CA2318000A1

CA2318000A1 - Composant de detergent contenant des solides finement divises

Composant de detergent contenant des solides finement divises Download PDF

Info

Publication number: CA2318000A1
Authority: CA; Canada
Prior art keywords: weight; detergent component; component composition; detergent; ingredient
Prior art date: 1999-09-10
Legal status : Abandoned

Application number

CA002318000A

Other languages

English (en)

Inventor

Peter Schmiedel

Arnd Kessler

Thomas Gassenmeier

Juergen Haerer

Rolf Bayersdoerfer

Matthias Sunder

Current Assignee

Individual

Original Assignee

Henkel AG and Co KGaA

Priority date

1999-09-10

Filing date

2000-09-11

Publication date

2001-03-10

1999-11-30 Priority claimed from DE19957505A external-priority patent/DE19957505A1/de

2000-09-11 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2001-03-10 Publication of CA2318000A1 publication Critical patent/CA2318000A1/fr

Status Abandoned legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims abstract description 295
239000007787 solid Substances 0.000 title claims abstract description 40
239000000203 mixture Substances 0.000 claims abstract description 200
239000000126 substance Substances 0.000 claims abstract description 95
238000002844 melting Methods 0.000 claims abstract description 78
230000008018 melting Effects 0.000 claims abstract description 76
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 72
229910001868 water Inorganic materials 0.000 claims abstract description 67
239000004094 surface-active agent Substances 0.000 claims abstract description 45
239000002245 particle Substances 0.000 claims abstract description 44
239000013543 active substance Substances 0.000 claims abstract description 35
239000004615 ingredient Substances 0.000 claims description 106
-1 aliphatic hydrocarbon radical Chemical class 0.000 claims description 83
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 65
239000002736 nonionic surfactant Substances 0.000 claims description 56
238000004851 dishwashing Methods 0.000 claims description 48
125000004432 carbon atom Chemical group C* 0.000 claims description 33
239000000463 material Substances 0.000 claims description 33
238000000034 method Methods 0.000 claims description 33
238000004806 packaging method and process Methods 0.000 claims description 32
239000000155 melt Substances 0.000 claims description 29
230000008569 process Effects 0.000 claims description 26
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 25
229910052799 carbon Inorganic materials 0.000 claims description 23
102000004190 Enzymes Human genes 0.000 claims description 19
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239000002585 base Substances 0.000 claims description 18
239000003205 fragrance Substances 0.000 claims description 18
229910052783 alkali metal Inorganic materials 0.000 claims description 17
150000002191 fatty alcohols Chemical class 0.000 claims description 17
239000012188 paraffin wax Substances 0.000 claims description 16
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238000004140 cleaning Methods 0.000 claims description 14
239000007844 bleaching agent Substances 0.000 claims description 13
238000004519 manufacturing process Methods 0.000 claims description 13
239000003945 anionic surfactant Substances 0.000 claims description 12
229920000642 polymer Polymers 0.000 claims description 12
239000012190 activator Substances 0.000 claims description 11
239000000975 dye Substances 0.000 claims description 10
238000005453 pelletization Methods 0.000 claims description 9
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 8
230000005540 biological transmission Effects 0.000 claims description 8
238000001816 cooling Methods 0.000 claims description 8
238000005406 washing Methods 0.000 claims description 8
238000004061 bleaching Methods 0.000 claims description 7
239000002734 clay mineral Substances 0.000 claims description 7
238000005260 corrosion Methods 0.000 claims description 7
230000007797 corrosion Effects 0.000 claims description 7
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 6
238000005507 spraying Methods 0.000 claims description 6
239000003054 catalyst Substances 0.000 claims description 5
239000003112 inhibitor Substances 0.000 claims description 5
150000007524 organic acids Chemical class 0.000 claims description 5
235000005985 organic acids Nutrition 0.000 claims description 5
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238000007493 shaping process Methods 0.000 claims description 5
239000002689 soil Substances 0.000 claims description 5
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239000008139 complexing agent Substances 0.000 claims description 4
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238000007790 scraping Methods 0.000 claims description 4
125000004398 2-methyl-2-butyl group Chemical group CC(C)(CC)* 0.000 claims description 3
239000004215 Carbon black (E152) Substances 0.000 claims description 3
125000000129 anionic group Chemical group 0.000 claims description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
239000003002 pH adjusting agent Substances 0.000 claims description 3
235000011056 potassium acetate Nutrition 0.000 claims description 3
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
239000011707 mineral Substances 0.000 claims description 2
239000000839 emulsion Substances 0.000 abstract description 8
230000007774 longterm Effects 0.000 abstract description 3
239000006185 dispersion Substances 0.000 abstract description 2
239000002253 acid Substances 0.000 description 36
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239000010410 layer Substances 0.000 description 26
239000001913 cellulose Substances 0.000 description 23
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 21
150000001298 alcohols Chemical class 0.000 description 20
239000011734 sodium Substances 0.000 description 20
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CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 18
150000001875 compounds Chemical class 0.000 description 18
150000007513 acids Chemical class 0.000 description 17
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239000000047 product Substances 0.000 description 17
229910052615 phyllosilicate Inorganic materials 0.000 description 16
235000019832 sodium triphosphate Nutrition 0.000 description 16
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 15
239000003921 oil Substances 0.000 description 14
235000019198 oils Nutrition 0.000 description 14
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239000007884 disintegrant Substances 0.000 description 11
150000004665 fatty acids Chemical class 0.000 description 11
235000019271 petrolatum Nutrition 0.000 description 11
229910052700 potassium Inorganic materials 0.000 description 11
238000002360 preparation method Methods 0.000 description 11
150000003254 radicals Chemical class 0.000 description 11
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
239000002535 acidifier Substances 0.000 description 10
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 10
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235000019809 paraffin wax Nutrition 0.000 description 10
229910000029 sodium carbonate Inorganic materials 0.000 description 10
239000010457 zeolite Substances 0.000 description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 9
239000007789 gas Substances 0.000 description 9
239000011591 potassium Substances 0.000 description 9
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 9
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical class OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
108091005804 Peptidases Proteins 0.000 description 8
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
239000004365 Protease Substances 0.000 description 8
229910021536 Zeolite Inorganic materials 0.000 description 8
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
238000009826 distribution Methods 0.000 description 8
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KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 7
230000008901 benefit Effects 0.000 description 7
235000015165 citric acid Nutrition 0.000 description 7
238000000576 coating method Methods 0.000 description 7
229910017052 cobalt Inorganic materials 0.000 description 7
239000010941 cobalt Substances 0.000 description 7
150000002148 esters Chemical class 0.000 description 7
239000011777 magnesium Substances 0.000 description 7
239000000843 powder Substances 0.000 description 7
150000004760 silicates Chemical class 0.000 description 7
239000003760 tallow Substances 0.000 description 7
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 7
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
229910019142 PO4 Inorganic materials 0.000 description 6
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 6
239000011575 calcium Substances 0.000 description 6
150000001768 cations Chemical class 0.000 description 6
239000011248 coating agent Substances 0.000 description 6
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 6
230000000694 effects Effects 0.000 description 6
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239000011572 manganese Substances 0.000 description 6
239000000123 paper Substances 0.000 description 6
230000036961 partial effect Effects 0.000 description 6
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235000011007 phosphoric acid Nutrition 0.000 description 6
150000003013 phosphoric acid derivatives Chemical class 0.000 description 6
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239000000344 soap Substances 0.000 description 6
239000001488 sodium phosphate Substances 0.000 description 6
235000000346 sugar Nutrition 0.000 description 6
229910052723 transition metal Inorganic materials 0.000 description 6
239000001226 triphosphate Substances 0.000 description 6
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244000060011 Cocos nucifera Species 0.000 description 5
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ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 5
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KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 5
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238000009517 secondary packaging Methods 0.000 description 5
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RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 4
ZGZHWIAQICBGKN-UHFFFAOYSA-N 1-nonanoylpyrrolidine-2,5-dione Chemical compound CCCCCCCCC(=O)N1C(=O)CCC1=O ZGZHWIAQICBGKN-UHFFFAOYSA-N 0.000 description 4
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108010065511 Amylases Proteins 0.000 description 4
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235000019418 amylase Nutrition 0.000 description 4
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 4
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239000001177 diphosphate Substances 0.000 description 4
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UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
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239000008103 glucose Substances 0.000 description 4
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HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 4
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GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 3
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