CA2475497A1 - Decoppering agent - Google Patents
Decoppering agent Download PDFInfo
- Publication number
- CA2475497A1 CA2475497A1 CA002475497A CA2475497A CA2475497A1 CA 2475497 A1 CA2475497 A1 CA 2475497A1 CA 002475497 A CA002475497 A CA 002475497A CA 2475497 A CA2475497 A CA 2475497A CA 2475497 A1 CA2475497 A1 CA 2475497A1
- Authority
- CA
- Canada
- Prior art keywords
- bismuth
- tin
- propellant
- decoppering agent
- decoppering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B5/00—Cartridge ammunition, e.g. separately-loaded propellant charges
- F42B5/02—Cartridges, i.e. cases with charge and missile
- F42B5/24—Cartridges, i.e. cases with charge and missile for cleaning; for cooling; for lubricating ; for wear reducing
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/04—Compositions characterised by non-explosive or non-thermic constituents for cooling the explosion gases including antifouling and flash suppressing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Powder Metallurgy (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Lubricants (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines Containing Plant Substances (AREA)
- Paints Or Removers (AREA)
Abstract
There is provided a decoppering agent that is incorporated into the propella nt to remove copper from the rifling of the internal bore of a gun barrel. The decoppering agent consists essentially of a lead-free pulverized additive mixed together with the other propellant compounds. We have found that a mixture of tin and bismuth is a very good decoppering agent. Especially in t he ratio 42% Sn/58%Bi, the melting point for this combination is 138 degree C. Much lower than each of the components. It can be all kinds of suitable tin and bismuth compounds. The bismuth and tin either vaporizes or liquefies whe n the propellant is ignited and either embrittles or dissolves the copper deposits facilitating removal.
Description
DECOPPERING AGENT
FIELD OF THE INVENTION
This invention relates to an addition to every kind of propellant effective for removing copper deposits from the inside surfaces of a gun barrels. More particularly, a composite addition has a pulverized decoppering agent mixed into the propellant.
BACKGROUND OF THE INVENTION
Most guns have a barrel with a rifled internal bore that imparts a stabilizing spin on an expelled projectile. The internal bore may be coated with a hard facing material, such as chromium, to minimize erosive wear increasing the number of projectiles that may be fired from the gun.
The typical large caliber projectile has a diameter slightly less than the diameter of the internal bore. One or more obturator, or rotating, bands gird the circumference of the .projectile. At the bands, the diameter of the projectile is slightly larger than the internal diameter of the gun barrel. When the projectile is expelled, the rotating band is engraved by the rifling, contacting the rifling throughout the length of the tube imparting the proj ectile with a stabilizing spin. Proj ectiles for rifles and pistols normally do not have a rotating band but they very often have a jacket made of tombac, which is engraved by the rifling.
The gun barrel is manufactured from a material such as steel and sometimes coated with a hard material such as a chromium facing. The gun barrel is haxder than the rotating band or j acket, which is typically copper or a copper alloy. As a result, a portion of the copper from the rotating band or the jacket is deposited on the rifling inside the gun barrel. This copper deposition referred to as "copper fouling" can affect the ballistics of the projectile and major fouling can prevent the projectile from being inserted and seated, positioned in the barrel prior to firing, properly.
Copper fouling is currently a major problem for large artillery weapons, such as 155-millimeter howitzers, and is also noted in small and medium caliber cannons, such as 20-millimeter canons. It has become a bigger problem in rifles today because of the use of the lead-free primers. Before the primer contained lead and that small amount of lead worked as a decoppering agent. The current solution to copper fouling is including a decoppering agent into the propellant. The decoppering agent removes the copper without damaging the gun barrel or the rifling.
A common decoppering agent is a sheet of lead foil deposited between the propellant and the projectile. On ignition of the propellant charge, the lead is vaporized and diffuses into the copper. The resultant alloy is brittle and easily shattered.
The combination of the heat generated by the burning propellant and the mechanical movement of the propellant gases separates the brittle lead/copper alloy from the surface of the barrel. The fractured debris is swept from the muzzle of the gun with the propellant gases.
A second theory as to why lead foil is effective as a decoppering agent is that the heat generated by the burning propellant melts the lead foil. Liquid lead contacts the copper deposition and dissolves the copper, the copper bearing lead solution is expelled as a liquid from the muzzle with the propellant gases.
While metallic lead and lead compounds are effective decoppering agents, the materials are toxic to humans working around the weapons. There is a need for a lead free decoppering agent.
Among the lead free decoppering agents that have been proposed are bismuth, bismuth subcarbonate (BiCO3), tin and tin alloys. Bismuth compounds are very brittle and even metallic bismuth cannot be rolled into a thin foil like lead. Alloys of bismuth metal with other metals can be rolled into a foil, but the alloys are very expensive and less effective as a decoppering agent. There are also solutions where one use especially made pellets of bismuth in a nitrocellulose binder, which will be added to the propellant charge.
There remains, therefore, a need for a method to effectively introduce a lead free decoppering agent into the propellant. To include the decoppering agent in the propellant composition makes it easier and cheaper when having to add a special made decoppering additive to the charge.
SUMMARY OF THE INVENTION
There is provided a decoppering agent that is incorporated into the propellant to remove copper from the rifling of the internal bore of a gun barrel. The decoppering agent consists essentially of a lead-free pulverized additive mixed together with the other propellant compounds. We have found that a mixture of tin and bismuth is a very good decoppering agent. Particularly, the ratio between tin and bismuth are between Sn and 90 - 38 %Bi. Especially in the ratio 42 %Sn/58%Bi, the melting point for this combination is 138 degree C. Much lower than each of the components. It can be all kinds of suitable tin and bismuth compounds. Suitably selected from the group consisting of metallic bismuth, bismuth alloys, bismuth compounds, metallic tin, tin alloys and tin compounds. The bismuth and tin either vaporizes or liquifies when the propellant is ignited and either embrittles or dissolves the copper deposits facilitating removal.
Accordingly, it is an object of the invention to provide an essentially lead free decoppering agent that is included in the propellant. It is a feature of the invention that the decoppering agent is a part of the propellant and distributed homogeneously.
It is an advantage of the invention that the decoppering agent is distributed to the barrel and trough the barrel with the propellant gases. When the decoppering agent is included in the propellant that also means that the powder gases always contains the same amount of decoppering agent.
The biggest advantage with this invention is that the decoppering agent always is there, it makes the loading easier and cheaper. No need for extra containers with especially made substances for decoppering.
FIELD OF THE INVENTION
This invention relates to an addition to every kind of propellant effective for removing copper deposits from the inside surfaces of a gun barrels. More particularly, a composite addition has a pulverized decoppering agent mixed into the propellant.
BACKGROUND OF THE INVENTION
Most guns have a barrel with a rifled internal bore that imparts a stabilizing spin on an expelled projectile. The internal bore may be coated with a hard facing material, such as chromium, to minimize erosive wear increasing the number of projectiles that may be fired from the gun.
The typical large caliber projectile has a diameter slightly less than the diameter of the internal bore. One or more obturator, or rotating, bands gird the circumference of the .projectile. At the bands, the diameter of the projectile is slightly larger than the internal diameter of the gun barrel. When the projectile is expelled, the rotating band is engraved by the rifling, contacting the rifling throughout the length of the tube imparting the proj ectile with a stabilizing spin. Proj ectiles for rifles and pistols normally do not have a rotating band but they very often have a jacket made of tombac, which is engraved by the rifling.
The gun barrel is manufactured from a material such as steel and sometimes coated with a hard material such as a chromium facing. The gun barrel is haxder than the rotating band or j acket, which is typically copper or a copper alloy. As a result, a portion of the copper from the rotating band or the jacket is deposited on the rifling inside the gun barrel. This copper deposition referred to as "copper fouling" can affect the ballistics of the projectile and major fouling can prevent the projectile from being inserted and seated, positioned in the barrel prior to firing, properly.
Copper fouling is currently a major problem for large artillery weapons, such as 155-millimeter howitzers, and is also noted in small and medium caliber cannons, such as 20-millimeter canons. It has become a bigger problem in rifles today because of the use of the lead-free primers. Before the primer contained lead and that small amount of lead worked as a decoppering agent. The current solution to copper fouling is including a decoppering agent into the propellant. The decoppering agent removes the copper without damaging the gun barrel or the rifling.
A common decoppering agent is a sheet of lead foil deposited between the propellant and the projectile. On ignition of the propellant charge, the lead is vaporized and diffuses into the copper. The resultant alloy is brittle and easily shattered.
The combination of the heat generated by the burning propellant and the mechanical movement of the propellant gases separates the brittle lead/copper alloy from the surface of the barrel. The fractured debris is swept from the muzzle of the gun with the propellant gases.
A second theory as to why lead foil is effective as a decoppering agent is that the heat generated by the burning propellant melts the lead foil. Liquid lead contacts the copper deposition and dissolves the copper, the copper bearing lead solution is expelled as a liquid from the muzzle with the propellant gases.
While metallic lead and lead compounds are effective decoppering agents, the materials are toxic to humans working around the weapons. There is a need for a lead free decoppering agent.
Among the lead free decoppering agents that have been proposed are bismuth, bismuth subcarbonate (BiCO3), tin and tin alloys. Bismuth compounds are very brittle and even metallic bismuth cannot be rolled into a thin foil like lead. Alloys of bismuth metal with other metals can be rolled into a foil, but the alloys are very expensive and less effective as a decoppering agent. There are also solutions where one use especially made pellets of bismuth in a nitrocellulose binder, which will be added to the propellant charge.
There remains, therefore, a need for a method to effectively introduce a lead free decoppering agent into the propellant. To include the decoppering agent in the propellant composition makes it easier and cheaper when having to add a special made decoppering additive to the charge.
SUMMARY OF THE INVENTION
There is provided a decoppering agent that is incorporated into the propellant to remove copper from the rifling of the internal bore of a gun barrel. The decoppering agent consists essentially of a lead-free pulverized additive mixed together with the other propellant compounds. We have found that a mixture of tin and bismuth is a very good decoppering agent. Particularly, the ratio between tin and bismuth are between Sn and 90 - 38 %Bi. Especially in the ratio 42 %Sn/58%Bi, the melting point for this combination is 138 degree C. Much lower than each of the components. It can be all kinds of suitable tin and bismuth compounds. Suitably selected from the group consisting of metallic bismuth, bismuth alloys, bismuth compounds, metallic tin, tin alloys and tin compounds. The bismuth and tin either vaporizes or liquifies when the propellant is ignited and either embrittles or dissolves the copper deposits facilitating removal.
Accordingly, it is an object of the invention to provide an essentially lead free decoppering agent that is included in the propellant. It is a feature of the invention that the decoppering agent is a part of the propellant and distributed homogeneously.
It is an advantage of the invention that the decoppering agent is distributed to the barrel and trough the barrel with the propellant gases. When the decoppering agent is included in the propellant that also means that the powder gases always contains the same amount of decoppering agent.
The biggest advantage with this invention is that the decoppering agent always is there, it makes the loading easier and cheaper. No need for extra containers with especially made substances for decoppering.
Claims (2)
1. A decoppering agent for a propellant, which comprises essentially of a lead free pulverized additive, consisting of a mixture of tin and bismuth compounds selected from the group consisting of metallic bismuth, bismuth alloys, bismuth compounds, metallic tin, tin alloys and tin compounds for effectively removing copper deposits from a gun barrel, which agent may be mixed into every kind of propellant generating a minimal amount of residue when burned, characterized in that the ratio between the tin and bismuth are between 10 - 62 % Sn and 90 - 38 %Bi.
2. The decoppering agent of claim 1, characterized in that the mixture is 42 % Sn and 58% Bi.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE0200366A SE523997C2 (en) | 2002-02-08 | 2002-02-08 | decoppering |
| SE0200366-3 | 2002-02-08 | ||
| PCT/SE2003/000028 WO2003066544A1 (en) | 2002-02-08 | 2003-01-13 | Decoppering agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2475497A1 true CA2475497A1 (en) | 2003-08-14 |
Family
ID=20286899
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002475497A Abandoned CA2475497A1 (en) | 2002-02-08 | 2003-01-13 | Decoppering agent |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US20050115452A1 (en) |
| EP (1) | EP1472199B1 (en) |
| JP (1) | JP4298512B2 (en) |
| KR (1) | KR100950907B1 (en) |
| CN (1) | CN1290803C (en) |
| AT (1) | ATE462680T1 (en) |
| AU (1) | AU2003201797A1 (en) |
| BR (1) | BR0307511B1 (en) |
| CA (1) | CA2475497A1 (en) |
| DE (1) | DE60331890D1 (en) |
| EA (1) | EA006416B1 (en) |
| HU (1) | HU228870B1 (en) |
| IL (1) | IL163376A (en) |
| RO (1) | RO122058B1 (en) |
| SE (1) | SE523997C2 (en) |
| WO (1) | WO2003066544A1 (en) |
| ZA (1) | ZA200406262B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10350024A1 (en) * | 2003-10-27 | 2005-05-25 | Metallwerk Elisenhütte GmbH | Cartridge with detection-relevant doping |
| WO2011123398A1 (en) * | 2010-03-30 | 2011-10-06 | Lockheed Martin Corporation | Methods for rework of a solder |
| CA2990862C (en) * | 2015-07-03 | 2022-05-31 | Nitrochemie Wimmis Ag | Propelling charge system for artillery shells |
| JP6727730B2 (en) * | 2017-09-19 | 2020-07-22 | 旭精機工業株式会社 | Bullets and bullets |
| CN111486744B (en) * | 2020-04-14 | 2022-07-22 | 重庆兴勇实业有限公司 | Firearm decoppering agent and preparation method thereof |
| CN111363950B (en) * | 2020-04-21 | 2021-05-28 | 中北大学 | Alloy copper removing agent for gun and preparation method |
| CN113154938A (en) * | 2021-04-07 | 2021-07-23 | 中北大学 | Efficient environment-friendly alloy copper remover as well as preparation method and application thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL9302056A (en) * | 1993-11-26 | 1995-06-16 | Billiton Witmetaal | Bullet and the use of an Sn alloy therefor. |
| US5463956A (en) * | 1994-02-08 | 1995-11-07 | Ici Americas Inc. | Wear decoppering liner |
| US5565643A (en) * | 1994-12-16 | 1996-10-15 | Olin Corporation | Composite decoppering additive for a propellant |
| JP2002025403A (en) * | 2000-07-03 | 2002-01-25 | Sorudaa Kooto Kk | Temperature fuse and wire material for temperature fuse element |
-
2002
- 2002-02-08 SE SE0200366A patent/SE523997C2/en not_active IP Right Cessation
-
2003
- 2003-01-13 BR BRPI0307511-7A patent/BR0307511B1/en not_active IP Right Cessation
- 2003-01-13 AU AU2003201797A patent/AU2003201797A1/en not_active Abandoned
- 2003-01-13 EA EA200401051A patent/EA006416B1/en not_active IP Right Cessation
- 2003-01-13 CA CA002475497A patent/CA2475497A1/en not_active Abandoned
- 2003-01-13 JP JP2003565922A patent/JP4298512B2/en not_active Expired - Fee Related
- 2003-01-13 RO ROA200400705A patent/RO122058B1/en unknown
- 2003-01-13 CN CNB038033666A patent/CN1290803C/en not_active Expired - Fee Related
- 2003-01-13 EP EP03700650A patent/EP1472199B1/en not_active Expired - Lifetime
- 2003-01-13 HU HU0402655A patent/HU228870B1/en not_active IP Right Cessation
- 2003-01-13 WO PCT/SE2003/000028 patent/WO2003066544A1/en active Application Filing
- 2003-01-13 AT AT03700650T patent/ATE462680T1/en not_active IP Right Cessation
- 2003-01-13 KR KR1020047012179A patent/KR100950907B1/en not_active IP Right Cessation
- 2003-01-13 DE DE60331890T patent/DE60331890D1/en not_active Expired - Lifetime
-
2004
- 2004-01-01 ZA ZA200406262A patent/ZA200406262B/en unknown
- 2004-08-05 IL IL163376A patent/IL163376A/en not_active IP Right Cessation
- 2004-08-09 US US10/913,426 patent/US20050115452A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CN1628085A (en) | 2005-06-15 |
| EP1472199A1 (en) | 2004-11-03 |
| EP1472199B1 (en) | 2010-03-31 |
| EA006416B1 (en) | 2005-12-29 |
| AU2003201797A1 (en) | 2003-09-02 |
| RO122058B1 (en) | 2008-11-28 |
| EA200401051A1 (en) | 2005-02-24 |
| KR20040102005A (en) | 2004-12-03 |
| SE0200366D0 (en) | 2002-02-08 |
| JP2005517146A (en) | 2005-06-09 |
| WO2003066544A1 (en) | 2003-08-14 |
| US20050115452A1 (en) | 2005-06-02 |
| SE523997C2 (en) | 2004-06-15 |
| ATE462680T1 (en) | 2010-04-15 |
| IL163376A (en) | 2009-12-24 |
| BR0307511A (en) | 2004-12-07 |
| DE60331890D1 (en) | 2010-05-12 |
| CN1290803C (en) | 2006-12-20 |
| HUP0402655A2 (en) | 2005-08-29 |
| BR0307511B1 (en) | 2011-10-04 |
| ZA200406262B (en) | 2008-01-30 |
| JP4298512B2 (en) | 2009-07-22 |
| SE0200366L (en) | 2003-08-09 |
| KR100950907B1 (en) | 2010-04-05 |
| HU228870B1 (en) | 2013-06-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |