CA2520850C - Process for the preparation of a hydrogen-rich stream - Google Patents

Process for the preparation of a hydrogen-rich stream Download PDF

Info

Publication number
CA2520850C
CA2520850C CA002520850A CA2520850A CA2520850C CA 2520850 C CA2520850 C CA 2520850C CA 002520850 A CA002520850 A CA 002520850A CA 2520850 A CA2520850 A CA 2520850A CA 2520850 C CA2520850 C CA 2520850C
Authority
CA
Canada
Prior art keywords
process according
shift
hydrogen
shift step
ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002520850A
Other languages
English (en)
French (fr)
Other versions
CA2520850A1 (en
Inventor
Poul Erik Hoejlund Nielsen
John Boegild Hansen
Niels Christian Schioedt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Topsoe AS
Original Assignee
Haldor Topsoe AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe AS filed Critical Haldor Topsoe AS
Publication of CA2520850A1 publication Critical patent/CA2520850A1/en
Application granted granted Critical
Publication of CA2520850C publication Critical patent/CA2520850C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
CA002520850A 2003-04-01 2004-03-25 Process for the preparation of a hydrogen-rich stream Expired - Fee Related CA2520850C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DKPA200300499 2003-04-01
DKPA200300499 2003-04-01
DKPA200300532 2003-04-07
DKPA200300532 2003-04-07
PCT/EP2004/003160 WO2004087566A1 (en) 2003-04-01 2004-03-25 Process for the preparation of a hydrogen-rich stream

Publications (2)

Publication Number Publication Date
CA2520850A1 CA2520850A1 (en) 2004-10-14
CA2520850C true CA2520850C (en) 2009-08-25

Family

ID=33132904

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002520850A Expired - Fee Related CA2520850C (en) 2003-04-01 2004-03-25 Process for the preparation of a hydrogen-rich stream

Country Status (12)

Country Link
US (1) US7517374B2 (enExample)
EP (1) EP1613551B1 (enExample)
JP (1) JP4391521B2 (enExample)
KR (1) KR20060002904A (enExample)
AT (1) ATE342226T1 (enExample)
AU (1) AU2004226237B2 (enExample)
CA (1) CA2520850C (enExample)
DE (1) DE602004002769T2 (enExample)
ES (1) ES2273240T3 (enExample)
MX (1) MXPA05010539A (enExample)
RU (1) RU2386583C2 (enExample)
WO (1) WO2004087566A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008195585A (ja) * 2007-02-15 2008-08-28 Toshiba Corp 水素製造装置
JP2008200656A (ja) * 2007-02-22 2008-09-04 Toshiba Corp ジメチルエーテル改質触媒およびその製造方法
CN100441294C (zh) * 2007-05-10 2008-12-10 湖北省化学研究院 一氧化碳原料气脱氧催化剂及其制备和应用
EP2336083A1 (en) * 2009-12-17 2011-06-22 Topsøe Fuel Cell A/S Gas generator and processes for the conversion of a fuel into an oxygen-depleted gas and/or hydrogen-enriched gas
WO2018004992A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Conversion of methane to dimethyl ether
WO2018004994A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Fluidized bed membrane reactor
WO2018004993A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Reduction of greenhouse gas emission

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4091086A (en) * 1976-12-20 1978-05-23 Engelhard Minerals & Chemicals Corporation Process for production of hydrogen
DK147705C (da) * 1982-09-07 1985-05-13 Haldor Topsoe As Fremgangsmaade til fremstilling af carbonhydrider ud fra syntesegas
US5498370A (en) * 1994-12-15 1996-03-12 Amoco Corporation Process for hydroshifting dimethyl ether
DK173416B1 (da) * 1995-07-21 2000-10-02 Topsoe Haldor As Fremgangsmåde til fremstilling af hydrogenrig gas
WO1999017875A1 (en) * 1997-10-07 1999-04-15 Nkk Corporation Catalyst for producing hydrogen or synthesis gas and method of producing hydrogen or synthesis gas
DE10010069A1 (de) 2000-03-02 2001-09-20 Xcellsis Gmbh Verfahren zum Betreiben einer Gaserzeugungsvorrichtung bzw. eines Brennstoffzellensystems, Gaserzeugungsvorrichtung und Brennstoffzellensystem
RU2165790C1 (ru) * 2000-03-13 2001-04-27 Институт катализа им. Г.К. Борескова СО РАН Катализатор и способ получения обогащенной по водороду газовой смеси из диметилового эфира
JP2003010685A (ja) 2001-06-27 2003-01-14 Nkk Corp 水素製造触媒およびその製造方法ならびに水素を製造する方法
JP4175452B2 (ja) 2001-08-07 2008-11-05 三菱重工業株式会社 ジメチルエーテル改質触媒およびジメチルエーテル改質方法

Also Published As

Publication number Publication date
KR20060002904A (ko) 2006-01-09
ES2273240T3 (es) 2007-05-01
DE602004002769T2 (de) 2007-02-08
RU2386583C2 (ru) 2010-04-20
EP1613551A1 (en) 2006-01-11
DE602004002769D1 (de) 2006-11-23
MXPA05010539A (es) 2005-11-23
EP1613551B1 (en) 2006-10-11
RU2005133159A (ru) 2006-03-20
AU2004226237A1 (en) 2004-10-14
WO2004087566A1 (en) 2004-10-14
JP2006521990A (ja) 2006-09-28
AU2004226237B2 (en) 2009-08-13
JP4391521B2 (ja) 2009-12-24
US7517374B2 (en) 2009-04-14
CA2520850A1 (en) 2004-10-14
US20060168888A1 (en) 2006-08-03
ATE342226T1 (de) 2006-11-15

Similar Documents

Publication Publication Date Title
CA2886004C (en) Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming
CA2860874A1 (en) Direct synthesis of dme at equilibrium
NO20034284L (no) Fremgangsmate til fremstilling av syntesegass
RU2510883C2 (ru) Способ получения синтез-газа для производства аммиака
CN1331731C (zh) 制备富氢物流的方法
US6797252B2 (en) Hydrocarbon gas to liquid conversion process
CA2520850C (en) Process for the preparation of a hydrogen-rich stream
CA2546181C (en) Process for the preparation of urea
Jeon et al. Methane steam reforming for synthetic diesel fuel production from steam-hydrogasifier product gases
Védrine Natural gas as feedstock
MXPA06005449A (en) Process forthe preparation of urea
Vasconcelos et al. Process development of dry reforming of natural gas hydrocarbons

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20130325