CA2356984A1 - Nickel mixed hydroxide, method for producing the same, and the use thereof as a cathode material in alkaline batteries - Google Patents
Nickel mixed hydroxide, method for producing the same, and the use thereof as a cathode material in alkaline batteries Download PDFInfo
- Publication number
- CA2356984A1 CA2356984A1 CA002356984A CA2356984A CA2356984A1 CA 2356984 A1 CA2356984 A1 CA 2356984A1 CA 002356984 A CA002356984 A CA 002356984A CA 2356984 A CA2356984 A CA 2356984A CA 2356984 A1 CA2356984 A1 CA 2356984A1
- Authority
- CA
- Canada
- Prior art keywords
- group
- mixed hydroxide
- hydroxide
- nickel
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title abstract 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 title abstract 6
- 229910052759 nickel Inorganic materials 0.000 title abstract 4
- 239000010406 cathode material Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 230000003647 oxidation Effects 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- 150000004679 hydroxides Chemical class 0.000 abstract 2
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 2
- 150000002910 rare earth metals Chemical class 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 abstract 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 238000000975 co-precipitation Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 230000036571 hydration Effects 0.000 abstract 1
- 238000006703 hydration reaction Methods 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 229910001453 nickel ion Inorganic materials 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
- C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/04—Oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/32—Nickel oxide or hydroxide electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/30—Nickel accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention describes a nickel mixed hydroxide with Ni as the main element and with a layer structure, comprising at least one element M a from the group comprising Fe, Cr, Co, Ti, Zr and Cu which is present in two different oxidation states which differ by one electron in terms of the number of outer electrons;
at least one element M b from the group comprising B, Al, Ga, In and RE (rare earth metals) present in the trivalent oxidation state; optionally at least one element M c from the group comprising Mg, Ca, Sr, Ba and Zn present in the divalent oxidation state;
apart from the hydroxide, at least one additional anion from the group comprising halides, carbonate, sulfate, oxalate, acetate, borate and phosphate in a quantity sufficient to preserve the electroneutrality of the mixed hydroxide; and water of hydration in a quantity which stabilises the relevant structure of the mixed hydroxide.
The preparation of the nickel mixed hydroxide according to the invention is carried out by co-precipitation of the hydroxides in an alkaline medium. The nickel mixed hydroxides according to the invention are characterised by very high electrochemical utilisation of the nickel ions and high mass-related capacity values with very good cycle stability and are therefore advantageously suitable as cathode material in alkaline batteries.
at least one element M b from the group comprising B, Al, Ga, In and RE (rare earth metals) present in the trivalent oxidation state; optionally at least one element M c from the group comprising Mg, Ca, Sr, Ba and Zn present in the divalent oxidation state;
apart from the hydroxide, at least one additional anion from the group comprising halides, carbonate, sulfate, oxalate, acetate, borate and phosphate in a quantity sufficient to preserve the electroneutrality of the mixed hydroxide; and water of hydration in a quantity which stabilises the relevant structure of the mixed hydroxide.
