CA2305351A1 - Process for making a high density granular detergent composition containing mid-chain branched surfactants - Google Patents
Process for making a high density granular detergent composition containing mid-chain branched surfactants Download PDFInfo
- Publication number
- CA2305351A1 CA2305351A1 CA002305351A CA2305351A CA2305351A1 CA 2305351 A1 CA2305351 A1 CA 2305351A1 CA 002305351 A CA002305351 A CA 002305351A CA 2305351 A CA2305351 A CA 2305351A CA 2305351 A1 CA2305351 A1 CA 2305351A1
- Authority
- CA
- Canada
- Prior art keywords
- detergent
- alkyl
- integer
- methyl
- sulfate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 151
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 127
- 239000003599 detergent Substances 0.000 title claims abstract description 122
- 238000000034 method Methods 0.000 title claims abstract description 58
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 86
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 84
- 150000008051 alkyl sulfates Chemical class 0.000 claims abstract description 52
- 239000008187 granular material Substances 0.000 claims abstract description 36
- 239000004615 ingredient Substances 0.000 claims abstract description 21
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 238000001694 spray drying Methods 0.000 claims abstract description 15
- 239000002002 slurry Substances 0.000 claims abstract description 14
- 239000007921 spray Substances 0.000 claims abstract description 14
- 238000000227 grinding Methods 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 7
- -1 polyhydroxy moieties Chemical class 0.000 claims description 90
- 239000001257 hydrogen Substances 0.000 claims description 47
- 229910052739 hydrogen Inorganic materials 0.000 claims description 47
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 36
- 239000002245 particle Substances 0.000 claims description 29
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 26
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 23
- 229910052799 carbon Inorganic materials 0.000 claims description 18
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 239000002689 soil Substances 0.000 claims description 9
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims description 8
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- 239000007844 bleaching agent Substances 0.000 claims description 6
- 150000004760 silicates Chemical class 0.000 claims description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 230000002209 hydrophobic effect Effects 0.000 claims description 4
- 229920000223 polyglycerol Polymers 0.000 claims description 4
- 102000004190 Enzymes Human genes 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 3
- 239000012190 activator Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 150000003871 sulfonates Chemical class 0.000 claims description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 2
- 229920000388 Polyphosphate Polymers 0.000 claims description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 2
- 125000005907 alkyl ester group Chemical group 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 150000002314 glycerols Chemical class 0.000 claims description 2
- 150000002462 imidazolines Chemical class 0.000 claims description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 239000001205 polyphosphate Substances 0.000 claims description 2
- 235000011176 polyphosphates Nutrition 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 27
- 238000001035 drying Methods 0.000 abstract description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 35
- 239000011734 sodium Substances 0.000 description 21
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 20
- REIUXOLGHVXAEO-UHFFFAOYSA-N n-pentadecyl alcohol Natural products CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 19
- 229910052708 sodium Inorganic materials 0.000 description 18
- 238000005342 ion exchange Methods 0.000 description 15
- 150000001298 alcohols Chemical class 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- 239000003945 anionic surfactant Substances 0.000 description 11
- 150000001768 cations Chemical class 0.000 description 10
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 10
- 239000002736 nonionic surfactant Substances 0.000 description 10
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 229910052700 potassium Inorganic materials 0.000 description 9
- 239000011591 potassium Substances 0.000 description 9
- 150000003839 salts Chemical group 0.000 description 9
- 125000003545 alkoxy group Chemical group 0.000 description 8
- 238000007046 ethoxylation reaction Methods 0.000 description 8
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 239000003093 cationic surfactant Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 230000019635 sulfation Effects 0.000 description 4
- 238000005670 sulfation reaction Methods 0.000 description 4
- 239000010457 zeolite Substances 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 150000003868 ammonium compounds Chemical class 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910001424 calcium ion Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 125000001165 hydrophobic group Chemical group 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 238000011031 large-scale manufacturing process Methods 0.000 description 3
- 238000004900 laundering Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PWZLQIQVQUDLDA-UHFFFAOYSA-N 10-methylpentadecyl hydrogen sulfate Chemical compound CCCCCC(C)CCCCCCCCCOS(O)(=O)=O PWZLQIQVQUDLDA-UHFFFAOYSA-N 0.000 description 2
- MNHLRNCAHKCHDZ-UHFFFAOYSA-N 3-methyltetradecan-1-ol Chemical compound CCCCCCCCCCCC(C)CCO MNHLRNCAHKCHDZ-UHFFFAOYSA-N 0.000 description 2
- QLPBYYNKEZROCN-UHFFFAOYSA-N 5-methylpentadecan-1-ol Chemical compound CCCCCCCCCCC(C)CCCCO QLPBYYNKEZROCN-UHFFFAOYSA-N 0.000 description 2
- IQOPFGOEBAYAFG-UHFFFAOYSA-N 6-methylpentadecyl hydrogen sulfate Chemical compound CCCCCCCCCC(C)CCCCCOS(O)(=O)=O IQOPFGOEBAYAFG-UHFFFAOYSA-N 0.000 description 2
- AATDUADOOPBKAU-UHFFFAOYSA-N 7-methylpentadecan-1-ol Chemical compound CCCCCCCCC(C)CCCCCCO AATDUADOOPBKAU-UHFFFAOYSA-N 0.000 description 2
- MGIKOYWPIYJKAR-UHFFFAOYSA-N 9-methylpentadecyl hydrogen sulfate Chemical compound CCCCCCC(C)CCCCCCCCOS(O)(=O)=O MGIKOYWPIYJKAR-UHFFFAOYSA-N 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical group 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000003606 oligomerizing effect Effects 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- VWIYQXVJELWBLM-UHFFFAOYSA-N 10-methylhexadecan-1-ol Chemical compound CCCCCCC(C)CCCCCCCCCO VWIYQXVJELWBLM-UHFFFAOYSA-N 0.000 description 1
- OLLCWJVCKKEGHY-UHFFFAOYSA-N 10-methylhexadecyl hydrogen sulfate Chemical compound CCCCCCC(C)CCCCCCCCCOS(O)(=O)=O OLLCWJVCKKEGHY-UHFFFAOYSA-N 0.000 description 1
- CRXZDFBSTYFRIG-UHFFFAOYSA-N 10-methylpentadecan-1-ol Chemical compound CCCCCC(C)CCCCCCCCCO CRXZDFBSTYFRIG-UHFFFAOYSA-N 0.000 description 1
- ZKWSPLIEWHHOBJ-UHFFFAOYSA-N 11-methylhexadecyl hydrogen sulfate Chemical compound CCCCCC(C)CCCCCCCCCCOS(O)(=O)=O ZKWSPLIEWHHOBJ-UHFFFAOYSA-N 0.000 description 1
- SXTIDWMSKSTTSS-UHFFFAOYSA-N 11-methylpentadecyl hydrogen sulfate Chemical compound CCCCC(C)CCCCCCCCCCOS(O)(=O)=O SXTIDWMSKSTTSS-UHFFFAOYSA-N 0.000 description 1
- RULGCHAXCANRBL-UHFFFAOYSA-N 12-methylhexadecan-1-ol Chemical compound CCCCC(C)CCCCCCCCCCCO RULGCHAXCANRBL-UHFFFAOYSA-N 0.000 description 1
- BCKAXDNYKPVPLB-UHFFFAOYSA-N 12-methylhexadecyl hydrogen sulfate Chemical compound CCCCC(C)CCCCCCCCCCCOS(O)(=O)=O BCKAXDNYKPVPLB-UHFFFAOYSA-N 0.000 description 1
- CIUGEUVAWSWBTB-UHFFFAOYSA-N 12-methylpentadecan-1-ol Chemical compound CCCC(C)CCCCCCCCCCCO CIUGEUVAWSWBTB-UHFFFAOYSA-N 0.000 description 1
- MNQMLYGCBSDWDH-UHFFFAOYSA-N 12-methylpentadecyl hydrogen sulfate Chemical compound CCCC(C)CCCCCCCCCCCOS(O)(=O)=O MNQMLYGCBSDWDH-UHFFFAOYSA-N 0.000 description 1
- OQVQCQIUBIEKFG-UHFFFAOYSA-N 13-methylhexadecan-1-ol Chemical compound CCCC(C)CCCCCCCCCCCCO OQVQCQIUBIEKFG-UHFFFAOYSA-N 0.000 description 1
- SWHQQXZXGYMQDI-UHFFFAOYSA-N 13-methylhexadecyl hydrogen sulfate Chemical compound CCCC(C)CCCCCCCCCCCCOS(O)(=O)=O SWHQQXZXGYMQDI-UHFFFAOYSA-N 0.000 description 1
- JWIWHDBXJLJNPH-UHFFFAOYSA-N 13-methylpentadecan-1-ol Chemical compound CCC(C)CCCCCCCCCCCCO JWIWHDBXJLJNPH-UHFFFAOYSA-N 0.000 description 1
- WZZLKARCGWTTIC-UHFFFAOYSA-N 13-methylpentadecyl hydrogen sulfate Chemical compound CCC(C)CCCCCCCCCCCCOS(O)(=O)=O WZZLKARCGWTTIC-UHFFFAOYSA-N 0.000 description 1
- WQBUQCSTGAHNSM-UHFFFAOYSA-N 14-methylhexadecan-1-ol Chemical compound CCC(C)CCCCCCCCCCCCCO WQBUQCSTGAHNSM-UHFFFAOYSA-N 0.000 description 1
- YLDJNUHNXZFZRF-UHFFFAOYSA-N 14-methylhexadecyl hydrogen sulfate Chemical compound CCC(C)CCCCCCCCCCCCCOS(O)(=O)=O YLDJNUHNXZFZRF-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- COTCQLIJYALEFP-UHFFFAOYSA-N 3-methylhexadecan-1-ol Chemical compound CCCCCCCCCCCCCC(C)CCO COTCQLIJYALEFP-UHFFFAOYSA-N 0.000 description 1
- ZMYJZDVCXUYYBV-UHFFFAOYSA-N 3-methylhexadecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCCC(C)CCOS(O)(=O)=O ZMYJZDVCXUYYBV-UHFFFAOYSA-N 0.000 description 1
- HZHCYXMBQIANDP-UHFFFAOYSA-N 3-methylpentadecan-1-ol Chemical compound CCCCCCCCCCCCC(C)CCO HZHCYXMBQIANDP-UHFFFAOYSA-N 0.000 description 1
- RVWSNQKFRMYPEF-UHFFFAOYSA-N 3-methylpentadecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCC(C)CCOS(O)(=O)=O RVWSNQKFRMYPEF-UHFFFAOYSA-N 0.000 description 1
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
- IEODIEWNJHUXPT-UHFFFAOYSA-N 4-methylhexadecan-1-ol Chemical compound CCCCCCCCCCCCC(C)CCCO IEODIEWNJHUXPT-UHFFFAOYSA-N 0.000 description 1
- SAXDBYIBHQTHFE-UHFFFAOYSA-N 4-methylhexadecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCC(C)CCCOS(O)(=O)=O SAXDBYIBHQTHFE-UHFFFAOYSA-N 0.000 description 1
- USCAIUBWMLHYMF-UHFFFAOYSA-N 4-methylpentadecan-1-ol Chemical compound CCCCCCCCCCCC(C)CCCO USCAIUBWMLHYMF-UHFFFAOYSA-N 0.000 description 1
- ZCWPDOIGRZOKCN-UHFFFAOYSA-N 4-methylpentadecyl hydrogen sulfate Chemical compound CCCCCCCCCCCC(C)CCCOS(O)(=O)=O ZCWPDOIGRZOKCN-UHFFFAOYSA-N 0.000 description 1
- VNEUMNOZRFLRPI-UHFFFAOYSA-M 4-nonanoyloxybenzenesulfonate Chemical compound CCCCCCCCC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 VNEUMNOZRFLRPI-UHFFFAOYSA-M 0.000 description 1
- HPHARAQGNCZJNL-UHFFFAOYSA-N 5-methylhexadecyl hydrogen sulfate Chemical compound CCCCCCCCCCCC(C)CCCCOS(O)(=O)=O HPHARAQGNCZJNL-UHFFFAOYSA-N 0.000 description 1
- FUAHKIOYTHTCFA-UHFFFAOYSA-N 5-methylpentadecyl hydrogen sulfate Chemical compound CCCCCCCCCCC(C)CCCCOS(O)(=O)=O FUAHKIOYTHTCFA-UHFFFAOYSA-N 0.000 description 1
- CDSRIXGDJPLOTE-UHFFFAOYSA-N 6-methylhexadecan-1-ol Chemical compound CCCCCCCCCCC(C)CCCCCO CDSRIXGDJPLOTE-UHFFFAOYSA-N 0.000 description 1
- QFKXISASHJEKNA-UHFFFAOYSA-N 6-methylhexadecyl hydrogen sulfate Chemical compound CCCCCCCCCCC(C)CCCCCOS(O)(=O)=O QFKXISASHJEKNA-UHFFFAOYSA-N 0.000 description 1
- QITMGEIDLGSWJI-UHFFFAOYSA-N 6-methylpentadecan-1-ol Chemical compound CCCCCCCCCC(C)CCCCCO QITMGEIDLGSWJI-UHFFFAOYSA-N 0.000 description 1
- HPGYNPDQRYCFRW-UHFFFAOYSA-N 7-methylhexadecan-1-ol Chemical compound CCCCCCCCCC(C)CCCCCCO HPGYNPDQRYCFRW-UHFFFAOYSA-N 0.000 description 1
- VGIREMRLGFCUCX-UHFFFAOYSA-N 7-methylhexadecyl hydrogen sulfate Chemical compound CCCCCCCCCC(C)CCCCCCOS(O)(=O)=O VGIREMRLGFCUCX-UHFFFAOYSA-N 0.000 description 1
- YRBQGXUZYACFPW-UHFFFAOYSA-N 7-methylpentadecyl hydrogen sulfate Chemical compound CCCCCCCCC(C)CCCCCCOS(O)(=O)=O YRBQGXUZYACFPW-UHFFFAOYSA-N 0.000 description 1
- TUCDQMRJIWBYSN-UHFFFAOYSA-N 8-methylhexadecan-1-ol Chemical compound CCCCCCCCC(C)CCCCCCCO TUCDQMRJIWBYSN-UHFFFAOYSA-N 0.000 description 1
- HGTZWQRPCGBVPT-UHFFFAOYSA-N 8-methylhexadecyl hydrogen sulfate Chemical compound CCCCCCCCC(C)CCCCCCCOS(O)(=O)=O HGTZWQRPCGBVPT-UHFFFAOYSA-N 0.000 description 1
- OYDBJGVJQMXASR-UHFFFAOYSA-N 8-methylpentadecan-1-ol Chemical compound CCCCCCCC(C)CCCCCCCO OYDBJGVJQMXASR-UHFFFAOYSA-N 0.000 description 1
- MXNAGTAMQHQIBG-UHFFFAOYSA-N 8-methylpentadecyl hydrogen sulfate Chemical compound CCCCCCCC(C)CCCCCCCOS(O)(=O)=O MXNAGTAMQHQIBG-UHFFFAOYSA-N 0.000 description 1
- MXNAGTAMQHQIBG-UHFFFAOYSA-M 8-methylpentadecyl sulfate Chemical compound CCCCCCCC(C)CCCCCCCOS([O-])(=O)=O MXNAGTAMQHQIBG-UHFFFAOYSA-M 0.000 description 1
- JRLTTZUODKEYDH-UHFFFAOYSA-N 8-methylquinoline Chemical group C1=CN=C2C(C)=CC=CC2=C1 JRLTTZUODKEYDH-UHFFFAOYSA-N 0.000 description 1
- ZMYYAKLNVBDHJK-UHFFFAOYSA-N 9-methylhexadecan-1-ol Chemical compound CCCCCCCC(C)CCCCCCCCO ZMYYAKLNVBDHJK-UHFFFAOYSA-N 0.000 description 1
- UWZKMZMCGUSPIY-UHFFFAOYSA-N 9-methylhexadecyl hydrogen sulfate Chemical compound CCCCCCCC(C)CCCCCCCCOS(O)(=O)=O UWZKMZMCGUSPIY-UHFFFAOYSA-N 0.000 description 1
- OJHUUXKGMSEIAL-UHFFFAOYSA-N 9-methylpentadecan-1-ol Chemical compound CCCCCCC(C)CCCCCCCCO OJHUUXKGMSEIAL-UHFFFAOYSA-N 0.000 description 1
- 238000006677 Appel reaction Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000004450 alkenylene group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000005192 alkyl ethylene group Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 125000005313 fatty acid group Chemical group 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- ZNYQHFLBAPNPRC-UHFFFAOYSA-N heptadecan-2-ol Chemical compound CCCCCCCCCCCCCCCC(C)O ZNYQHFLBAPNPRC-UHFFFAOYSA-N 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical group 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Chemical class 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000011182 sodium carbonates Nutrition 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- QXLNOOZGLABQMM-UHFFFAOYSA-M sodium;16-methylheptadecyl sulfate Chemical compound [Na+].CC(C)CCCCCCCCCCCCCCCOS([O-])(=O)=O QXLNOOZGLABQMM-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6187897P | 1997-10-10 | 1997-10-10 | |
| US60/061,878 | 1997-10-10 | ||
| PCT/US1998/021420 WO1999019453A1 (en) | 1997-10-10 | 1998-10-09 | Process for making a high density granular detergent composition containing mid-chain branched surfactants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2305351A1 true CA2305351A1 (en) | 1999-04-22 |
Family
ID=22038721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002305351A Abandoned CA2305351A1 (en) | 1997-10-10 | 1998-10-09 | Process for making a high density granular detergent composition containing mid-chain branched surfactants |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1021521A1 (zh) |
| JP (1) | JP2001520271A (zh) |
| CN (1) | CN1281505A (zh) |
| BR (1) | BR9812756A (zh) |
| CA (1) | CA2305351A1 (zh) |
| WO (1) | WO1999019453A1 (zh) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6677289B1 (en) | 1999-07-16 | 2004-01-13 | The Procter & Gamble Company | Laundry detergent compositions comprising polyamines and mid-chain branched surfactants |
| US6696401B1 (en) | 1999-11-09 | 2004-02-24 | The Procter & Gamble Company | Laundry detergent compositions comprising zwitterionic polyamines |
| EP2338969B1 (en) | 2009-12-18 | 2017-07-26 | The Procter & Gamble Company | A spray-drying process |
| EP2338968A1 (en) * | 2009-12-18 | 2011-06-29 | The Procter & Gamble Company | Spray-drying process |
| ES2642101T3 (es) | 2009-12-18 | 2017-11-15 | The Procter & Gamble Company | Proceso de secado por pulverización |
| ES2390219T3 (es) | 2009-12-18 | 2012-11-07 | The Procter & Gamble Company | Procedimiento de secado por pulverización |
| WO2017079959A1 (en) | 2015-11-13 | 2017-05-18 | The Procter & Gamble Company | Detergent compositions |
| ES2794400T5 (es) * | 2015-11-13 | 2023-07-04 | Procter & Gamble | Composiciones de limpieza que contienen un tensioactivo de tipo alquilsulfonato ramificado y un tensioactivo no iónico de cadena corta |
| EP3666868B1 (en) * | 2015-11-13 | 2023-12-20 | The Procter & Gamble Company | Cleaning compositions containing branched alkyl sulfate surfactants and linear alkyl sulfate surfactants |
| EP3374483A4 (en) * | 2015-11-13 | 2019-06-12 | The Procter and Gamble Company | CLEANING AGENT WITH BRANCHED ALKYLSULFATE TENSID WITH LOW OR NO ALKOXYLATED ALKYLSULFATE |
| JP2020169325A (ja) * | 2020-06-04 | 2020-10-15 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 分岐状アルキルサルフェート界面活性剤及び短鎖非イオン性界面活性剤を含有する洗浄組成物 |
| JP2020169324A (ja) * | 2020-06-04 | 2020-10-15 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 分岐状アルキルサルフェート界面活性剤及び直鎖状アルキルサルフェート界面活性剤を含有する洗浄組成物 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4715979A (en) * | 1985-10-09 | 1987-12-29 | The Procter & Gamble Company | Granular detergent compositions having improved solubility |
| US6015784A (en) * | 1996-03-08 | 2000-01-18 | The Procter & Gamble Company | Secondary alkyl sulfate particles with improved solubility by compaction/coating process |
| ATE225840T1 (de) * | 1996-04-16 | 2002-10-15 | Procter & Gamble | Ausgewählte mitten in der kette verzweigte primäre oberflachenaktive alkylsulfat-substanzen enthaltende tenside |
-
1998
- 1998-10-09 EP EP98952221A patent/EP1021521A1/en not_active Withdrawn
- 1998-10-09 WO PCT/US1998/021420 patent/WO1999019453A1/en not_active Application Discontinuation
- 1998-10-09 BR BR9812756-0A patent/BR9812756A/pt not_active IP Right Cessation
- 1998-10-09 CA CA002305351A patent/CA2305351A1/en not_active Abandoned
- 1998-10-09 JP JP2000516007A patent/JP2001520271A/ja not_active Withdrawn
- 1998-10-09 CN CN 98812004 patent/CN1281505A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN1281505A (zh) | 2001-01-24 |
| JP2001520271A (ja) | 2001-10-30 |
| WO1999019453A1 (en) | 1999-04-22 |
| EP1021521A1 (en) | 2000-07-26 |
| BR9812756A (pt) | 2000-08-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |