CA2344339A1 - Procede de desulfuration - Google Patents

Procede de desulfuration Download PDF

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Publication number
CA2344339A1
CA2344339A1 CA002344339A CA2344339A CA2344339A1 CA 2344339 A1 CA2344339 A1 CA 2344339A1 CA 002344339 A CA002344339 A CA 002344339A CA 2344339 A CA2344339 A CA 2344339A CA 2344339 A1 CA2344339 A1 CA 2344339A1
Authority
CA
Canada
Prior art keywords
sulfur
carbonaceous material
radiation
source
active oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002344339A
Other languages
English (en)
Inventor
James K. Jeanblanc
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2344339A1 publication Critical patent/CA2344339A1/fr
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/14—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with ozone-containing gases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G32/00—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00—Treating solid fuels to improve their combustion
    • C10L9/02—Treating solid fuels to improve their combustion by chemical means
    • C10L9/06—Treating solid fuels to improve their combustion by chemical means by oxidation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

Pour désulfurer des matières carbonées contenant du soufre on fait réagir ces matières avec un mélange constitué d'un agent oxydant et d'un solvant oxygéné tel que de l'éther de diéthyle dans des conditions alcalines à une température variant de préférence de la température ambiante à environ 250 ·F (121 ·C) et à une pression préférée située entre environ 1 atmosphère et 2 atmosphères. L'utilisation de rayonnements - tels que les rayons X, infrarouges, visibles, hyperfréquences, ou ultraviolets, alpha, bêta ou gamma ou d'autres rayonnements atomiques émanant d'une matière radioactive, ou les ultrasons - facilite la désulfuration. Les produits issus de la réaction sont une matière carbonée désulfurée dans laquelle la teneur en soufre est (par exemple) inférieure à environ 1 %, et des composés de soufre séparés.
CA002344339A 1998-09-16 1999-09-16 Procede de desulfuration Abandoned CA2344339A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10057698P 1998-09-16 1998-09-16
US60/100,576 1998-09-16
PCT/US1999/021478 WO2000015734A1 (fr) 1998-09-16 1999-09-16 Procede de desulfuration

Publications (1)

Publication Number Publication Date
CA2344339A1 true CA2344339A1 (fr) 2000-03-23

Family

ID=22280457

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002344339A Abandoned CA2344339A1 (fr) 1998-09-16 1999-09-16 Procede de desulfuration

Country Status (8)

Country Link
EP (1) EP1115812A1 (fr)
JP (1) JP2002524651A (fr)
AU (1) AU762639B2 (fr)
BR (1) BR9913755A (fr)
CA (1) CA2344339A1 (fr)
EA (1) EA003072B1 (fr)
ID (1) ID29461A (fr)
WO (1) WO2000015734A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104342202A (zh) * 2013-08-06 2015-02-11 中国石油大学(北京) 一种润滑油基础油原料脱酸装置与方法

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6402939B1 (en) 2000-09-28 2002-06-11 Sulphco, Inc. Oxidative desulfurization of fossil fuels with ultrasound
US6500219B1 (en) * 2001-03-19 2002-12-31 Sulphco, Inc. Continuous process for oxidative desulfurization of fossil fuels with ultrasound and products thereof
US7871512B2 (en) 2001-05-10 2011-01-18 Petrosonics, Llc Treatment of crude oil fractions, fossil fuels, and products thereof
US7081196B2 (en) 2001-05-10 2006-07-25 Mark Cullen Treatment of crude oil fractions, fossil fuels, and products thereof with sonic energy
US6827844B2 (en) 2002-10-23 2004-12-07 Sulphco, Inc. Ultrasound-assisted desulfurization of fossil fuels in the presence of dialkyl ethers
US7393513B2 (en) 2003-06-02 2008-07-01 S&B Engineers And Constructors, Ltd. System and process for treating sulfur
AU2004299837B2 (en) * 2003-12-12 2010-09-23 Jy Capital Investment Llc A pre-burning, dry process methodology and systems for enhancing solid fuel properties
DE102004044687A1 (de) * 2004-09-15 2006-03-30 Baerlocher Gmbh Verfahren zur Herstellung von Metallcarboxylaten
BRPI0518551A2 (pt) * 2004-12-23 2008-11-25 Solvay processos para a fabricaÇço de 1, 2 - dicloroetano, de cloreto de vinila, e de cloreto de polivinila, e, uso de uma soluÇço alcalina
US20060180500A1 (en) * 2005-02-15 2006-08-17 Sulphco, Inc., A Corporation Of The State Of Nevada Upgrading of petroleum by combined ultrasound and microwave treatments
US7744749B2 (en) 2005-09-08 2010-06-29 Saudi Arabian Oil Company Diesel oil desulfurization by oxidation and extraction
US8715489B2 (en) 2005-09-08 2014-05-06 Saudi Arabian Oil Company Process for oxidative conversion of organosulfur compounds in liquid hydrocarbon mixtures
US8585786B2 (en) 2006-03-31 2013-11-19 Coaltek, Inc. Methods and systems for briquetting solid fuel
US8585788B2 (en) 2006-03-31 2013-11-19 Coaltek, Inc. Methods and systems for processing solid fuel
US20110189049A1 (en) 2008-05-09 2011-08-04 Martin Beaulieu Method for treating odors
KR101689797B1 (ko) * 2008-10-28 2016-12-26 질레코 인코포레이티드 재료의 처리방법
BRPI0923020A2 (pt) 2008-12-19 2015-12-15 Xyleco Inc método de redução da recalcitrância em materiais celulósicos ou lignocelulósicos e composição.
PL2419196T3 (pl) 2009-04-14 2018-01-31 Uniboard Canada Inc Sposób zmniejszania zawartości rozpuszczalnych w wodzie lotnych związków organicznych w gazie
US8926825B2 (en) 2010-03-19 2015-01-06 Mark Cullen Process for removing sulfur from hydrocarbon streams using hydrotreatment, fractionation and oxidation
US20120138449A1 (en) * 2012-02-12 2012-06-07 King Abdulaziz City for Science and Technology (KACST) Method of removing sulfur from crude oil and diesel using ionizing radiation
WO2013123308A1 (fr) * 2012-02-15 2013-08-22 Arizona Board Of Regents, A Body Corporate Of The State Of Arizona Acting For And On Behalf Of Arizona State University Matières multifonctionnelles et composites
CN103623774A (zh) * 2012-08-21 2014-03-12 华南理工大学 一种用于燃油脱硫的改性活性炭的制备方法
IL269957B (en) 2017-04-18 2022-08-01 Breakthrough Tech Llc Sulfur production
CN106995736A (zh) * 2017-06-08 2017-08-01 重庆科技学院 煤炭燃前脱硫方法
CN107022394A (zh) * 2017-06-08 2017-08-08 重庆科技学院 一种高硫煤中去除有机硫的方法
CN107177396A (zh) * 2017-06-29 2017-09-19 广东固特超声股份有限公司 聚能超声波脱硫装置
RU2677462C1 (ru) * 2017-12-07 2019-01-17 Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) Способ обессеривания сырой нефти пероксидом водорода с выделением продуктов окисления
CN108998060B (zh) * 2018-08-23 2021-06-08 中石化（洛阳）科技有限公司 一种低硫焦炭生产新工艺
CN109266418A (zh) * 2018-09-30 2019-01-25 青岛大学 一种利用烟气在紫外光照射下浸出煤中砷的方法
RU2708629C1 (ru) * 2019-05-30 2019-12-10 Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" (ТГУ, НИ ТГУ) Способ обессеривания тяжелого нефтепродукта с применением микроволнового излучения

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3964994A (en) * 1969-11-28 1976-06-22 Marathon Oil Company H2 O2 -containing micellar dispersions
US4097244A (en) * 1976-12-13 1978-06-27 Atlantic Richfield Company Process for removing sulfur from coal
US4152120A (en) * 1978-02-06 1979-05-01 General Electric Company Coal desulfurization using alkali metal or alkaline earth compounds and electromagnetic irradiation
US4391608A (en) * 1980-03-31 1983-07-05 Dondelewski Michael A Process for the beneficiation of carbonous materials with the aid of ultrasound

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104342202A (zh) * 2013-08-06 2015-02-11 中国石油大学(北京) 一种润滑油基础油原料脱酸装置与方法
CN104342202B (zh) * 2013-08-06 2016-08-10 中国石油大学(北京) 一种润滑油基础油原料脱酸装置与方法

Also Published As

Publication number Publication date
AU6252799A (en) 2000-04-03
ID29461A (id) 2001-08-30
WO2000015734A9 (fr) 2000-08-17
AU762639B2 (en) 2003-07-03
BR9913755A (pt) 2001-06-05
EA200100360A1 (ru) 2001-10-22
JP2002524651A (ja) 2002-08-06
EA003072B1 (ru) 2002-12-26
WO2000015734A1 (fr) 2000-03-23
EP1115812A1 (fr) 2001-07-18

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Legal Events

Date Code Title Description
EEER Examination request
FZDE Discontinued