The preparation of the nickel mixed hydroxide according to the invention is carried out by co-precipitation of the hydroxides in an alkaline medium. The nickel mixed hydroxides according to the invention are characterised by very high electrochemical utilisation of the nickel ions and high mass-related capacity values with very good cycle stability and are therefore advantageously suitable as cathode material in alkaline batteries.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19860143.3 | 1998-12-24 | ||
| DE19860143 | 1998-12-24 | ||
| DE19939025A DE19939025A1 (en) | 1998-12-24 | 1999-08-18 | Nickel mixed hydroxide, process for its production and its use as cathode material in alkaline batteries |
| DE19939025.8 | 1999-08-18 | ||
| PCT/EP1999/009912 WO2000039865A1 (en) | 1998-12-24 | 1999-12-14 | Nickel mixed hydroxide, method for the producing the same, and the use thereof as a cathode material in alkaline batteries |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2356984A1 true CA2356984A1 (en) | 2000-07-06 |
| CA2356984C CA2356984C (en) | 2009-05-05 |
Family
ID=26051046
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002356984A Expired - Fee Related CA2356984C (en) | 1998-12-24 | 1999-12-14 | Nickel mixed hydroxide, method for producing the same, and the use thereof as a cathode material in alkaline batteries |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6849208B1 (en) |
| EP (1) | EP1145346B1 (en) |
| JP (1) | JP4590104B2 (en) |
| KR (1) | KR100665140B1 (en) |
| CN (1) | CN1192446C (en) |
| AU (1) | AU1979000A (en) |
| BR (1) | BR9916824A (en) |
| CA (1) | CA2356984C (en) |
| CZ (1) | CZ302880B6 (en) |
| DE (2) | DE19939025A1 (en) |
| TW (1) | TW482742B (en) |
| WO (1) | WO2000039865A1 (en) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2198845C2 (en) * | 2001-02-23 | 2003-02-20 | Открытое акционерное общество "Чепецкий механический завод" | Nickelous hydroxide |
| CN100336265C (en) * | 2005-06-17 | 2007-09-05 | 宜兴新兴锆业有限公司 | High temperature nickel-hydrogen battery |
| WO2007000075A1 (en) * | 2005-06-27 | 2007-01-04 | Shenzhen Bak Battery Co., Ltd | Method for preparing spherical nickelous hydroxide which is dopped and multiple metal oxides, and lithium ion secondary battery |
| CN101267047B (en) * | 2007-03-16 | 2010-10-06 | 深圳市力可兴电池有限公司 | Nickel-hydrogen rechargeable battery |
| DE102007039471A1 (en) * | 2007-08-21 | 2009-02-26 | H.C. Starck Gmbh | Powdered compounds, process for their preparation and their use in lithium secondary batteries |
| JP2009076430A (en) * | 2007-08-28 | 2009-04-09 | Sanyo Electric Co Ltd | Negative electrode for alkaline storage battery, and alkaline storage battery |
| DE102007049108A1 (en) * | 2007-10-12 | 2009-04-16 | H.C. Starck Gmbh | Powdered compounds, process for their preparation and their use in batteries |
| WO2010120560A1 (en) * | 2009-03-31 | 2010-10-21 | Battelle Memorial Institute | Supercapacitor materials and devices |
| KR101296789B1 (en) * | 2011-06-22 | 2013-08-14 | 한국전기연구원 | Zinc based negative Active Material, Manufacturing Method thereof And Lithium Secondary Battery Comprising The Same |
| CN102931396A (en) * | 2012-11-05 | 2013-02-13 | 湖南丰日电源电气股份有限公司 | Anode material for high-performance alkaline batteries and method for preparing anode material |
| CN103137962B (en) * | 2013-03-11 | 2014-11-26 | 广东邦普循环科技有限公司 | Method for preparing nickel-cobalt-manganese hydroxide |
| CN106207106B (en) * | 2016-07-12 | 2018-10-19 | 广东工业大学 | A kind of preparation method and applications of α nickel hydroxides |
| CN107512811B (en) * | 2017-07-31 | 2020-06-23 | 四川思达能环保科技有限公司 | Method for treating wastewater in production process of spherical nickel hydroxide |
| JP7109723B2 (en) * | 2019-06-28 | 2022-08-01 | トヨタ自動車株式会社 | Nickel hydroxide, positive electrode material, alkaline battery, and method of making nickel hydroxide |
| JP6916333B1 (en) * | 2020-03-17 | 2021-08-11 | 日本碍子株式会社 | Electrolyte material and electrochemical cell |
| JP6916332B1 (en) * | 2020-03-17 | 2021-08-11 | 日本碍子株式会社 | Electrochemical cell |
| JP6916334B1 (en) * | 2020-03-17 | 2021-08-11 | 日本碍子株式会社 | Electrochemical cell |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2645142B1 (en) * | 1989-03-29 | 1991-07-12 | Centre Nat Etd Spatiales | PROCESS FOR THE PREPARATION OF A NICKEL HYDROXIDE SUBSTITUTED FOR STRUCTURED COBALT (ALPHA), STABLE IN AN ALKALINE MEDIUM AND ITS USE IN AN ELECTROCHEMICAL GENERATOR |
| US5518704A (en) * | 1993-07-06 | 1996-05-21 | Aristech Chemical Corporation | Nickel and cobalt containing hydrotalcite-like materials having a sheet-like morphology and process for production thereof |
| JP3397890B2 (en) * | 1994-05-20 | 2003-04-21 | 三洋電機株式会社 | Non-sintered nickel electrode for alkaline storage batteries |
| JP3443209B2 (en) * | 1994-08-04 | 2003-09-02 | 三洋電機株式会社 | Active material powder for non-sintered nickel electrode of alkaline storage battery and method for producing the same, and non-sintered nickel electrode for alkaline storage battery and method for producing the same |
| DE69505911T2 (en) * | 1994-08-04 | 1999-04-08 | Sanyo Electric Co., Ltd., Moriguchi, Osaka | Active mass powder for non-sintered nickel electrode, non-sintered nickel electrode for alkaline battery and process for their production |
| JP2802482B2 (en) * | 1994-10-28 | 1998-09-24 | 古河電池株式会社 | Nickel electrode for alkaline secondary batteries |
| DE4439989C2 (en) | 1994-11-09 | 1997-06-19 | Starck H C Gmbh Co Kg | Manganese-containing nickel (II) hydroxide powder, process for their preparation and their use |
| JPH09237630A (en) | 1996-02-29 | 1997-09-09 | Matsushita Electric Ind Co Ltd | Active material for alkaline storage battery and positive electrode |
| JP3579545B2 (en) * | 1996-09-20 | 2004-10-20 | 株式会社田中化学研究所 | Nickel hydroxide for alkaline storage batteries and method for producing the same |
| FR2760567B1 (en) * | 1997-03-06 | 1999-04-16 | Alsthom Cge Alcatel | POSITIVE ACTIVE MATERIAL FOR NICKEL ELECTRODE OF ALKALINE ELECTROLYTE BATTERY |
| JPH10316431A (en) | 1997-05-14 | 1998-12-02 | Fuji Chem Ind Co Ltd | Lithium nickel composite oxide, method for producing the same, and positive electrode active material for lithium secondary battery |
-
1999
- 1999-08-18 DE DE19939025A patent/DE19939025A1/en not_active Withdrawn
- 1999-12-14 JP JP2000591676A patent/JP4590104B2/en not_active Expired - Fee Related
- 1999-12-14 CN CNB998149780A patent/CN1192446C/en not_active Expired - Fee Related
- 1999-12-14 EP EP99963528A patent/EP1145346B1/en not_active Expired - Lifetime
- 1999-12-14 WO PCT/EP1999/009912 patent/WO2000039865A1/en not_active Ceased
- 1999-12-14 DE DE59914227T patent/DE59914227D1/en not_active Expired - Lifetime
- 1999-12-14 BR BR9916824-3A patent/BR9916824A/en not_active Application Discontinuation
- 1999-12-14 US US09/868,995 patent/US6849208B1/en not_active Expired - Fee Related
- 1999-12-14 CZ CZ20012304A patent/CZ302880B6/en not_active IP Right Cessation
- 1999-12-14 KR KR1020017008099A patent/KR100665140B1/en not_active Expired - Fee Related
- 1999-12-14 CA CA002356984A patent/CA2356984C/en not_active Expired - Fee Related
- 1999-12-14 AU AU19790/00A patent/AU1979000A/en not_active Abandoned
- 1999-12-20 TW TW088122374A patent/TW482742B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US6849208B1 (en) | 2005-02-01 |
| TW482742B (en) | 2002-04-11 |
| KR100665140B1 (en) | 2007-01-09 |
| CA2356984C (en) | 2009-05-05 |
| WO2000039865A1 (en) | 2000-07-06 |
| CN1331845A (en) | 2002-01-16 |
| EP1145346A1 (en) | 2001-10-17 |
| DE59914227D1 (en) | 2007-04-12 |
| JP4590104B2 (en) | 2010-12-01 |
| DE19939025A1 (en) | 2000-06-29 |
| EP1145346B1 (en) | 2007-02-28 |
| CN1192446C (en) | 2005-03-09 |
| BR9916824A (en) | 2001-10-16 |
| CZ20012304A3 (en) | 2001-11-14 |
| JP2002533907A (en) | 2002-10-08 |
| AU1979000A (en) | 2000-07-31 |
| KR20010099941A (en) | 2001-11-09 |
| CZ302880B6 (en) | 2012-01-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20151214 |