CA2512822C - Methode de separation assistee par gel et deshydratation/desalage d'hydrocarbures - Google Patents
Methode de separation assistee par gel et deshydratation/desalage d'hydrocarbures Download PDFInfo
- Publication number
- CA2512822C CA2512822C CA2512822A CA2512822A CA2512822C CA 2512822 C CA2512822 C CA 2512822C CA 2512822 A CA2512822 A CA 2512822A CA 2512822 A CA2512822 A CA 2512822A CA 2512822 C CA2512822 C CA 2512822C
- Authority
- CA
- Canada
- Prior art keywords
- gel
- hydrocarbon oil
- hydrocarbon
- water
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 152
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 123
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 120
- 239000003921 oil Substances 0.000 title claims description 133
- 238000000926 separation method Methods 0.000 title claims description 24
- 238000011033 desalting Methods 0.000 title claims description 15
- 238000000034 method Methods 0.000 claims abstract description 61
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 67
- 239000010779 crude oil Substances 0.000 claims description 47
- 150000003839 salts Chemical class 0.000 claims description 32
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 230000001351 cycling effect Effects 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 12
- 125000005608 naphthenic acid group Chemical group 0.000 claims description 12
- 238000011282 treatment Methods 0.000 claims description 11
- -1 hydrocarbons compounds Chemical class 0.000 claims description 10
- 239000003245 coal Substances 0.000 claims description 9
- 239000000571 coke Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol group Chemical group [C@@H]1(CC[C@H]2[C@@H]3CC=C4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C)[C@H](C)CCCC(C)C HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 229920005610 lignin Polymers 0.000 claims description 6
- 238000005119 centrifugation Methods 0.000 claims description 5
- 230000005484 gravity Effects 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical class [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 235000011148 calcium chloride Nutrition 0.000 claims description 3
- 150000002898 organic sulfur compounds Chemical class 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- LKVLGPGMWVYUQI-UHFFFAOYSA-L calcium;naphthalene-2-carboxylate Chemical class [Ca+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 LKVLGPGMWVYUQI-UHFFFAOYSA-L 0.000 claims 2
- 235000019198 oils Nutrition 0.000 description 91
- 239000000499 gel Substances 0.000 description 66
- 235000002639 sodium chloride Nutrition 0.000 description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000004458 analytical method Methods 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 230000000737 periodic effect Effects 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 230000005686 electrostatic field Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 235000019476 oil-water mixture Nutrition 0.000 description 2
- 230000003534 oscillatory effect Effects 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 210000000707 wrist Anatomy 0.000 description 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000000196 viscometry Methods 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/02—Non-metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/08—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by treating with water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G33/00—Dewatering or demulsification of hydrocarbon oils
- C10G33/04—Dewatering or demulsification of hydrocarbon oils with chemical means
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59089104P | 2004-07-23 | 2004-07-23 | |
| US60/590,891 | 2004-07-23 | ||
| US11/173,975 US20060016727A1 (en) | 2004-07-23 | 2005-07-01 | Gel assisted separation method and dewatering/desalting hydrocarbon oils |
| US11/173,975 | 2005-07-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2512822A1 CA2512822A1 (fr) | 2006-01-23 |
| CA2512822C true CA2512822C (fr) | 2013-05-21 |
Family
ID=35655986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2512822A Expired - Fee Related CA2512822C (fr) | 2004-07-23 | 2005-07-21 | Methode de separation assistee par gel et deshydratation/desalage d'hydrocarbures |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US20060016727A1 (fr) |
| CA (1) | CA2512822C (fr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008027131A1 (fr) * | 2006-08-31 | 2008-03-06 | Exxonmobil Chemical Patents Inc. | Disposition de goudron de vapocraquage |
| US8864996B2 (en) * | 2007-08-28 | 2014-10-21 | Exxonmobil Research And Engineering Company | Reduction of conradson carbon residue and average boiling points utilizing high pressure ultrafiltration |
| US7897828B2 (en) * | 2007-08-28 | 2011-03-01 | Exxonmobile Research And Engineering Company | Process for separating a heavy oil feedstream into improved products |
| US7871510B2 (en) * | 2007-08-28 | 2011-01-18 | Exxonmobil Research & Engineering Co. | Production of an enhanced resid coker feed using ultrafiltration |
| US8177965B2 (en) * | 2007-08-28 | 2012-05-15 | Exxonmobil Research And Engineering Company | Enhancement of saturates content in heavy hydrocarbons utilizing ultrafiltration |
| US7815790B2 (en) | 2007-08-28 | 2010-10-19 | Exxonmobil Research And Engineering Company | Upgrade of visbroken residua products by ultrafiltration |
| US7867379B2 (en) * | 2007-08-28 | 2011-01-11 | Exxonmobil Research And Engineering Company | Production of an upgraded stream from steam cracker tar by ultrafiltration |
| US7736493B2 (en) * | 2007-08-28 | 2010-06-15 | Exxonmobil Research And Engineering Company | Deasphalter unit throughput increase via resid membrane feed preparation |
| CA2911610C (fr) * | 2014-11-13 | 2017-12-12 | Weatherford Technology Holdings, Llc | Separation d'une emulsion petrole/bitume |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2182145A (en) * | 1937-01-26 | 1939-12-05 | Petrolite Corp | Process and apparatus for treating oil |
| FR2229440B1 (fr) * | 1973-05-17 | 1977-07-29 | Inst Francais Du Petrole | |
| US4737265A (en) * | 1983-12-06 | 1988-04-12 | Exxon Research & Engineering Co. | Water based demulsifier formulation and process for its use in dewatering and desalting crude hydrocarbon oils |
| US5219471A (en) * | 1991-11-12 | 1993-06-15 | Amoco Corporation | Removal of metals and water-insoluble materials from desalter emulsions |
| US7125912B2 (en) * | 2001-10-09 | 2006-10-24 | Simax Technologies, Inc. | Doped sol-gel materials and method of manufacture utilizing reduced mixing temperatures |
-
2005
- 2005-07-01 US US11/173,975 patent/US20060016727A1/en not_active Abandoned
- 2005-07-21 CA CA2512822A patent/CA2512822C/fr not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20060016727A1 (en) | 2006-01-26 |
| CA2512822A1 (fr) | 2006-01-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20170721 |