CA2446406A1 - Maleated polypropylenes and processes for the preparation thereof - Google Patents
Maleated polypropylenes and processes for the preparation thereof Download PDFInfo
- Publication number
- CA2446406A1 CA2446406A1 CA002446406A CA2446406A CA2446406A1 CA 2446406 A1 CA2446406 A1 CA 2446406A1 CA 002446406 A CA002446406 A CA 002446406A CA 2446406 A CA2446406 A CA 2446406A CA 2446406 A1 CA2446406 A1 CA 2446406A1
- Authority
- CA
- Canada
- Prior art keywords
- polypropylene
- malefic anhydride
- maleic anhydride
- bound
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- -1 polypropylenes Polymers 0.000 title claims abstract description 90
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 83
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 81
- 238000000034 method Methods 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title description 2
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 24
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims description 42
- 239000011541 reaction mixture Substances 0.000 claims description 21
- 239000000047 product Substances 0.000 claims description 13
- 239000000155 melt Substances 0.000 claims description 8
- 229920000578 graft copolymer Polymers 0.000 claims 2
- 150000008064 anhydrides Chemical group 0.000 description 107
- 229920000642 polymer Polymers 0.000 description 19
- 239000003054 catalyst Substances 0.000 description 11
- 239000004698 Polyethylene Substances 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 150000002978 peroxides Chemical class 0.000 description 6
- 239000002243 precursor Substances 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920005606 polypropylene copolymer Polymers 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 description 1
- PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical class CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000001064 degrader Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229930004008 p-menthane Natural products 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- CFJYNSNXFXLKNS-UHFFFAOYSA-N trans-p-menthane Natural products CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28926901P | 2001-05-06 | 2001-05-06 | |
| US60/289,269 | 2001-05-06 | ||
| PCT/US2002/014320 WO2002090403A1 (en) | 2001-05-06 | 2002-05-06 | Maleated polypropylenes and processes for the preparation thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2446406A1 true CA2446406A1 (en) | 2002-11-14 |
Family
ID=23110793
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002446406A Abandoned CA2446406A1 (en) | 2001-05-06 | 2002-05-06 | Maleated polypropylenes and processes for the preparation thereof |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP1434809A4 (enExample) |
| JP (3) | JP2005509688A (enExample) |
| KR (3) | KR20090006238A (enExample) |
| CN (1) | CN100491427C (enExample) |
| AU (1) | AU2002309651B2 (enExample) |
| CA (1) | CA2446406A1 (enExample) |
| WO (1) | WO2002090403A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7659000B2 (en) * | 2004-04-12 | 2010-02-09 | Boston Scientific Scimed, Inc. | Adhesion technique for incompatible polymers using modified polymer tie layers |
| CN100532413C (zh) * | 2005-04-18 | 2009-08-26 | 中国科学院化学研究所 | 一种聚丙烯接枝共聚物及其制备方法与应用 |
| US7750078B2 (en) * | 2005-12-07 | 2010-07-06 | Exxonmobil Chemical Patents Inc. | Systems and methods used for functionalization of polymeric material and polymeric materials prepared therefrom |
| CN101597358B (zh) * | 2008-06-02 | 2011-01-12 | 张发饶 | 一种马来酸酐接枝聚丙烯蜡的生产制备方法及其装置 |
| CN101724128B (zh) * | 2008-10-31 | 2012-03-07 | 中国石油化工股份有限公司 | 一种马来酸酐接枝的聚丙烯树脂接枝物的制备方法 |
| CN101717474B (zh) * | 2009-11-20 | 2012-02-15 | 广州市合诚化学有限公司 | 一种用于制备聚丙烯类热熔胶的胶粘剂母料及其制备方法 |
| WO2016026121A1 (en) * | 2014-08-21 | 2016-02-25 | Dow Global Technologies Llc | Adhesive compositions comprising low molecular weight functionalized olefin-based polymers |
| US10472487B2 (en) | 2015-12-30 | 2019-11-12 | Greenmantra Recycling Technologies Ltd. | Reactor for continuously treating polymeric material |
| BR112018016499B1 (pt) | 2016-02-13 | 2022-03-29 | Greenmantra Recycling Technologies Ltd | Método para formar uma cera e empregar a referida cera para modificar asfalto |
| WO2017161463A1 (en) | 2016-03-24 | 2017-09-28 | Greenmantra Recycling Technologies Ltd. | Wax as a melt flow modifier and processing aid for polymers |
| CN114479173A (zh) | 2016-09-29 | 2022-05-13 | 绿色颂歌再生科技有限公司 | 用于处理聚苯乙烯材料的反应器 |
| CN112204100A (zh) | 2018-05-31 | 2021-01-08 | 绿色颂歌再生科技有限公司 | 通过解聚的聚苯乙烯衍生的苯乙烯类聚合物的用途 |
| JP7766586B2 (ja) * | 2019-09-09 | 2025-11-10 | スリーエム イノベイティブ プロパティズ カンパニー | 共押出ポリマー接着剤物品 |
| CN115244125A (zh) * | 2019-12-11 | 2022-10-25 | 绿色颂歌再生科技有限公司 | 通过解聚聚丙烯的马来化衍生的聚合物组合物 |
| CN114213590B (zh) * | 2021-12-15 | 2024-03-19 | 江苏中利集团股份有限公司 | 一种硅烷交联聚乙烯的质量评估方法和系统 |
| CN114316147A (zh) * | 2021-12-15 | 2022-04-12 | 江苏中利集团股份有限公司 | 一种硅烷交联聚乙烯的方法及产品 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3480580A (en) | 1965-10-22 | 1969-11-25 | Eastman Kodak Co | Modified polymers |
| US3642722A (en) * | 1967-11-29 | 1972-02-15 | Eastman Kodak Co | Process for preparing modified polyolefins |
| US4506056A (en) * | 1982-06-07 | 1985-03-19 | Gaylord Research Institute Inc. | Maleic anhydride-modified polymers and process for preparation thereof |
| JPH07316239A (ja) * | 1994-03-31 | 1995-12-05 | Kawasaki Steel Corp | 変性ポリオレフィンの製造方法およびガラス繊維強化ポリオレフィン |
| KR970705587A (ko) | 1994-08-25 | 1997-10-09 | 그윈넬 해리 제이 | 고산가 고분자량 저색도 말레화 폴리프로필렌(maleated high acid number high molecular weight polypropylene of low color) |
| US5667575A (en) | 1995-09-21 | 1997-09-16 | Eastman Chemical Company | Process for reducing the color of an emulsion containing functionalized polyolefin wax |
| CN1230554A (zh) * | 1999-04-02 | 1999-10-06 | 清华大学 | 一种用马来酸酐接枝制备高极性改性聚丙烯材料的方法 |
| US20060046279A1 (en) * | 2004-08-24 | 2006-03-02 | Truong Palestrina R | Analytical methods utilizing real-time energy/particle interaction-based determination techniques |
-
2002
- 2002-05-06 CA CA002446406A patent/CA2446406A1/en not_active Abandoned
- 2002-05-06 CN CNB028135466A patent/CN100491427C/zh not_active Expired - Lifetime
- 2002-05-06 EP EP02736665A patent/EP1434809A4/en not_active Withdrawn
- 2002-05-06 KR KR1020087032048A patent/KR20090006238A/ko not_active Ceased
- 2002-05-06 WO PCT/US2002/014320 patent/WO2002090403A1/en not_active Ceased
- 2002-05-06 JP JP2002587479A patent/JP2005509688A/ja active Pending
- 2002-05-06 AU AU2002309651A patent/AU2002309651B2/en not_active Expired
- 2002-05-06 KR KR1020107011678A patent/KR101040689B1/ko not_active Expired - Lifetime
- 2002-05-06 KR KR10-2003-7014465A patent/KR20030096358A/ko not_active Ceased
-
2009
- 2009-06-17 JP JP2009144373A patent/JP5718555B2/ja not_active Expired - Lifetime
-
2014
- 2014-09-26 JP JP2014196793A patent/JP5837166B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1434809A1 (en) | 2004-07-07 |
| JP2009280821A (ja) | 2009-12-03 |
| KR20030096358A (ko) | 2003-12-24 |
| KR20100070383A (ko) | 2010-06-25 |
| EP1434809A4 (en) | 2005-04-27 |
| CN100491427C (zh) | 2009-05-27 |
| JP2015028180A (ja) | 2015-02-12 |
| WO2002090403A1 (en) | 2002-11-14 |
| JP5718555B2 (ja) | 2015-05-13 |
| JP2005509688A (ja) | 2005-04-14 |
| AU2002309651B2 (en) | 2006-04-06 |
| KR101040689B1 (ko) | 2011-06-10 |
| CN1524096A (zh) | 2004-08-25 |
| KR20090006238A (ko) | 2009-01-14 |
| WO2002090403A8 (en) | 2003-09-04 |
| JP5837166B2 (ja) | 2015-12-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5718555B2 (ja) | マレエート化ポリプロピレンおよびその調製方法 | |
| AU2002309651A1 (en) | Maleated polypropylenes and processes for the preparation thereof | |
| US20070287805A1 (en) | Maleated polypropylenes and processes for the preparation thereof | |
| US5194509A (en) | Peroxide-free grafting of homopolymers and copolymers of ethylene having densities equal to or greater than 0.930 g/cm3, and use of the graft copolymers for the preparation of ionomers of adhesion promoters | |
| US5137975A (en) | Method for manufacture of modified polypropylene compositions | |
| US9074062B2 (en) | Process for preparing high melt strength propylene polymers | |
| US6569950B2 (en) | Process for producing acid modified polypropylene resin | |
| EP0210307A1 (en) | Process for the grafting of monomers onto polyolefins | |
| CA2495593A1 (en) | Grafted propylene copolymers | |
| EP1155052B1 (en) | Functionalized polypropylenes and process for production | |
| JP4708340B2 (ja) | ポリオレフィンの制御されたラジカルグラフト方法 | |
| KR20000048239A (ko) | 에틸렌 공중합체 및 삼원중합체의 분자량 감소방법 | |
| US5344886A (en) | Process for making graft propylene polymers | |
| US4939209A (en) | Unsaturated copolymer resin composite | |
| WO2002093157A2 (de) | Verfahren zur herstellung von durch maleinsäureanhydrid modifizierten polypropylenen | |
| US5189120A (en) | Peroxide-free grafting of homopolymers and copolymers of ethylene having densities less than 0.930 g/cm3, and use of the graft copolymers for the preparation of ionomers or adhesion promoters | |
| EP0261786A1 (en) | Modification of crystalline propylene polymers | |
| WO1996041824A1 (en) | Graft copolymers and their production | |
| WO2003078487A1 (en) | Process for the functionalization of polyolefins | |
| WO1991002760A1 (en) | Substantially non-crosslinked ethylene-methylacrylate copolymers grafted with a grafting agent and processes for their preparation | |
| MXPA01008831A (es) | Polipropilenos funcionalizados y proceso para produccion |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Dead |