CA2293659C - A process for producing liquid and, optionally, gaseous products from gaseous reactants - Google Patents
A process for producing liquid and, optionally, gaseous products from gaseous reactants Download PDFInfo
- Publication number
- CA2293659C CA2293659C CA002293659A CA2293659A CA2293659C CA 2293659 C CA2293659 C CA 2293659C CA 002293659 A CA002293659 A CA 002293659A CA 2293659 A CA2293659 A CA 2293659A CA 2293659 C CA2293659 C CA 2293659C
- Authority
- CA
- Canada
- Prior art keywords
- downcomer
- slurry
- gaseous
- slurry bed
- region
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000376 reactant Substances 0.000 title claims abstract description 48
- 239000007788 liquid Substances 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000002002 slurry Substances 0.000 claims abstract description 132
- 239000007789 gas Substances 0.000 claims abstract description 50
- 239000000047 product Substances 0.000 claims abstract description 42
- 239000002245 particle Substances 0.000 claims abstract description 34
- 239000012263 liquid product Substances 0.000 claims abstract description 18
- 239000000725 suspension Substances 0.000 claims abstract description 18
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 14
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 11
- 239000007787 solid Substances 0.000 claims abstract description 11
- 239000007791 liquid phase Substances 0.000 claims abstract description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 4
- 239000001257 hydrogen Substances 0.000 claims abstract description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000003054 catalyst Substances 0.000 claims description 37
- 239000012071 phase Substances 0.000 claims description 30
- 238000009434 installation Methods 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 239000011949 solid catalyst Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 230000003628 erosive effect Effects 0.000 claims description 4
- 230000015556 catabolic process Effects 0.000 claims description 3
- 238000006731 degradation reaction Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- QVYYOKWPCQYKEY-UHFFFAOYSA-N [Fe].[Co] Chemical compound [Fe].[Co] QVYYOKWPCQYKEY-UHFFFAOYSA-N 0.000 claims 1
- 238000007872 degassing Methods 0.000 description 19
- 238000002474 experimental method Methods 0.000 description 6
- 238000013461 design Methods 0.000 description 5
- 238000004364 calculation method Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 230000005587 bubbling Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000700 radioactive tracer Substances 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
- C07C1/063—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system
- C07C1/066—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system used for dissolving, suspending or transporting the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00026—Controlling or regulating the heat exchange system
- B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
- B01J2208/0007—Pressure measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/00141—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00725—Mathematical modelling
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA97/6254 | 1997-07-15 | ||
| ZA976254 | 1997-07-15 | ||
| PCT/GB1998/002070 WO1999003574A1 (en) | 1997-07-15 | 1998-07-14 | A process for producing liquid and, optionally, gaseous products from gaseous reactants |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2293659A1 CA2293659A1 (en) | 1999-01-28 |
| CA2293659C true CA2293659C (en) | 2006-09-05 |
Family
ID=25586480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002293659A Expired - Lifetime CA2293659C (en) | 1997-07-15 | 1998-07-14 | A process for producing liquid and, optionally, gaseous products from gaseous reactants |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6201031B1 (https=) |
| EP (1) | EP0998346B1 (https=) |
| JP (1) | JP4203129B2 (https=) |
| AR (1) | AR015404A1 (https=) |
| AT (1) | ATE206070T1 (https=) |
| AU (1) | AU730075B2 (https=) |
| CA (1) | CA2293659C (https=) |
| DE (1) | DE69801826T2 (https=) |
| DK (1) | DK0998346T3 (https=) |
| ES (1) | ES2162460T3 (https=) |
| MY (1) | MY115757A (https=) |
| NO (1) | NO319808B1 (https=) |
| PE (1) | PE115199A1 (https=) |
| RU (1) | RU2201800C2 (https=) |
| WO (1) | WO1999003574A1 (https=) |
| ZA (1) | ZA985992B (https=) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2038774C (en) | 1990-04-04 | 2001-09-25 | Eric Herbolzheimer | Slurry bubble column |
| EG22489A (en) * | 1999-02-05 | 2003-02-26 | Sasol Technology | Process for producing liquid and optionally gaseous products from gaseous reactants |
| FR2806736B1 (fr) | 2000-03-27 | 2002-05-10 | Inst Francais Du Petrole | Procede de production d'hydrocarbures a partir de gaz de synthese dans un reacteur triphasique |
| US6762209B1 (en) | 2001-08-31 | 2004-07-13 | University Of Kentucky Research Foundation | Bubble column apparatus for separating wax from catalyst slurry |
| FR2832416B1 (fr) * | 2001-11-20 | 2004-09-03 | Inst Francais Du Petrole | Procede de conversion de gaz de synthese dans des reacteurs en serie |
| US7022741B2 (en) * | 2003-03-28 | 2006-04-04 | Conocophillips Company | Gas agitated multiphase catalytic reactor with reduced backmixing |
| US20040235968A1 (en) * | 2003-03-28 | 2004-11-25 | Conocophillips Company | Process and apparatus for controlling flow in a multiphase reactor |
| EP1636151B1 (en) * | 2003-05-16 | 2008-08-20 | Sasol Technology (Proprietary) Limited | Process for producing liquid and, optionally, gaseous products from gaseous reactants |
| AU2004255038B2 (en) * | 2003-07-15 | 2008-11-13 | Sasol Technology (Proprietary) Limited | Process for separating a catalyst from a liquid |
| WO2005107935A1 (en) * | 2004-05-10 | 2005-11-17 | Sasol Technology (Proprietary) Limited | The production of liquid and, optionally, gaseous hydrocarbons from gaseous reactants into an expanded slurry bed |
| FR2877950B1 (fr) * | 2004-11-17 | 2006-12-29 | Inst Francais Du Petrole | Dispositif de production d'hydrocarbures liquides par synthese fischer-tropsch dans un reacteur a lit triphasique |
| BRPI0608541B1 (pt) * | 2005-03-17 | 2015-07-28 | Sasol Techology Proprietary | Métodos para operar um reator de leito fluidizado bifásico e para operar um reator de lama trifásico, e, reatores de leito fluidizado bifásico e de lama trifásico |
| CN101396647B (zh) * | 2007-09-29 | 2011-03-16 | 中科合成油技术有限公司 | 用于费-托合成的气-液-固三相悬浮床反应器及其应用 |
| KR100992835B1 (ko) * | 2008-02-29 | 2010-11-08 | 한국화학연구원 | 피셔-트롭쉬 합성반응용 고체촉매와 생성물의 연속분리배출장치 및 방법 |
| JP2013537250A (ja) | 2010-09-07 | 2013-09-30 | セイソル テクノロジー （プロプライエタリー） リミテッド | ディーゼルエンジンの効率向上 |
| JP5990389B2 (ja) * | 2012-03-26 | 2016-09-14 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 炭化水素油の製造方法、気泡塔型スラリー床反応装置及び炭化水素油の製造システム |
| WO2014075112A2 (en) | 2012-10-30 | 2014-05-15 | Sasol Technology (Pty) Ltd | Diesel fuel composition |
| JP2014136767A (ja) * | 2013-01-17 | 2014-07-28 | Japan Oil Gas & Metals National Corp | 炭化水素合成反応装置 |
| CN103962069B (zh) * | 2013-01-31 | 2017-03-08 | 中国科学院上海高等研究院 | 一种浆态床反应器 |
| CN103962067B (zh) * | 2013-01-31 | 2017-02-08 | 中国科学院上海高等研究院 | 一种用来进行浆态床反应的方法 |
| CN113877488B (zh) * | 2021-11-16 | 2023-07-04 | 中国石油大学(华东) | 一种基于管式微孔介质发泡机理的上流式加氢反应装置 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3124518A (en) * | 1964-03-10 | Product | ||
| JPS565572B1 (https=) * | 1970-12-30 | 1981-02-05 | ||
| SU477734A1 (ru) * | 1973-01-23 | 1975-07-25 | Институт тепло- и массообмена АН БССР | Аппарат с псевдоожиженным слоем |
| JPS6490030A (en) * | 1987-10-01 | 1989-04-05 | Mitsubishi Heavy Ind Ltd | Three-phase fluidized reactor |
| US5382748A (en) * | 1992-12-18 | 1995-01-17 | Exxon Research & Engineering Co. | Hydrocarbon synthesis reactor employing vertical downcomer with gas disengaging means |
| US5962537A (en) * | 1997-05-06 | 1999-10-05 | Exxon Research And Engineering Co | Multizone downcomer for slurry hydrocarbon syntheses process |
-
1998
- 1998-07-07 ZA ZA9805992A patent/ZA985992B/xx unknown
- 1998-07-11 MY MYPI98003185A patent/MY115757A/en unknown
- 1998-07-14 DK DK98933793T patent/DK0998346T3/da active
- 1998-07-14 JP JP50671499A patent/JP4203129B2/ja not_active Expired - Lifetime
- 1998-07-14 EP EP98933793A patent/EP0998346B1/en not_active Expired - Lifetime
- 1998-07-14 CA CA002293659A patent/CA2293659C/en not_active Expired - Lifetime
- 1998-07-14 DE DE69801826T patent/DE69801826T2/de not_active Expired - Fee Related
- 1998-07-14 WO PCT/GB1998/002070 patent/WO1999003574A1/en not_active Ceased
- 1998-07-14 AU AU83491/98A patent/AU730075B2/en not_active Expired
- 1998-07-14 ES ES98933793T patent/ES2162460T3/es not_active Expired - Lifetime
- 1998-07-14 AT AT98933793T patent/ATE206070T1/de not_active IP Right Cessation
- 1998-07-14 RU RU99124178/12A patent/RU2201800C2/ru active
- 1998-07-14 PE PE1998000621A patent/PE115199A1/es not_active Application Discontinuation
- 1998-07-15 AR ARP980103458A patent/AR015404A1/es not_active Application Discontinuation
-
1999
- 1999-12-07 US US09/454,849 patent/US6201031B1/en not_active Expired - Lifetime
-
2000
- 2000-01-14 NO NO20000190A patent/NO319808B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ES2162460T3 (es) | 2001-12-16 |
| EP0998346B1 (en) | 2001-09-26 |
| DE69801826T2 (de) | 2002-03-28 |
| NO319808B1 (no) | 2005-09-19 |
| US6201031B1 (en) | 2001-03-13 |
| AR015404A1 (es) | 2001-05-02 |
| JP4203129B2 (ja) | 2008-12-24 |
| AU730075B2 (en) | 2001-02-22 |
| PE115199A1 (es) | 1999-12-03 |
| JP2002510246A (ja) | 2002-04-02 |
| EP0998346A1 (en) | 2000-05-10 |
| AU8349198A (en) | 1999-02-10 |
| RU2201800C2 (ru) | 2003-04-10 |
| DK0998346T3 (da) | 2002-01-28 |
| NO20000190D0 (no) | 2000-01-14 |
| WO1999003574A1 (en) | 1999-01-28 |
| MY115757A (en) | 2003-08-30 |
| ATE206070T1 (de) | 2001-10-15 |
| ZA985992B (en) | 2000-01-10 |
| NO20000190L (no) | 2000-03-01 |
| DE69801826D1 (de) | 2001-10-31 |
| CA2293659A1 (en) | 1999-01-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20180716 |