CA2482896A1 - Procede de production de poly-alpha-olefines a haute viscosite en utilisant des catalyseurs liquides ioniques - Google Patents

Procede de production de poly-alpha-olefines a haute viscosite en utilisant des catalyseurs liquides ioniques Download PDF

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Publication number
CA2482896A1
CA2482896A1 CA002482896A CA2482896A CA2482896A1 CA 2482896 A1 CA2482896 A1 CA 2482896A1 CA 002482896 A CA002482896 A CA 002482896A CA 2482896 A CA2482896 A CA 2482896A CA 2482896 A1 CA2482896 A1 CA 2482896A1
Authority
CA
Canada
Prior art keywords
ionic liquid
recited
product
polyalphaolefin
range
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002482896A
Other languages
English (en)
Inventor
Kenneth D. Hope
Donald W. Twomey
Donald A. Stern
J. Barry Collins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron Phillips Chemical Co LP
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2482896A1 publication Critical patent/CA2482896A1/fr
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • C07C2/22—Metal halides; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C07C2527/126—Aluminium chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)

Abstract

La présente invention concerne un procédé de production continue d'un produit poly-alpha-oléfinique à haute viscosité en introduisant conjointement un monomère et un catalyseur liquide ionique dans une zone de réaction tout en enlevant en même temps de la zone de réaction un effluent de zone de réaction contenant le poly-alpha-oléfine à haute viscosité. La zone de réaction est utilisée dans des conditions de réaction convenables pour produire le produit poly-alpha-oléfinique à haute viscosité. Le poly-alpha-oléfine à haute viscosité préféré présente une viscosité cinématique dépassant environ 8 cSt et constitue le produit réactionnel issu de la trimérisation, oligomérisation ou polymérisation d'un alpha-oléfine ou d'un mélange d'un ou plusieurs de ses produits. Les poly-alpha-oléfines selon l'invention sont utilisables en tant que lubrifiants or additifs lubrifiants.
CA002482896A 2002-04-22 2003-04-22 Procede de production de poly-alpha-olefines a haute viscosite en utilisant des catalyseurs liquides ioniques Abandoned CA2482896A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US37452802P 2002-04-22 2002-04-22
US60/374528 2002-04-22
PCT/US2003/012821 WO2003089390A2 (fr) 2002-04-22 2003-04-22 Procede de production de poly-alpha-olefines a haute viscosite en utilisant des catalyseurs liquides ioniques

Publications (1)

Publication Number Publication Date
CA2482896A1 true CA2482896A1 (fr) 2003-10-30

Family

ID=29251200

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002482896A Abandoned CA2482896A1 (fr) 2002-04-22 2003-04-22 Procede de production de poly-alpha-olefines a haute viscosite en utilisant des catalyseurs liquides ioniques

Country Status (7)

