;alliage destine au stockage d&#39;hydrogene et son procede de production
Barua et al. Nanostructured icosahedral phase formation in Al 70 Cu 20 Fe 10 by mechanical alloying: comprehensive study
JP3720250B2 (ja) 高水素吸蔵合金とその製造方法
JPH0790517A (ja) アルミニウム基合金
JP3731041B2 (ja) 高耐食性マグネシウム合金および高耐食性マグネシウム材料の作製方法
JP7336038B2 (ja) 水素貯蔵材料、水素貯蔵容器及び水素供給装置
JP3872465B2 (ja) 高水素吸蔵材料とその製法
EP4019653A1 (fr) Matériau de stockage d&#39;hydrogène, récipient de stockage d&#39;hydrogène et dispositif d&#39;alimentation en hydrogène
Jurczyk Nanostructured electrode materials for Ni-MH x batteries prepared by mechanical alloying
JP4524384B2 (ja) 準結晶含有チタン合金及びその製造方法
Scudino et al. Production of customized hybrid porous structures by powder metallurgy of Ni59Zr20Ti16Si2Sn3 glassy powders
WO2023153207A1 (fr) Matériau de stockage d&#39;hydrogène, récipient de stockage d&#39;hydrogène et dispositif d&#39;alimentation en hydrogène
US12031197B2 (en) Hydrogen storage material, hydrogen storage container, and hydrogen supply apparatus

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20130408