CA2288212A1 - Spray nozzle and a process using this nozzle - Google Patents
Spray nozzle and a process using this nozzle Download PDFInfo
- Publication number
- CA2288212A1 CA2288212A1 CA002288212A CA2288212A CA2288212A1 CA 2288212 A1 CA2288212 A1 CA 2288212A1 CA 002288212 A CA002288212 A CA 002288212A CA 2288212 A CA2288212 A CA 2288212A CA 2288212 A1 CA2288212 A1 CA 2288212A1
- Authority
- CA
- Canada
- Prior art keywords
- nozzle
- spray
- fluid
- range
- supply line
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/02—Spray pistols; Apparatus for discharge
- B05B7/06—Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane
- B05B7/061—Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane with several liquid outlets discharging one or several liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/06—Spray cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
- B01D53/185—Liquid distributors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/02—Spray pistols; Apparatus for discharge
- B05B7/10—Spray pistols; Apparatus for discharge producing a swirling discharge
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Nozzles (AREA)
Abstract
Disclosed is a dual feed injector comprising two spray nozzles housed concentrically in a compact nozzle body with inner and outer spray nozzles spraying over a broad flow range and a process of contacting materials with fluid discharged from the dual feed injector.
Description
SPRAY NOZZLE AND A PROCESS USING THIS NOZZLE
BACKGROUND OF THE INVENTION
The present invention relates to a dual feed injector comprising two spray nozzles housed concentrically in a compact nozzle body with an inner spray nozzle supplying a full divergent cone spray and an outer spray nozzle supplying a hollow divergent or convergent cone spray, and, more particularly, to a method of contacting materials with a broad flow range of fluid discharged from the dual feed injector.
Spray nozzles may be classified as pressure nozzles, rotating nozzles and gas-atomizing nozzles. Spray nozzles are used for atomizing a liquid into droplets and are well known in various applications. For example, U.S. Patent 3,717,306 describes a nozzle for mixing and spraying foam resin components and is made up of two concentric spray nozzle members defining a central.path and a cylindrical path concentric to the central path. Communicating passages therein are arranged so that material in the nozzle is given a swirling motion for good mixing and then the mixture is discharged in a single spray cone.
A single spray nozzle can effectively spray over a limited flow range.
For effective use of sprays in confined spaces, there is a need to spray over a broad flow range. The present invention meets this need.
SUMMARY OF THE INVENTION
According to the invention there is provided a dual feed injector comprising:
(a) an outer spray nozzle having an outer fluid supply line communicating with a means for determining an angle of a spray from about 10 degrees to about 90 degrees, said outer nozzle terminating with an annular orifice far supplying a hollow divergent or convergent cone spray;
(b) an inner spray nozzle having an inner fluid supply line communicating with a means for determining an angle of a spray from about 10 degrees to about 90 degrees, said inner nozzle terminating with a central orifice for supplying a full divergent cone spray; and (c) means for atomizing a fluid near a tercTtinal end of the outer and inner nozzles, said inner and outer nozzles being disposed concentric to each other and housed in a compact nozzle body.
~RI,~,~F D~~", .RIPTION OF'1',~F.~RA
Fig. IA and Fig. IC are a side view and top view, respectively, of the dual feed injector of this invention.
Fig. 1B is an end view of the dual feed injector of this invention.
Fig. 2 is a longitudinal cross sectional view of the dual feed injector of 1S this invention.
DETAILED DESCRIPTI01~1 OF THE INVENTION
The dual feed injector of this invention is uniquely capable of providing two streams of atomized fluid within a broad flow range for good contacting between a fluid discharged from the dual feed injector and a fluid in a . vessel, pipe or the like. The dual feed injector is especially applicable for rapidly cooling an effluent gas stream in a confined space from about 800°C.1500°C down to about 200°C-550°C. Rapid cooling from about 900°C-1000°C down to about 450°C-SSa°C is preferred.
Illustrative of such a process is chlorinating ferrotitaniferous materials and separating titanium tetrachloride as described in greater detail in U.S.
Patent 3,261,664 and U.S. Patent 4,066,424, the teachings of which are incorporated herein by reference. Hot chlorination gases produced from the reaction are primarily titanium tetrachloride, ferric chloride and ferrous chloride. These gases are passed to a transfer duct whereby a single spray injection nozzle introduces a liquid coolant, e.g., liquid titanium tetrachloride to perform the essential step of contacting and cooling the hot chlorination gases to about 450°C to about 550°C. The dual feed injector of this invention is an improvement over this single spray injection nozzle.
Referring now to Fig. 1B, the dual feed injector end view shows the 3S tangential entry 30 of the fluid supplying the outer nozzle 10. The tangential entry 30 contributes to the flow and spray pattern of the fluid. It will be appreciated by those skilled in the art chat depending upon the particular application, the entry can be tangential or concentric. Referring now to Fig. 2, the inner spray nozzle terminates with a central orifice 8 which discharges a full divergent cone spray. Full divergent cone spray is defined herein to refer to small particles or droplets forming a substantially whole conical region fanning outward. The outer spray nozzle terminates with an annular orifice 9 which discharges a hollow divergent or convergent cone spray. Hollow divergent or convergent cone spray is defined herein to refer to small particles or droplets forming a ring shape around a perimeter of a circle fanning outward or merging towards the full divergent cone spray. The inner nozzle feed 1 and outer nozzle feed 2 are typically fed from different sources of the same liquid. The feed can be simultaneous or sequential. In an alternative embodiment the inner nozzle feed 1 and outer nozzle feed 2 may be fed from the same source or with different fluids. Further, two liquids may be contacted with a third liquid and slurries or pastes can be extruded through the outer spray nozzle for contact or tre.atmeni with other fluids. The dual feed injector of this invention can be used for many processes or purposes, including but not limited to, atomizing, cooling, heating, chemically reacting, mixing, evaporating, spray drying, contacting or treatitig. Combinations of the foregoing can be used.
Upstream from a mounting flange 5, the fluid then enters a concentric or tangential outer fluid supply line 3 supplied from outer nozzle feed 2 and a concentric or tangential inner fluid supply line 4 supplied from inner nozzle feed 1.
For industrial applications or processes, the fluid flow ranges and pressure ranges can be readily determined for the desired application or process. For example, in cooling an effluent gas stream, the fluid flow range in the inner nozzle can be a high flow range, e.g., about 100 to about 600 gallons per minute at a pressure of about 1 to about 90 psig. The outer nozzle can be a low flow range, e.g., about 20 to about 200 gallons per minute at a pressure of about 1 to about 60 psig. The outer fluid supply line 3 and the inner fluid supply line 4 communicates with a means for determining an angle of the spray 6a, 6b, 7a and 7b. For example, stationary turning vanes 6a and 6b can provide a swirling motion. The swirl of the fluid in turn and, in conjunction with a decreased diameter 7a and 7b near the terminating end of the inner and outer nozzles, determine the angle of the spray. Spray angle may range from about 10 to about 90 degrees but may be selected based on the particular application with 15, 30 and 60 degrees being common. When the confined space is a relatively narrow pipe, the angle of the spray should be minimized if it is desirable to virtually avoid the spray impinging on the pipe wall. The direction of the jet of fluid can be at any angle relative to the direction of flow of the gaseous mixture, e.g., counter current or corurrent. Counter current flow is preferred in cooling an effluent gas since it promotes rapid cooling and complete evaporation of the liquid coolant. Near the terminating end, the inner nozzle diameter 7a and the outer nozzle diameter 7b decrease and the volume available for the fluid l7ow also decreases. The change in the available volume also provides the energy needed to atomize the fluid, or break it up into many small particles or droplets. It has been observed that smaller particles or droplets provide better contacting when cooling an effluent gas. The dual feed injector can be designed for any given droplet size.
In a process for cooling an effluent gas stream, it may be desirable for the mean liquid spray droplet diameter to be in the range of about 0.2 to 20 mm. It will be appreciated by those skilled in the art that depending upon the different industrial application or fluid being fed through the dual feed injector that operating parameters, vane configuration. and dimensions may be readily determined by constructing a model dual feed injector and testing the operating parameters, vane configuration and dimensions for the desired flow range and spray pattern. By ways of example and not limitation, the dimensions suitable for cooling an effluent gas can be an'overall length of about 2b" long. The overall height can be about 15.25", i The upstream inner diameter of the outer nozzle can be about 5.75" and the upstream inner diameter of the inner nozzle can be about 2.9". -The diameter then reduces near the terminal end wherein the reduced diameter 7a of the inner nozzle can be about 1.5". The reduced diameter 7b of the outer nozzle can be about 2.2"
and the width of the annular orifice can be about 0.3".
The dual feed injector can be constructed of any material that is suitable for the fluid being fed through it. Typically, a stainless steel alloy will be appropriate for most applications but a more corrosion resistant material such as Hastelloy~ can be used.
The present invention provides greater efficiency and process flexibility than found in conventional spray nozzles and has wide applications. The dual feed injector combines compactness with the ability to produce an excellent spray pattern over a much larger range of flow rates than a conventional nozzle.
-~ The terms and expressions which have been employed are used as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding any equivalent of the features shown and described or any portion thereof, but it is recognized that various modifications are possible within the scope of the appended claims.
BACKGROUND OF THE INVENTION
The present invention relates to a dual feed injector comprising two spray nozzles housed concentrically in a compact nozzle body with an inner spray nozzle supplying a full divergent cone spray and an outer spray nozzle supplying a hollow divergent or convergent cone spray, and, more particularly, to a method of contacting materials with a broad flow range of fluid discharged from the dual feed injector.
Spray nozzles may be classified as pressure nozzles, rotating nozzles and gas-atomizing nozzles. Spray nozzles are used for atomizing a liquid into droplets and are well known in various applications. For example, U.S. Patent 3,717,306 describes a nozzle for mixing and spraying foam resin components and is made up of two concentric spray nozzle members defining a central.path and a cylindrical path concentric to the central path. Communicating passages therein are arranged so that material in the nozzle is given a swirling motion for good mixing and then the mixture is discharged in a single spray cone.
A single spray nozzle can effectively spray over a limited flow range.
For effective use of sprays in confined spaces, there is a need to spray over a broad flow range. The present invention meets this need.
SUMMARY OF THE INVENTION
According to the invention there is provided a dual feed injector comprising:
(a) an outer spray nozzle having an outer fluid supply line communicating with a means for determining an angle of a spray from about 10 degrees to about 90 degrees, said outer nozzle terminating with an annular orifice far supplying a hollow divergent or convergent cone spray;
(b) an inner spray nozzle having an inner fluid supply line communicating with a means for determining an angle of a spray from about 10 degrees to about 90 degrees, said inner nozzle terminating with a central orifice for supplying a full divergent cone spray; and (c) means for atomizing a fluid near a tercTtinal end of the outer and inner nozzles, said inner and outer nozzles being disposed concentric to each other and housed in a compact nozzle body.
~RI,~,~F D~~", .RIPTION OF'1',~F.~RA
Fig. IA and Fig. IC are a side view and top view, respectively, of the dual feed injector of this invention.
Fig. 1B is an end view of the dual feed injector of this invention.
Fig. 2 is a longitudinal cross sectional view of the dual feed injector of 1S this invention.
DETAILED DESCRIPTI01~1 OF THE INVENTION
The dual feed injector of this invention is uniquely capable of providing two streams of atomized fluid within a broad flow range for good contacting between a fluid discharged from the dual feed injector and a fluid in a . vessel, pipe or the like. The dual feed injector is especially applicable for rapidly cooling an effluent gas stream in a confined space from about 800°C.1500°C down to about 200°C-550°C. Rapid cooling from about 900°C-1000°C down to about 450°C-SSa°C is preferred.
Illustrative of such a process is chlorinating ferrotitaniferous materials and separating titanium tetrachloride as described in greater detail in U.S.
Patent 3,261,664 and U.S. Patent 4,066,424, the teachings of which are incorporated herein by reference. Hot chlorination gases produced from the reaction are primarily titanium tetrachloride, ferric chloride and ferrous chloride. These gases are passed to a transfer duct whereby a single spray injection nozzle introduces a liquid coolant, e.g., liquid titanium tetrachloride to perform the essential step of contacting and cooling the hot chlorination gases to about 450°C to about 550°C. The dual feed injector of this invention is an improvement over this single spray injection nozzle.
Referring now to Fig. 1B, the dual feed injector end view shows the 3S tangential entry 30 of the fluid supplying the outer nozzle 10. The tangential entry 30 contributes to the flow and spray pattern of the fluid. It will be appreciated by those skilled in the art chat depending upon the particular application, the entry can be tangential or concentric. Referring now to Fig. 2, the inner spray nozzle terminates with a central orifice 8 which discharges a full divergent cone spray. Full divergent cone spray is defined herein to refer to small particles or droplets forming a substantially whole conical region fanning outward. The outer spray nozzle terminates with an annular orifice 9 which discharges a hollow divergent or convergent cone spray. Hollow divergent or convergent cone spray is defined herein to refer to small particles or droplets forming a ring shape around a perimeter of a circle fanning outward or merging towards the full divergent cone spray. The inner nozzle feed 1 and outer nozzle feed 2 are typically fed from different sources of the same liquid. The feed can be simultaneous or sequential. In an alternative embodiment the inner nozzle feed 1 and outer nozzle feed 2 may be fed from the same source or with different fluids. Further, two liquids may be contacted with a third liquid and slurries or pastes can be extruded through the outer spray nozzle for contact or tre.atmeni with other fluids. The dual feed injector of this invention can be used for many processes or purposes, including but not limited to, atomizing, cooling, heating, chemically reacting, mixing, evaporating, spray drying, contacting or treatitig. Combinations of the foregoing can be used.
Upstream from a mounting flange 5, the fluid then enters a concentric or tangential outer fluid supply line 3 supplied from outer nozzle feed 2 and a concentric or tangential inner fluid supply line 4 supplied from inner nozzle feed 1.
For industrial applications or processes, the fluid flow ranges and pressure ranges can be readily determined for the desired application or process. For example, in cooling an effluent gas stream, the fluid flow range in the inner nozzle can be a high flow range, e.g., about 100 to about 600 gallons per minute at a pressure of about 1 to about 90 psig. The outer nozzle can be a low flow range, e.g., about 20 to about 200 gallons per minute at a pressure of about 1 to about 60 psig. The outer fluid supply line 3 and the inner fluid supply line 4 communicates with a means for determining an angle of the spray 6a, 6b, 7a and 7b. For example, stationary turning vanes 6a and 6b can provide a swirling motion. The swirl of the fluid in turn and, in conjunction with a decreased diameter 7a and 7b near the terminating end of the inner and outer nozzles, determine the angle of the spray. Spray angle may range from about 10 to about 90 degrees but may be selected based on the particular application with 15, 30 and 60 degrees being common. When the confined space is a relatively narrow pipe, the angle of the spray should be minimized if it is desirable to virtually avoid the spray impinging on the pipe wall. The direction of the jet of fluid can be at any angle relative to the direction of flow of the gaseous mixture, e.g., counter current or corurrent. Counter current flow is preferred in cooling an effluent gas since it promotes rapid cooling and complete evaporation of the liquid coolant. Near the terminating end, the inner nozzle diameter 7a and the outer nozzle diameter 7b decrease and the volume available for the fluid l7ow also decreases. The change in the available volume also provides the energy needed to atomize the fluid, or break it up into many small particles or droplets. It has been observed that smaller particles or droplets provide better contacting when cooling an effluent gas. The dual feed injector can be designed for any given droplet size.
In a process for cooling an effluent gas stream, it may be desirable for the mean liquid spray droplet diameter to be in the range of about 0.2 to 20 mm. It will be appreciated by those skilled in the art that depending upon the different industrial application or fluid being fed through the dual feed injector that operating parameters, vane configuration. and dimensions may be readily determined by constructing a model dual feed injector and testing the operating parameters, vane configuration and dimensions for the desired flow range and spray pattern. By ways of example and not limitation, the dimensions suitable for cooling an effluent gas can be an'overall length of about 2b" long. The overall height can be about 15.25", i The upstream inner diameter of the outer nozzle can be about 5.75" and the upstream inner diameter of the inner nozzle can be about 2.9". -The diameter then reduces near the terminal end wherein the reduced diameter 7a of the inner nozzle can be about 1.5". The reduced diameter 7b of the outer nozzle can be about 2.2"
and the width of the annular orifice can be about 0.3".
The dual feed injector can be constructed of any material that is suitable for the fluid being fed through it. Typically, a stainless steel alloy will be appropriate for most applications but a more corrosion resistant material such as Hastelloy~ can be used.
The present invention provides greater efficiency and process flexibility than found in conventional spray nozzles and has wide applications. The dual feed injector combines compactness with the ability to produce an excellent spray pattern over a much larger range of flow rates than a conventional nozzle.
-~ The terms and expressions which have been employed are used as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding any equivalent of the features shown and described or any portion thereof, but it is recognized that various modifications are possible within the scope of the appended claims.
Claims (4)
1. A process for cooling chlorine gases produced from reacting ferrotitaniferous materials with chlorine, comprising the steps of:
(a) injecting a cooling fluid through an outer spray nozzle (10) in a dual feed injector at a flow rate in the range of about 20 to about 200 gallons per minute and pressure of about 1 to about 60 psig to contact the chlorine gases, wherein the nozzle has an outer fluid supply line (3) communicating with a means for providing a spray angle, said nozzle terminating with an annular orifice (9) having a smaller diameter than the fluid supply line for atomizing a fluid; and (b) injecting the cooling fluid through an inner spray nozzle (20) in the dual feed injector at a flow rate in the range of about 100 to about 600 gallons per minute and pressure of about 1 to about 90 psig to contact the chlorine gases, wherein the nozzle has an inner fluid supply line (4) communicating with a means for providing a spray angle, said nozzle terminating with a central orifice (8) having a smaller diameter than the inner fluid supply line for atomizing a fluid; wherein said inner and outer nozzles are disposed concentric to each other and housed in a compact nozzle body.
(a) injecting a cooling fluid through an outer spray nozzle (10) in a dual feed injector at a flow rate in the range of about 20 to about 200 gallons per minute and pressure of about 1 to about 60 psig to contact the chlorine gases, wherein the nozzle has an outer fluid supply line (3) communicating with a means for providing a spray angle, said nozzle terminating with an annular orifice (9) having a smaller diameter than the fluid supply line for atomizing a fluid; and (b) injecting the cooling fluid through an inner spray nozzle (20) in the dual feed injector at a flow rate in the range of about 100 to about 600 gallons per minute and pressure of about 1 to about 90 psig to contact the chlorine gases, wherein the nozzle has an inner fluid supply line (4) communicating with a means for providing a spray angle, said nozzle terminating with a central orifice (8) having a smaller diameter than the inner fluid supply line for atomizing a fluid; wherein said inner and outer nozzles are disposed concentric to each other and housed in a compact nozzle body.
2. The process of claim 1, wherein the cooling fluid is a liquid having a mean droplet diameter size in the range of about 0.2 to about 20 mm.
3. The process of claim 1, wherein the cooling fluid cools the chlorine gases from a temperature in the range of 800°C to 1500°C to a temperature in the range of 200°C to 550°C.
4. The process of claim 1, wherein the cooling fluid is titanium tertrachloride.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1997/007443 WO1998050165A1 (en) | 1997-05-01 | 1997-05-01 | Spray nozzle and a process using this nozzle |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2288212A1 true CA2288212A1 (en) | 1998-11-12 |
Family
ID=22260831
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002288212A Abandoned CA2288212A1 (en) | 1997-05-01 | 1997-05-01 | Spray nozzle and a process using this nozzle |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP2000512903A (en) |
AU (1) | AU736656B2 (en) |
CA (1) | CA2288212A1 (en) |
DE (1) | DE69717158T2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103657385A (en) * | 2012-09-10 | 2014-03-26 | 杨建华 | Double-atomization spray gun for SNCR (selective non-catalytic reduction) denitration system |
CN107470050A (en) * | 2017-09-30 | 2017-12-15 | 江西远达环保有限公司 | Has the desulphurization denitration spray gun of cooling effect |
CN107470049A (en) * | 2017-09-30 | 2017-12-15 | 江西远达环保有限公司 | Desulphurization denitration lance tube with anti-vaporization |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103506234B (en) * | 2013-09-27 | 2016-03-16 | 中节能六合天融环保科技有限公司 | A kind of SNCR denitrating flue gas spray gun two-chamber hybrid double-layer spray technology |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3261664A (en) * | 1963-11-21 | 1966-07-19 | Du Pont | Process for the production and separation of titanium tetrachloride from crystalline ferrous chloride |
US3717306A (en) * | 1971-03-10 | 1973-02-20 | Hushon R | Nozzle for spraying foaming materials |
-
1997
- 1997-05-01 CA CA002288212A patent/CA2288212A1/en not_active Abandoned
- 1997-05-01 DE DE69717158T patent/DE69717158T2/en not_active Expired - Fee Related
- 1997-05-01 JP JP10547993A patent/JP2000512903A/en active Pending
- 1997-05-01 AU AU27518/97A patent/AU736656B2/en not_active Ceased
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103657385A (en) * | 2012-09-10 | 2014-03-26 | 杨建华 | Double-atomization spray gun for SNCR (selective non-catalytic reduction) denitration system |
CN107470050A (en) * | 2017-09-30 | 2017-12-15 | 江西远达环保有限公司 | Has the desulphurization denitration spray gun of cooling effect |
CN107470049A (en) * | 2017-09-30 | 2017-12-15 | 江西远达环保有限公司 | Desulphurization denitration lance tube with anti-vaporization |
CN107470049B (en) * | 2017-09-30 | 2023-04-18 | 江西远达环保有限公司 | Spray gun pipe with anti-vaporization function for desulfurization and denitrification |
CN107470050B (en) * | 2017-09-30 | 2023-04-18 | 江西远达环保有限公司 | Spray gun with cooling effect for desulfurization and denitrification |
Also Published As
Publication number | Publication date |
---|---|
DE69717158T2 (en) | 2003-09-18 |
DE69717158D1 (en) | 2002-12-19 |
AU2751897A (en) | 1998-11-27 |
JP2000512903A (en) | 2000-10-03 |
AU736656B2 (en) | 2001-08-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
FZDE | Dead |