Country Link
US (2) US7351780B2 (fr)
EP (2) EP1497243A2 (fr)
JP (1) JP2005523320A (fr)
AU (1) AU2003223727A1 (fr)
CA (1) CA2482896A1 (fr)
RU (1) RU2004133895A (fr)
WO (1) WO2003089390A2 (fr)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7259284B2 (en) * 2000-05-31 2007-08-21 Chevron Phillips Chemical Company, Lp Method for manufacturing high viscosity polyalphaolefins using ionic liquid catalysts
CA2482896A1 (fr) 2002-04-22 2003-10-30 Chevron Phillips Chemical Company Lp Procede de production de poly-alpha-olefines a haute viscosite en utilisant des catalyseurs liquides ioniques
AU2003223729A1 (en) * 2002-04-22 2003-11-03 Chevron Phillips Chemical Company Lp Method for manufacturing ionic liquid catalysts
WO2005042447A1 (fr) * 2003-10-31 2005-05-12 Chevron Phillips Chemical Company, Lp Procede et systeme pour le contact entre un catalyseur ionique liquide et de l'oxygene, permettant d'ameliorer une reaction chimique
CA2543969A1 (fr) * 2003-10-31 2005-05-12 Chevron Phillips Chemical Company Lp Procede et systeme permettant d'augmenter le cisaillement afin d'ameliorer une reaction chimique catalysee a liquide ionique
US7550640B2 (en) * 2005-01-14 2009-06-23 Exxonmobil Chemical Patents Inc. High viscosity PAOs based on 1-decene/1-dodecene
GB0525251D0 (en) 2005-12-12 2006-01-18 Univ Belfast Oligomerisation
US7572943B2 (en) * 2005-12-20 2009-08-11 Chevron U.S.A. Inc. Alkylation of oligomers to make superior lubricant or fuel blendstock
US7572944B2 (en) * 2005-12-20 2009-08-11 Chevron U.S.A. Inc. Process for making and composition of superior lubricant or lubricant blendstock
US7592497B2 (en) * 2006-03-24 2009-09-22 Exxonmobil Chemical Patents Inc. Low viscosity polyalphapolefin based on 1-decene and 1-dodecene
US7544850B2 (en) * 2006-03-24 2009-06-09 Exxonmobil Chemical Patents Inc. Low viscosity PAO based on 1-tetradecene
US7547811B2 (en) * 2006-03-24 2009-06-16 Exxonmobil Chemical Patents Inc. High viscosity polyalphaolefins based on 1-hexene, 1-dodecene and 1-tetradecene
US8143467B2 (en) * 2007-12-18 2012-03-27 Exxonmobil Research And Engineering Company Process for synthetic lubricant production
US8865959B2 (en) * 2008-03-18 2014-10-21 Exxonmobil Chemical Patents Inc. Process for synthetic lubricant production
CA2740217C (fr) * 2008-10-31 2017-03-28 Chevron Phillips Chemical Company Lp Systeme et methode de desactivation et d'etanchement d'un catalyseur d'oligomerisation
US8471085B2 (en) 2008-10-31 2013-06-25 Chevron Phillips Chemical Company Lp Oligomerization catalyst system and process for oligomerizing olefins
EP2418228A4 (fr) * 2009-04-10 2013-09-04 Idemitsu Kosan Co Oligomère d'a-oléfine et son procédé de fabrication
MX362816B (es) * 2009-06-16 2019-02-15 Chevron Phillips Chemical Co Lp Oligomerizacion de alfa olefinas usando sistemas de catalizador de metaloceno-ssa y uso de las polialfaolefinas resultantes para preparar mezclas lubricantes.
US8604258B2 (en) 2009-08-10 2013-12-10 Chevron U.S.A. Inc. Base oil having high kinematic viscosity and low pour point
US8124821B2 (en) 2009-08-10 2012-02-28 Chevron U.S.A. Inc. Oligomerization of propylene to produce base oil products using ionic liquids-based catalysis
US8101809B2 (en) * 2009-08-10 2012-01-24 Chevron U.S.A. Inc. Base oil composition comprising oligomerized olefins
US9267091B2 (en) 2009-08-10 2016-02-23 Chevron U.S.A. Inc. Tuning an oligomerizing step that uses an acidic ionic liquid catalyst to produce a base oil with selected properties
US8487154B2 (en) * 2010-03-17 2013-07-16 Chevron U.S.A. Inc. Market driven alkylation or oligomerization process
US8895794B2 (en) * 2010-03-17 2014-11-25 Chevron U.S.A. Inc. Process for producing high quality gasoline blending components in two modes
US8455708B2 (en) 2010-03-17 2013-06-04 Chevron U.S.A. Inc. Flexible production of alkylate gasoline and distillate
US8471086B2 (en) * 2010-06-28 2013-06-25 Chevron U.S.A. Inc. Process to control product selectivity
EP2593224A4 (fr) 2010-07-07 2014-01-29 Conocophillips Co Supports hétérogènes pour catalyseurs homogènes
US8524968B2 (en) 2010-12-13 2013-09-03 Chevron U.S.A. Inc. Process to make base oil by oligomerizing low boiling olefins
US8222471B2 (en) * 2010-12-13 2012-07-17 Chevron U.S.A. Inc. Process for making a high viscosity base oil with an improved viscosity index
CN102776023B (zh) * 2011-05-11 2015-02-25 中国石油化工股份有限公司 一种高粘度聚α-烯烃合成油及其制备方法
US9669377B2 (en) * 2014-12-12 2017-06-06 Uop Llc Ionic liquid reactor with heat exchanger
WO2016161203A1 (fr) * 2015-03-31 2016-10-06 Uop Llc Procédés d'oligomérisation d'oléfines faisant appel à des microémulsions de liquide ionique de type halogénométallate
WO2016161200A1 (fr) 2015-03-31 2016-10-06 Uop Llc Micro-émulsions de liquide ionique halométallate
US10435491B2 (en) 2015-08-19 2019-10-08 Chevron Phillips Chemical Company Lp Method for making polyalphaolefins using ionic liquid catalyzed oligomerization of olefins
EP3896141B1 (fr) * 2020-04-14 2023-08-30 Indian Oil Corporation Limited Procédé de contrôle de la viscosité cinématique d'une polyalphaoléfine

