CA2394542C - Oligomerisation selective d'olefine - Google Patents

Oligomerisation selective d'olefine Download PDF

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Publication number
CA2394542C
CA2394542C CA002394542A CA2394542A CA2394542C CA 2394542 C CA2394542 C CA 2394542C CA 002394542 A CA002394542 A CA 002394542A CA 2394542 A CA2394542 A CA 2394542A CA 2394542 C CA2394542 C CA 2394542C
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CA
Canada
Prior art keywords
isobutylene
zone
selectivity
tertiary butanol
oligomerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002394542A
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English (en)
Other versions
CA2394542A1 (fr
Inventor
Thomas I. Evans
Lawrence J. Karas
Ramesh Rameswaran
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lyondell Chemical Technology LP
Original Assignee
Arco Chemical Technology LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arco Chemical Technology LP filed Critical Arco Chemical Technology LP
Publication of CA2394542A1 publication Critical patent/CA2394542A1/fr
Application granted granted Critical
Publication of CA2394542C publication Critical patent/CA2394542C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/28—Catalytic processes with hydrides or organic compounds with ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • C07C2531/08—Ion-exchange resins
    • C07C2531/10—Ion-exchange resins sulfonated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un procédé destiné à la production d'une fraction de carburant riche en isooctane, dans un réacteur (5), par dimérisation d'isobutylène en utilisant de l'alcool tertiobutylique comme agent de transformation et un alcane inférieur comme agent de dilution. De manière avantageuse, l'isobutylène provient de la déshydratation de l'alcool tertiobutylique, réalisée dans une zone de déshydratation (2).
CA002394542A 2000-01-14 2001-01-08 Oligomerisation selective d'olefine Expired - Fee Related CA2394542C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/483,531 US6376731B1 (en) 2000-01-14 2000-01-14 Selective olefin oligomerization
US09/483,531 2000-01-14
PCT/US2001/000538 WO2001051435A1 (fr) 2000-01-14 2001-01-08 Oligomerisation selective d'olefine

Publications (2)

Publication Number Publication Date
CA2394542A1 CA2394542A1 (fr) 2001-07-19
CA2394542C true CA2394542C (fr) 2008-09-23

Family

ID=23920432

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002394542A Expired - Fee Related CA2394542C (fr) 2000-01-14 2001-01-08 Oligomerisation selective d'olefine

Country Status (11)

Country Link
US (1) US6376731B1 (fr)
EP (1) EP1254094A4 (fr)
JP (1) JP2003519671A (fr)
KR (1) KR20020073154A (fr)
CN (1) CN1227191C (fr)
AU (1) AU2001226353A1 (fr)
BR (1) BR0107611A (fr)
CA (1) CA2394542C (fr)
MX (1) MXPA02005762A (fr)
TW (1) TW555732B (fr)
WO (1) WO2001051435A1 (fr)

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CN100340532C (zh) * 2005-01-26 2007-10-03 中国石油化工股份有限公司 异丁烯选择性二聚制异辛烯的方法
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US8193402B2 (en) * 2007-12-03 2012-06-05 Gevo, Inc. Renewable compositions
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US8067655B2 (en) * 2008-05-29 2011-11-29 Lyondell Chemical Technology, L.P. Diisobutylene process
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8415517B2 (en) 2008-07-18 2013-04-09 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US8853483B2 (en) * 2008-12-02 2014-10-07 Catalytic Distillation Technologies Oligomerization process
US20100145122A1 (en) * 2008-12-04 2010-06-10 Zak Thomas S Diisobutylene process
US8492603B2 (en) * 2009-01-12 2013-07-23 Catalytic Distillation Technologies Selectivated isoolefin dimerization using metalized resins
BRPI1008287A2 (pt) * 2009-02-24 2016-03-15 Gevo Inc métodos de preparação de butadieno e isopreno renováveis
US8502006B2 (en) * 2009-09-11 2013-08-06 Catalytic Distillation Technologies Dimerization process
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Also Published As

Publication number Publication date
MXPA02005762A (es) 2003-01-28
CN1227191C (zh) 2005-11-16
US6376731B1 (en) 2002-04-23
TW555732B (en) 2003-10-01
CA2394542A1 (fr) 2001-07-19
EP1254094A1 (fr) 2002-11-06
JP2003519671A (ja) 2003-06-24
WO2001051435A1 (fr) 2001-07-19
AU2001226353A1 (en) 2001-07-24
EP1254094A4 (fr) 2009-04-29
CN1394194A (zh) 2003-01-29
KR20020073154A (ko) 2002-09-19
WO2001051435A8 (fr) 2002-08-08
BR0107611A (pt) 2002-11-19

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Effective date: 20140108

MKLA Lapsed

Effective date: 20140108