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2405950A (en) * 1943-03-27 1946-08-20 Du Pont Process for polymerizing olefins
US3647912A (en) * 1969-03-04 1972-03-07 Exxon Research Engineering Co Preparation of linear olefin products
CA1208196A (fr) 1982-03-10 1986-07-22 Raymond F. Watts Produit lubrifiant
US4827064A (en) * 1986-12-24 1989-05-02 Mobil Oil Corporation High viscosity index synthetic lubricant compositions
US5334569A (en) 1987-02-24 1994-08-02 Nalco Chemical Company Alkylation aid
US5087782A (en) * 1989-04-28 1992-02-11 Mobil Oil Corporation Dehydrocyclization of polyalpha-olefin lubricants
TW408155B (en) * 1989-08-31 2000-10-11 Dow Chemical Co Blends of <alpha>-olefin/vinylidene aromatic monomer or hindered aliphatic vinylidene monomer interpolymers with polymers of vinylidene aromatic monomers
US5573657A (en) * 1991-07-24 1996-11-12 Mobil Oil Corporation Hydrogenation process
US5196574A (en) * 1991-12-23 1993-03-23 Uop Detergent alkylation process using a fluorided silica-alumina
IT1254182B (it) * 1992-02-03 1995-09-14 Processo per la preparzione di alchilbenzeni lineari
EP0558187B1 (fr) 1992-02-19 1996-04-10 BP Chemicals Limited Polymères de butène
DE69423165T2 (de) * 1993-09-22 2000-07-06 Inst Francais Du Petrole Nickel enthaltende Katalysatorzusammensetzung und Verfahren zum Dimerisieren und Oligomerisieren von Olefinen
GB9402612D0 (en) 1994-02-10 1994-04-06 British Petroleum Co Plc Ionic liquids
CN1123031A (zh) 1994-02-10 1996-05-22 英国石油化学品有限公司 离子液体
GB9603754D0 (en) * 1996-02-22 1996-04-24 Bp Chem Int Ltd Lubricating oils
US5824832A (en) * 1996-07-22 1998-10-20 Akzo Nobel Nv Linear alxylbenzene formation using low temperature ionic liquid
US5731101A (en) * 1996-07-22 1998-03-24 Akzo Nobel Nv Low temperature ionic liquids
US5891830A (en) * 1997-01-31 1999-04-06 Baker Hughes Incorporated Lubricating grease
WO1998050153A1 (fr) 1997-05-01 1998-11-12 Akzo Nobel N.V. Formation in-situ de catalyseur liquide ionique pour une reaction chimique catalysee liquide ionique
FR2763869B1 (fr) * 1997-05-27 1999-07-16 Inst Francais Du Petrole Procede et installation pour realiser une reaction sur une charge organique, telle que la dimerisation ou la metathese, en presence d'une phase polaire contenant un catalyseur
FR2765573B1 (fr) * 1997-07-04 1999-08-27 Inst Francais Du Petrole Enchainement de procedes pour l'oligomerisation des olefines
EP0933416A1 (fr) 1998-01-30 1999-08-04 Chevron Chemical S.A. Utilisation de poly alpha oléfines (PAO) de 1-docecène ou 1-tetradecène pour améliorer la stabilité thermique d'huile de moteur dans un moteur à combustion interne
US6087307A (en) * 1998-11-17 2000-07-11 Mobil Oil Corporation Polyether fluids miscible with non-polar hydrocarbon lubricants
US20020010291A1 (en) 1998-12-04 2002-01-24 Vince Murphy Ionic liquids and processes for production of high molecular weight polyisoolefins
WO2000041809A1 (fr) 1999-01-15 2000-07-20 Bp Chemicals Limited Catalyseur a base de liquide ionique pour alkylation
US6398946B1 (en) * 1999-12-22 2002-06-04 Chevron U.S.A., Inc. Process for making a lube base stock from a lower molecular weight feedstock
AU2001240646A1 (en) 2000-03-01 2001-09-12 Akzo Nobel N.V. Process for the preparation of a dry suspension of an ammonium halide
US7259284B2 (en) * 2000-05-31 2007-08-21 Chevron Phillips Chemical Company, Lp Method for manufacturing high viscosity polyalphaolefins using ionic liquid catalysts
US6395948B1 (en) * 2000-05-31 2002-05-28 Chevron Chemical Company Llc High viscosity polyalphaolefins prepared with ionic liquid catalyst
US20020128532A1 (en) * 2000-05-31 2002-09-12 Chevron Chemical Company Llc High viscosity polyalphaolefins prepared with ionic liquid catalyst
JP2002097488A (ja) 2000-09-19 2002-04-02 Ethyl Corp 増強された最終動力伝達装置性能のギア油配合物
US6414099B1 (en) * 2000-10-18 2002-07-02 Equistar Chemicals, Lp Single-site catalysts based on caged diimide ligands
US6608149B2 (en) * 2000-12-04 2003-08-19 Univation Technologies, Llc Polymerization process
WO2003040264A1 (fr) * 2001-11-06 2003-05-15 Extractica, Llc Procede d'extraction de composes organo-sulfureux a partir d'hydrocarbures a l'aide de liquides ioniques
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
CA2482896A1 (fr) 2002-04-22 2003-10-30 Chevron Phillips Chemical Company Lp Procede de production de poly-alpha-olefines a haute viscosite en utilisant des catalyseurs liquides ioniques
AU2003223729A1 (en) * 2002-04-22 2003-11-03 Chevron Phillips Chemical Company Lp Method for manufacturing ionic liquid catalysts
CA2543969A1 (fr) * 2003-10-31 2005-05-12 Chevron Phillips Chemical Company Lp Procede et systeme permettant d'augmenter le cisaillement afin d'ameliorer une reaction chimique catalysee a liquide ionique
WO2005042447A1 (fr) * 2003-10-31 2005-05-12 Chevron Phillips Chemical Company, Lp Procede et systeme pour le contact entre un catalyseur ionique liquide et de l'oxygene, permettant d'ameliorer une reaction chimique

Also Published As

Publication number Publication date
AU2003223727A1 (en) 2003-11-03
US20040030075A1 (en) 2004-02-12
US7351780B2 (en) 2008-04-01
WO2003089390A3 (fr) 2004-03-18
EP1497243A2 (fr) 2005-01-19
US20080161623A1 (en) 2008-07-03
EP2272814A2 (fr) 2011-01-12
RU2004133895A (ru) 2005-06-10
WO2003089390A2 (fr) 2003-10-30
US7615598B2 (en) 2009-11-10
JP2005523320A (ja) 2005-08-04

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Legal Events

Date Code Title Description
EEER Examination request
FZDE Discontinued